2293 results about "Composite coating" patented technology

The invention provides a high-stability lithium-rich manganese-based positive electrode material and a preparation method thereof, and relates to the technical field of lithium-rich manganese-based positive electrode materials, and the method comprises three steps of preparation of a homogeneous precursor, solid-state mechanical fusion doping and coating, and high-temperature sintering; a lithium-rich manganese-based precursor is prepared by adopting a homogeneous coprecipitation process, uniform distribution of metal ions is ensured, then an aluminum source, a zirconium source and a fluorine source are introduced as doping agents, phosphate and a titanate coating agent are combined, doping and coating integrated treatment is realized through mechanical ball milling, and the lithium-rich manganese-based composite material is obtained. And finally, mixing with a lithium source in an argon atmosphere, and carrying out high-temperature sintering of temperature programming and staged heat preservation to form a stable composite coating layer in situ. Therefore, manganese ion migration is effectively inhibited through lattice doping, a layered structure is prevented from being converted into spinel or rock salt phase, meanwhile, a nanoscale ion / electron transmission channel is constructed, interface impedance is reduced, and the charging and discharging efficiency under high voltage is improved.

The invention discloses an uvioresistant acrylic resin coating and a preparation method thereof, and belongs to the technical field of acrylic resin paints.The uvioresistant acrylic resin coating is characterized in that step-by-step functional design is adopted, a functional polyurethane prepolymer is constructed through prepolymerization reaction and double-bond end capping, fluorosilicone modified acrylate emulsion is prepared through a core-shell emulsion polymerization process, and the uvioresistant acrylic resin coating is obtained. Then carrying out surface silane modification on hexagonal boron nitride and carrying out composite coating to obtain a modified boron nitride auxiliary agent; and finally, carrying out composite emulsification and dispersion compounding on all the components to obtain the anti-ultraviolet acrylic resin coating. Through the synergistic enhancement effect of the fluorosilicone modified core-shell structure and the surface modified boron nitride, the ultraviolet aging resistance and the insulation reliability of the coating are remarkably improved on the basis of keeping high adhesive force, excellent flexibility and impact resistance of the coating; the problems that a traditional acrylic coating is prone to yellowing and pulverization under long-term ultraviolet radiation, and the mechanical property is reduced are effectively solved, and the acrylic coating is suitable for the field of electronic equipment protective coatings with high requirements for weather resistance, mechanical strength and electrical insulating property.

The invention relates to the technical field of biomedical materials, in particular to a titanium implant multifunctional composite coating with anti-active oxygen and anti-inflammatory dual performance and a preparation method of the titanium implant multifunctional composite coating. The coating is composed of a lanthanum oxide (La2O3) nano-particle layer growing on the surface of the titanium implant in situ and queen lily glycoside A (RA) loaded on the lanthanum oxide (La2O3) nano-particle layer and can continuously release La < 3 + > and RA. The preparation method comprises the following steps: performing alkali heat treatment on the titanium substrate; a La (OH) 3 coating is synthesized on the surface in situ through a hydrothermal reaction; the La2O3 nano-particles are calcined and converted into a La2O3 nano-particle layer with a porous structure; and finally loading RA through an impregnation method. The coating can effectively remove ROS, regulate immune inflammatory response, promote osteogenic differentiation and inhibit osteoclast activity, thereby remarkably promoting osseointegration. The problem of osseointegration under the osteoporosis pathological microenvironment is effectively solved, the preparation process is simple and controllable, and the composition is suitable for bone defect repair of osteoporosis patients and has important clinical application value.

The invention discloses a high-strength wear-resistant self-lubricating drill bit for a coal mine and a preparation method of the high-strength wear-resistant self-lubricating drill bit. The preparation process comprises the steps that a drill bit blank is prepared from low-alloy carbon structural steel, a high-strength and high-toughness matrix is obtained through thermal refining, and then sand blasting activation is conducted to clean and coarsen the surface. After diamond particles are subjected to acid pickling pretreatment, metal modified diamond composite powder is obtained through salt bath metal and reduction prefabrication. The preparation method comprises the following steps: mixing MoS2 with the carbon dioxide, spraying the mixture on the surface of a matrix through high velocity oxy-fuel to form a wear-resistant coating, and then improving the density and interface bonding strength of the coating through high-frequency induction instantaneous remelting, thereby finally obtaining the coal mine drill bit with high hardness, strong bonding force and self-lubricating performance. The metal modified diamond composite coating containing the metal transition layer and the MoS2 lubricating phase is constructed on the steel substrate, and a high-frequency remelting process is combined, so that the wear resistance, the bonding strength and the self-lubricating performance of the drill bit are synergistically improved, and the drill bit has the advantages of high strength and toughness matching and low cost.

The invention relates to the technical field of nano materials, and particularly discloses a preparation method of surface modified nano calcium carbonate for a battery diaphragm coating. According to the method, the technical paths of microemulsion confinement crystal form regulation and control, gradient surface modification and boehmite compounding and porosity regulation and control are fused, and the functional nano calcium carbonate adaptive to the battery diaphragm coating is prepared. According to the technical scheme, limestone is used as a raw material, after calcination and digestion, the particle size of nano calcium carbonate is controlled through microemulsion carbonization (a cyclohexane-span 80-n-butyl alcohol system); a silane coupling agent KH560-KH570 is adopted for gradient modification to introduce an electrophilic functional group, boehmite is compounded to form a composite coating, and the porosity is regulated and controlled by adjusting the solid content in coating slurry and the coating speed. The method is stable in process and high in compatibility, and meets the requirements of diaphragm coatings of lithium ion batteries and solid-state batteries.

The invention relates to a preparation method of an etching-resistant and wear-resistant Y2O3-AlxOy composite coating. The preparation method comprises the following steps: carrying out ultrasonic cleaning on a corrosion-resistant matrix; performing plasma bombardment cleaning activation on the surface of the corrosion-resistant matrix; a Y2O3 coating and an AlxOy coating are alternately deposited on a corrosion-resistant base body in a double-target magnetron sputtering mode to form the Y2O3-AlxOy composite coating, the sputtering power of a Y target is larger than that of an Al target, and the ratio of x to y in the AlxOy coating is larger than 1. According to the method, the amorphous AlxOy coating dominated by the metal state is introduced into the Y2O3 coating, growth of Y2O3 columnar crystals is continuously broken, crystal grains are refined, formation of intergranular easy-to-etch point locations is inhibited, and an yttrium aluminum oxide composite strengthening phase is formed at an interface, so that plasma etching resistance is improved; the thickness of a single-layer coating in the composite coating is very thin; under the action of growth stress, the structure of the coating presents a wave-shaped microstructure and a soft and hard alternate mechanical structure, and the soft and hard alternate mechanical structure is beneficial to inhibiting generation of transverse cracks, guiding friction crack level expansion, prolonging the friction life of the coating and reducing the wear rate.

The invention discloses a bacillus coagulans feed additive and a preparation method thereof, and relates to the technical field of feed additives, the bacillus coagulans feed additive comprises bacillus coagulans spores, the content of the spores is 1.0 * 10 < 8 >-1.0 * 10 < 11 > CFU / g; the protective agent system comprises the following components: maltodextrin or lactose, vegetable protein, polyhydric alcohol and an antioxidant; the invention discloses a microcapsule coating structure. A microcapsule is a two-layer composite coating of an inner layer alginate matrix and an outer layer polycation or polymer coating. According to the invention, bacillus coagulans spores which can still keep high survival rate under short-time high-temperature and low-pH conditions are obtained through screening and fermentation strategies of strains with high sporulation and heat and acid tolerance, the problem that common strains are easy to inactivate in granulation, extrusion and gastric acid environments is solved, the problem of product failure caused by insufficient tolerance of the strains is reduced, and the product quality is improved. And the original biological activity basis is improved, so that the protection effect of the subsequent formula and the coating can be played at a higher starting point, and the zoology effect of the final preparation is improved.

The invention relates to the technical field of metal wire processing, and discloses a high-performance metal wire plastic coating process for aerospace engineering, which comprises the following steps: carrying out base material type selection on a metal wire, and carrying out surface treatment of precise cleaning, etching and depth gradient activation; a Ti-Cr alloy and graphene-copper composite transition layer is deposited through a magnetron sputtering technology, and a multi-layer coating structure is formed through electrostatic spraying of a base coating, a fluidized bed dipping function layer and high velocity oxy-fuel spraying of a nano composite coating in sequence; the molybdenum-gold composite sealing layer is prepared by adopting an electric arc spraying technology, and is subjected to vacuum ultraviolet curing enhancement, high-temperature gradient annealing, gradient sintering and vacuum curing treatment; and heat radiation on the surface of the coating is enhanced through laser-induced micro-nano structure regulation and silicon nitride film sputtering. Through collaborative optimization of base material treatment, coating construction, function strengthening and quality control, the interface bonding strength, the comprehensive performance and the environmental adaptability of the spaceflight metal wire coating are remarkably improved, and the service life of the spaceflight metal wire coating is remarkably prolonged.

The invention relates to the field of metal material surface strengthening, in particular to an in-situ reaction multi-element ceramic phase reinforced titanium-based composite coating and a preparation method thereof. The preparation method comprises the steps that titanium alloy powder and B4C powder are mixed, and mixed powder is obtained; the mixed powder is conveyed to a cladding focus under atmosphere protection, reaction gas is introduced, laser cladding is conducted, and the in-situ reaction multi-element ceramic phase reinforced titanium-based composite coating is formed on the surface of the metal sample; the reaction gas is nitrogen; the laser power is 1-2 kW, the scanning speed is 5-20 mm / s, and the multi-pass cladding lap joint rate is 40%-80%. By regulating and controlling the laser cladding process, optimizing the laser power, the scanning speed and the reaction gas flow and utilizing a dispersion strengthening mechanism and a solid solution strengthening mechanism of a ceramic phase generated through in-situ reaction, the hardness and the wear resistance of the composite coating are improved, the problems that a traditional titanium-based coating is low in hardness and poor in wear resistance are effectively solved, and the service life of the coating is prolonged. The method is suitable for surface strengthening of key components in the fields of aerospace, ocean engineering and the like.

The invention provides a titanium alloy-based composite coating structure, a method for inhibiting upward dilution of Ti during cladding of a wear-resistant layer on the surface of a titanium alloy and application of the titanium alloy-based composite coating structure. The method comprises the steps that an aluminum bronze barrier layer is formed on a titanium alloy substrate, the phase structure of the aluminum bronze barrier layer comprises a Cu phase and a Cu2TiAl phase, the Cu phase and the Cu2TiAl phase are each of an FCC crystal structure, and the Cu2TiAl phase is formed by reacting Ti in the titanium alloy substrate with Cu and Al; the volume ratios of a Cu phase and a Cu2TiAl phase in the aluminum bronze barrier layer are 40%-45% and 55%-60% respectively; and forming the transition alloy wear-resistant layer on the titanium alloy substrate with the aluminum bronze barrier layer by adopting a laser cladding technology. The aluminum bronze barrier layer is arranged to reduce upward dilution of Ti elements in the cladding process of the transition alloy wear-resistant layer, generation of a large number of hard brittle phases is avoided, the difference between the wear-resistant layer and a titanium alloy matrix in the thermophysical property aspect is relieved, and coating cracking is reduced.

The invention provides a composite lithium manganate positive electrode material, a preparation method thereof, a pole piece and a battery, and relates to the technical field of lithium batteries. The composite lithium manganate positive electrode material is of a core-shell structure; the core is lithium manganate, and the shell is a composite coating layer coating the surface of lithium manganate; the composite coating layer comprises a first coating layer and a second coating layer; the first coating layer is CuCe < x > Fe < 2-x > O < 4-y > Li; and the second coating layer comprises PVDF particles. The invention provides a lithium manganate material with a double-layer core-shell structure. The CuCexFe2-xO4-yLi inner layer reduces impedance and stabilizes crystal lattices by virtue of spinel isomorphism and doping, and anchors the PVDF outer layer based on oxygen vacancy; and in cooperation with the surface lithium gradient effect, the structural stability and electrochemical performance of the material are remarkably improved.

The invention relates to a self-repairing hydrogen barrier composite coating for a hydrogen storage or transportation device as well as a preparation method and application of the self-repairing hydrogen barrier composite coating, and belongs to the technical field of hydrogen energy storage and transportation materials. The coating is of a double-layer structure and is composed of a bottom coating and a humidity response microcapsule self-repairing barrier layer. The humidity response microcapsule is composed of a capsule core containing a polyurethane prepolymer and a hybrid capsule shell formed by polyurethane and siloxane, and has good hydrogen barrier performance and environmental response characteristics. In a certain humidity environment, the microcapsule is stimulated to release the capsule core material, and in-situ self-repairing is achieved. The problem that a traditional hydrogen-resistant coating is short of repairing capacity is solved, and the hydrogen-resistant coating has a wide application prospect in the aspect of improving the safety of a hydrogen conveying and storage system.

The invention discloses a high-temperature-resistant and corrosion-resistant coating for an aluminum alloy heat exchange tube and a preparation method thereof, and relates to the technical field of coating materials. The method comprises the following steps that the aluminum alloy heat exchange tube is cleaned and deoiled, then a treating agent is sprayed, composite coating slurry is sprayed to the surface of the aluminum alloy heat exchange tube after curing, and the high-temperature-resistant and corrosion-resistant coating for the aluminum alloy heat exchange tube is obtained after curing treatment. Wherein the treating agent is prepared from NS-30 silica sol, deionized water and methyltrimethoxysilane; the composite coating slurry is prepared from a polyamide acid solution, a synergist, functionalized boron nitride nanosheets, modified hexagonal boron nitride, a flatting agent and a defoaming agent. The silane film introduced into the treating agent and the synergist, the functionalized boron nitride nanosheet and the modified hexagonal boron nitride introduced into the composite coating slurry effectively improve the high temperature resistance, the corrosion resistance, the adhesive force, the thermal conductivity, the aging resistance and the toughness of the coating. Therefore, the method has a wider application prospect.

The invention belongs to the technical field of thermal power heating surface treatment, and provides a gradient functional composite coating applied to a boiler heating surface and a preparation method of the gradient functional composite coating in order to solve the technical problems that an existing protective coating of the boiler heating surface is prone to abrasion and oxidation and high in cost. Collaborative design is formed, and gradient matching of mechanical properties and environmental failure resistance is achieved. The low-melting-point glass powder is combined with the rare earth catalytic effect, low-temperature ceramization is achieved, and thermal damage to a matrix is avoided. After the metal ceramic transition layer is sprayed, high-frequency induction remelting treatment is carried out, meanwhile, laser cladding is carried out on the surface of the ceramic surface layer, a nanocrystalline-amorphous composite structure is formed, and the bonding strength of the coating is improved.

The invention provides a nickel-based rare earth composite powder material for high-speed laser cladding and a preparation method of a nickel-based rare earth composite coating, and relates to the technical field of laser cladding and metal surface modification. The nickel-based rare earth composite coating takes Inconel 625 nickel-based alloy as a matrix phase material; a trace amount of rare earth oxide Y2O3 is introduced into a powder system to serve as a second phase enhancing component, and the material is prepared and formed at a time under the condition of a high-speed laser cladding process; in the high-speed laser cladding process, due to high scanning speed, low heat input per unit length and high cooling rate, metal liquid in a molten pool has the characteristic of rapid solidification; the rare earth oxide Y2O3 can stably exist in a molten pool, the particle surface of the rare earth oxide Y2O3 provides a large number of heterogeneous nucleation cores for the alloy solidification process, meanwhile, grain growth is restrained through the grain boundary pinning effect, and therefore the solidification structure form of the nickel-based cladding coating is remarkably improved.

The invention discloses a sulfide-oxide composite solid electrolyte based on Lewis acid-base reaction, a preparation method of the sulfide-oxide composite solid electrolyte and a battery, and relates to the technical field of solid-state batteries. Comprising a sulfide electrolyte and a composite coating coated on the surface of the sulfide electrolyte, and the composite coating comprises an oxide electrolyte and a Lewis alkaline substance. The oxide electrolyte and the Lewis alkaline substance are adopted as the composite coating material, so that the sulfide electrolyte can be isolated from air, the air stability of the sulfide electrolyte is effectively improved, and the phenomenon that the sulfide electrolyte is subjected to oxidation-reduction decomposition in the charge-discharge process is reduced; and by-products generated in the use process of the sulfide electrolyte can be neutralized in situ by the Lewis alkaline substance, so that the great increase of interface impedance is reduced, the cycle performance and high-current stability of the battery are remarkably improved, and the problem that the interface impedance is increased in the charge-discharge process of the traditional sulfide solid electrolyte is solved.

The invention discloses a coating, a preparation method and application, and relates to the technical field of anticorrosive coatings. The included angle between the plane of most of the lamellar filler in the coating and the macroscopic surface of the base material is controlled to be smaller than 45 degrees through a magnetron orientation method, that is, the lamellar filler is close to the state of being parallel to the surface of the base material, the transmission path of a corrosive medium can be longer and more zigzag, the maze effect can be further strengthened, and the corrosion resistance of the coating is improved. Therefore, the corrosion path of the corrosive medium is greatly prolonged, and the heat-conducting property of the matrix is reserved to the greatest extent. The dry film of the coating still has high corrosion resistance in the ultrathin state, the heat conduction performance of the fin base material of the heat exchanger can be reserved to the maximum degree, the service life of the heat exchanger is greatly prolonged, and the energy-saving long-term effect of the heat exchanger is greatly improved. In addition, the composite coating provided by the invention is simple in preparation process and relatively low in cost, and has extremely high market application value.

The invention discloses a high-light-resistance nano lignin-based composite coating as well as a preparation method and application thereof, and belongs to the technical field of wood protection. Compared with traditional unmodified lignin, the high-light-resistance nano lignin-based composite coating prepared by taking lignin nanoparticles prepared from quaternized lignin and nano TiO2 as raw materials has more excellent light resistance; according to the high-light-resistance nano lignin-based composite coating provided by the invention, the original texture of wood can be reserved, and the defects of a traditional protection method are effectively overcome. In addition, according to the preparation method of the high-light-resistance nano lignin-based composite coating, raw materials are saved, and the high resource utilization rate is achieved. The high-light-resistance nano lignin-based composite coating can remarkably improve the ageing resistance of wood, and the application prospect of the wood in the fields of outdoor landscape building materials, durable furniture, wood packaging and the like is expanded.

The invention discloses an AlCrN / AlCrSiWN nano multilayer composite coating with ultrahigh hardness and a preparation process of the AlCrN / AlCrSiWN nano multilayer composite coating, and belongs to the technical field of material surface coatings. The composite coating comprises an AlCrN transition layer, an AlCrN / AlCrSiWN nano multilayer modulation coating and an AlCrSiWN functional layer which are sequentially deposited on a substrate, the AlCrN / AlCrSiWN nano multilayer modulation coating is formed by alternately overlapping AlCrN layers and AlCrSiWN layers, the modulation period is 5-200 nm, and the modulation ratio of the AlCrSiWN layers to the AlCrN layers is 1: (1.5-5). The coating is prepared by adopting an arc ion plating technology. According to the preparation method, the AlCrN / AlCrSiWN nano multilayer composite coating with ultrahigh hardness is prepared by alternately depositing the AlCrSiWN coating and the AlCrN coating, and the hardness and the toughness of the coating are synchronously improved.

The invention belongs to the technical field of metal anticorrosive coating materials, and particularly relates to a super-hydrophobic composite coating and a preparation method thereof. According to the invention, MoS2 is used as a skeleton, CeO2 nanoparticles are uniformly loaded on the surface of a MoS2 two-dimensional layered structure, polydopamine is used as a connecting agent to form a stable Ce-MoS2 composite filler, and an active and passive protective layer with the Ce-MoS2 composite filler is constructed on the surface of a matrix and is used as a bottom layer. And then, forming a hydrophobic coating containing modified SiO2 on the bottom layer to serve as a surface layer, so as to obtain the super-hydrophobic composite coating with double protection mechanisms. According to the coating, the active corrosion inhibition function of CeO2 and the physical shielding effect of MoS2 are combined, meanwhile, hydrophobic SiO2 nano-particles are introduced into the surface layer, the hydrophobic performance of the surface is further enhanced, and therefore the technical problems that a traditional coating is prone to corrosion at the defect position and a corrosive medium is prone to permeation, and consequently the protection effect is remarkably reduced are effectively solved.

The present invention provides a substrate with a coating comprising, in order: a) a substrate; b) a primer layer comprising a first transition metal or an oxide thereof; c) one or more corrosion resistant layers, each layer comprising a first sub-layer, a second sub-layer and a third sub-layer, the sub-layers comprising the first transition metal and a second transition metal, where the ratio of the first transition metal and the second transition metal varies between the sub-layers; d) a conductive layer comprising the second transition metal, or a nitride thereof and / or an oxide thereof. The invention also describes a method for producing such a substrate with a coating. The coated substrate has good electrical conductivity and corrosion resistance.

The invention belongs to the technical field of nano composite coatings, and particularly provides an anti-dust-sticking carbon nano polymer coating as well as a preparation method and application thereof. The invention relates to an anti-dust-sticking carbon nano polymer coating which comprises the following raw materials: epoxy resin, polytetrafluoroethylene, a reinforcing medium, a filler, an auxiliary agent and a curing agent, the reinforcing medium is prepared by mixing polyurethane, modified cyclodextrin and graphene, so that stacking among graphene is reduced, and the graphene is effectively dispersed. The ash sticking prevention carbon nano polymer coating prepared by the invention has the advantages of abrasion resistance and corrosion resistance.

The invention belongs to the field of electrochemistry, and particularly relates to a positive pole piece containing a metal organic framework derived amorphous composite coating as well as a preparation method and application of the positive pole piece. The positive pole piece comprises a current collector, a first positive functional coating and a second positive functional coating. The first positive functional coating is arranged on at least one side surface of the current collector and contains a positive active material, a binder and a conductive material; and the second positive electrode functional coating is arranged on the surface of the first positive electrode functional coating and contains an aluminum-based metal organic framework (MOF) derived amorphous material, a binder and a conductive material. The structure can significantly inhibit the dissolution of transition metal ions and oxygen, has excellent performance in a wide temperature range and high rate, and is suitable for electrochemical devices such as lithium ion batteries and the like.

The invention discloses a biological adhesion prevention nano-composite coating for a marine aquaculture netting and a coating process of the biological adhesion prevention nano-composite coating. The coating slurry is composed of a waterborne polyurethane dispersion, an antifouling functional filler and an auxiliary agent; the antifouling functional filler is nano microspheres formed by encapsulating capsaicin by using hydrogenated rosin as a wall material. The preparation method comprises the following steps: preparing the nano-microspheres through a specific process, and dispersing the nano-microspheres in water-based resin to obtain slurry; performing air low-temperature plasma pretreatment on the netting to improve the surface activity; and finally, coating the surface of the netting with the slurry and curing. The problems of dispersion and controllable slow release of natural hydrophobic antifouling components are solved through a nano packaging technology, and meanwhile, the ultrahigh adhesive force of the coating on a flexible hydrophobic base material is realized through a plasma interface activation technology. The two components have a synergistic effect, so that the coating has the outstanding advantages of environmental friendliness, long-acting antifouling property and firm adhesive force, and the technical bottlenecks that the traditional environment-friendly coating is easy to peel and short in service life are effectively overcome.

The invention belongs to the technical field of water-based ink, and provides high-temperature-resistant water-based ink for laminated iron and a preparation method thereof.According to the high-temperature-resistant water-based ink for laminated iron and the preparation method of the high-temperature-resistant water-based ink for laminated iron, the design of a double-resin system formed by compounding waterborne polyurethane resin and flexible segment copolymer modified ternary vinyl chloride-vinyl acetate resin is adopted, and the synergistic effect of surface modified nanometer aluminum oxide reinforcing filler and an elastomer modifier is combined; the interface compatibility is improved through a siloxane coupling agent surface treatment technology, a composite coating structure with balanced flexibility and heat resistance is formed, the high temperature resistance can reach 200 DEG C or above, continuous use is free of failure, the flexibility is free of cracking through a T-bend test, the adhesion of a coating film reaches the 0-level standard, the drying time is shortened to be within 30 minutes, and the service life of the coating film is prolonged. The comprehensive performance index that the storage stable period is prolonged to 12 months or above is achieved, the technical problems that an existing laminated iron coating is insufficient in flexibility and poor in thermal stability in a high-temperature environment are solved, and the high-temperature-resistant laminated iron coating has wide food packaging and industrial protection application value.

The invention relates to a normal-temperature curing high-corrosion-resistance self-lubricating composite coating which is prepared from the following components in parts by weight: 25 to 35 parts of modified epoxy resin, 12 to 22 parts of waterborne polyurethane-acrylate copolymer, 6 to 14 parts of lubricating filler, 4 to 9 parts of corrosion-resistant filler, 10 to 18 parts of composite curing agent, 1 to 4 parts of dispersing agent, 0.5 to 3.5 parts of flatting agent, 0.8 to 2.5 parts of defoaming agent and 35 to 55 parts of auxiliary solvent. According to the coating disclosed by the invention, an interpenetrating network matrix is constructed through modified epoxy resin and a waterborne polyurethane-acrylate copolymer, and is matched with components such as a nano molybdenum disulfide / graphene composite lubricating filler and a nano titanium dioxide-zinc oxide composite corrosion-resistant filler, and a photoinitiator-amine composite curing agent is combined, so that dual curing is realized. The coating has excellent properties of rapid curing at normal temperature, high corrosion resistance, self-lubrication and the like, is low in VOC content and wide in application range, and provides an innovative solution for the field of surface protection.

The invention relates to a carbon fiber reinforced silicon carbide-based composite material with an anti-ablation gradient composite coating on the surface and a preparation method of the carbon fiber reinforced silicon carbide-based composite material. The preparation method comprises the following steps: depositing an interface layer on fibers of a fiber woven body; carrying out primary densification by using polycarbosilane through a precursor impregnation liquid process; further densifying by using a furfuryl ketone resin steeping liquor containing molybdenum powder; implementing a Si powder reactive infiltration process; and preparing an Hf2Ta6O17 coating by using an embedding infiltration process to prepare the C / SiC composite material with the anti-ablation gradient composite coating on the surface. The invention also provides the carbon fiber reinforced silicon carbide-based composite material prepared by the method. In the gradient coating of the prepared composite material, the SiC-MoSi2 layer relieves the difference of thermal expansion coefficients and realizes self-healing, and the Hf2Ta6O17 layer provides ultrahigh-temperature stability. The composite material prepared by the method disclosed by the invention has excellent ablation resistance and high-temperature mechanical property at the temperature of 2200 DEG C or above.

The application provides a wear-resistant transparent flexible fluorine-free super-hydrophobic composite coating and a preparation method thereof. The preparation method comprises the following steps: mixing and reacting hydroxyl-terminated polydimethylsiloxane, gamma-aminopropyl triethoxysilane and dibutyl tin dilaurate to obtain a modified precursor solution, adding swelled epoxy resin into the modified precursor solution, and obtaining a siloxane modified epoxy resin after heating reaction; dispersing nano-silicon dioxide in an ethyl acetate solution to form a SiO2 suspension; uniformly mixing the modified epoxy resin and the SiO2 suspension, adding polyether amine as a curing agent, and stirring and mixing, and then adopting an air spraying mode to build an epoxy resin / hydroxyl-terminated polydimethylsiloxane / nano-silicon dioxide super-hydrophobic coating on a substrate. The preparation method can prepare a super-hydrophobic coating with excellent transparency and flexibility, good adhesion and wear resistance, and has a wide application prospect in the fields of wearable electronic devices and optoelectronic devices.

The invention discloses a multifunctional aerogel composite coating, which is prepared from the following components: hydrophobic modified silica aerogel, nano hollow carbon spheres, a microcapsule phase change material, organic silicon modified acrylic emulsion, acrylic acid modified polyurethane emulsion, cerium-doped zinc oxide, P25 titanium dioxide, reduced graphene oxide and the like. The heat conductivity coefficient is 0.022 to 0.032 W / (m.K); the temperature is actively adjusted through the microcapsule phase change material, and the anti-condensation temperature difference is 9-18 DEG C; through synergistic photocatalysis of cerium-doped zinc oxide and P25, the visible light degradation rate is 85%-98%; through the cooperation of the organic silicon / polyurethane interpenetrating network resin and the graphene, the salt fog resistance of 1650-2100 hours is realized; the VOC content is 2.8-4.0 g / L, and the paint is suitable for the fields of industrial pipelines, storage tanks, building exterior walls and the like.

The invention relates to a high-performance hafnium-based ultrahigh-temperature ceramic-based composite material and a preparation method thereof. The method comprises the following steps: depositing pyrolytic carbon on the carbon fiber surface of a carbon fiber preform through a CVD (Chemical Vapor Deposition) method; preparing a hafnium oxide interface layer on the surface of the pyrolytic carbon through an atomic layer deposition method, and performing ultra-fast annealing treatment to form a pyrolytic carbon-hafnium oxide composite interface layer; carrying out a reaction with a matrix containing a pyrolytic carbon-hafnium oxide composite interface layer through an impregnation pyrolysis method; a hafnium carbide coating is prepared on the surface of the composite material matrix through a CVD method; and preparing a hafnium oxide coating on the surface of the hafnium carbide coating through an atomic layer deposition method, and carrying out ultra-fast annealing treatment to prepare the high-performance hafnium-based ultra-high-temperature ceramic-based composite material. According to the preparation method, the pyrolytic carbon-hafnium oxide composite interface layer is prepared by adopting an atomic layer deposition process and depending on ultra-fast annealing treatment, and meanwhile, the hafnium carbide-hafnium oxide composite coating is prepared, so that the mechanical property of the composite material in a high-temperature aerobic environment is remarkably improved.