457 results about "Argon atmosphere" patented technology

The invention provides a high-stability lithium-rich manganese-based positive electrode material and a preparation method thereof, and relates to the technical field of lithium-rich manganese-based positive electrode materials, and the method comprises three steps of preparation of a homogeneous precursor, solid-state mechanical fusion doping and coating, and high-temperature sintering; a lithium-rich manganese-based precursor is prepared by adopting a homogeneous coprecipitation process, uniform distribution of metal ions is ensured, then an aluminum source, a zirconium source and a fluorine source are introduced as doping agents, phosphate and a titanate coating agent are combined, doping and coating integrated treatment is realized through mechanical ball milling, and the lithium-rich manganese-based composite material is obtained. And finally, mixing with a lithium source in an argon atmosphere, and carrying out high-temperature sintering of temperature programming and staged heat preservation to form a stable composite coating layer in situ. Therefore, manganese ion migration is effectively inhibited through lattice doping, a layered structure is prevented from being converted into spinel or rock salt phase, meanwhile, a nanoscale ion / electron transmission channel is constructed, interface impedance is reduced, and the charging and discharging efficiency under high voltage is improved.

The invention belongs to the technical field of superfine tungsten powder, and particularly relates to superfine tungsten powder and a preparation method thereof.The preparation method includes the steps that an ammonium tungstate solution, hydrochloric acid and carbon black serve as raw materials to prepare a mixture of tungstic acid and a carbon precursor; calcining the tungstic acid and carbon precursor mixture in a nitrogen atmosphere to obtain a tungsten oxide and carbon mixture; a tungsten oxide and carbon mixture is calcined in an argon atmosphere, the argon atmosphere is kept for natural cooling, the superfine tungsten powder is obtained, the superfine tungsten powder is uniform in dispersion, complete in grain development, smooth in surface, free of pores and complex in morphology, the crystal structure of the superfine tungsten powder is a body-centered cube, the average particle size is smaller than or equal to 0.7 micrometer, and the specific surface area is smaller than or equal to 1.0 m < 2 > / g.

The invention discloses a carbon-doped titanium dioxide nanotube-molybdenum disulfide energy-storage antibacterial material and a preparation method thereof. The preparation method comprises the following steps: carrying out primary anodic oxidation on a clean titanium foil in a mixed electrolyte of ethylene glycol, water and ammonium fluoride; after ultrasonic treatment is carried out in a hydrochloric acid solution for set time, secondary anodic oxidation is carried out, and the mixed electrolyte of the secondary anodic oxidation is the same as that of the primary anodic oxidation; annealing the titanium foil subjected to anodic oxidation twice in an argon atmosphere, putting an annealed sample into a mixed solution of sodium molybdate, a sulfur source and glucose, and carrying out hydrothermal treatment; and the titanium foil subjected to hydro-thermal treatment is cleaned and dried, and the carbon-doped titanium dioxide titanium foil with the surface covered with molybdenum disulfide is obtained. The MoS2-coated carbon-doped titanium dioxide nanotube (TNT-C-atMoS2) with high biocompatibility developed by the invention has a synergistic effect of charge antibiosis and chemical sterilization, so that the problem of intractable biological fouling of a titanium-based metal material in ocean engineering equipment is effectively solved.

The application discloses a kind of derived biomass hard carbon material pulverization process, belong to biomass charcoal material processing technical field, first, pulverization process includes the following steps: after drying, the coconut shell derived hard carbon block is carried out primary crushing, while spraying first modifier, obtain the particle size 1~3mm of coarse crushing modified particle;Coarse crushing modified particle is carried out secondary precision crushing under argon atmosphere, while spraying second modifier, obtain the precision crushing modified particle of D 50 Particle size is 15 μm;Precision crushing modified particle is carried out roll grinding spheroidization, while spraying third modifier, obtain the spherical modified particle of D 50 Particle size is 10 μm;Spherical modified particle is carried out flash drying after cooling, then add magnesium stearate to it, after mixing, obtain derived biomass hard carbon material.Then, the application realizes breakthrough in tap density, particle size distribution, first efficiency and other core indexes by the coordination of three-stage gradient modification and progressive pulverization process.

The invention discloses preparation of a high-performance carbon matrix embedded iron-based catalyst based on a metal organic framework precursor and application of the high-performance carbon matrix embedded iron-based catalyst in reverse water-gas shift reaction. In the preparation process, commercially available 1, 3, 5-trimesic acid iron (the chemical formula is C9H3FeO6, abbreviated as Fe-BTC) is selected as a raw material, pyrolysis treatment is carried out in an argon atmosphere, then air passivation is carried out, and finally the high-performance carbon matrix embedded iron-based catalyst based on the metal organic framework precursor is successfully prepared. The MOF-600 has excellent performance in many catalysts, the carbon dioxide production rate reaches 24.0 mmol CO.gcat <-1 >. S <-1 > at the temperature of 400 DEG C in a reverse water gas shift reaction, the performance is remarkably superior to that of an existing non-noble metal catalyst, and extremely high catalytic efficiency and application potential are shown.

The invention discloses high-flexibility low-reflection flexible photovoltaic glass and a preparation method thereof, and belongs to the technical field of photovoltaic glass preparation. The preparation method comprises the following steps: carrying out cleaning and plasma activation treatment on a flexible glass substrate in an argon atmosphere at the power of 100W for 5 minutes; spin-coating a perovskite precursor solution and annealing to form an active layer, and depositing a transparent conductive layer and a back electrode; carrying out vacuum lamination packaging by adopting an EVA material; coating an acrylic acid adhesive transition layer; spin-coating ultraviolet cured SiO2 sol to form an inorganic coating; a PVDF / Ag / PVDF sandwich structure is constructed, the coverage rate of the nano-silver is 40-50%, and the PVDF layer contains 0.5% of antioxidant. After the flexible photovoltaic glass is circularly bent for 1000 times under the curvature radius of 5mm, the recovery rate is greater than 95%, the PAR transmittance is greater than 92.5%, the NIR reflectivity is greater than 89.3%, the reflectivity retention rate is greater than 96% after the flexible photovoltaic glass is aged for 100 hours at 85 DEG C / 85% RH, and the flexible photovoltaic glass has excellent flexibility, optical performance and environmental stability.

The invention relates to the technical field of waste resourceful treatment, in particular to a sponge titanium weight bottom skin crushing and impurity removing method which comprises the following steps of peeling, bottom skin brake cutting, water jet cutting and crushing, acid leaching and impurity removing, ultrasonic cleaning, argon drying and screening and recycling. The bottom skin is crushed into small-granularity particles by adopting a cross grid water jet cutting technology, metal impurities such as Fe and Ni are removed in combination with acid leaching treatment, residual impurities are removed through multi-stage ultrasonic cleaning, oxidation discoloration is avoided through argon atmosphere drying, and meanwhile water jet sand is recycled; in the process, key indexes such as brake cutting pressure, cutting parameters, acid leaching time and ultrasonic frequency are accurately controlled through a quantification formula. The method effectively solves the problems that equipment is easy to damage during crushing and impurities are difficult to remove in a traditional process, remarkably improves the grade of bottom leather materials, widens the downstream application range, improves the resource utilization rate and economic benefits, and is suitable for industrial batch production.

The invention discloses an all-chemical vapor deposition preparation method of a carbon-carbon heater with the density of 1.6-1.8 g / cm < 3 >, and belongs to the technical field of carbon-carbon heater preparation. The scheme comprises the following steps: 1) preparing a carbon fiber preform with the volume density of 0.5 + / -0.03 g / cm < 3 > by adopting a needling process; 2) taking natural gas as a carbon source, taking low-molecular mixed hydrocarbon gas as auxiliary gas, and performing densification treatment on the carbon fiber preform by adopting an all-chemical vapor deposition method in a nitrogen or argon atmosphere; and (3) carrying out high-temperature graphitization treatment on the densified preform, and sleeving a graphite tool into the heater for fixing in the treatment process, so as to prepare the carbon-carbon heater with the density of 1.6-1.8 g / cm < 3 >. The carbon-carbon heater prepared by the preparation method has the characteristics of stable heat supply, no resistance fluctuation, good corrosion resistance, long service life, short preparation period and the like.

The preparation method of the Ni-Mn bimetallic oxide modified magnesium-based hydrogen storage composite material comprises the steps that 1, under the protection of an argon atmosphere, pure magnesium powder is placed in a reaction kettle, and a product MgH2 is obtained; step 2, dissolving nickel nitrate hydrate and manganous nitrate hydrate in absolute ethyl alcohol, adding urea into the mixed solution, continuously stirring at room temperature, and then carrying out constant-temperature reaction in a tetrafluoropolyvinyl chloride high-pressure reaction kettle in a drying oven; after the reaction is finished, cooling to room temperature, and carrying out centrifugal washing; supernate obtained after centrifugal washing is poured out, precipitates are reserved and transferred into a vacuum drying box, and vacuum drying is conducted; grinding a block obtained after drying, and transferring the block into a tubular furnace for heat treatment to obtain a bimetallic oxide NiMn2O4; 3, MgH2, NiMn2O4 and stainless steel ball milling beads are weighed and put into a mechanochemical reaction ball milling kettle, intermittent ball milling is conducted for a certain time under the protection of a specific atmosphere, and then a composite sample MgH2-NiMn2O4 is collected. The practical application benefit of the magnesium-based hydrogen storage technology can be greatly improved.

The invention discloses a ZnF2 (at) FeF3. 0.33 H2O positive electrode material as well as a preparation method and application of the ZnF2 (at) FeF3. 0.33 H2O positive electrode material. The preparation method comprises the following steps: step 1, uniformly mixing ethanol and PEG-400 to obtain a mixed solvent; 2, ferric nitrate and zinc nitrate are dissolved in a mixed solvent, then an HF aqueous solution is dropwise added into the obtained solution under stirring, after stirring, the obtained mixed solution is transferred into a stainless steel high-pressure kettle to be heated in a closed mode and cooled to the room temperature, a product is washed, centrifuged and dried in vacuum, and powder is obtained; 3, the powder is placed in a tubular furnace and subjected to heat preservation treatment in the argon atmosphere, then the powder is naturally cooled to the room temperature, a product is taken out and ground, and the ZnF2-coated FeF3. 333 H2O material is obtained. By doping ZnF2, FeF3. 0.33 H2O has higher electronic conductivity and a more stable structure, and an all-solid-state lithium battery prepared from the FeF3. 0.33 H2O has higher specific capacity and better cycling stability.

The invention discloses a one-dimensional tubular selenide-carbon composite material assembled by hollow particles and a preparation method and application thereof.The preparation method comprises the following steps that ZnCo-ZIF nanotubes and 2, 5-dihydroxyterephthalic acid are mixed, N, N-dimethylformamide is added, a reaction is conducted, after the reaction is completed, a product is subjected to centrifugal separation, and the one-dimensional tubular selenide-carbon composite material assembled by the hollow particles is obtained. And washing and drying to obtain the one-dimensional tubular MOF material assembled by the hollow particles. And annealing the MOF material in an argon atmosphere to obtain the one-dimensional porous carbon nanotube material assembled by the hollow particles. And then uniformly mixing with selenium powder, and annealing under argon protection to obtain the one-dimensional tubular selenide-carbon composite material assembled by hollow particles. The method is simple to operate and controllable in process, and the prepared product is widely applied to the fields of energy storage, catalysis, environmental governance, biomedicine and the like.

The application discloses a high-performance stainless steel-based electrolytic water dual-function electrode and application thereof, and the electrode is prepared through the following steps: step 1, pretreating a stainless steel surface to remove impurities on the surface; step 2, placing the stainless steel obtained after the treatment in step 1 and a phosphorus source in an argon atmosphere under the condition of 350-450 DEG C, phosphorizing the stainless steel for 1-3 hours to obtain a phosphorized stainless steel electrode, wherein the linear distance between the phosphorus source and the stainless steel is kept at 5-10 cm; and step 3, placing the phosphorized stainless steel electrode obtained after the treatment in step 2 in a RuCl3 solution, and performing electrodeposition on the phosphorized stainless steel as a cathode to obtain the electrode, wherein the concentration of the RuCl3 solution is 2-8 mmol / L, the potential window during the electrodeposition is-2 V-0 V, and the electrodeposition time is 15-25 cycles.

The invention relates to the technical field of preparation of silicon carbide ceramics, in particular to an in-situ reaction sintered silicon carbide ceramic and a preparation method thereof.The preparation method comprises the following technological stages which are conducted in sequence: S1, preparation of silicon carbide slurry, specifically, organic matter precursor raw materials are weighed according to the mass content percentage to form the silicon carbide slurry; s2, vacuum grouting: injecting the silicon carbide slurry in the vacuum grouting tank into the shaping mold from the bottom of the shaping mold to form a silicon carbide green body; and S3, in-situ reaction sintering is conducted, specifically, the silicon carbide green body is placed in a sintering furnace, heating, heat preservation and cooling are conducted on the silicon carbide green body in the argon atmosphere through a segmented temperature control technology, and the silicon carbide ceramic is obtained. The silicon carbide ceramic prepared by the method disclosed by the invention has relatively high density and excellent mechanical properties.

The invention belongs to the technical field of powder preparation, and relates to a preparation method of submicron 3C-SiC powder, which comprises the following steps: (1) mixing silicon powder, a carbon-containing raw material and a fluorine-containing raw material according to a certain proportion, fully ball-milling and uniformly mixing the powder and then drying, (2) putting the dried powder into an atmosphere furnace, introducing argon atmosphere, heating to 1400-1500 DEG C, preserving heat for 1-3 hours, and cooling to room temperature to obtain the submicron 3C-SiC powder. And (3) putting the reacted powder into a muffle furnace, and carrying out carbon removal treatment, so as to obtain the high-purity 3C-SiC powder. And the prepared powder is uniform in morphology and granularity and relatively high in purity. The method is simple, has low requirements on instruments and equipment, and is suitable for batch production. The 3C-SiC powder synthesized and prepared through the method is uniform in particle size (about 130 nm) and special in morphology, and a spherical structure is formed. The method is relatively simple in preparation process and convenient to operate, and lays a certain foundation for industrial production.

The invention relates to an easy-to-prepare low-cost high-performance sodium ion battery hydrogen peroxide modified hard carbon negative electrode material, and a preparation method comprises the following steps: S1, crushing alfalfa, cleaning, filtering, and carrying out vacuum drying to obtain a biomass precursor material; s2, performing low-temperature cracking, and annealing in an argon atmosphere to obtain a hard carbon precursor carbon material; s3, completely dispersing the hard carbon precursor material in the step S2 in deionized water to obtain a hard carbon precursor material mixed solution, dropwise adding an acid solution to adjust the pH value, then dropwise adding a hydrogen peroxide aqueous solution, filtering and washing to be neutral after reaction to obtain an intermediate product, and performing vacuum drying to obtain a modified hard carbon precursor carbon material; and S4, performing high-temperature pyrolysis and annealing under the protection of an argon atmosphere. The biomass alfalfa is used as a main raw material, and compared with a hard carbon negative electrode material prepared from a traditional biomass material, the specific capacity, the first coulombic efficiency and the capacity retention rate are remarkably improved.

The invention discloses a high-toughness and high-entropy alloy with dynamically-enhanced dislocation cells and a preparation method of the high-toughness and high-entropy alloy, and relates to the technical field of alloy preparation. The preparation method sequentially comprises the following steps that S1, in a high-purity argon atmosphere, an alloy ingot is prepared through a suspension melting method, and then homogenization treatment is conducted for 24 h at the temperature of 1200 DEG C; and S2, multi-pass small-strain rolling is carried out in three steps, namely cold rolling, hot rolling and cold rolling, the total thickness is reduced by 84%, and the high-toughness and high-entropy alloy with the dynamically-enhanced dislocation cells is obtained. According to the preparation method, the dislocation cell structure can be prepared in the high-entropy alloy, the steps are simple, the efficiency is high, the risk caused by additional defects is avoided, and meanwhile the preparation method is not limited by the sample size. More importantly, the obtained dislocation cell structure can be dynamically enhanced in the deformation process, so that the alloy has higher ductility under the flow stress of kilomega Pa, and the balance between the strength and the ductility is avoided.

The invention belongs to the technical field of powder metallurgy, and particularly relates to a high-fluidity MIM metal feed and a forming process thereof.The high-fluidity MIM metal feed is composed of the following materials: metal powder: spherical metal powder (a titanium alloy TC4 material), polycaprolactone and graphene nanosheets; wherein the volume ratios are 68-72 vol%, 0.5-2 wt% (based on the mass of the metal powder) and 0.1-0.5 wt% (based on the mass of the metal powder) respectively; a powder oxide layer is removed through vacuum plasma cleaning (300-500 W, argon atmosphere), a metal core-PCL / graphene shell structure is prepared in combination with ultrasonic-assisted in-situ polymerization, lubrication and adhesion enhancement are synchronously achieved, the powder oxygen content is controlled to be smaller than 500 ppm, and sintering oxidation defects are reduced.

The present invention provides a zinc oxide / titanium dioxide / titanium carbide composite microwave absorbing material and a preparation method thereof, belonging to the technical field of electromagnetic wave absorbing materials. The method first adds Ti3C2T x nanosheets into deionized water and stirs evenly to obtain a Ti3C2T x nanosheet suspension; dissolves Zn(CH3COO)2·2H2O in methanol to obtain a Zn(CH3COO)2·2H2O solution; finally mixes the two solutions, transfers them to a Teflon-sealed autoclave for reaction, and performs heat treatment in a tubular furnace under an argon atmosphere to obtain a zinc oxide / titanium dioxide / titanium carbide composite microwave absorbing material. The composite microwave absorbing material has a rose-shaped, sandwich-like hamburger-shaped or spiny sea urchin-shaped structure. By partially oxidizing titanium carbide and introducing a material with a moderate dielectric constant, a zinc oxide / titanium dioxide / titanium carbide composite microwave absorbing material with a special morphology is prepared to improve the problem of limited microwave absorbing performance caused by the too high conductivity of titanium carbide.

The invention relates to the fields of green energy materials, electrochemical sensing detection, food and medicine, in particular to a preparation method, a product and application of a waste coffee residue derived in-situ monatomic iron loaded nitrogen-doped carbon nanomaterial. The preparation method of the waste coffee residue derived in-situ monatomic iron loaded nitrogen-doped carbon nanomaterial comprises the following steps: carbonizing coffee residues in an argon atmosphere to obtain the waste coffee residue derived in-situ monatomic iron loaded nitrogen-doped carbon nanomaterial, the carbonization specifically comprises the step of heating to 800-1000 DEG C at the rate of 5 DEG C / min and carbonizing for 2 hours. The waste coffee residue derived in-situ monatomic iron loaded nitrogen-doped carbon nanomaterial prepared by the method has selectivity and high efficiency on chlorogenic acid detection, and the detection limit of chlorogenic acid is as low as 66.67 nmol / L.

The present invention discloses a MOF-derived cobalt trioxide @ cobalt oxide @ cobalt diphosphide composite material and its preparation method and application, which belongs to the technical field of MOF-derived composite materials. It includes: the present invention synthesizes Co‑MOF‑74 by a hydrothermal method, then in-situ oxidation under an air atmosphere, and then in-situ partial phosphating under an argon atmosphere, and the obtained sample is Co3O4@CoO@Co2P composite photocatalyst. The advantage of the present invention is that the composite photocatalyst prepared with rod-shaped Co‑MOF‑74 as a template inherits the regular rod-shaped morphology and porous structure of the MOF precursor, provides more contact and reaction sites for surface charge and mass transfer in the photocatalytic reaction, and promotes the migration and separation of photogenerated carriers. The preparation process of the method of the present invention is simple, the reaction conditions are suitable, it is suitable for large-scale promotion, and has good application prospects in the fields of environment, energy, etc.

The invention discloses a method for preparing a porous negative electrode silicon-carbon material from a one-dimensional silicon-carbon compound, and relates to the technical field of electrode materials.The method comprises the steps that firstly, nanometer silicon is deposited on the surface of CNT through a chemical vapor deposition method, and an S / CNT compound is formed; then mixing the compound and a surfactant in water, adding an ethanol mixed solution containing resin, performing ultrasonic stirring, and drying to obtain an S / CNT / C precursor; sintering the precursor in an argon atmosphere to obtain an S / CNT / C material; and mixing the material with a biomass material, carrying out vacuum drying, sintering in an argon atmosphere, and carrying out jet milling to finally obtain the porous negative electrode silicon-carbon material. According to the method for preparing the porous negative electrode silicon-carbon material from the one-dimensional silicon-carbon compound, nano silicon is deposited on the surface of a carbon nanotube CNT, so that volume expansion is effectively relieved; through double-layer carbon coating and a porous structure, electrolyte permeation and the contact area between electrolyte and silicon carbon are promoted, and the rate capability of the negative electrode material is improved.

The invention belongs to the related technical field of two-dimensional materials, and discloses a two-dimensional degenerate semiconductor film material and a preparation method and application thereof, and the preparation method comprises the following steps: S1, uniformly spin-coating a niobium salt compound solution on a substrate; and S2, based on the obtained substrate, preparing the two-dimensional degenerate semiconductor film material by adopting a chemical vapor deposition method, specifically, in a tubular furnace with an argon atmosphere, placing a sulfur source or a selenium source at the reaction upstream, placing a molybdenum foil in a sleeve in the tubular furnace and in the reaction midstream, and placing the substrate at the reaction downstream, so as to obtain the two-dimensional degenerate semiconductor film material. And introducing oxygen midway, and heating to a reaction temperature to generate the two-dimensional degenerate semiconductor film material. According to the method, the uniformly-covered precursor substance is formed on the surface (substrate) of the two-dimensional material through the spin-coating process, a high-temperature vacuum environment and complex equipment are not needed, modification and polarity regulation and control of the material can be completed only by regulating and controlling the concentration of the precursor solution, the spin-coating rotating speed and the spin-coating time, and low-cost batch processing can be achieved.

The invention provides a method for simulating the influence of montmorillonite clay mineral water on organic matter pyrolysis hydrocarbon generation, and belongs to the technical field of organic matter pyrolysis. The method comprises the following steps: heating montmorillonite to obtain dehydrated montmorillonite, mixing organic matters and the dehydrated montmorillonite in an argon atmosphere and a dry environment, transferring a mixed sample into a gold tube, and loading the sample; putting the gold tube into an iron reaction kettle, filling the reaction kettle with water, and cooling after heating reaction; putting the cooled gold tube into a gas collecting device, and calculating the amount of substance of gas according to an ideal gas state equation; the collected gas is subjected to GC analysis to obtain the percentage of each gas, the yield of each gas is calculated by combining the amount of substance of the gas, and the influence of the montmorillonite clay endogenous water on hydrocarbon generation by thermal decomposition of organic matters is evaluated. Under the condition that only the unified boundary condition of clay mineral water is changed, a verifiable judgment system of'endogenous water type-product spectrum characteristic-reaction channel 'is established for the first time.

The invention discloses a monatomic loaded lignin carbon-based photocatalyst as well as a preparation method and application thereof. The preparation method of the photocatalyst comprises the following steps: S1, grinding and blending lignin and melamine, then adding the mixture into water, transferring the obtained solution into a hydrothermal reaction container, reacting at 175-195 DEG C for 4-10 hours, and after the reaction is finished, cooling at room temperature, washing and centrifugally separating to obtain a solid mixture; s2, dispersing the solid mixture in an aqueous solution containing metal salt, stirring at room temperature, and drying after the reaction is finished; and S3, putting the dried solid into a container, putting the container into a pyrolysis reactor, heating to 800-1000 DEG C in an argon atmosphere, pyrolyzing for 2-6 hours, and naturally cooling to obtain the monatomic loaded lignin carbon-based photocatalyst. The monatomic loaded lignin carbon-based photocatalyst provided by the invention can efficiently catalyze glucose to synthesize glucaric acid under mild conditions, and the obtained target product is relatively high in yield and easy to separate, and has a very good industrial application prospect.

This invention relates to the field of ferroalloy smelting technology and discloses a high-carbon ferromanganese and its preparation method, comprising the following steps: raw material pretreatment; converter preheating and bottom material laying: pretreated high-grade manganese ore, lime, and coke powder are mixed and added as bottom material to the CLU converter for preheating; iron addition and initial reduction: high-carbon ferromanganese is added to the converter, and graphite fragments are added, and initial reduction is carried out under a pure argon atmosphere; atmosphere control and second-stage reduction: when the carbon content of the molten iron drops to 5.0-5.8%, the reblowing gas is switched to a mixed gas of argon, CO, and CH4, and the remaining high-grade manganese ore, silicon carbide, ferrosilicon manganese alloy, and supplementary coke powder are added in batches, while adjusting the slag composition; endpoint judgment and iron tapping. The high-carbon ferromanganese of this invention has precise composition and high purity, and the preparation method is characterized by high efficiency, low consumption, greenness, and high manganese recovery rate, enabling the industrial-scale production of high-carbon ferromanganese.

The application discloses a method for preparing a carbon-carbon heater by means of pitch impregnation, and the carbon-carbon composite material prepared through the process steps of preform preparation, pitch impregnation and solidification, high-pressure pitch impregnation, low-temperature carbonization, repeated impregnation and carbonization and high-temperature graphitization has the advantages of high density and low resistivity, and the photovoltaic single crystal furnace heater is further machined. First, micron composite powder of boron carbide-tungsten carbide is uniformly applied on the surface of the heater and is subjected to high-temperature treatment, so as to form a dense ceramic coating, and then a mixed pyrolytic graphite layer is deposited in a methane-argon atmosphere, and through the above two coating processes, the silicon vapor corrosion resistance of the carbon-carbon heater is significantly enhanced, so that the service stability and service life of the carbon-carbon heater are improved.

The invention discloses a flocculent vanadium-doped MoN / CNT composite material and a preparation method and application thereof.The method comprises the steps that 1, ammonium molybdate is added into absolute ethyl alcohol to be dissolved, and a solution A is obtained; 2, adding 2-methylimidazole into deionized water, and dissolving to obtain a solution B; 3, adding the solution A into the solution B, stirring, carrying out suction filtration, separating out a precipitate, and drying to obtain a precursor I; 4, adding the precursor I into deionized water, and stirring to obtain a turbid solution; 5, ammonium metavanadate and polyvinylpyrrolidone are added into absolute ethyl alcohol, and a solution C is obtained; 6, adding the solution C into the turbid solution, stirring, carrying out suction filtration, separating out a precipitate, and drying to obtain a precursor II; 7, performing low-temperature sintering on the precursor II in an argon atmosphere to obtain a precursor III; and 8, mixing the precursor III with urea, and performing high-temperature sintering in an argon atmosphere to obtain the vanadium-doped MoN / CNT composite material which has high energy density and high conductivity and can endow an energy storage device with high rate capability and long cycle life.

The invention relates to the technical field of alloy shaped charge liners for perforating bullets, and particularly discloses an energy-releasing alloy shaped charge liner for a perforating bullet and a preparation method of the energy-releasing alloy shaped charge liner for the perforating bullet to solve the problems that when an alloy shaped charge liner is prepared through an existing Zr-Ti-Nb composite material system, a blank is prone to expanding and cracking, and the dynamic tensile property of a product is insufficient. Comprising the following steps: S1, respectively taking zirconium powder, niobium powder, titanium powder and TiH2 powder, and mixing to obtain a premix; s2, taking the premix, and performing dry bag static pressure to obtain a dry bag static pressure blank; s3, the dry bag static pressure blank is taken and subjected to stepped hydrogen control sintering, and a hydrogen control sintering blank is obtained; s4, the hydrogen-controlled sintered blank is taken and placed in an argon atmosphere, heating and pressure sintering are conducted, and a hot isostatic pressing sintered blank is obtained; and S5, the hot isostatic pressing sintered blank is subjected to oil quenching at the temperature of 1050 + / -50 DEG C, and the energy release alloy shaped charge liner for the perforating bullet is obtained. And meanwhile, multiple processes such as oil quenching heat treatment are combined, the energy-releasing alloy shaped charge liner of the full-beta-phase structure can be stably obtained, and the effects such as the sneaking effect and the chambering effect can be achieved on the premise that the penetrating depth of a perforating bullet is not reduced.

The invention discloses a silicon-oxygen-carbon-based negative electrode material and a preparation method thereof, and belongs to the technical field of lithium battery negative electrode materials, and the preparation method comprises the following steps: (1) mixing alcohol, water and acid to prepare an acid solution with the pH value of 2-4, adding organosiloxane into the acid solution, and stirring in a water bath to obtain a siloxane hydrolysate; (2) adding a pyrene compound into the siloxane hydrolysate, and carrying out ultrasonic treatment; (3) adding alkali, stirring in a water bath at 20-50 DEG C for 1-3 hours, and then freeze-drying to obtain a precursor of SiOC; and (4) placing the precursor in an atmosphere furnace, sintering in an argon atmosphere, and naturally cooling to obtain the modified negative electrode material SiOC. The amorphous carbon content of the prepared SiOC is increased, on one hand, the electronic conductivity of the SiOC can be improved, and on the other hand, volume expansion in the charging and discharging process can be relieved.

The invention belongs to the nuclear industry and can be used for the production of fuel pellets from uranium-molybdenum metal powder enriched with uranium-235 to 7%, which can be used as fuel elements for nuclear reactors. The sintering of the pellets is carried out in an inert argon atmosphere at a temperature in the range of 1100°C to 1155°C, as the initial powder, a particle size of 160 μm is used, with a molybdenum content of 9.0 to 10.5 wt.%. The powder is preheated at a temperature of 500°C for 10-20 hours (in an argon medium), and then cold-pressed into pellets in a mold at a pressure of up to 950 MPa. According to another method, when preparing uranium-molybdenum pellets using a binder (plasticizer), the pellets are heated in argon from 300°C to 450°C for a duration of 2-4 hours before sintering, in order to remove the binder. The invention allows to increase the uranium content in the fuel, to reduce the heat accumulated in the core of the nuclear reactor, and to reduce the energy release in the event of a violation of the normal operating conditions of the nuclear reactor, which will improve its safety and emergency stability.