4642 results about "Composite coating" patented technology

The invention discloses slurry, a battery diaphragm, a preparation method of the battery diaphragm and a battery, and belongs to the technical field of batteries. The slurry comprises the following components: ceramic particles, carbon nanofibers, a binder I and a solvent I, the ceramic particles comprise ceramic particles I and ceramic particles II; the particle size of the ceramic particles I is 0.55-1 [mu] m, and the particle size of the ceramic particles II is 0.05-0.45 [mu] m. The battery diaphragm comprises a base membrane and a composite coating, the composite coating is attached to at least one surface of the base film; the composite coating is formed by curing the slurry provided by the invention. The battery diaphragm provided by the invention has good thermal stability and mechanical strength, the passing rate of the lithium ion battery in coping with safety tests such as extrusion, puncture and heavy object impact is greatly improved, and meanwhile, the electrochemical performance of the lithium ion battery is also improved.

The invention belongs to the technical field of composite coatings, and particularly relates to a corrosion-resistant and ultraviolet-resistant protective coating for wind power generation equipment and a preparation method thereof.The corrosion-resistant and ultraviolet-resistant protective coating for the wind power generation equipment is prepared from, by mass, 40-60 parts of gradient fluorosilicone modified polyurethane resin, 5-12 parts of core-shell type ZnO-coated MOFs composite particles, 1-3 parts of a curing agent, 1-3 parts of a curing agent and 1-3 parts of a curing agent. According to the invention, the problems of poor ultraviolet resistance, poor weather resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance, poor corrosion resistance and the like in the existing coating and the preparation process thereof are well solved; the shielding layer is single and incapable and has a poor self-repairing effect; and the coating toughness of an epoxy resin system is insufficient and cannot adapt to fatigue deformation of equipment under a vibration working condition.

The invention discloses a titanium base material bipolar plate corrosion-resistant and hydrogen embrittlement-resistant composite coating and a preparation method thereof. The surface of a titanium base material is sequentially coated with a titanium transition layer, a titanium black hydrogen resistance layer, a titanium hole sealing layer and a precious metal conducting layer; the titanium transition layer is an elemental titanium layer, and the thickness of the titanium transition layer is 10-30 nm; the material of the titanium black hydrogen blocking layer is Magneli-phase titanium black with the molecular formula of TinO2n-1, wherein n is greater than or equal to 4 and less than or equal to 10, and the thickness is 100-150nm; the titanium hole sealing layer is an elemental titanium layer, and the thickness of the titanium hole sealing layer is 10-50nm; the precious metal conducting layer is made of at least one of platinum, gold, ruthenium and iridium, and the thickness of the precious metal conducting layer is 20-50 nm. The corrosion-resistant and hydrogen embrittlement-resistant composite coating disclosed by the invention can effectively block diffusion and permeation of hydrogen in a cathode environment of a PEM water electrolyser while ensuring corrosion-resistant and conductive performance, so that the hydrogen embrittlement-resistant performance of the cathode side of the bipolar plate is greatly improved, and the processing cost and the process complexity of the coating are reduced.

The invention discloses a hydrophilic polyacrylate / epoxy silica sol composite coating and a preparation method thereof. The composite coating is prepared from a polyacrylate epoxy silica sol solution containing carboxyl and a polyethylene glycol side chain through blending, coating, drying and heating crosslinking. The polyacrylate is synthesized by taking methyl methacrylate, methacrylic acid, hydroxyethyl methylacrylate and allyl polyethylene glycol as comonomers through a solution free radical copolymerization method, and the epoxy silica sol solution is prepared by taking tetraethoxysilane and gamma-glycidoxypropyltrimethoxysilane as raw materials through a solution polymerization method. The composite material is prepared through a sol-gel and core-shell preparation process. The preparation method comprises the following steps: carrying out solution blending on polyacrylate and epoxy silica sol, and carrying out coating, drying and other processes to generate the cross-linked polyacrylate / epoxy silica sol composite coating through a cross-linking reaction between carboxyl and epoxy. The prepared composite coating has the characteristics of long durability, wear resistance, hydrophilicity, antifogging, protein adsorption resistance and the like.

The invention belongs to the technical field of semiconductors, and particularly relates to a gradient transition composite tantalum carbide coating and a preparation method thereof.The gradient transition composite tantalum carbide coating is located on the surface of a graphite substrate material and sequentially comprises a pyrolytic carbon coating, a tantalum carbide-pyrolytic carbon composite coating and a tantalum carbide coating from inside to outside; wherein the thermal expansion coefficient of the pyrolytic carbon coating is 2.5-4.5 * 10 <-6 > / K, the thermal expansion coefficient of the composite coating is 4.5-6.0 * 10 <-6 > / K, and the thermal expansion coefficient of the tantalum carbide coating is 6.1-8.0 * 10 <-6 > / K. According to the gradient transition structure of the coating, the problem that thermal expansion coefficients between the coating and a base body are not matched is solved, the thermal shock resistance of the coating is effectively improved, meanwhile, the pinning effect can be achieved, the adhesive force between the coatings is enhanced, and the service life of a product is prolonged; compared with a single tantalum carbide coating, crack accumulation and through holes cannot be generated.

The invention belongs to the technical field of material surface plating, and particularly relates to an aero-engine blade and a preparation method thereof. According to the preparation method, the component nano silicon carbide of the blade material is subjected to modification treatment, meanwhile, the carbon fiber composite material is introduced for common use, and the composite coating is formed on the surface through spraying treatment, so that the aero-engine blade is prepared, the cold and heat cycle resistance is effectively improved, and meanwhile, good erosion resistance is obtained.

The invention discloses an epoxy group modified zwitterionic polymer / heparin composite coating and a preparation method thereof. The preparation method comprises the following steps: firstly, constructing an amino-containing adhesion layer on the surface of a substrate by adopting a dip-coating method; then, the substrate is soaked in a mixed solution of the zwitterionic polymer and the heparin, and grafting of the zwitterionic polymer and the heparin on the surface of the medical material is completed through incubation. The coating provided by the invention has excellent hydrophilicity, can form a hydration layer, provides a physical barrier, and remarkably prevents adhesion and colonization of microorganisms. The inhibition rate of the coating on escherichia coli and staphylococcus aureus exceeds 99%, protein adhesion is remarkably reduced in an anti-protein adhesion experiment, and the coating is simple in strategy design, has a potential application prospect in the aspect of preventing blood contact catheter related infection and thrombosis, and has a wide application prospect. The complication occurrence rate and the medical care cost can be reduced.

The invention discloses a production method of a high-performance sintered neodymium-iron-boron magnet. The production method comprises the steps of rapid quenching flaking, hydrogen decrepitation mixing, magnetic field forming, multi-stage treatment and composite coating. A nanocrystalline sheet is prepared through a rapid quenching technology, and uniform distribution of a grain boundary phase and rare earth elements is achieved through hydrogen decrepitation and material mixing; forming in a strong magnetic field and applying high pressure to improve the orientation degree; through high-temperature sintering, medium-temperature annealing and low-temperature aging treatment, magnet densification, grain boundary phase reconstruction and a magnetic domain structure are optimized; and finally, the corrosion resistance is improved by adopting a composite coating. The high-performance sintered neodymium-iron-boron magnet produced by the method comprises a main phase alloy, a grain boundary phase additive and a rare earth supplementary phase. Through low-oxygen nanocrystal preparation, grain boundary coordinated regulation and green process integration, compatibility of high performance, low cost and environmental protection is realized, and sustainable development of the rare earth permanent magnet material is promoted.

The invention discloses a micro proportional valve gradient composite coating and a preparation method thereof, and belongs to the technical field of micro proportional valve surface strengthening manufacturing. Aiming at the corrosion-resistant and wear-resistant requirements of the micro proportional valve under the working conditions of strong corrosion, multiple impurities and high pressure difference, the interface strengthening and corrosion-resistant and wear-resistant performance optimization of a metal matrix and a functional coating are combined, and metal / ceramic / polymer gradient material design, spraying parameter suitability research and a coating porosity / bonding strength control method are covered; the valve core and valve seat protection device is suitable for high-efficiency protection technical systems of valve cores and valve seats of precise instruments such as gas chromatographs and mass spectrometers.

The invention discloses a preparation method of a ceramic particle reinforced high-temperature alloy wear-resistant coating of a boiler water-cooled tube. The preparation method comprises the following steps: carrying out roughening treatment on a matrix; the prepared NiCr powder and ZrB2 powder are subjected to high-energy ball milling and mixing, drying is conducted after treatment, and dried NiCr-based composite powder is obtained; niCr-based composite powder is sprayed through atmospheric plasma, and a composite coating with the thickness ranging from 200 micrometers to 300 micrometers is deposited on the roughened surface of the base body; the composite coating is subjected to remelting treatment, and a remelting coating is formed on the surface of the base body; wherein the matrix is 304 stainless steel, and the composition proportions of the NiCr powder and the ZrB2 powder are as follows: 80-99 wt% of NiCr and 1-20 wt% of ZrB2 respectively; by means of the method, the wear resistance of the coating is remarkably improved, and controllable deposition of the high-performance ceramic particle reinforced high-temperature alloy wear-resistant coating is achieved.

The invention discloses a ZnFeP-particle gradient abrasion-resistant chemical composite coating and a preparation method of the ZnFeP-particle gradient abrasion-resistant chemical composite coating. The ZnFeP-particle gradient abrasion-resistant chemical composite coating is divided into a passivation layer, a low-iron ZnFeP-particle chemical composite coating and a high-iron ZnFeP-particle chemical composite coating from outside to inside, and a gradient coating with the corrosion potential from low to high is formed; the content of iron in the low-iron ZnFeP-particle chemical composite coating ranges from 0.03 wt% to 1.0 wt%, the thickness of the low-iron ZnFeP-particle chemical composite coating ranges from 8 micrometers to 18 micrometers, and the hardness of the low-iron ZnFeP-particle chemical composite coating ranges from 150 HV to 300 HV. The content of iron in the high-iron ZnFeP-particle chemical composite coating ranges from 5 wt% to 30 wt%, the thickness ranges from 8 micrometers to 18 micrometers, and the hardness ranges from 500 HV to 650 HV. By means of the ZnFeP-particle gradient abrasion-resistant chemical composite coating, a metal component can be resistant to abrasion and corrosion, and therefore the service capacity of the metal component such as electric power fittings in the abrasion working condition is obviously improved.

The invention provides an aerogel-based heat-preservation, heat-insulation and waterproof composite coating material for a building outer wall and a preparation method thereof, and belongs to the field of building materials. Through hydrophobic modified silicon dioxide aerogel, a lightweight heat insulation frame is provided, and the waterproofness and compatibility are improved; the mechanical property and the crack resistance are enhanced through the modified potassium titanate nanofibers, and self-adaptive heat insulation is achieved; the thermoelectric effect, the wear resistance and the thermal regulation performance are optimized through plasma treatment and polyaniline coated tungsten carbide nanoparticles; the heat management performance, the crack resistance and the comprehensive heat insulation and waterproof capacity are improved through graphene oxide composite modified boron nitride; the flexibility, the hydrophobicity and the interfacial compatibility are improved through organic silicon modified bisphenol A epoxy resin; and the performance of the coating is optimized through the synergistic effect of the components.

The invention belongs to the technical field of protective coatings, and discloses an anti-corrosion, wear-resistant and high-temperature-resistant coating as well as a preparation method and application thereof. The coating comprises a primer, a middle transition layer and a finish; the raw materials of the primer comprise a primer material and a primer curing agent component; the primer material comprises modified epoxy phenolic resin, a primer functional filler, a first mixed solvent, a high-temperature-resistant coupling agent and an anti-settling agent; the raw materials of the middle transition layer comprise a middle transition layer material and a middle curing agent component; the materials of the middle transition layer comprise polyimide modified epoxy resin, a wear-resistant filler, a reactive diluent, a carbon nanotube, a first dispersant and a compatilizer; the raw materials of the finishing paint comprise a finishing paint material and a finishing paint curing agent component; the finishing paint material comprises organic silicon modified fluorocarbon resin, finishing paint functional filler, a second mixed solvent, a second dispersing agent and a flatting agent. According to the invention, a resin-based composite coating system is synergistically designed through multi-phase materials, so that optimal balance of corrosion resistance, wear resistance, toughness and high temperature resistance of the coating is realized.

A wear-resistant and low-friction coated piston ring and a preparation method therefor are provided. The OD surface diamond-like carbon coating consists sequentially of a first metal interlayer, a second metal interlayer, a gradient DLC layer, alternating high / low hardness DLC layers, and an outer running-in DLC layer. The side surface diamond-like carbon coating consists sequentially of a metal interlayer, a gradient DLC layer, and alternating high / low hardness DLC layers. The preparation method employs physical vapor deposition to sequentially deposit composite DLC coatings on the OD surface and side surface of the piston ring. The coating is a tetrahedral amorphous carbon structure, exhibiting good thickness uniformity and fine grain structure. This improves the wear resistance of the piston ring's OD surface and side surface, reduces the aggressiveness of the piston ring side surface against the piston ring groove, and meanwhile avoids adhesion.

The invention discloses a composite coated graphite negative electrode material, a preparation method thereof and a lithium ion solid-state battery, and belongs to the technical field of lithium ion solid-state batteries, the composite coated graphite negative electrode material comprises a graphite matrix and a composite coating layer, and the composite coating layer comprises an inner layer amorphous lithium chloride and an outer layer nanocrystalline LiF / Li3N composite phase. Mixing graphite, lithium chloride containing crystal water and ammonium fluoride to obtain a mixed material; placing the mixed material in a microwave reaction cavity, heating the mixed material to 600-700 DEG C at the microwave power of 800-1200 W in an H2 / Ar mixed atmosphere, and keeping the temperature for 20-60 minutes; and cooling the sintered mixed material, grinding, and sieving with a 100-300 mesh sieve to obtain the composite coated graphite negative electrode material with a coating layer thickness of 10-50 nm. The invention provides an innovative amorphous LiCl / nanocrystalline LiF-Li3N gradient coating layer design, the performance of the lithium ion battery is remarkably improved by optimizing an ion migration path, enhancing the interface stability and reducing the process cost, and a new engineering way is provided for realizing high magnification and long cycle performance of the sulfide all-solid-state battery.

The invention discloses a composition based on hollow glass beads and a preparation method thereof, and relates to the technical field of material science. The preparation method comprises the following steps: firstly, constructing a pre-composite functional microsphere with a specific hierarchical structure as a core basic functional unit, then matching with a plurality of components such as a thermosetting resin matrix, a latent curing system, a functional synergistic aid package and a composite solvent system, and matching with a preparation process which has a synergistic effect with the components. The composition based on the hollow glass beads is expected to realize uniform dispersion of the hollow glass beads in a coating system and strong bonding of a microscopic interface on the premise of ensuring the structural integrity of the hollow glass beads. Therefore, the high-performance composite coating material with ultra-light weight, high heat insulation efficiency, excellent mechanical strength and long-term service stability is obtained.

The invention provides a high-stability lithium-rich manganese-based positive electrode material and a preparation method thereof, and relates to the technical field of lithium-rich manganese-based positive electrode materials, and the method comprises three steps of preparation of a homogeneous precursor, solid-state mechanical fusion doping and coating, and high-temperature sintering; a lithium-rich manganese-based precursor is prepared by adopting a homogeneous coprecipitation process, uniform distribution of metal ions is ensured, then an aluminum source, a zirconium source and a fluorine source are introduced as doping agents, phosphate and a titanate coating agent are combined, doping and coating integrated treatment is realized through mechanical ball milling, and the lithium-rich manganese-based composite material is obtained. And finally, mixing with a lithium source in an argon atmosphere, and carrying out high-temperature sintering of temperature programming and staged heat preservation to form a stable composite coating layer in situ. Therefore, manganese ion migration is effectively inhibited through lattice doping, a layered structure is prevented from being converted into spinel or rock salt phase, meanwhile, a nanoscale ion / electron transmission channel is constructed, interface impedance is reduced, and the charging and discharging efficiency under high voltage is improved.

The invention relates to the field of high-temperature anti-oxidation coatings, in particular to a tantalum-tungsten alloy surface high-temperature anti-oxidation composite coating and a preparation method thereof.The coating is composed of two layers of coatings with different components, the thermal expansion coefficients of the coatings and a base body are matched, the thermal expansion coefficients of the coatings are matched, and residual stress and thermal stress are reduced. The coating is prepared by adopting an embedding boriding and slurry melting method, and the used material components comprise ZrB2, MoSi2, 8YSZ, B, La2O3, Al2O3, NaF, TaSi2 and the like. The preparation method specifically comprises the following steps: putting a substrate into embedding powder for boronizing treatment, then mixing a coating material with ethanol and a binder, putting the mixture into a ball mill for wet mixing to prepare coating slurry, spraying the coating slurry on the surface of the substrate, and putting the substrate into a vacuum tube furnace for sintering to prepare a coating, thereby obtaining the high-temperature anti-oxidation composite coating. The binding force between the developed coating and the tantalum-tungsten alloy matrix is strong, and the tantalum-tungsten alloy matrix can be protected from oxidation corrosion or the oxidation rate can be slowed down within 500-2500s at the high temperature (2000 DEG C or above).

The invention discloses an uvioresistant acrylic resin coating and a preparation method thereof, and belongs to the technical field of acrylic resin paints.The uvioresistant acrylic resin coating is characterized in that step-by-step functional design is adopted, a functional polyurethane prepolymer is constructed through prepolymerization reaction and double-bond end capping, fluorosilicone modified acrylate emulsion is prepared through a core-shell emulsion polymerization process, and the uvioresistant acrylic resin coating is obtained. Then carrying out surface silane modification on hexagonal boron nitride and carrying out composite coating to obtain a modified boron nitride auxiliary agent; and finally, carrying out composite emulsification and dispersion compounding on all the components to obtain the anti-ultraviolet acrylic resin coating. Through the synergistic enhancement effect of the fluorosilicone modified core-shell structure and the surface modified boron nitride, the ultraviolet aging resistance and the insulation reliability of the coating are remarkably improved on the basis of keeping high adhesive force, excellent flexibility and impact resistance of the coating; the problems that a traditional acrylic coating is prone to yellowing and pulverization under long-term ultraviolet radiation, and the mechanical property is reduced are effectively solved, and the acrylic coating is suitable for the field of electronic equipment protective coatings with high requirements for weather resistance, mechanical strength and electrical insulating property.

The invention relates to a preparation method of a'microstructure-liquid-like surface 'underwater drag-reduction, noise-reduction and antifouling multifunctional composite coating, and belongs to the field of underwater equipment. The multifunctional composite coating provided by the invention comprises an anti-drag microstructure arranged on the surface of a substrate and a liquid-like surface arranged on the surface of the anti-drag microstructure, and the liquid-like surface retains the original morphology of the anti-drag microstructure. According to the micro-structure, the distance between the wall face and a turbulent vortex can be increased, the frequency and strength of a flow vortex pair can be restrained, and resistance reduction is achieved; and on the liquid-like surface, resistance reduction can be achieved by enabling fluid to generate wall face slippage and reducing the speed gradient of the fluid on the boundary. The two mechanisms of action are different but do not interfere with each other, and a better drag reduction effect can be achieved through the synergistic effect. Meanwhile, the composite coating can achieve the noise reduction effect by reducing the turbulence intensity of the wall face. In addition, the liquid-like surface can resist adhesion of marine organisms, the integrity of the microstructure is guaranteed, and therefore the long-term drag reduction effect is achieved.

The invention discloses a modified nickel-cobalt-aluminum ternary positive electrode material, a preparation method thereof and a lithium battery, the modified nickel-cobalt-aluminum ternary positive electrode material provided by the invention comprises a bulk phase material and a coating layer coating the surface of the bulk phase material, the coating layer is composed of boric acid and at least one of transition metal nitride containing effective metal and aluminum-containing metal oxide. According to the invention, at least one of the binary compound containing the effective metal or the aluminum-containing metal oxide and the boric acid are used as the composite coating source for composite coating, so that the coating effect of the nickel-cobalt-aluminum ternary positive electrode material is optimized, and the ultrahigh nickel-nickel-cobalt-aluminum ternary positive electrode material with better physical and chemical properties is prepared. Meanwhile, the problems that the material is poor in structural stability, high in residual alkali content, relatively low in capacity and poor in rate and cycle performance exertion are solved.

The invention discloses an online composite coating system for an ultrathin copper foil and a modified resin film, and relates to the field of composite coating. The unwinding pretreatment module accurately controls tension and speed of a copper foil and a resin film and cleans and activates the copper foil; the coating liquid preparation and supply module adopts a neural network and other liquid control performance and conveying; the precision coating module controls film thickness by combining a bionic runner coating head with temperature; the composite pressing module intelligently controls a temperature roller and performs gradient cooling; the on-line detection and feedback control module carries out multi-modal detection and fusion data high-speed linkage adjustment on each module. Parameters of the ultrathin copper foil and modified resin film composite coating link are accurately controlled, defects are reduced, the film layer quality and adhesive force are improved, the system environment adaptability and stability are enhanced, the production efficiency and the product percent of pass are improved, and the cost is reduced.

The invention belongs to the technical field of iodine-resistant material preparation, and particularly discloses a high-barrier composite packaging material and a preparation method thereof.The high-barrier composite packaging material is composed of an aluminum foil layer, a vinyl resin heat-seal coating, a composite coating, a VC glue coating, a polyurethane heat-seal coating and a polyvinyl chloride sheet from top to bottom; wherein the composite coating is obtained by coating a coating liquid, and a preparation method of the coating liquid comprises the following steps: (1) adding PVA resin into deionized water, stirring, then adding a first part of functional particles, and heating and stirring to obtain a solution I for later use; (2) adding polylactic acid into the mixed solution, stirring, then adding the second part of functional particles, and heating and stirring to obtain a solution II; and (3) adding the obtained solution I into the obtained solution II, and uniformly stirring. The iodine-resistant packaging material prepared by the invention is good in iodine resistance, oxygen resistance and water vapor resistance, good in tensile strength and excellent in comprehensive performance.

The invention belongs to the technical field of paint coatings, and particularly relates to a hydrophobic heat-conducting self-repairing coating and a preparation method thereof. The preparation method of the hydrophobic heat-conducting self-repairing coating comprises the following steps: ultrasonically dispersing a heat-conducting filler and polyethylene glycol in an organic solvent, dropwise adding into a water-borne epoxy resin solution, and stirring to obtain a heat-conducting coating solution; the method comprises the following steps: dropwise adding a liquid A containing polysiloxane and a fluorine-containing monomer into a liquid B containing polyethylene glycol, stirring, carrying out centrifugal suction filtration, and drying to obtain the self-repairing microcapsule. Then adding the self-repairing microcapsules and silicon dioxide into the fluorine-containing polymer solution and / or the hydrophobic resin solution, and carrying out ultrasonic dispersion to prepare a self-repairing hydrophobic coating solution; the heat-conducting coating liquid and the self-repairing hydrophobic coating liquid are uniformly sprayed or spin-coated on the surface of a metal base material in sequence and then are subjected to UV curing, and the hydrophobic heat-conducting self-repairing coating is prepared. According to the method, the process and raw materials are simple, and the prepared coating has heat conduction and self-repairing performance and is excellent in anti-aging performance.

The invention belongs to the technical field of cement concrete surface coatings, and discloses a cement concrete surface coating structure with acid-resistant and corrosion-resistant functions, which has the advantages that the acid resistance is improved: a composite coating structure is adopted, and the advantages of modified epoxy resin, nano filler and polyurea are combined, so that the acid resistance and durability of the coating are remarkably improved. The modified epoxy resin primer has good permeability, so that the adhesive force between the coating and a concrete base layer can be effectively enhanced, and the falling risk is reduced. And compared with a traditional epoxy resin coating, the preparation method of the composite coating simplifies the curing process and reduces the construction difficulty. And the cost is reduced: the nanofiller is adopted to replace part of the polyurea material, so that the cost of the coating is reduced, and the performance is improved. The coating is endowed with excellent hydrophobicity and self-cleaning capability through surface hydrophobic treatment, dirt adhesion is reduced, and the service life is prolonged.

The invention relates to the technical field of biomedical materials, in particular to a titanium implant multifunctional composite coating with anti-active oxygen and anti-inflammatory dual performance and a preparation method of the titanium implant multifunctional composite coating. The coating is composed of a lanthanum oxide (La2O3) nano-particle layer growing on the surface of the titanium implant in situ and queen lily glycoside A (RA) loaded on the lanthanum oxide (La2O3) nano-particle layer and can continuously release La < 3 + > and RA. The preparation method comprises the following steps: performing alkali heat treatment on the titanium substrate; a La (OH) 3 coating is synthesized on the surface in situ through a hydrothermal reaction; the La2O3 nano-particles are calcined and converted into a La2O3 nano-particle layer with a porous structure; and finally loading RA through an impregnation method. The coating can effectively remove ROS, regulate immune inflammatory response, promote osteogenic differentiation and inhibit osteoclast activity, thereby remarkably promoting osseointegration. The problem of osseointegration under the osteoporosis pathological microenvironment is effectively solved, the preparation process is simple and controllable, and the composition is suitable for bone defect repair of osteoporosis patients and has important clinical application value.

The invention relates to the technical field of composite material surface magnetron sputtering coating, and particularly discloses a composite material surface magnetron sputtering coating process and method, and the composite material surface magnetron sputtering coating process comprises the steps of S1, surface treatment, S2, process equipment condition setting, S3, intelligent control, S4, multi-target co-sputtering process, S5, post-treatment and S6, surface topography detection. Through the multi-target co-sputtering technology, multiple layers of composite coatings such as TiN, CrN, Al2O3, ITO and other different functional layers can be deposited on the surface of the composite material, the base material is endowed with the properties such as abrasion resistance, corrosion resistance, insulation and electric conduction, and the comprehensive performance of the coatings is further improved through the synergistic effect of all the layers; the intelligent control system monitors and adjusts sputtering parameters in real time, so that the compactness and uniformity of the film are ensured, the defect rate of the film is reduced, the protection effect of a coating is enhanced, the service life of the coating is prolonged, key parameters such as sputtering power and temperature can be accurately adjusted, fluctuation caused by manual intervention is reduced, and the service life of the coating is prolonged. And the result of each process operation has high consistency.

The invention belongs to the technical field of polymer composite materials, and particularly relates to an oil-resistant interior material. The material comprises a porous base material layer, a fluorine-containing polymer and organic silicon resin blended oil-resistant functional layer and a micro-nano structure layer with a periodic micro-bulge array, surface modified nanoparticles are distributed in the functional layer in a gradient manner, and the micro-bulge surface is covered with a perfluoropolyether / fluorinated silicon dioxide composite coating; through a synergistic effect of a low-surface-energy oleophobic interface formed through chemical bonding and curing and a micro-structure capillary lifting effect, anti-permeation barrier of high-viscosity grease is realized, and meanwhile, mechanical wear resistance and thermal stability are improved by virtue of a nano-particle enhanced cross-linked network; and continuous imprinting and an ultraviolet-thermal dual-curing process are combined to achieve high-efficiency manufacturing with zero solvent residue, and finally the interior material with long-acting oil resistance, high environmental tolerance and industrial mass production feasibility is obtained.

The invention discloses a method for enhancing the interface performance of a carbon fiber composite coating through two-step chemical reaction synergistic modification, modified carbon fibers and application. The method comprises the following steps: carrying out silanization modification treatment and hyperbranched modification treatment on carbon fibers subjected to oxidation treatment to prepare the modified carbon fibers. The method for enhancing the interface performance of the carbon fiber composite coating through two-step chemical reaction synergistic modification is suitable for improving the interface performance of the carbon fiber composite coating, and the prepared modified carbon fiber is mixed with resin and a curing agent and cured; the obtained carbon fiber reinforced composite coating has excellent mechanical properties, wear resistance and erosive wear resistance, and can effectively reduce damages such as corrosion, erosive wear and the like of complex and harsh marine environments such as a spray splashing area and the like to steel structure facilities.

The invention provides a wear-resistant, transparent, flexible and fluoride-free super-hydrophobic composite coating and a preparation method thereof. The preparation method comprises the following steps: mixing hydroxyl-terminated polydimethylsiloxane, gamma-aminopropyltriethoxysilane and dibutyltin dilaurate for reaction to obtain a modified precursor solution, adding swelled epoxy resin into the modified precursor solution, and heating for reaction to obtain siloxane modified epoxy resin; the preparation method comprises the following steps: dispersing nano silicon dioxide in an ethyl acetate solution to form a SiO2 suspension; and uniformly mixing the modified epoxy resin with a SiO2 suspension, adding polyether amine as a curing agent, stirring and mixing, and constructing the epoxy resin / hydroxyl-terminated polydimethylsiloxane / nano-silica super-hydrophobic coating on a substrate by adopting an air spraying mode. According to the preparation method disclosed by the invention, the super-hydrophobic coating with excellent transparency and flexibility and good adhesive force and wear resistance can be prepared, and the super-hydrophobic coating has a wide application prospect in the fields of wearable electronic equipment, photoelectric devices and the like.