351 results about "Dimethyl formamide" patented technology

The invention relates to the technical field of microfiber material preparation, in particular to a preparation method of an insulating flame-retardant automotive interior microfiber material, which comprises the following steps: spinning sea-island fibers by taking PA6 as an island component and LDPE as a sea component and matching with master batches; performing opening, carding, lapping, pre-needling by a pre-needling machine and needling by a needling machine on the sea-island fibers to prepare non-woven fabric; carrying out heat setting on the non-woven fabric; preparing insulating flame-retardant polyurethane slurry, infiltrating the heat-set non-woven fabric to enable the non-woven fabric to be fully impregnated, and then feeding the non-woven fabric into an aqueous solution of dimethylformamide to be subjected to water bath curing, so as to prepare a semi-finished synthetic leather product; extracting sea components in the sea-island fibers from the synthetic leather semi-finished product by adopting a stripping process; and drying the reduced superfine fiber synthetic leather base cloth, immersing the base cloth into a softening agent aqueous solution, and then carrying out drying and leather rubbing treatment to obtain the insulating flame-retardant superfine fiber leather. The product provided by the invention is used for external protection of an intelligent auxiliary driving steering wheel sensing layer, and the resistance of the microfiber material reaches 1.2 megohm or above.

The invention relates to a preparation method of a terephthalic acid and 2-methylimidazole organic framework catalyst, and relates to a preparation method of a high polymer material catalyst, the preparation method comprises the following steps: weighing C6H4 (COOH) 2 and 2-methylimidazole, dissolving C6H4 (COOH) 2 and C4H6N2 in N, N-dimethylformamide (DMF), weighing zinc nitrate hexahydrate (Zn (NO3) 2.6 H2O), dissolving in DMF, and preparing into a solution; the preparation method comprises the following steps: mixing a C6H4 (COOH) 2 solution and a C4H6N2 solution in proportion, and uniformly stirring; slowly adding the mixed ligand solution into a mixed solution of zinc nitrate hexahydrate (Zn (NO). 6HO) dissolved in DMF (Dimethyl Formamide), and transferring into a high-pressure reaction kettle for reaction; after cooling, centrifugally separating to obtain a white solid product, washing with methanol, and drying to obtain the Zn-MOF catalyst. The Zn-MOF catalyst provided by the invention can be widely applied to polyester synthesis, esterification reaction and other organic catalytic reactions, and especially has significant advantages in PBAT synthesis.

The invention belongs to the technical field of thermal management materials, and provides aerogel fibers of a three-dimensional porous structure and a preparation method and application of the aerogel fibers. The preparation method comprises the following steps: preparing a polyurethane spinning solution by taking N, N-dimethylformamide as a solvent; then carrying out wet spinning on the polyurethane spinning solution to obtain wet gel state fibers; and immersing the wet gel-state fiber into an organic solvent for solvent exchange, and drying after the solvent exchange is completed to obtain the aerogel fiber. The method is simple, low in cost and low in equipment requirement, efficient and continuous production of the aerogel fibers can be achieved, different spinning solutions can be adopted for preparing the aerogel fibers of different pore structures, meanwhile, the problem that the porous structures of the aerogel fibers are prone to collapsing when the aerogel fibers are dried at normal pressure is solved, and the aerogel fibers are suitable for large-scale production. The aerogel fiber with the three-dimensional porous structure is stable in porous structure, not prone to collapse, excellent in mechanical property and excellent in heat preservation and heat insulation performance.

The invention discloses a preparation method of an optical OCA (Optical Clear Adhesive) and application of the optical OCA in a mobile phone folding screen, and relates to the technical field of optical cement, the optical OCA is prepared from the following raw materials in parts by weight: 50 parts of acrylate prepolymers, 2-4 parts of 3-allyl-2-mercapto-3H-quinazoline-4-ketone, 1-3 parts of diallyl disulfide, 1-3 parts of 3-[N, N-dimethyl formamide], 1-3 parts of 2, 3, 5-trimethyl-1, 3-pentanediol monoisobutyronitrile, 1-3 parts of 2, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3 The preparation method comprises the following steps: adding 3-5 parts of N, N-dimethyl-[2-(2-methylpropane-2-enoyloxy) ethyl] ammonium] propane-1-sulfonic acid inner salt, 1-3 parts of allyl succinimido carbonate, 2-4 parts of dicyclopentene methacrylate, 1-3 parts of 1, 3, 5-triacryloyl hexahydro-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5- The invention relates to a graphene quantum dot photoinitiator which is prepared from the following components in parts by weight: 1-3 parts of 1, 3, 5-triazine, 0.8-1.2 parts of a photoinitiator, 1-3 parts of an aziridine cross-linking agent, 1-3 parts of graphene quantum dots, 0.8-1.2 parts of a coupling agent and 40-50 parts of a diluent. The optical OCA adhesive is high in light transmittance and bonding strength, good in weather resistance and excellent in folding resistance.

The invention relates to a Fe3C-Ru / NFs catalyst as well as a preparation method and application thereof. Wherein the Fe3C-Ru / NFs catalyst comprises carbon nanofibers NFs, and Fe3C and sub-nanoscale Ru particles which are loaded on the carbon nanofibers NFs, and the average particle size of the Ru particles is less than 3nm. The preparation method of the catalyst comprises the following steps: dissolving PVP (Polyvinyl Pyrrolidone), an iron source and a ruthenium source in a mixed solvent of DMF (Dimethyl Formamide) and ethanol to obtain a precursor solution; and preparing FeRu / PVP nanofibers from the precursor solution through an electrostatic spinning method, and then carrying out pre-oxidation and high-temperature carbonization to obtain the Fe3C-Ru / NFs catalyst. According to the invention, Fe3C and sub-nanoscale Ru particles are highly dispersed on the carbon nanofibers, and the Fe3C particles enable the electronic environment of Ru sites to be changed and to be in an electron-deficient state, so that the generation of a catalytic reaction is facilitated, and the catalyst has extremely high electro-catalysis full-water-splitting performance and stability.

The invention belongs to the technical field of all-vanadium redox flow battery diaphragms, and particularly discloses a sulfonated polyetheretherketone / polyaniline composite membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing polyetheretherketone and concentrated sulfuric acid, and carrying out water bath heating reaction to prepare a sulfonated polyetheretherketone solid; molybdenum disulfide and methylbenzene are mixed and subjected to ultrasonic treatment, 1, 3-propane sultone is added, oil bath heating is conducted, and sulfonated molybdenum disulfide powder is prepared; the preparation method comprises the following steps: mixing and stirring sulfonated molybdenum disulfide powder, polyaniline and a DMF (Dimethyl Formamide) solution, performing ultrasonic treatment, adding a sulfonated polyether-ether-ketone solid, stirring to obtain membrane casting slurry, coating a glass plate with the membrane casting slurry, drying to form a membrane, and soaking the membrane in a sulfuric acid solution and deionized water in sequence to obtain the sulfonated polyether-ether-ketone / polyaniline composite membrane. The invention discloses a sulfonated polyetheretherketone / polyaniline composite membrane as well as a preparation method and application thereof. The sulfonated polyetheretherketone / polyaniline composite membrane has high proton conductivity, can maintain relatively low vanadium ion permeability and can improve the electrochemical performance of an all-vanadium redox flow battery.

The invention relates to a platinum-zinc alloy supported nitrogen-doped porous multi-layer carbon material and preparation and application thereof, the carbon material takes a rod-like graded porous carbon nanomaterial as a carrier, and platinum-zinc alloy particles and zinc monatomic are jointly supported on the surface of the carrier; the preparation method comprises the following steps: S1, adding zinc acetate and hexadecyl trimethyl ammonium bromide into DMF (Dimethyl Formamide), carrying out ultrasonic treatment, adding into a polyacrylonitrile solution, and stirring; s2, performing electrostatic spinning on the obtained spinning precursor solution; s3, adding the obtained nanofiber into a zinc acetate dihydrate solution, then adding a dimethylimidazole solution, carrying out hydrothermal reaction, soaking the obtained product in a chloroplatinic acid methanol solution, and then carrying out freeze drying; and S4, heating carbonization is carried out under the protection of an inert atmosphere, then annealing and cooling are carried out, and the PtZn-Zn-N4-HPCNFs material is obtained. Compared with the prior art, the catalytic performance and the like in the reaction processes of oxygen reduction reaction (ORR), chlorine evolution reaction (CER) and the like can be effectively improved.

The invention belongs to the technical field of chemical synthesis, and particularly relates to a method for preparing 5-methylfurfural by using 2-methylfuran. The special solid acid catalyst is used for replacing traditional phosphorus oxychloride, hydrogen chloride and phosphorus-containing wastewater are eliminated from the source, and the sulfolane is used for replacing DMF (Dimethyl Formamide), so that solvent residues in the product are reduced. The solid catalyst SO4 < 2-> is modified to form a strong Bronsted acid site (-SO3H) which cooperates with Ce < 3 + > / Ce < 4 + > redox to inhibit carbon deposition, selectively activate 2-methylfuran alpha-C and inhibit side reactions, so that the selectivity and yield of a target product are improved. Na2CO3 neutralization is replaced by electrochemical neutralization, salt slag solid waste is eliminated, and environmental pollution is reduced. After the organic phase is dried and dewatered through a molecular sieve, most of the solvent is removed through rotary evaporation, and the residual crude product is subjected to centrifugal molecular distillation, so that unreacted raw materials and trace impurities are effectively removed, and the product purity is remarkably improved.

The invention relates to a phase change energy storage fiber with ultraviolet shielding and heat regulation and control functions and a preparation method of the phase change energy storage fiber. The preparation method comprises the following steps: dissolving thermoplastic polyurethane in N, N-dimethylformamide to form a spinning mother solution; the preparation method comprises the following steps: firstly, adding nano titanium dioxide and uniformly dispersing, then adding a silicon dioxide shell layer-octadecane core layer phase change microcapsule, and stirring and ultrasonically defoaming to obtain a uniform composite spinning solution; extruding the spinning solution into a coagulating bath consisting of isopropanol and deionized water through an injection pump, and coagulating and forming to obtain nascent fibers; finally, washing, solvent replacement, tension setting and drying treatment are conducted, and compared with the prior art, the obtained fiber has efficient ultraviolet shielding performance and remarkable phase change energy storage capacity and has wide application prospects in the fields of intelligent temperature adjusting textiles, outdoor protective garments, building heat management and the like.

The invention discloses a degradable nanocellulose sustained-release drug-loaded film and a preparation method thereof, and belongs to the technical field of drug functional materials. The preparation method comprises the following steps: mixing and stirring microcrystalline cellulose and 64wt% sulfuric acid solution, centrifuging, dialyzing to be neutral, and freeze-drying to obtain CNCs; cNCs, NaIO4 and water are mixed and then subjected to a light-shielding reaction, ethanol precipitation is added, dialysis purification is conducted, freeze drying is conducted, and formylation modified CNCs are obtained; mixing and stirring the aldehyde modified CNCs, sericin, polyvinyl alcohol, water and a target drug to obtain a core layer solution; dissolving a polylactic acid-glycolic acid copolymer into a mixed solution of chloroform and DMF (Dimethyl Formamide) to obtain a shell solution; the core layer solution and the shell layer solution are subjected to coaxial electrostatic spinning forming to obtain the drug-loaded fiber, then the drug-loaded fiber is subjected to biomimetic mineralization surface modification to obtain the degradable nanocellulose sustained-release drug-loaded film, the drug loading rate is increased, the mechanical property of the drug-loaded film is improved, and the sustained-release and release-controllable effects are achieved.

The invention discloses a synthesis method of a felinone intermediate, and relates to the technical field of medicine synthesis. The synthesis method comprises the following steps: firstly, taking a 500ml four-neck flask, adding 200ml of dichloromethane, adding 40g of 3-hydroxypropionitrile, finally adding 5g of a DMAP solid material, and stirring for 1 hour; continuously dropwise adding 50 g of ketene dimer, and after temperature-controlled dropwise adding is completed, carrying out heat preservation reaction for 2 hours to obtain a reaction solution; and taking the reaction liquid, washing with 200ml of saturated saline solution, preserving heat, taking the lower-layer material, washing with 200ml of purified water, preserving heat, taking the lower-layer material, finally washing with 200ml of saturated saline solution, taking the lower-layer material, distilling, and desolventizing to obtain the target product. The preparation method comprises the following steps: putting 40g of a target product and 200ml of DMF (Dimethyl Formamide) into a 500ml four-mouth flask, stirring, then adding 50g of 4-cyano-2-methoxybenzaldehyde into a constant-pressure dropping funnel and the like; the synthesis method is stable in reaction, low in raw material price, reasonable in synthesis route, basically free of by-products in the synthesis process, and high in target product purity.

The invention discloses modified bamboo charcoal powder, a modified bamboo charcoal powder / polyacrylonitrile composite film and a preparation method thereof, and relates to the technical field of polymer composite films. The preparation method comprises the following steps: firstly, carrying out ball milling treatment on bamboo charcoal fibers to prepare superfine bamboo charcoal powder with nanoscale particle size, cleaning, oxidizing and modifying the superfine bamboo charcoal powder to obtain modified bamboo charcoal powder, and then jointly dispersing the modified bamboo charcoal powder and PAN in a DMF (Dimethyl Formamide) solvent, stirring and dissolving to prepare a uniform membrane casting solution. A wet film is formed on a glass substrate in a film coating mode, and the superfine modified bamboo charcoal powder / PAN composite film is finally obtained through the steps of solidification, cleaning and drying. The film has the good film-forming property of PAN and the excellent adsorption property of bamboo charcoal, and shows good mechanical strength and high thermal stability and adsorption efficiency. The method is simple in process and wide in material source, has a good industrialization prospect, and is suitable for the fields of environment-friendly filtering materials, energy storage and high-temperature-resistant materials and the like.

The utility model relates to the technical field of wet synthetic leather dimethyl formamide dilute liquid distillation, and discloses a wet synthetic leather dimethyl formamide dilute liquid distillation device which comprises a distillation cylinder, a connecting ring is fixedly mounted at the top of the distillation cylinder, a fixing bolt is in threaded connection with the top of the connecting ring, and a top cover is in threaded connection with the surface of the fixing bolt. A stirring assembly is arranged in the middle of the top surface of the top cover, an electric valve is fixedly mounted at the bottom of the distillation cylinder, and a retention cylinder is fixedly mounted on the surface of the electric valve. According to the wet synthetic leather dimethylformamide dilute liquid distillation device, through the arrangement of the distillation cylinder, the stirring assembly and the top cover, when a worker carries out distillation operation on dimethylformamide dilute liquid, the dimethylformamide dilute liquid can be placed in the distillation cylinder, and then the liquid in the distillation cylinder is heated by utilizing a temperature controller and a heating wire; and then a power supply of a servo motor is switched on, so that a stirring rod quickly mixes the liquid in the distillation cylinder, and the distillation effect of the liquid is accelerated.

The invention relates to a monovalent selective cation exchange membrane and a preparation method thereof, and belongs to the technical field of cation exchange membranes, and the specific steps are as follows: weighing DA and ammonium persulfate, adding into a buffer solution to obtain a PDA coating solution, pouring the PDA coating solution on the surface of a base membrane for soaking, and depositing a PDA coating on the surface of the activated base membrane to obtain a membrane I; the preparation method comprises the following steps: dissolving zirconium tetrachloride and 2-aminoterephthalic acid in DMF (Dimethyl Formamide), performing solvothermal synthesis on amino-functionalized MOF (UIO-66-NH2) under an acidic condition, weighing PEI and MOF (UIO-66-NH2) powder, adding into a buffer solution, pouring on the surface of a membrane I, depositing a PEI-MOF composite coating to obtain a membrane II, and air-drying the membrane II to obtain the monovalent selective cation exchange membrane. Therefore, the monovalent selective cation exchange membrane which is low in cost, high in selectivity and stable in performance can be prepared by modifying the cation exchange membrane through a simple and easy-to-operate method.

The preparation method comprises the following steps: mixing cobalt acetate, a modified ligand, a modified additive and DMF (Dimethyl Formamide), carrying out ultrasonic treatment, adding deionized water and a modified filler, carrying out ultrasonic treatment, carrying out heating reaction, carrying out centrifugation to remove a supernatant, and carrying out drying treatment to prepare the rapid-charge high-capacity artificial graphite negative electrode material, when the cobalt acetate, the modified ligand, the modified additive and the modified filler are subjected to blending reaction, carboxyl on the modified ligand and carboxyl on the modified additive can form coordinate bonds with cobalt ions of the cobalt acetate, then a cobalt metal organic framework is formed on the surface of the modified filler, and a fluorine element in the modified ligand can react with lithium to form lithium fluoride; electron penetration is effectively blocked, and side reactions are reduced; the lithium ion diffusion energy barrier is reduced, rapid charging and discharging are achieved, pyridine groups on the surface of the modified filler can provide lone pair electrons and serve as binding sites of lithium ions, pseudocapacitance is formed, and then the capacity is increased.

The invention provides a solid proton electrolyte membrane preparation method and application thereof.The electrolyte has the advantages of being high in safety, capable of widening a voltage window, environmentally friendly, low in cost, long in service life and the like, and the synthesis method of the solid proton electrolyte membrane comprises the steps that polyvinylidene fluoride and polyethylene oxide serve as synthesis main bodies, phosphoric acid is added into the synthesis main bodies, and the mixture is placed in N, N-dimethyl formamide to be dissolved; heating, stirring and dissolving in an N, N-dimethylformamide solvent to obtain a transparent clear solution, and performing ultrasonic treatment under a heating condition to remove a small amount of bubbles in the solution, so as to obtain a uniform transparent solution; and placing the solution in a corresponding mold, and removing the solvent in a vacuum oven to obtain the solid electrolyte membrane with uniform thickness. When being used in the proton battery, the composite material can widen a voltage window and prolong the cycle life of the proton battery, and has the advantages of low cost, easiness in synthesis, high safety and the like.

The invention discloses a UiO-66-based monovalent cation selective separation membrane as well as a preparation method and application thereof, and belongs to the technical field of membrane separation. The preparation method comprises the following steps: mixing a zirconium n-propoxide solution with n-propyl alcohol, glacial acetic acid and DMF (Dimethyl Formamide) to prepare a zirconium cluster solution; performing oxygen plasma etching and acrylic acid grafting pretreatment on the BPPO base film to obtain a BPPO / CA film; finally, the BPPO / CA membrane, a zirconium cluster solution, terephthalic acid and triethylamine are subjected to an original growth reaction in a two-chamber reaction tank, and the UiO-66-based monovalent cation selective separation membrane is prepared. The preparation method provided by the invention is simple and mild in condition, and the prepared membrane has good cation selectivity and is suitable for the fields of industrial-grade TMAH solution purification and the like.

The invention belongs to the technical field of lithium ion batteries, and particularly relates to a preparation method of a composite solid electrolyte membrane with a three-dimensional mutual transmission network structure. The preparation method comprises the following steps: firstly, adding PVDF-HFP and PVDF into DMF (Dimethyl Formamide) for fully dissolving, then adding lithium salt for fully dissolving, and introducing an initiator to form a solution A; adding solid electrolyte powder and triazine monomers into DMF (Dimethyl Formamide), and fully stirring to form a solution B; uniformly stirring the solution A and the solution B again to form a glue solution C; and dripping the glue solution C on a glass plate for blade coating, placing the glass plate in a drying box for thermal insulation polymerization, and then vacuumizing and drying to obtain the composite solid electrolyte diaphragm. The triazine monomers are added to form a three-dimensional mutual transmission network structure, the flame retardance and cohesiveness of the three-dimensional mutual transmission network structure are improved, finally, the composite solid electrolyte diaphragm with great commercial value is obtained, and the diaphragm has good effects in the aspects of improving the ionic conductivity, the flame retardance, the viscosity after hot pressing and the like.

The invention relates to the technical field of lithium-ion solid-state batteries, in particular to a three-dimensional polymer modified intermediate layer for a lithium-ion solid-state battery and a preparation method of the three-dimensional polymer modified intermediate layer, and the preparation method comprises the following steps: adding polyacrylonitrile into N, N-dimethylformamide, and stirring until the polyacrylonitrile is completely dissolved; and then adding the modified polyamide acid-phosphonate copolymer, continuously stirring to obtain an electrostatic spinning precursor solution, and carrying out electrostatic spinning on the electrostatic spinning precursor solution to obtain the composite nanofiber membrane. According to the invention, the indium-containing heterocyclic modified diamine is used as a core monomer of the polyamide acid-phosphonate copolymer, the lithium deposition nucleation overpotential can be reduced by the excellent lithium-loving activity of the indium-containing heterocyclic modified diamine, the lithium is enabled to be compact and free of dendritic crystal deposition, and the indium-containing heterocyclic group is uniformly dispersed in a three-dimensional framework through a cross-linked network of the modified polyamide acid-phosphonate copolymer, so that the performance of the polymer is improved. The contact interface of the intermediate layer and the lithium metal forms a global uniform lithium-loving site, and concentrated deposition of lithium atoms caused by local lithium-loving activity difference is avoided.

The invention belongs to the technical field of nano materials and environment-friendly functional coatings, and discloses a preparation method and application of a lignin-based super-hydrophobic coating. The method comprises the steps that lignin is pretreated with ethylene carbonate to break steric hindrance and improve the grafting rate, then hexadecyl trimethoxy silane is added for grafting to form a hydrophobic chain, and surface energy is reduced; then adding silicon dioxide and N, N-dimethylformamide, carrying out ultrasonic dispersion to synergistically construct a micro-nano coarse structure, spraying the micro-nano coarse structure on a base material by using a spraying method, and putting the base material into a drying oven for curing, so as to obtain the lignin-based super-hydrophobic coating material. According to the method disclosed by the invention, a high-activity epoxy group is grafted on a lignin skeleton through ethylene carbonate pretreatment, so that steric hindrance in a three-dimensional space is broken, and dense anchor points are provided for a subsequent hydrophobic chain; then cocondensing with hexadecyl trimethoxy silane to form an alkyl-siloxane double network, and cooperating with nano silicon dioxide to construct micro-nano double roughness, so that a stable super-hydrophobic core under a fluorine-free condition is realized, and the technical route is simple and efficient.

The invention provides halogen-free flame-retardant liquid epoxy resin, solid epoxy resin for powder coating and a preparation method of the solid epoxy resin, and belongs to the technical field of powder coating. The liquid epoxy resin disclosed by the invention is prepared by polymerizing 2, 4-diamino-6-phenyl-1, 3, 5-triazine, formaldehyde, triethyl phosphite, epoxy chloropropane, sodium hydroxide, DMF (Dimethyl Formamide) and the like. The contents of halogen-free flame-retardant elements nitrogen and phosphorus in the product are high, a solid epoxy resin product obtained by carrying out chain extension on liquid epoxy resin serving as a synthetic monomer of solid epoxy resin of the powder coating and bisphenol F is good in flame retardance, the oxygen index reaches 37% or above, and the flame retardance is high. A coating film obtained after the powder coating and an accelerated dicyandiamide curing agent are subjected to low-temperature rapid curing (150 DEG C / 10 min) is high in gloss and leveling grade and good in impact resistance, hardness and the like, and the application requirements of the powder coating are met.

The invention discloses a method for synthesizing N, N-dimethylformamide through electrochemical catalytic conversion of dimethylamine. The synthesis method provided by the invention comprises the following steps: by taking dimethylamine as a single substrate, carrying out in-situ electrochemical oxidation reaction to obtain N, N-dimethylformamide; a working electrode used in the in-situ electrochemical oxidation reaction is a composite electrode loaded with a co-oxide Cr2WO6 crystal. According to the synthesis method provided by the invention, only dimethylamine is used as a substrate, and the substrate is few in variety and low in concentration, so that the raw material cost is greatly reduced, and the damage of the high-concentration substrate to a catalyst and reaction equipment is reduced; in addition, the method is high in Faraday efficiency, has important practical application value for efficient resource utilization of dimethylamine, and has far-reaching significance in the aspect of carbon neutralization at present.

The application discloses a police clothing fabric convenient for heat dissipation and a processing technology, and the processing technology comprises the following steps: after carbon fibers are pretreated by a potassium permanganate solution and a KH550 aqueous solution, the carbon fibers are added into N,N-dimethylformamide, then ethylenediaminetetraacetic dianhydride is added into the mixture under stirring, and stirring reaction is carried out; the product is extracted, washed and dried to obtain ethylenediaminetetraacetic dianhydride modified carbon fibers; the modified carbon fibers are added into deionized water, then mannitol is added, concentrated sulfuric acid is used as a catalyst, and stirring reaction is carried out; the product is centrifuged, washed and dried to obtain modified carbon fibers; the modified carbon fibers and PET chips are mixed, then melt spinning is carried out, and the police clothing fabric convenient for heat dissipation is obtained through weaving; the fabric greatly improves the moisture absorption, sweat releasing, air permeability and heat dissipation performance of the fabric, improves the breaking strength of the fabric, and is suitable for being used as a police fabric.

The application relates to a super-hydrophobic cotton fabric and a preparation method thereof. The fabric can be prepared by the following method: firstly, a pore-forming agent and polystyrene are dissolved in dimethylformamide to prepare a spinning solution; secondly, the cotton fabric is pretreated; thirdly, the spinning is performed by using an electrostatic spinning technology; and finally, the super-hydrophobic cotton fabric is prepared by washing under the assistance of ultrasonic waves. The super-hydrophobic cotton fabric prepared by the application contains the hydrophobic material polystyrene on the surface, the apparent contact angle of water drops on the surface of the cotton fabric ranges between 151 DEG and 154 DEG, the super-hydrophobic property is very good, the hydrophobic property of the cotton fabric is not obviously weakened after 10 times of washing, and this indicates that the hydrophobic material polystyrene can be firmly attached to the surface of the cotton fabric.

The invention provides a preparation method of clindamycin hydrochloride alcoholate. The preparation method comprises the following steps: firstly, preparing a chlorination reagent from an oily solvent, DMF (Dimethyl Formamide), a chlorination solvent and an antioxidant; carrying out temperature-controlled chlorination reaction with lincomycin hydrochloride to obtain a chlorination reaction solution; adjusting the pH value of the reaction solution to 10-11, controlling the temperature to react, taking an oil phase after the reaction is finished, concentrating under reduced pressure, diluting with water, and adjusting the pH value to 3-5 to obtain a column loading solution; the preparation method comprises the following steps: dissolving clindamycin hydrochloride in water, adsorbing by using resin, eluting impurities by using dilute alkaline water, analyzing by using ethanol and deionized water in sequence, collecting an analysis solution, concentrating under reduced pressure, adding ethanol, heating for dissolving, adjusting the pH value to 1-1.5, cooling for crystallizing, and drying to obtain the clindamycin hydrochloride alcoholate. According to the preparation method disclosed by the invention, the clindamycin alcoholate with high yield and high purity is prepared by pertinently designing processes such as reaction conditions, a specific oily reagent, temperature control conditions, column adsorption, dilute alkaline water impurity elution, ethanol desorption and the like, only one-time crystallization is needed, repeated refining is not needed, the HPLC (High Performance Liquid Chromatography) purity is up to 99.5% or above, and the clindamycin alcoholate is suitable for industrial production. And 0.14% or less of 2, 7-epiclindamycin.

The invention provides SMMS non-woven fabric and a preparation method thereof, and belongs to the technical field of non-woven fabric. The preparation method comprises the steps of preparing the spunbond layer, preparing the melt-blown layer and compounding. The step of preparing the spunbond layer comprises the steps of preparing reinforced filler and mixing and forming; the preparation of the reinforced filler comprises the following steps: adding maleic anhydride grafted polypropylene into N, N-dimethylformamide, uniformly stirring, adding polypropylene oxide glycol and p-toluenesulfonic acid at 62-66 DEG C, heating to 120-130 DEG C, and refluxing for 3.5-4.0 hours in a nitrogen atmosphere to obtain a modified liquid; adding nano calcium carbonate into the modified liquid, controlling the temperature to be 78-83 DEG C, and adding polyglycerol fatty acid ester to obtain enhanced filler; according to the prepared SMMS non-woven fabric, the strength of the non-woven fabric is improved, meanwhile, the air permeability is guaranteed, and the SMMS non-woven fabric is good in production stability, good in softness, good in light aging resistance and excellent in overall stability.

The invention discloses an azeotrope separation method, and belongs to the technical field of chemical engineering. The separation and purification method comprises the following steps: adding an extracting agent into an azeotrope of 1-chloro-3, 3, 3-trifluoropropene and 1, 1, 1, 3, 3-pentachloropropane, and extracting the azeotrope of 1-chloro-3, 3, 3-trifluoropropene and 1, 1, 1, 3, 3-pentachloropropane; wherein the extracting agent is selected from one or more of ethylene glycol, furfural, acetonitrile and DMF (Dimethyl Formamide). According to the separation method disclosed by the invention, the azeotropic equilibrium between the 1-chloro-3, 3, 3-trifluoropropene and the 1, 1, 1, 3, 3-pentachloropropane is destroyed by adding the efficient, cheap and easily available extraction agent, so that the effective separation of the azeotrope of the 1-chloro-3, 3, 3-trifluoropropene and the 1, 1, 1, 3, 3-pentachloropropane is realized. And introducing the separated 1-chloro-3, 3, 3-trifluoropropene and 1, 1, 1, 3, 3-pentachloropropane into a subsequent rectification system for rectification and purification, and finally obtaining two products of high-purity 1-chloro-3, 3, 3-trifluoropropene and 1, 1, 1, 3, 3-pentachloropropane.

The invention discloses a preparation method of a high-quality perovskite thick film for an X-ray detector, and relates to the technical field of radiation detection materials and devices. The preparation method of the thick film comprises the following steps: preparing a precursor solution from lead iodide, cesium iodide, formamidine iodide, methylamine iodide, 4-guanidinobenzoic acid hydrochloride, N, N-dimethylformamide and acetonitrile; a bulk phase functional additive is introduced to optimize a large number of Schottky defects at the grain boundary of the perovskite thick film; depositing onto a heated conductive glass substrate using a spray coating technique; and in combination with a low-temperature solvent atmosphere annealing process, secondary growth of crystal grains and grain boundary healing are promoted, and a large-area polycrystalline thick film can be obtained.

The invention discloses a warp-wise elastic tatting antibacterial fabric and a preparation method thereof, and belongs to the technical field of antibacterial fabric preparation. The preparation method of the warp-wise elastic tatting antibacterial fabric comprises the following steps: step 1, adding composite polyester particles into a mixed solution of N, N-dimethylformamide and acetone, heating and stirring, adding a modified antibacterial agent, and carrying out electrostatic spinning treatment, drying, hot pressing and cutting to obtain composite polyester staple fibers; 2, wool is treated to obtain pretreated wool, the pretreated wool is mixed with composite polyester staple fibers, an antistatic agent and emulsified oil are added, opening mixing, carding, drawing and roving processing are carried out, and mixed roving yarn is obtained; 3, spandex yarn serves as core yarn, the core yarn is wrapped with the pretreated wool, elastic wrap yarn is formed, the elastic wrap yarn and the mixed coarse yarn are mixed, spinning, weaving and heat setting are conducted, and the warp-wise elastic tatting antibacterial fabric is obtained. The fabric prepared by the method has excellent antibacterial property and mechanical property.

The invention belongs to the technical field of oil exploitation, and particularly relates to a clay stabilizer for an oil field as well as a preparation method and application thereof. The preparation method comprises the following steps: adding 1, 1 '-bis (4-aminophenyl)-[4, 4'-dipyridyl]-1, 1 '-ammonium dichloride, DMF (Dimethyl Formamide), triethylamine and (3-chloropropyl)-trimethyl ammonium chloride into a reactor, and carrying out a first heat preservation reaction; adding chloroalkane into the reactor, and carrying out a second heat preservation reaction; adding diacyl chloride into the reactor, and carrying out a third heat preservation reaction; and carrying out reduced pressure distillation to remove DMF to obtain a clay stabilizer crude product, adding water and ethyl acetate, fully mixing, separating out ethyl acetate, and carrying out reduced pressure distillation to obtain the clay stabilizer. The clay stabilizer has the advantages of high anti-swelling rate and washing resistance, the anti-swelling rate reaches 97% or above, and the washing anti-swelling rate reaches 93.5% or above.