593results about How to "Reduce secondary pollution" patented technology

The invention discloses a supercritical water oxidation treatment system for printing and dyeing wastewater and sludge. The system comprises a concentration pretreatment device, a supercritical water oxidation device, an oxidizing agent supply device and a wastewater recycling system, wherein the concentration pretreatment device comprises a waste liquid storage tank, a nanofiltration membrane concentration module and a printing and dyeing sludge storage pool, the oxidizing agent supply device comprises a liquid oxygen storage tank, a liquid oxygen gasifier and a buffer tank, and the supercritical water oxidization device comprises an auxiliary heating supercritical water oxidization reactor, a methyl alcohol starting preheater, a methyl alcohol preheater and a waste liquid preheater. The system can be used for realizing efficient, clean and harmless treatment of high-concentration printing and dyeing wastewater and sludge at low cost.

The invention discloses a device and a method for producing cardboard paper by utilizing paper mill sludge and waste paper. According to the invention, impurity removal, sterilization, deodorization and the like are carried out on the paper mill sludge so that the paper mill sludge becomes paper pulp capable of being used for paper making, and then the paper pulp is combined with sizing agent prepared from the waste paper to produce the cardboard paper. According to the device and the method, the utilization value of the paper mill sludge is improved, and secondary pollution of paper making sludge to the environment is avoided; and simultaneously, the problem of timber resource shortage is solved, and the production cost of producing the cardboard paper is further reduced.

The invention provides a beta-cyclodextrin functionalized Fe3O4 magnetic nanometer adsorbent. The beta-cyclodextrin functionalized Fe3O4 magnetic nanometer adsorbent is prepared through a lay-by-lay assembling method. The beta-cyclodextrin functionalized Fe3O4 magnetic nanometer adsorbent has good stability, good dissolvability and strong adsorption capability. The beta-cyclodextrin functionalized Fe3O4 magnetic nanometer adsorbent has strong effects of adsorbing azo dyes such as methylene blue, methylene red and the like in waste water. The invention also provides a method for removing methylene blue in waste water. The method comprises the following steps of putting the beta-cyclodextrin functionalized Fe3O4 magnetic nanometer adsorbent into an aqueous solution containing methylene blue, adjusting a pH value of the reaction system to a pH value of 7 to 8, carrying out ultrasonic dispersion for 0.5 to 1 hour, carrying out oscillation for 8 to 10 hours, and separating out precipitates by a permanent magnet. The method for removing methylene blue in waste water has the advantages of good adsorption effects, mild reaction, simple processes, simplification of solid-liquid separation, less secondary pollution and good feasibility for large-scale application.

The invention discloses a city management intelligent streetlamp which comprises a streetlamp body arranged on a municipal road. A core controller is arranged in a lamp post of the streetlamp body. The core controller is connected with an illumination system, a water supply pipeline, an environment monitoring system and a communication system. The illumination system comprises a city streetlamp and a streetlamp controller. The streetlamp controller is in controlled connection through the core controller. The communication system comprises a wireless GPRS gateway module, a WiFi router and a ZigBee wireless unvarnished transmission module. The communication system is connected to a cloud service platform. The cloud service platform is connected with a government public information platform. A public information display is installed on the streetlamp body. The core controller is connected to a public security video monitoring system, a sky net monitoring system and a well lid monitoring managing system. By means of the city management intelligent streetlamp, the air humidity and temperature can be adjusted to a certain degree, the PM2.5 value in the air is reduced, the public information display is further arranged and can play government public information in real time, and due to the arranged public security video monitoring system and the interconnected sky net monitoring system and well lid monitoring managing system, good security work can be done.

The invention discloses a rain and flood utilization system, which integrates project measures and ecological environment, is widely applied to the technical field of rain water utilization and particularly relates to the rain and flood utilization system in building zones. The whole process of the rain and flood utilization system is completed through rain water converging, safe diversion, abandoned flow control, filtration, storage, water quality keeping, purifying treatment and comprehensive utilization. The system has a security function of automatic alarm, avoids blockage and siltation, ensures smooth filtration, reduces potential safety hazard, realizes quaternity integrated recycle treatment, namely sterilization, activation, filtration and oxygenation, of stored water, further guarantees the water quality, prevents secondary pollution of an impounding reservoir, reduces load of water quality treatment and saves investment and operation cost.

The invention discloses an intelligent automatic tea making machine device, which is composed of an intelligent control chip, a control panel, a tea pushing mechanism, a tea making mechanism and a tea pouring mechanism arranged under the tea pushing mechanism. The intelligent control chip includes: central processing unit CPU: includes a tea-making data storage module for pre-storing different tea-making water temperature, tea-making water volume, and tea-making time; tea type identification system: used to realize the identification of tea types Identify and feed back the signal to the system central processing unit CPU to select the corresponding brewing method. The present invention is an intelligent full-automatic tea infuser with fast tea production speed, low energy consumption, convenient operation, safety and reliability, capable of intelligently identifying various teas, and intelligently adjusting corresponding tea making processes for different teas. All processes are intelligentized to realize automatic tea bag loading, automatic water boiling, automatic tea making, automatic overturning of brewed tea, and automatic addition of new tea bags. Small size, low energy consumption, suitable for various public places, entertainment places, enterprises and institutions, etc.

The invention discloses a desulfurized wastewater treatment process. Firstly, NaOH or lime milk is added into the acidic desulfurized wastewater so as to adjust the pH value to be 8 to 9; then, the desulfurized wastewater is pumped into an electric flocculation treatment device by a pumpp, effluent after electric flocculation treatment enters an inclined pipe settling tank so as to be further treated, and then the treated wastewater reaching the standard is discharged or reused. The scruff discharged by the electric flocculation treatment device and the settled sludge discharged by the inclined pipe settling tank enter a sludge thickening tank so as to be further concentrated; the concentrated sludge is pumped into a sludge dewatering machine so as to be dried; and the dried sludge is shipped out for disposal, and the supernatant in the thickening tank and the filter-press fluid in the dewatering machine flow back to a regulating reservoir. The treatment process is characterized by simple flow and good treatment effect.

The invention provides a method for preparing magnetic cellulose aerogel from wastepaper, and relates to an aerogel preparation method. The invention aims at providing a method for preparing regenerated magnetic cellulose aerogel from the wastepaper. According to the method, the wastepaper material in life is used as a raw material for preparing a green, ultralight and highly porous aerogel oil absorbing material. The method comprises the following steps: step one. preparing regenerated cellulose from wastepaper; step two. preparing regenerated cellulose aerogel; step three. carrying out hydrophobic modification on the regenerated cellulose aerogel; and step four. preparing the regenerated magnetic cellulose aerogel oil absorbing material. The method has the advantages that the magnetic cellulose aerogel oil absorbing material is prepared from the wastepaper in life, the material can be greatly saved, the waste is turned into wealth, the regenerated magnetic cellulose aerogel is simple in a preparation technology, low in cost, convenient to use, capable of effectively absorbing multiple organic solvents and oil matters leaked in water, and high in absorption rate, the oil absorption is thorough, the oil absorbing material is nontoxic and harmless and causes very little secondary pollution, and an adopted magnetic collection method is simple, convenient and easy to use.

The invention provides a device and method for preparing an activated carbon material for an electrochemical capacitor, belonging to the technical fields of coal chemical industry and microwave chemistry. The method comprises the following preparation processes of: deashing coal particles serving as raw materials by using hydrochloric acid and hydrofluoric acid, modifying the deashed coal by using nitric acid in an auxiliary way, mixing the modified coal serving as a carbon source with potassium hydroxide and deionized water, stirring to obtain a mixture, stirring and evaporating the mixture to obtain a solid mixture, and then performing microwave-assisted activating, washing, drying and grinding on the solid mixture to obtain the activated carbon. The invention has the advantages that the activation time is only 20-30 minutes, the mass ratio of potassium hydroxide to coal is (0.5-3):1, the preparation process is simple, the microwave-assisted heating is uniform, efficient and energy-saving, the consumption of the potassium hydroxide is reduced, and the activation process has the advantages of uniformity and high efficiency. The prepared activated carbon is used as an electrode material of the electrochemical capacitor and has better stability and excellent comprehensive property.

The invention discloses a synchronous grouting material used for a tunnel and a preparation method thereof. The grouting material is the grout which is prepared by taking sediment grout as a main raw material, wherein the sediment grout comprises 30 to 65 percent of clay and fine sand totally and the weight ratio of soil to sand in the sediment grout is 0.1-0.18:1; and adding 80 to 120 kg of cement, 300 to 450 kg of coal ash, 200 to 500 kg of water or mud water and 3 to 10 kg of sodium carboxymethyl cellulose into per cubic meter of the sediment grout, wherein the grout density is between 1.85 and 2.05 g/cm<3> and the grout consistency is between 10.5 and 12 cm. In the preparation method, sediment and the mud water generated in a construction process are adopted as grouting materials, so that the sediment and the mud water can be changed into treasure from waste; and therefore, the preparation method has the characteristics of great reduction of the dosage of high-energy consumption cement, capability of working inside and outside tunnels, and convenient construction.

The invention discloses an organic contaminated site reinforced repair system which comprises an extraction system, a medicament injection system, a heating system and a blocking repair layer. According to the organic contaminated site reinforced repair system, the in-situ thermal desorption technology and the chemical oxidization technology are combined, meanwhile, a repair material layer is added, the repair material layer is prepared from slow release oxidization materials and mainly prepared from persulfate, natural clay materials, nonmetallic mineral, cement and the like, and sulfate radical produced after persulphate reaction can be fixed. By means of the repair system, on one hand, the organic contaminated site in-situ thermal desorption repair cost can be reduced; on the other hand, the in-situ chemical oxidation repair efficiency can be improved, secondary pollution can be reduced, accordingly, the repair cost is reduced, and the repair efficiency is improved.

The invention relates to an intelligent dredging vehicle for municipal sewer pipelines, comprising: a pipeline robot for breaking up and cleaning the dirt in municipal pipelines, a power line group for providing energy and control cables for the robot system, and a control The coiled and telescopic hose reel of the power group, the sewage suction device for sucking the dispersed dirt in the pipeline, the solid-liquid separation device for solid-liquid separation of the dirt sucked by the sewage suction device, and the separated waste water Sewage recycling device for recycling. The desilting and dredging vehicle described in the present invention can adapt to a variety of silting situations. The pipeline robot is used to scatter and mill the silt and scrape it into the inspection well. The vacuum suction system is organically combined with the solid-liquid separation system to realize continuous work and on-site silt separation. Effectively improve the construction efficiency.

A washing method of automatic washer includes controlling water inlet valve to let washer flow water in continuously; checking whether water level in washer is reached on water overflow level or not and starting up timing if water overflow level is reached as well as closing water inlet valve when timing is on preset time; enabling to drain out oil stain in clothes, washing powder foam, detergent foam and floated ¿C dirt from overflow outlet before water is discharged when washing procedure is finished in order to raise cleaning ration.

The invention provides antibacterial and moldproof polymer modified spray asphalt waterproof paint and an application method thereof. The paint is composed of a component A and a component B. The component A is prepared from, by weight, 90-120 parts of anionic emulsified asphalt, 40-90 parts of polymer emulsion, 0.5-5 parts of a thickening agent and 10-60 parts of filler. The component B is prepared from, by weight, 100 parts of water, 5-15 parts of a curing agent and 0.5-5 parts of an antibacterial agent. The invention further provides the application method of the antibacterial and moldproof polymer modified spray asphalt waterproof paint. The antibacterial and moldproof polymer modified spray asphalt waterproof paint has high ductility, high resilience and high adhering strength, is antibacterial and moldproof, excellent in low-temperature performance and high in construction speed and can be closely connected with a basic layer, and influences of deformation of the basic layer on the waterproof performance of a material can be effectively resisted; meanwhile, the situation that bacteria are bred on the surface of a coating film, and the coating function of a waterproof layer is damaged can be effectively prevented, and the possibility that an antibacterial agent has secondary pollution on water is reduced.

The invention relates to a mechanical arm which is used for transporting silicon chips. The invention is characterized in that the mechanical arm comprises a horizontal driving mechanism, a vertical driving mechanism, a rotationally driving mechanism and a frame which is used for installing the three driving mechanisms, wherein the horizontal driving mechanism comprises a horizontal driving motor connected with a bracket which can horizontally move along two horizontal feeding rods through a first transmission device; the vertical driving mechanism comprises a vertical driving motor which is connected to the bracket, and the vertical driving motor is connected with a lifting frame which moves along two vertical feeding rods from top to bottom through a second transmission device; and the rotationally driving mechanism comprises a rotationally driving motor which is connected to the lifting frame and is connected with a main arm through a third transmission device, the top of the main arm perforates through the top of the bracket and is connected with a paw, the upper surface of the paw is provided with a sucking disk, and a vacuum air channel which is communicated with the sucking disk is arranged in the center of the main arm and the paw. The invention has simple structure, small volume and low cost, and can be widely used for a transporting process of various silicon chips.

The invention provides a thallium-containing wastewater strongly oxidizing, coagulating, adsorbing and recovering process. The process includes the following procedures: thallium-containing wastewater concentration, pH regulation, strong oxidization, coagulation, flocculation, precipitated sludge treatment, pH regulation, solid impurity filtration, removal of Zn, Pb, Cd and Tl, and the like. The process has the beneficial effects that the process has the advantages of advanced technology, maturity, good effluent quality, stability in operation, conciseness in process, strong practicability, easiness in start and stop, convenience in maintenance and management, small investment, low operating cost, small floor area for construction, short construction period and large application ranges of projects; treatment of heavy metal ion polluted sewage is not limited by temperatures; the limitation that a biological method can not be used in cold regions in the north can be overcome.

The invention discloses a fused salt heat treatment method for rubbish incineration fly ash, and belongs to ash treatment methods. The method solves the problems that the treatment temperature is high, the energy consumption is large and poisonous trace elements cause secondary pollution through existing treatment methods for the rubbish incineration fly ash. The method includes the steps of preparing mixed fused salt, carrying out fusing heat treatment, detecting the content of heavy metal and extracting and recovering the heavy metal. According to the method, chlorides, sulfate and partial heavy metal in the fly ash can be dissolved out through the fusing, heat storing and reacting characteristics of the fused salt, processes are relatively simple, reaction conditions are mild and easy to control, leaching of the heavy metal in the fly ash can be effectively controlled in an environment, the treated fused salt can be recycled, deep enrichment and recovery of the dissolved heavy metal can be carried out, the harm level of treated residues is greatly lowered, building material utilization and secure landfill of the treated residues can be conveniently carried out, secondary pollution is effectively reduced, the resource utilization efficiency is improved, and light reduction, harmlessness and resource utilization of the rubbish incineration fly ash can be realized synchronously.

The invention discloses a high-dust holding capacity and high-efficiency composite electrostatic air purification device, which sequentially comprises a primary filtering screen, a carbon brush charge region, an electrostatic dust removal region, an air filter and a dust hopper, wherein a differential pressure transducer is arranged at the two ends of the air filter; a material level sensor is arranged in the dust hopper. According to the composite electrostatic air purification device, charged particles are collected by the electrostatic dust removal region, so that the air filter is protected, and the service life of the air filter is prolonged; the dust holding capacity of the air filter is reduced, pressure drop is reduced, and labor is saved; the exposure time of air, dust and particles on the air filter is reduced, and secondary pollution to the air caused by gas pollutants and bacterial viruses in a particle filtering process is reduced; the filtering efficiency of the electrostatic dust removal region is insensitive to blast volume changes, and the influence of proper increase of the blast volume to the overall dust removal efficiency of the device is limited, so that the purification device is suitable for blast volume variable buildings.

The invention provides a method for comprehensive treatment of household refuses and secondary pollution control. The method comprises the following procedures of: 1) coarse separation of the household refuses; 2) pretreatment of the household refuses; 3) fine separation of the household refuses; 4) aerobic composting of the household refuses; 5) biological organic fertilizer preparation; 6) fabrication of refuse derived fuels; and 7) secondary pollution control. The method employs parallel dual-separation lines which are compact in arrangement; each functional unit device is rational in configuration, easy to operate and mechanically control; the sorting efficiency and the energy source recovery effect are obviously improved; and minimization, harmless treatment, recycling and energy conversion of the household refuses can be realized.

The invention belongs to the field of catalyst materials for waste water treatment, and provides a supported advanced oxidation catalyst material and a preparation method thereof. The method includes the steps: (1) pre-treating carrier materials; (2) placing the pretreated carrier materials into plating solution with a pH (potential of hydrogen) value of 3-13, stirring mixture for at least 5 minutes at the temperature ranging from 30 DEG C to 90 DEG C, performing solid-liquid separation, cleaning a solid phase by the aid of water and organic solvents, and drying the cleaned solid phase to chemically-plated carrier materials; (3) aerobically roasting the chemically-plated carrier materials for 1-8 hours at the temperature ranging from 200 DEG C to 1000 DEG C to obtain the catalyst material. According to the catalyst material, metal oxides are uniformly loaded on the surfaces of the carrier materials, binding force among the loaded metal oxides and the carrier materials can be effectively improved, loading capacity is improved, the service life of the catalyst material is prolonged, catalytic activity is improved, and secondary pollution caused by metal ion leaching is effectively relieved.

The invention discloses an ultra-clean treatment method for incinerated tail gas. The ultra-clean treatment method is characterized by sequentially comprising the steps that the tail gas continues to be combusted through a secondary combustion chamber; heat recovery is conducted on the tail gas through a waste heat boiler; the tail gas is cooled through a quench tower; baking soda powder and active carbon powder are sprayed into the tail gas exhausted out of the quench tower, and the tail gas, the baking soda powder and the active carbon powder are mixed and fed into a dust remover provided with a catalytic filtering bag to remove heavy metal and dioxin in the tail gas; and the qualified tail gas with the acid gas being removed is exhausted into the atmosphere through an induced draft fan and a chimney. The ultra-clean processing method is simple in technique. By treating and incinerating the tail gas through the method, spraying, washing and smoke reheating are not needed, the effect for removing the dioxin in the tail gas is good, fire disasters can be avoided, and the operation cost is reduced; and in addition, secondary pollution such as sewage is avoided. The ultra-clean processing method is suitable for treating the tail gas exhausted from household refuse and hazardous waste combustion furnaces.

The invention mainly discloses a fabric cutting table with a cleaning device. Its technical proposal includes a workbench and a support frame. Both sides of the workbench are provided with chip falling grooves. The workbench is provided with a cleaning device. The cleaning device includes The driver, the chip suction pipe and the cleaning brush are respectively located on the left and right sides of the workbench. The driver is connected to the chip suction pipe. The driver drives the chip suction pipe to move back and forth on the workbench. The chip suction pipe is connected to the chip suction pump through the connecting pipe. The outlet end of the chip suction pump is connected with the first collection box, the bottom of the chip suction pipe is uniformly provided with chip suction holes, the cleaning brush is detachably connected with the chip suction pipe, and the bottom surface of the cleaning brush is provided with bristles. The invention has a simple structure, and through the joint action of the chip suction pipe and the cleaning brush, it is convenient to remove waste cloth and broken threads on the workbench, greatly improving the cleaning speed and efficiency, reducing the amount of manual labor, and saving manpower.

The invention discloses an automatic quick rice noodle boiling machine, and relates to a device applied to the catering industry. The automatic quick rice noodle boiling machine comprises a bowl feeding mechanism, a bowl conveying mechanism, a rice noodle transmission mechanism, a rice noodle boiling mechanism, a material feeding mechanism and a central control mechanism; the central control mechanism controls the bowl feeding mechanism to place bowls onto a conveyor belt I of the bowl conveying mechanism; then the central control mechanism controls the bowl conveying mechanism to automatically place the bowls to one side of the rice noodle boiling mechanism; the rice noodle transmission mechanism puts rice noodles to the rice noodle boiling mechanism for boiling the rice noodles; the boiled rice noodles are poured to the bowls on the conveyor belt I; the central control mechanism then controls the bowl conveying mechanism to continuously convey the bowls forwards to automatically place the bowls to one side of the material feeding mechanism; the material feeding mechanism pours meat dish and soup to the bowls on the conveyor belt I; the central control mechanism then controls the bowl conveying mechanism to continuously convey the bowls forwards to the tail end of the conveyor belt I; people who eat the rice noodles can fetch the boiled rice noodles. The automatic quick rice noodle boiling machine disclosed by the invention has the advantages that the rice noodle boiling efficiency can be improved, the rice noodle boiling quality can be guaranteed, and the safety of boiled rice noodle foods can be improved.

The invention discloses a treatment method for unsymmetrical dimethylhydrazine-containing wastewater. The treatment method comprises the following steps: (1) adding hydrogen peroxide and a solid catalyst into the unsymmetrical dimethylhydrazine-containing wastewater, feeding air or oxygen, reacting, and performing solid-liquid separation; (2) adjusting the pH of the wastewater to be 5 to 9, and adding chlorine-containing oxidant into the wastewater for reacting for 5 to 30 minutes, wherein the hydrogen peroxide and the unsymmetrical dimethylhydrazine are in the molar ratio of (0.2-11):1, and the chlorine-containing oxidant and the unsymmetrical dimethylhydrazine are in the molar ratio of (11-0.2):1. Compared with a pure chlorine-containing oxidant oxidation method or a pure hydrogen peroxide oxidation method, the method disclosed by the invention has a good treatment effect, the treatment is thorough, the time is short, the using amount of the chorine-containing oxidant is greatly reduced, and the secondary pollution of a water body is reduced.

The invention provides a moringa oleifera water purifying agent. The water purifying agent is characterized in that: the water purifying agent is prepared from components of, by mass: 90% to 100% of moringa oleifera extract, and 0 to 10% of a chemical water purifying agent. According to the invention, moringa oleifera oil extraction residuals are adopted; moringa oleifera effective components areextracted; and a complete and comprehensive utilization of moringa oleifera seeds is realized. The moringa oleifera water purifying agent is a pure plant extract. When the moringa oleifera water purifying agent is used for purifying water, no toxicity or harm is brought in. Therefore, harms to human and secondary pollutions to the environment brought by chemical water purifying agents can be solved from the source. The moringa oleifera water purifying agent is suitable for rural water purification. With the water purifying agent, a problem of drinking-water safety of rural population can be solved. The water purifying agent is applied in the purifications of turbid waters such as river water, lake water and rainwater, and brings better purification effects than chemical water purifying agents. The moringa oleifera water purifying agent can be blended with chemical water purifying agents for purifying urban sewage. Therefore, adoption amount of chemical water purifying agents is greatly reduced.

The invention discloses a production method of calcium peroxide particles for slowly releasing oxygen. The production method of the calcium peroxide particles for slowly releasing the oxygen comprisesthe steps of using calcium peroxide powder as an oxygen releasing agent, using polylactic acid particles as an embedding medium, using dichloromethane as an intermediate medium for dissolving the polylactic acid particles, after the dissolved polylactic acid particles and the calcium peroxide powder are completely mixed, conducting volatilizing under a ventilation condition to remove the dichloromethane, placing an obtained mixture in a tubular mold after the mixture is in a gelatinous semi-solid state, and conducting extrusion molding and shearing balling to finally obtain the calcium peroxide particles for slowly releasing the oxygen after the dichloromethane is completely volatilized. By means of the production method of the calcium peroxide particles for slowly releasing the oxygen, the calcium peroxide powder and the polylactic acid particles can be completely mixed and embedded, the oxygen release speed of the calcium peroxide in water can be effectively controlled, and in the production process, loss, due to contact between the calcium peroxide and the water, of an oxygen releasing component is avoided. The produced calcium peroxide particles for slowly releasing the oxygencan slowly and continuously release the oxygen in the water, and meanwhile, due to the biodegradability of the PLA, no secondary pollution is generated during material use.

The present invention relates to a metal phthalocyanine fiber-supported metal phthalocyanine having catalytic activity and preparation method, said metal phthalocyanine with fiber or fabric through covalent bond conjoint mode combining to form supported fiber having catalytic activity. The used etal phthalocyanine is transition metal ion such as characterized in having the structure of formula 1, in which M is a Fe,Co,Cu,Mn,Rb,Al,Zn and Ni; R1,R2,R3,R4 each can be H, any of the five in formular (1), and others are all H, the construction of the radical R5 can be -NH2, -NHCOCH3, -NHSO3Na, and -NHSO3H. Said preparation method is selecting metal phthalocyanine as reactive group having triazine structure under pH 8- 11 reaction temperature 45 -95 degree centigrade condition, adding fiber or fabric to finite concentration reactivity metal phthalocyanine aqueous solution, continuously stirring, after reaction taking out fiber or fabric and respectively to make caustic washing and water washing, drying to obtain fiber-supported metal phthalocyanine or fabric. Said invention has simple equipment, easy to operate etc advantages.

The invention discloses a preparation method of a polypyrrole functional mediator doped with a water-soluble anthraquinone or naphthoquinone compound and application thereof. Specifically, the preparation method comprises: (1) preparing a polymerization solution: firstly preparing a saturated solution of the water-soluble anthraquinone or naphthoquinone compound, then adding 0.33-0.67mL of pyrrole to every 100mL of the saturated solution and mixing well; (2) pretreating active carbon felt and platinum plate electrodes; (3) embedding the pretreated platinum plate electrodes in step (2) into the active carbon felt, then conducting electrochemical polymerization in the polymerization solution, with a polymerization potential of 0.30-0.50V, a polymerization time of 1-3h and a potential changerate of 0.03-0.07V/s. The polypyrrole functional mediator provided in the invention plays an accelerating role in a microorganism denitrification process, and is recyclable and free of secondary pollution.

The invention discloses a recovery technology and a separation device of a waste lithium iron phosphate battery cathode material. The recovery technology is characterized by firstly separating a lithium iron phosphate material from an aluminum foil by adopting a physical method of heating treatment and mechanical force separation, and then obtaining a novel lithium iron phosphate material by adopting the technologies of fine smashing, dissolving and impurity removing, and roasting, repairing and lithium supplementing; separating and obtaining a lithium iron phosphate recovery material by the separation device through a grinding mode of a millstone. The safe and industrial recovery method and the separation device are provided for recycling of the waste lithium iron phosphate battery cathode material, the material recovery rate can be increased, the cost is reduced, a chemical recovery technology is simplified, the resources are saved, and environment pollution is reduced.

The invention relates to a preparation method of a modified magnetic chitosan microsphere heavy metal ion adsorbent, and in particular relates to a modified magnetic chitosan material which has good selectivity and adsorptive property for heavy metal ions in food, and can be recycled, and a preparation method of the modified magnetic chitosan material. Specifically, the invention discloses the preparation method of the modified magnetic chitosan microsphere heavy metal ion adsorbent. The method comprises the steps of preparing magnetic chitosan microspheres by taking chitosan powder as a raw material, further preparing the magnetic chitosan microspheres into hydroxypropyl chlorine magnetic chitosan microspheres, and carrying out chemical grafting on the hydroxypropyl chlorine magnetic chitosan microspheres by taking the hydroxypropyl chlorine magnetic chitosan microspheres as parents and 2-aminothiazole as ligands to obtain the modified magnetic chitosan microsphere heavy metal ion adsorbent. The modified magnetic chitosan microsphere heavy metal ion adsorbent prepared by the method has preferential adsorption for Hg2+ ions.