818 results about "Triethylamine" patented technology

The invention relates to the field of phosphorus-nitrogen flame retardants, and discloses a preparation method and application of a novel phosphorus-containing nitrogen oxide flame retardant, the preparation method comprises the following steps: S1, under the protection of nitrogen, dissolving diphenylphosphinyl hydroxylamine and triethylamine in a tetrahydrofuran solvent to prepare a reaction substrate solution; s2, slowly dropwise adding a diphenylphosphinyl chloride solution into the solution, and then sufficiently carrying out the reaction in a staged heating and heating reflux mode; s3, cooling and filtering to remove solid byproducts generated by reaction, and concentrating filtrate to obtain a crude product solid; and S4, recrystallizing and purifying the crude product by using ethyl acetate, and finally heating and drying the obtained crystal under a vacuum condition to obtain the product. An N-O group is innovatively introduced into the molecular structure of the flame retardant, so that the effect of efficiently capturing gas-phase free radicals in cooperation with a phosphorus-containing group is achieved, and the substantive technical progress that the material can be endowed with excellent flame retardant property with extremely low addition amount is realized.

The invention discloses a wood-based composite phase-change material and a preparation method thereof, and belongs to the technical field of phase-change materials.The preparation method of the wood-based composite phase-change material comprises the following steps that wood is cut and then added into delignification liquid to be heated, the wood is taken out and washed with water, and delignified wood is obtained; the delignification wood is added into the modification liquid to be heated, and after being taken out, the delignification wood is washed and dried to obtain pretreated wood; mixing polyethylene glycol, citric acid and boric acid, heating and stirring to obtain a phase change material; dipping the pretreated wood into the phase change material for vacuum dipping, taking out and drying to obtain the phase change material. The modified liquid is prepared from an ethanol water solution, a modified filler, 2-(3, 4-cyclohexene oxide) ethyltrimethoxysilane and triethylamine. The delignification liquid and the modification liquid are adopted for pretreating the wood, so that the wood can be better firmly combined with the phase change material, leakage is prevented, and the finally prepared wood-based composite phase change material has excellent heat management capacity and stability.

The invention discloses a DA bond polymer with antibacterial and self-repairing functions for a wood surface as well as a preparation method and a use method of the DA bond polymer. Chitosan serves as a wall material, cinnamon essential oil serves as a core material, the cinnamon essential oil and chitosan antibacterial microcapsules are prepared through emulsification, crosslinking and spray drying, and essential oil controlled release is achieved. Then bisphenol A diglycidyl ether DGEBA and furfuryl alcohol FA are used as raw materials, furyl functional epoxy resin FER is prepared under the catalysis of triethylamine TEA, bismaleimide BMI is added, and a DA bond self-repairing polymer is prepared through a DA reaction; and adding 4, 4-diaminodiphenylmethane DDM into the system, reacting with redundant DGEBA to generate a cross-linked polymer network, and adding the microcapsules into a DA bond semi-interpenetrating self-repairing network solution to obtain the DA bond polymer. A thin film formed by brushing and curing wood has antibacterial and self-repairing functions, scratches and microcracks on the surface of the wood can be repaired, and microbial erosion is inhibited.

The invention relates to the technical field of organic synthesis, and particularly discloses a synthesis process of 2-chloronicotinic acid. The synthesis process of the 2-chloronicotinic acid comprises the following steps: S1, mixing water, concentrated sulfuric acid, 3-cyanopyridine and a composite catalyst, performing pre-reaction, adding hydrogen peroxide, performing oxidation reaction, adjusting pH, performing solid-liquid separation, and washing to obtain an oxide intermediate; s2, in an inert atmosphere, adding phosphorus oxychloride into a reactor, adding the oxide intermediate and triethylamine for a chlorination reaction, recovering phosphorus oxychloride after the reaction is finished, hydrolyzing remaining materials, and performing solid-liquid separation and washing to obtain chloride; and S3, carrying out alkali dissolution, neutralization, decoloration and acidification on the chloride, carrying out solid-liquid separation, washing, carrying out secondary alkali dissolution, neutralization and secondary decoloration, adding a complexing agent, carrying out secondary acidification, carrying out solid-liquid separation, washing, drying and crushing to obtain the 2-chloronicotinic acid. The 2-chloronicotinic acid prepared by the method disclosed by the invention has relatively high purity and yield.

The invention belongs to the field of separation membranes, and particularly relates to an anti-pollution and washable reverse osmosis membrane and a preparation method thereof. The reverse osmosis membrane provided by the invention is prepared according to the following steps: soaking a nascent state polyamide reverse osmosis membrane in a first treatment solution, taking out and cleaning, then soaking in a second treatment solution, taking out and draining to obtain the anti-pollution and washing-resistant reverse osmosis membrane, the nascent state polyamide reverse osmosis membrane comprises a non-woven fabric layer, a porous support layer and a polyamide separation layer which are in contact in sequence; the first treating fluid contains double-end amino polyethylene glycol and triethylamine; the second treatment liquid contains polyvinyl alcohol and alpha-aldehyde group-omega-carboxyl polyethylene glycol. Experimental results show that the reverse osmosis membrane provided by the invention has relatively high anti-pollution capacity, desalting rate and acid and alkali cleaning resistance.

The invention belongs to the technical field of textile materials, and discloses an easy-to-dye composite polyester fiber and a preparation method thereof. The preparation method comprises the following steps: by taking polyethylene glycol terephthalate as a core layer and low-melting-point polyester as a skin layer, carrying out melt spinning to prepare skin-core composite fibers; after heating and melting a skin layer, bombarding by using a titanium dioxide nano particle flow to obtain roughened fibers; after plasma treatment, dipping with an activating solution of triethylamine and 4-methylbenzenesulfonyl chloride to obtain activated fibers; carrying out ultrasonic reaction on the activated fiber and a modifier under the catalysis of tetrabutyl titanate, and washing and drying to obtain the easy-to-dye composite polyester fiber. The prepared composite polyester fiber not only has the advantage of being easy to dye, but also has excellent antibacterial performance and flame retardant performance, and the quality of the composite polyester fiber is effectively guaranteed.

The invention belongs to the field of flame retardance of high polymer materials, and relates to a preparation method of a metal organic framework polyphosphazene flame retardant and application of the flame retardant in PET flame retardant modification.The preparation method comprises the steps that a metal salt solution and a phytic acid solution are mixed according to the molar ratio of (3-15): 1, the pH is adjusted to 7-8, alcohol is added for a reaction, and phytic acid-based MOFs are obtained; mixing the phytic acid-based MOFs with a 4, 4 '-disubstituted diphenyl compound, triethylamine and alcohol to obtain a second mixed solution; hexachlorocyclotriphosphazene (HCCP) is mixed with the second mixed solution, the molar ratio of the 4, 4 '-disubstituted diphenyl compound to the HCCP is (2-4): 1, the mixture reacts at the temperature of 20-90 DEG C, and the phytic acid group MOFs (at) HCCP is obtained. HCCP is hybridized on the surface of phytic acid-based MOFs, and the flame retardant has excellent flame retardance and environmental protection performance by utilizing the char-forming catalytic capability of the phytic acid-based MOFs and the phosphorus-nitrogen flame retardance characteristic of HCCP.

The invention relates to the technical field of chemical synthesis, and discloses a preparation method of anhydrous N, N-dimethyl amino sulfuryl fluoride, which comprises the following steps: (1) introducing sulfuryl fluoride gas into a dimethylamine organic solution to carry out nucleophilic substitution reaction, and then adding triethylamine to obtain a mixed solution containing N, N-dimethyl amino sulfuryl fluoride; and (2) sequentially carrying out normal-pressure rectification and reduced-pressure rectification on the mixed solution containing the N, N-dimethyl amino sulfonyl fluoride to obtain the N, N-dimethyl amino sulfonyl fluoride. According to the method, water is not introduced in the whole process, the risk of water residue is avoided, and the prepared product is high in yield and purity.

The invention provides a silicon-phosphorus-containing macromolecular flame retardant, flame-retardant low-dielectric polycarbonate containing the flame retardant and a preparation method of the flame-retardant low-dielectric polycarbonate. The preparation method comprises the following steps: mixing and dissolving dichloromethane, triethylamine, bisphenol containing an R structure and bis (aminopropyl)-terminated siloxane to prepare a solution A; dissolving isophthaloyl dichloride and / or paraphthaloyl dichloride and phenylphosphoryl dichloride in dichloromethane to prepare a solution B; dropwise adding the solution B into the solution A, stirring and reacting, and then carrying out end capping treatment to obtain the silicon-phosphorus-containing macromolecular flame retardant. The flame-retardant low-dielectric polycarbonate containing the flame retardant has the advantages of high flame retardance, low dielectric constant and low loss, can meet the flame-retardant requirement of UL 94V-0 level under the condition that the thickness is 0.8-3.2 mm, and belongs to a halogen-free flame-retardant environment-friendly high polymer material.

The invention discloses heat-resistant polymethyl methacrylate, a preparation method thereof and an optical film. The heat-resistant polymethyl methacrylate comprises a methyl methacrylate repetitive unit, a glutarimide repetitive unit and an N-methyl methacrylamide repetitive unit, and the sum of the number of the glutarimide constitutional unit and the number of the N-methyl methacrylamide constitutional unit is 1-20 mol% of the total number of the constitutional units. The glutarimide structural unit can be obtained by further cyclization reaction of an N-methyl methacrylamide structural unit, and the cyclization rate can be increased to 80-90% by adding a cyclization accelerator such as triethylamine, so that the thermal stability of the resin is improved, and the water absorption rate is reduced. The material can be used for preparing an optical film, has excellent heat resistance and moisture resistance, and is suitable for the field of optical display.

The invention relates to a preparation technology of a multifunctional plastic clothes hanger through cooperation of degradable color master batches and nitrogen filling injection molding, and belongs to the technical field of plastic products. Adding the polylactic acid, the styrene-acrylonitrile copolymer, the modified stone powder, the degradable color master batch and the compound additive into a horizontal helical ribbon mixer, stirring and drying to obtain a mixture; the dried mixture is added into an injection molding machine to be melted and plasticized, a screw pushes melt to be injected into a mold, high-pressure nitrogen is injected into the melt, and the melt is pushed to completely fill a cavity; the plastic clothes hanger is obtained through pressure maintaining, cooling and demolding; the compound additive is prepared from allyl alcohol polyoxyethylene ether, 2-octenyl succinic anhydride, 14-mercaptotetradecanoic acid, anhydrous tetrahydrofuran, 2-hydroxy-4 '-(2-hydroxyethoxy)-2-methyl propiophenone and triethylamine. The preparation method comprises the following steps: preparing the compound additive; the degradable material is adopted, the biodegradation rate is high, the mechanical property is stable, the coloring effect is good, fading is not prone to occurring, and the service life is long.

The invention belongs to the technical field of synthetic leather, and particularly discloses breathable stripping-resistant water-based / solvent-free polyurethane synthetic leather and a preparation method thereof.The synthetic leather comprises base cloth, a solvent-free polyurethane layer and a water-based polyurethane surface layer, and the solvent-free polyurethane layer and the water-based polyurethane surface layer are sequentially arranged on the base cloth; modifying and activating the base cloth by a wide plasma cleaning machine; the solvent-free polyurethane layer slurry is prepared from a carbon dioxide-based polyether type A material prepolymer, a polyether type B material prepolymer, color paste, a dispersing agent, isocyanate modified aerogel and nano filler; the waterborne polyurethane surface layer slurry is prepared from epoxy resin modified carboxylic acid type waterborne polyurethane emulsion neutralized by triethylamine, epoxy modified aerogel, waterborne color paste, a defoaming agent and a thickening agent. The modified aerogel is introduced into the solvent-free polyurethane layer and the waterborne polyurethane surface layer, and oxygen plasma pretreatment activation on the base cloth is cooperated, so that the obtained waterborne / solvent-free polyurethane synthetic leather has an excellent breathable function and high peel strength, and has a wide market prospect.

The invention relates to the technical field of light building boards, in particular to a heat preservation and insulation polyurethane sandwich building board and a preparation method thereof. The method comprises the following steps: polishing, washing and drying the inner surface of an aluminum plate to obtain a pretreated aluminum plate; the two pretreated aluminum plates are fixed in parallel, and the peripheries are sealed to form a pouring cavity; the preparation method comprises the following steps: mixing polyether polyol, a hydroxylated flame retardant, flame-retardant polyol, a surfactant, triethylamine, triethylene diamine, dibutyltin dilaurate and deionized water, uniformly stirring, then adding polyisocyanate, and uniformly stirring again to obtain a polyurethane foaming mixture; and pouring the polyurethane foaming mixed material into the cavity, and curing to obtain the polyurethane sandwich building board. The polyurethane sandwich building board prepared by the invention has excellent thermal insulation property and flame retardance, so that the polyurethane sandwich building board has a wide application prospect in the technical field of light building boards.

The invention relates to the field of separation and purification, in particular to an anti-pollution nanofiltration membrane for magnesium-lithium separation, the anti-pollution nanofiltration membrane comprises a base membrane and a functional layer, and the functional layer is prepared from the following raw materials in parts by weight: a water phase: 1.5-2.5 parts of piperazine, 0.1-1 part of lauryl sodium sulfate, 0.5-2 parts of glycerol, 1-2 parts of triethylamine, 0.6-2 parts of ionic polymer, and the balance of water for supplementing the total amount of the water phase to 100 parts; the ionic polymer comprises at least one of sulfobetaine metacrylic acid ester, sulfobetaine and carboxyl betaine metacrylic acid ester; and an oil phase: 0.1-1 part of trimesoyl chloride, and the total amount of the oil phase is supplemented to 100 parts by normal hexane or isoparaffin. The ionic polymer is added, and a compact hydration layer is formed on the surface of the membrane by using a betaine group of the ionic polymer, so that the membrane pollution probability is reduced, and common inorganic scaling and organic pollution in the high-salt brine are remarkably inhibited; in addition, the ionic polymer enables the membrane surface to have strong negative electricity, and the magnesium ion rejection rate is improved; and the ionic polymer can also reduce the lithium ion transmission energy barrier and reduce the rejection rate.

The invention discloses a preparation method of bis (trifluoromethylsulfonyl) imide salt, and belongs to the technical field of metal ion battery electrolyte materials, and the preparation method comprises the following steps: mixing trifluoromethylsulfonyl fluoride and organic amine alkali to obtain a mixed solution A; dropwise adding the mixed solution A into a reaction kettle filled with ammonia gas, and completely reacting to generate bis (trifluoromethanesulfonyl) imide quaternary ammonium salt; carrying out reduced pressure distillation on the reaction product to obtain pure bis (trifluoromethanesulfonyl) imide quaternary ammonium salt; the preparation method comprises the following steps: mixing bis (trifluoromethylsulfonyl) imide triethylamine salt and metal salt according to a molar ratio of 1: (1-3), and completely reacting in an organic solvent to generate bis (trifluoromethylsulfonyl) imide salt; and filtering the reaction liquid, and carrying out reduced pressure distillation to obtain the final product bis (trifluoromethylsulfonyl) imide salt. The preparation method provided by the invention has the characteristics of simple process, high yield and high product purity, and solves the problems of complex process, low yield, low product purity and the like in the existing preparation method.

The invention belongs to the technical field of new materials and electronic information, and particularly relates to a transition metal doped ZnIn2S4 gas sensor as well as a preparation method and application thereof. The gas sensor comprises a substrate and a transition metal doped ZnIn2S4 nano array growing on the surface of the substrate in situ, the nano array is composed of a plurality of two-dimensional nano sheet layers, the two-dimensional nano sheet layers are arranged in a staggered stacking mode and extend at an included angle of + / -5 degrees relative to the normal direction of the surface of the substrate, and the transition metal doped ZnIn2S4 nano array is arranged on the surface of the substrate. And a network assembly with a three-dimensional flower-shaped topological structure is formed through physical or chemical connection. The preparation method is simple, the energy band structure of the material is effectively regulated and controlled, the forbidden band width is reduced, on the other hand, the specific surface area of the material is remarkably increased, and the pore size distribution is optimized. And the prepared gas sensor shows excellent gas selectivity to triethylamine, is high in response value and high in recovery speed, and is expected to be applied to the fields of environmental monitoring and food safety.

The invention discloses a 96-hole preassembled plate fat-soluble vitamin pretreatment kit, and belongs to the technical field of in-vitro diagnostic reagents. Comprising magnetic bead suspension liquid, equilibrium liquid, leacheate 1, leacheate 2 and eluent which are carried on a preassembled plate, and the magnetic bead suspension liquid comprises absolute ethyl alcohol and magnetic beads; the preparation process of the magnetic beads comprises the following steps: activating carboxyl of the carboxyl magnetic beads through EDC and NHS; then nitrochlorobenzene and triethylamine are added for a coupling reaction; mixing the coupling reaction product with pyrrolidone, ammonium persulfate and a pore-foaming agent to obtain target magnetic beads; the magnetic beads can be specifically combined with fat-soluble vitamins in human serum or plasma, efficient separation and release of an object to be detected are achieved through a magnetic separation technology, and the magnetic beads are suitable for follow-up mass spectrum quantitative analysis. The kit disclosed by the invention has the characteristics of simplicity and convenience in operation, high extraction efficiency and good stability, the pretreatment time can be remarkably shortened, the detection accuracy is improved, and an efficient solution is provided for clinical detection of fat-soluble vitamins.

The invention discloses a preparation process of coating slurry for a lithium ion battery diaphragm. Comprising the following steps: step 1, uniformly mixing polyether polyol, a modified additive, dibutyltin dilaurate, dimethylolpropionic acid and isophorone diisocyanate, under a protective atmosphere, raising the temperature to 80-90 DEG C, reacting for 3-4 hours, then adding 1, 4-butanediol, continuously reacting for 3-4 hours, after the reaction is finished, cooling to 40-50 DEG C, then adding triethylamine, stirring for 30-40 minutes, and then, carrying out heat preservation for 30-40 minutes, so as to obtain a polyurethane prepolymer; slowly adding deionized water to obtain a polyurethane adhesive; 2, inorganic particles, a polyurethane adhesive and a dispersing agent are mixed and stirred at the normal temperature for 10-12 h, and the coating slurry is obtained. The flame-retardant battery diaphragm has the beneficial effects that the flame-retardant unit and the modified additive of the quaternary ammonium salt group are introduced into a polyurethane adhesive system, so that the prepared battery diaphragm has excellent flame retardance, enhanced mechanical property and good electrolyte wettability.

The invention relates to a polyimide composite film for realizing high-dispersion carbon nanotubes through chemical anchoring and a preparation method of the polyimide composite film, which are used for solving the problems that carbon nanotubes in the existing carbon nanotube / polyimide composite material are easy to agglomerate, poor in interfacial compatibility and low in grafting efficiency. The preparation method comprises the following steps: S1, ultrasonically dispersing aminated carbon nanotubes in anhydrous dimethylacetamide to obtain a stable dispersion liquid; s2, slowly dropwise adding pyromellitic dianhydride into the stable dispersion liquid under an ice bath condition, and enabling the pyromellitic dianhydride to react with the aminated carbon nanotubes under the assistance of triethylamine to form anchor points; s3, adding a diamine monomer 4, 4 '-diaminodiphenyl ether, and gradually adding the residual pyromellitic dianhydride to carry out in-situ polymerization; and S4, preparing a wet film by adopting a curtain coating or spin coating method, and carrying out step-by-step thermal imidization at 80-300 DEG C to obtain the covalent composite film. Controllable covalent connection of the carbon nanotubes and pure polyimide chain segments can be achieved on the molecular level, and therefore the composite film with excellent heat conductivity, electromagnetic shielding performance and mechanical performance is obtained.

The application relates to the field of graphene preparation, and particularly provides a method for preparing reduced graphene oxide (rGO) by visible light in an aqueous solution, which uses an LED lamp simulating the visible light section of sunlight as a light source under normal temperature and pressure, and reduces industrial-grade graphene oxide (GO) to prepare rGO in a homogeneous aqueous solution system in the presence of an organic dye molecule eosin Y (water-soluble) as a photosensitizer and triethylamine as an electron sacrificial agent. The method overcomes the shortcomings of a low yield, the need for a strong reducing agent and high pollution in a traditional preparation process, and has the advantages of simple process, easy separation, high yield, low energy consumption, low cost and no pollution, and the prepared rGO has a smooth structure, a thin thickness and a perfect graphitization degree.

This invention relates to the field of polymer materials, and specifically discloses a waterborne polyurethane, its neutralization preparation method, and its applications. This waterborne polyurethane is prepared by mixing the following raw materials in parts by weight: 10-30 parts by weight of a polyurethane prepolymer containing carboxyl functional groups, 5-25 parts by weight of a polyurethane prepolymer containing amino functional groups, 0.6-2.0 parts by weight of an organic amine chain extender, and 50-80 parts by weight of deionized water; wherein the polyurethane solid content accounts for 20-50% of the total weight of the raw materials. The preparation process of this invention is simple, the product is stable during storage, and it does not contain volatile or migrating amine neutralizing agents such as triethylamine or dimethylethanolamine, thus meeting the stringent regulatory requirements for applications such as food contact materials.

The invention belongs to the technical field of polymer materials, and particularly relates to a conductive polymer material as well as a preparation method and application thereof. The conductive polymer material is prepared from the following components in parts by weight: 0.1 to 5 parts of ionic liquid, 0.1 to 10 parts of filler and 1 to 100 parts of polymer, the ionic liquid comprises at least one of organic salt and metal salt; the organic salt comprises at least one of p-toluenesulfonic acid triethylamine salt, p-toluenesulfonic acid tripropylamine salt, trifluoromethanesulfonic acid triethylamine salt and trifluoromethanesulfonic acid tripropylamine salt; the metal salt comprises at least one of potassium trifluoromethanesulfonate and sodium trifluoromethanesulfonate. The conductive polymer material prepared by the invention has the advantages of excellent conductivity, high transparency, good water resistance, good mechanical properties, good environmental stability, strong thermal stability and strong self-repairing ability.

The invention discloses a polyolefin graft modification method based on coating and photochemical reaction, which comprises the following steps: step 1, raw material preparation: mixing 20-50 parts by weight of glycidyl methacrylate (GMA), 1-5 parts by weight of benzophenone (BP) and 1-2 parts by weight of triethylamine (TEA), and uniformly stirring to obtain a mixed solution; 2, coating: coating the surface of a polyolefin film with the mixed solution obtained in the step 1, wherein the coating weight is 1g / m < 2 >-3g / m < 2 >; the method has the beneficial effects that a peroxide initiator is not needed, the reaction is initiated by ultraviolet light, the reaction condition is mild, polyolefin degradation and side reaction are reduced, and the grafting rate is greater than 3.5%; ethyl acetate and other low-toxicity solvents are adopted, residual solvents can be removed through oven treatment, and the environment-friendly requirement is met; active groups such as an epoxy group are introduced into a grafted product, so that the compatibility with a polar material is remarkably improved, and the breaking strength is improved by more than 50% compared with that of common PP; the polyolefine can be used as an interface compatibilizer, a macromolecular coupling agent and the like, and the application of the polyolefine in the high-end field is expanded.

The invention provides a purification method of a naphthalimide high-purity electronic-grade photoacid generator. The method solves the problem that photo-acid cannot be purified by traditional recrystallization or directly through ion exchange columns and other methods. The method comprises the following steps: firstly synthesizing and preparing 1, 3-diketone-2-hydroxy-6-(1-hexyne) benzisoquinoline, then reacting with triethylamine and trifluoromethylsulfonyl chloride to generate a crude product 1, 3-diketone-2-(1, 1, 1-trifluoromethyl) methanesulfonic ester-6-(1-hexyne) benzisoquinoline, removing impurities from normal hexane to obtain a pure product, sublimating the material into a gas phase by using a quartz vacuum sublimation instrument, and purifying to obtain the 1, 3-diketone-2-(1, 1, 1-trifluoromethyl) methanesulfonic ester-6-(1-hexyne) benzisoquinoline. And then passing through Pure MTS9500 amino phosphonic acid type chelating resin, and finally cooling in a quartz tube to obtain the high-purity electronic-grade photoacid generator. According to the invention, the stability is high, the metal ion content is low, the purification process is convenient to process, the product is used as a photoresist-level core main material, the product is widely applied in the fields of semiconductor photoresist, other imaging systems, photocureable coatings and the like, the market scale is continuously expanded, and the product is an indispensable key material in semiconductor manufacturing and other related fields.

The present application relates to photosensitive polyimide oligomer, preparation method and polyimide photosensitive resin composition prepared by the same, the present application provides the molecular formula of photosensitive polyimide oligomer, which is prepared from 1, 4, 5, 8-naphthalene tetracarboxylic anhydride, N, N-dimethylacetamide, triethylamine, tetramethyl benzene dimethyl diisocyanate, hydroquinone methyl ether, dibutyl tin dilaurate and hydroxyethyl acrylate according to the molar ratio of 2.5:10-15:1.2-1.6:3.0:0.0035-0.0045:0.007-0.01:2-2.5.The good solubility group is introduced into the molecular structure, so that it has good solubility in active diluent, and the polyimide oligomer can be photocured reaction;The device printed by the polyimide photosensitive resin composition prepared by the same has small shrinkage, high precision, and has the excellent performance of photosensitive polyimide oligomer, and has certain toughness and excellent weather resistance.

The invention discloses a method for preparing an aromatic phosphate salt nucleating agent by using nanoscale aluminum chloride, and belongs to the technical field of polymer nucleating agents. 2, 2-methylene-bis (4, 6-di-tert-butylphenol) and phosphorus oxychloride are used as raw materials, the nanoscale aluminum chloride with the particle size of 20-50nm is selected as an inorganic Lewis acid catalyst and acid binding agent, and the aromatic phosphate salt nucleating agent is prepared by using a one-step method. The preparation method comprises the following steps: replacing the traditional organic acid-binding agents such as triethylamine and pyridine, and synthesizing bis [2, 2 '-methylene bis (4, 6-di-tert-butylphenoxy) phosphate] hydroxyl sodium salt by a one-pot method of condensation, hydrolysis for salt removal and neutralization for salt formation; the purity of the product can reach 99% or above through one-time suction filtration, multiple times of washing are not needed, salt-containing wastewater can be recycled as industrial water after being neutralized, and the environmental protection pressure is greatly reduced; the nucleating agent is suitable for modification processing of polymers such as polypropylene (PP), polyethylene glycol terephthalate (PET), polybutylene terephthalate (PBT), polyamide (PA) and the like, and especially meets the strict requirements on the purity and environmental protection property of the nucleating agent in an olefin polymerization process.

The application belongs to the technical field of soft capsules, and discloses a starch-based soft capsule material and a preparation method thereof. The preparation method comprises the following steps: mixing wheat starch and deionized water, adding a sodium periodate solution to react, so as to obtain dialdehyde starch; reacting the dialdehyde starch with glycidyl methacrylate and triethylamine, so as to obtain grafted modified starch; mixing the grafted modified starch with modified nano-silicon dioxide, and reacting after ultrasonic oscillation, so as to obtain nano-silicon dioxide composite modified starch; mixing the composite modified starch with polyvinyl alcohol and polyvinylpyrrolidone, so as to obtain a film forming solution; and after the film forming solution is cast and dried, hot pressing is performed, so that the starch-based soft capsule material is finally obtained. The starch is subjected to multiple hydrophobic modifications, so that the hydrophilic performance is reduced, and the stability of the soft capsule is improved.

Disclosed is a method for preparing oxetan-2-ylmethanamine, which belongs to the field of organic synthesis. [2-(1-ethoxyethoxy)methyl]propylene oxide is used as an initial raw material, and reacted in the presence of potassium tert-butoxide and trimethylsulfoxonium iodide; the resulting product is reacted with a sulfonyl compound and triethylamine; the resulting product is reacted with a compound of phthalimide; the resulting product is reacted with an amino group-containing compound, to obtain oxetan-2-ylmethanamine. The method according to the disclosure allows for an overall yield of not less than 30% in scale-up production (kilogram level), which is higher. Moreover, compared with the traditional method for preparing oxetan-2-ylmethanamine, a palladium-carbon catalytic hydrogenation step is not required, and dangerous chemical-sodium azide is not required in the method according to the disclosure. Thus, the method has high safety, low production cost, simple operations, and thereby is suitable for industrial production.

The present application relates to a kind of based on Pickering emulsion method preparation heat-conducting filler-polyimide core-shell microspheres method, the method includes the following steps: aromatic diamine monomer is added with aromatic dianhydride monomer and organic polar solvent into reaction vessel and is reacted;Deposition in water, crush, wash and dry, to obtain polyamide acid salt precursor powder;Then with triethylamine and water stirring reaction, to obtain aqueous phase;Heat-conducting filler and hydrophobic polymer are dispersed in solvent to obtain oil phase;Oil phase and aqueous phase are mixed and emulsified, to obtain water-in-oil Pickering emulsion;Demulsification in precipitator, dry, to obtain heat-conducting filler-polyimide core-shell structure microspheres.The present application also provides the heat-conducting filler-polyimide core-shell microspheres prepared by the method, the method for preparing polyimide-based heat-conducting composite material using the core-shell microspheres and the composite material obtained therefrom.The present application method can efficiently prepare three-dimensional heat-conducting composite material with high thermal conductivity in horizontal and vertical directions.

The application relates to a method for enhancing electrochemiluminescence signals by ion-pi interaction, belonging to the fields of electrochemiluminescence and analytical chemistry. 2+ By modifying the working electrode with a conjugated pi system, cation-pi interaction is introduced into the Ru(bpy)3 / triethylamine (TEA) system, efficient enrichment of TEA protonated cations near the electrode is realized, thereby greatly enhancing the electrochemical reaction rate and ECL signal. Further, anion-pi interaction is utilized to realize ECL signal enhancement of the luminol ECL system. In addition, the conjugated pi system is exposed to the outermost boundary of the electrode, so as to provide effective ion-pi interaction for ECL; when the pi system is covered by an alkyl chain, the modified electrode can only exhibit hydrophobic interaction. The method disclosed by the application provides a new strategy for extending ion-pi interaction to all types of ECL systems and constructing a high-sensitivity ECL analysis platform.