3782 results about "Reverse osmosis" patented technology

The invention provides a zero-discharge treatment process for recycling production wastewater, and relates to the technical field of water treatment and recycling, and the zero-discharge treatment process comprises the following steps: S1, oxidizing and degrading COD through ozone and a Fenton reagent, and generating a flocculatable intermediate; s2, intercepting suspended matters by using a gradient aperture filter bed in a grading manner, and monitoring a dynamic membrane resistance coefficient delta Rm in real time to automatically trigger backwashing; s3, coupling an ultrafiltration reverse osmosis membrane to realize that the organic matter rejection rate eta is greater than or equal to 98%, and synchronously regulating and controlling flux and operation pressure by an online spectrometry; s4, regulating and controlling the current density by adopting a rotational flow electric flocculation reactor for directional crystallization to produce industrial salt with Cl <-> less than or equal to 50mg / L; and S5, based on the total dissolved solid recovery rate TR and the comprehensive energy consumption, establishing a multi-target optimization model for real-time parameter adjustment. According to the method, a membrane pollution early warning and backwashing dynamic response mechanism is constructed through cross-scale cooperative regulation and control of delta Rm and the retention rate eta, and a catalytic oxidation effect strengthening and electric crystallization parameter self-tuning technology is combined, so that the problem of cooperative optimization of high-salinity wastewater salt gradient separation and pollutant deep removal is solved.

The invention relates to the technical field of water treatment equipment, and particularly discloses intelligent dynamic water-saving two-stage reverse osmosis water treatment equipment which comprises a treatment pipe, the two ends of the treatment pipe are fixedly connected between two sections of water conveying pipes in a sealed mode through bolts, and the outer surface of the treatment pipe is fixedly sleeved with a baffle ring. According to the intelligent dynamic water-saving two-stage reverse osmosis water treatment equipment, along with continuous upward movement of a driving rod, a sealing disc is driven to move upwards along a sliding rod, so that the water pressure of a cavity above the sealing disc is increased, a reverse extrusion force is generated on a filter plate, and impurities blocked at the filter plate generate a reverse extrusion force; after the filtering disc is dredged, the pressure disc and the sealing disc are reset under the action of elastic force to enable the filtering disc to work again, so that the filtering disc is automatically dredged after the filtering disc is blocked in the water treatment process, and the working time of equipment is greatly prolonged; the problem of insufficient water treatment efficiency caused by frequent cleaning of equipment is avoided.

The invention discloses an intelligent detection and dynamic early warning system based on machine learning and multi-source data fusion, which relates to the technical field of membrane separation process monitoring and consists of a data acquisition and preprocessing part, a physical model and data driving model part, a dynamic weight fusion and self-adaptive mechanism part and a man-machine interaction and alarm part. According to the system, parameters such as membrane flux, transmembrane pressure difference, solution concentration, temperature, water inlet flow and operation pressure are collected, an improved XGBoost machine learning model is combined, and a comprehensive pollution index is constructed to quantify the membrane pollution degree; the model realizes double analysis of a pollution mechanism and a data rule through feature engineering. The system supports full-closed-loop management from minute-level early warning to hour-level cleaning decision making, the threshold value is dynamically adjusted through Bayesian optimization, the generalization and anti-interference capacity of the system are remarkably improved, and the system is suitable for intelligent operation and maintenance of membrane separation processes such as reverse osmosis and ultrafiltration.

The invention relates to the technical field of water resource purification, in particular to a control method and equipment of a reverse osmosis water purification system.The control method comprises the steps that firstly, on the fluctuation dimension of the pre-membrane pressure, the adjusting requirement of the frequency of a high-pressure pump is preliminarily determined on the dimension of the pre-membrane pressure according to an obtained pressure fluctuation index; determining a membrane resistance increase factor representing the pollution state of the reverse osmosis membrane on the basis of the transmembrane pressure difference on the dimension of separation function failure of the reverse osmosis membrane; finally, a membrane separation abnormal value is comprehensively represented by combining a pressure fluctuation index and a membrane resistance increase factor, and a purified water recovery rate is introduced to a membrane separation result end, so that the finally obtained frequency reduction demand degree is more accurate, and the control effect of the reverse osmosis water purification system is improved; therefore, the stable, efficient and sustainable operation of the reverse osmosis water purification system can be ensured while the membrane surface pollutant deposition driving force can be effectively reduced and the membrane pollution speed can be slowed down.

The invention discloses an integrated process for cooperative treatment and up-to-standard discharge of industrial wastewater and domestic wastewater of a power plant, and relates to the field of cooperative treatment of wastewater and sewage, and the integrated process comprises the following steps: configuring a raw water collection system, setting a raw water source, configuring a multi-stage filtration and heating pretreatment process, configuring an ultrafiltration membrane system, and setting a fine filtration path. A first-stage reverse osmosis system is configured, reverse osmosis parameters are set, a second-stage reverse osmosis system is configured, a low-conductivity water treatment path is set, a mixed ion exchanger is configured, a desalted water output path is set, a standby pool body is set, and the adjusting capacity is set. A raw water collecting system, a multi-stage filtering and heating pretreatment process, an ultrafiltration membrane system, a first-stage reverse osmosis system, a second-stage reverse osmosis system, a mixed ion exchanger and a standby pool body are sequentially arranged in the process. The problems of unstable effluent quality, insufficient deep desalination capability and poor emergency regulation capability in a traditional power plant wastewater treatment mode can be effectively solved.

The invention provides a low-carbon circulating technological process for treating high-total-nitrogen wastewater. A main treatment unit and a resource recycling and circulating unit are included; the main treatment unit is characterized in that high-total-nitrogen wastewater sequentially passes through a pH regulating tank, a sulfur autotrophic denitrification tank, a biochemical system, a secondary sedimentation tank, a deep treatment line and ultrafiltration reverse osmosis, produced reclaimed water enters produced water for delivery, and a part of produced concentrated water enters a resource recovery and circulation unit; the resource recovery and circulation unit is characterized in that after concentrated water is treated by a vertical electrophoresis device, mixed acid, mixed alkali and low-salt water are separated out, the mixed alkali is sent to a sulfur autotrophic denitrification tank to be used for supplementing alkalinity consumption of the sulfur autotrophic denitrification system, and the mixed acid sequentially passes through an anaerobic regulating tank, an anaerobic reactor, an alkali washing tower, a biological desulfurization reactor and a sedimentation tank; the recovered sulfur can be sold as elemental sulfur or reused in the sulfur autotrophic denitrification tank, and supernate flows back to the alkaline tower; a green, low-carbon and recyclable water treatment process flow is realized.

The invention discloses an energy-saving and consumption-reducing method for a reverse osmosis membrane system, which belongs to the technical field of water treatment and comprises the following steps: step 1, acquiring various parameter data of the reverse osmosis membrane system in real time; 2, establishing an energy consumption prediction mathematical model of the reverse osmosis membrane system; 3, inputting the real-time parameter data into the energy consumption prediction mathematical model, and judging whether the operation power of the high-pressure pump is reasonable or not according to an output result; 4, when the operation power is not reasonable, the operation power of the high-pressure pump is adjusted in real time; and 5, establishing a membrane pollution concentration early warning model, and carrying out alarm response. According to the method, comprehensive analysis can be carried out in real time according to various parameters of inflow water quality to accurately predict the predicted power, so that whether the set operation power of the high-pressure pump is reasonable or not is judged, the operation power of the high-pressure pump can be dynamically adjusted, the output of energy consumption can be reduced as much as possible under the condition that treatment is qualified, and the operation efficiency of the high-pressure pump is improved. And the cost is saved.

The invention discloses a modularized ultrapure water preparation and on-line monitoring system, which comprises a pretreatment module, a purification module, a monitoring module and a control module, and is characterized in that a dynamic monitoring end is arranged, and when ultrapure water preparation is monitored in real time, a multi-parameter fusion detection mechanism and self-adaptive threshold analysis are integrated; meanwhile, the abnormal state of the water quality is dynamically judged based on the conductivity, TOC and particulate matter data collected in real time, the sudden change risk of the water quality output by the purification module can be recognized in real time, error accumulation caused by traditional single-point monitoring is avoided, and therefore the purity detection reliability of the ultrapure water is improved; and the reverse osmosis unit and the electrode deionization unit of the purification module can immediately respond to the effluent parameter change of the pretreatment module, so that the hidden dangers of membrane blockage and recovery rate reduction caused by water quality fluctuation are reduced, and the energy consumption redundancy is reduced while the water quality stability is ensured.

The invention relates to the technical field of water treatment, in particular to a high-recovery-rate short-process salt-tolerant reverse osmosis system and treatment method.The system comprises a pretreatment unit, a sensor monitoring unit, a self-adaptive pressure-flow coupling control unit, an intelligent operation and maintenance unit and a gradient boosting reverse osmosis membrane set. According to the invention, ultrahigh recovery rate and desalination performance are realized, gradient boost membrane module design is combined with concentration polarization inhibition technology, membrane surface flow state distribution is optimized, osmotic pressure influence is significantly reduced, pressure-flow coupling control and concentrated water excess pressure energy recovery technology are integrated, energy dynamic cyclic utilization is realized, energy consumption is reduced, and the method is suitable for industrial production. By monitoring the membrane flux attenuation rate and the transmembrane pressure difference in real time and dynamically optimizing a pulse cleaning strategy, dynamic optimization of high-salinity wastewater treatment is realized, and the problems of low recovery rate, high energy consumption and quick membrane pollution in high-salinity wastewater treatment are solved.

The invention provides a method and system for salt separation, evaporation and crystallization of printing and dyeing wastewater, and the method comprises the following steps: sequentially carrying out multi-stage synergistic pretreatment on textile printing and dyeing wastewater to remove suspended solids, degrade organic matters and reduce hardness; the pretreated wastewater is subjected to membrane salt separation treatment, and preliminary separation of salt is achieved through reverse osmosis pre-concentration and nanofiltration salt separation; and respectively carrying out evaporative crystallization treatment on the separated high-concentration salt solution to obtain high-purity sodium sulfate and sodium chloride products. According to the method, the salt recovery rate and the product purity are remarkably improved, the energy consumption and the operation cost are reduced, meanwhile, the problems that in traditional printing and dyeing wastewater treatment, salt is difficult to separate, and the crystallization purity is low are solved, and an innovative solution is provided for high-valued resource recovery of industrial wastewater.

The invention discloses a regulation and control method for stably improving the water quality of water produced by a reverse osmosis system of a power plant, and relates to the field of water quality regulation and control, which comprises the following steps: configuring a water inlet flow regulation device, performing initial setting, configuring the position of an online sensor, performing data acquisition, setting judgment rules of turbidity, differential pressure and transmembrane pressure difference, and determining the water quality. And configuring a flocculant adding device and adding control logic, configuring a backwashing and adding linkage control state machine, and carrying out data smoothing, trend analysis and self-adaptive threshold adjustment. When the water quality of the raw water fluctuates for a short time or the pollution load is increased, dynamically adjusting the water inlet flow, the backwashing intensity and the flocculant adding concentration based on parameters such as turbidity, pollution index, conductivity and pressure difference which are acquired by an online sensor in real time; and meanwhile, the concentrated water reflux proportion and the high-pressure pump frequency are automatically corrected by continuously calculating the desalting rates of the first-stage and second-stage reverse osmosis devices, so that the running state of the membrane component is kept in an optimal interval.

The invention relates to the technical field of ammonia water preparation, in particular to a raw water reverse osmosis treatment device for ammonia water preparation, which comprises a shell, the shell is formed by fixing an upper shell and a lower shell, a water inlet pipe is fixed in the middle of the top of the shell, a high-pressure water inlet component is arranged at the top of the water inlet pipe, and a concentrated water outlet pipe is fixed in the middle of the bottom of the shell. A drain valve is fixedly mounted at the bottom of the concentrated water outlet pipe; and the water pressure stabilizing assembly is arranged at the top of the inner wall of the shell. A multi-level pressure regulation and control mechanism is constructed in the reverse osmosis process, the problem of instantaneous pressure impact when the high-pressure pump is started is solved, physical damage to the membrane is avoided, a dual anti-blocking system of active rotary cleaning and back flushing is constructed, the membrane blocking probability is greatly reduced, meanwhile, the impact force of water flow is fully weakened in the back flushing stage, and the reverse osmosis efficiency is improved. It is ensured that the reverse osmosis membrane bears stable pressure all the time, and the problem of secondary damage to the reverse osmosis membrane caused by too large instantaneous pressure in the backwashing stage is avoided.

The invention discloses a printing and dyeing wastewater advanced treatment and salt control recycling process and system, and belongs to the technical field of wastewater treatment. According to the process, the printing and dyeing wastewater is sequentially subjected to pretreatment of grating interception, adjustment and homogenization, and coagulating sedimentation; carrying out hydrolytic acidification and biochemical treatment in a membrane bioreactor; softening treatment of ozone oxidation complex breaking and fluidization crystallization softening; carrying out nanofiltration separation to obtain a permeate and a concentrated solution; carrying out seed crystal fluidization descaling on the concentrated solution; respectively carrying out membrane concentration on the nanofiltration permeate and the descaled concentrated solution through reverse osmosis to obtain sodium chloride and sodium sulfate concentrated solutions; and finally, carrying out evaporation curing treatment on the sludge and the crystallized waste residues. Through multi-step cooperative treatment, deep purification of the printing and dyeing wastewater and efficient separation and recycling of salt are realized, and the problems of impure nanofiltration salt separation and high system scaling risk in the prior art are solved.

The invention relates to the technical field of wastewater treatment, and discloses a double-membrane reclaimed water recycling device and a recycling method.The double-membrane reclaimed water recycling device comprises a support and an ultrafiltration membrane tank arranged in the support, a reverse osmosis membrane tank is fixed in the support, a settling tank is fixed in the support, a water storage tank is fixed in the support, and the double-membrane reclaimed water recycling device further comprises a tubular ultrafiltration membrane, a water storage tank and a water storage tank, the ultrafiltration membrane tank is fixed in the ultrafiltration membrane tank; the tubular reverse osmosis membrane is fixed in the reverse osmosis membrane tank; the wastewater is efficiently treated; when to-be-treated water is in a normal working state, the cleaning float bowl is driven by water pressure to move up and down in the tubular ultrafiltration membrane and the tubular reverse osmosis membrane: on one hand, intercepted substances attached to the wall surfaces of internal channels of the tubular ultrafiltration membrane and the tubular reverse osmosis membrane are scraped by a first cleaning scraping ring, a second cleaning scraping ring and a spiral scraping ring; on the other hand, intercepted objects attached to the scraping rings are washed and cleaned by means of water flow pressure, the intercepted objects are discharged through the spiral drainage channel, and therefore self-cleaning of the cleaning buoy is achieved.

The invention relates to a composite reverse osmosis membrane acidic cleaning agent, a preparation method and a cleaning process thereof, and belongs to the technical field of environment-friendly water treatment. The cleaning agent comprises the following components in percentage by mass: 4-8% of inorganic acid, 20-40% of organic acid, 1-3% of a surfactant, 0.5-1% of a chelating agent, 0.5-1% of a compound corrosion inhibitor and the balance of deionized water. The composite corrosion inhibitor is formed by compounding 2-mercaptobenzothiazole and the like according to a specific mass ratio, the molecular weight of polyaspartic acid is 5000, and the molar ratio of Zn to Mo in the zinc-molybdate compound is 2: 1. The preparation method comprises the following four steps: firstly preparing a compound corrosion inhibitor premix, then preparing an acidic base solution, and then sequentially adding the components to finally obtain the cleaning solution. According to the cleaning process, a cleaning agent and deionized water are mixed, the membrane flux recovery rate is larger than or equal to 85% through cleaning of a specific process, the reverse osmosis membrane can be effectively cleaned, and the performance of the reverse osmosis membrane can be recovered.

The invention discloses an advanced treatment and recycling method for cold-rolled silicon steel magnesium oxide wastewater, and particularly relates to the technical field of wastewater treatment. Through pH adjustment, coagulation pretreatment, pre-membrane fine filtration and medicament stabilization of wastewater, stable control of inlet water quality is realized; a two-stage reverse osmosis system is combined with a dynamic flow and cross flow structure, so that the risks of concentration polarization and local stress corrosion are remarkably inhibited; by combining real-time monitoring of membrane surface pressure difference and recovery rate and an intelligent algorithm, self-adaptive optimization regulation and control of operation parameters of the system are realized; according to the method, the problems of serious membrane pollution, poor system stability, low recycling efficiency and the like in the prior art are effectively solved, and the wastewater resource utilization level and the system operation safety are remarkably improved.

The invention relates to the technical field of reverse osmosis membrane supports, in particular to a polyester non-woven fabric and a preparation method and application thereof.The preparation method comprises the steps that S1, polyester main body fibers and polyester adhesive fibers are used as raw materials to prepare high-quantitation original cloth M0 and low-quantitation original cloth H0; carrying out hot pressing pretreatment on the H0 to obtain a product H0 '; s2, overlapping and hot-pressing M0 and H0 'to obtain a composite non-woven fabric M1H1; s3, the M1H1 is impregnated with a functional solution, and the functional solution contains para-aramid nanofibers and nano calcium carbonate modified by hexadecyl trimethyl ammonium bromide; and then carrying out cold pressing on the composite non-woven fabric impregnated with the functional solution to obtain the nano-material modified composite non-woven fabric. And S4, carrying out secondary hot pressing treatment to obtain the polyester non-woven fabric. The polyester non-woven fabric can effectively avoid the problems of excessive curling, excessive permeation of a polysulfone solution and the like during curing after being coated with polysulfone, and is more beneficial to application in a reverse osmosis membrane.

The invention relates to the technical field of industrial wastewater treatment, and discloses an efficient two-stage reverse osmosis petroleum coke water treatment system, which comprises pretreatment execution ends, a reverse osmosis core end, a concentration regeneration end and an intelligent control end which are commonly configured with a data feedback module. A step-by-step mechanism is established at the initial stage of wastewater treatment, quartz sand is adopted to intercept large-particle suspended solids, activated carbon is adopted to adsorb and degrade organic matters, softening resin is adopted to replace and remove scaling ions, ozone is adopted to catalyze, oxidize and decompose refractory pollutants, an oxidation-reduction potential dynamic regulation and control mechanism is innovatively introduced, and the dosage of an oxidizing agent is automatically regulated according to water quality and chemical quality; by means of the design, the blocking problem caused by high-hardness waste water is solved, the membrane is prolonged, the solution period is stably solved, the chemical cleaning frequency and agent consumption are reduced, a pollution early warning and closed response linkage mechanism is constructed, membrane damage caused by manual intervention delay is avoided, and the service life of membrane elements is prolonged and reduced.

The invention discloses a preparation method of a TA modified aminated ZIF-90 polyamide reverse osmosis membrane, which comprises the following steps: by taking a self-made polysulfone membrane as a base membrane, firstly soaking the base membrane in a water phase solution, then soaking the base membrane in an oil phase solution containing aminated ZIF-90, then treating the base membrane with a tannic acid (TA) / ethanol solution, and finally performing heat treatment to obtain the target polyamide reverse osmosis membrane. Aminated ZIF-90 is used for modifying a polyamide membrane, then TA is used for modifying a surface layer, and compared with an original membrane, the prepared membrane material is effectively improved in water flux and salt interception; after chlorine treatment, the attenuation rate of water flux and salt interception is smaller than that of the original membrane, which indicates that the chlorine resistance of the modified polyamide membrane is superior to that of the original membrane; meanwhile, the modified polyamide membrane has excellent anti-pollution performance.

The present invention discloses a high-performance reverse osmosis membrane and a method for preparing the same. The reverse osmosis membrane comprises a polyester non-woven fabric layer, a polysulfone-based membrane, and a polyamide skin layer stacked in sequence. The polysulfone-based membrane has a micron-scale prism structure on the side away from the polyester non-woven fabric layer. The preparation method comprises coating the surface of the polyester non-woven fabric layer with the polysulfone-based membrane, and forming the micron-scale prism structure on the surface of the polysulfone-based membrane by cold pressing with a roller mold during the process of converting the polysulfone-based membrane from a liquid state to a solid state. The present invention improves the flux without affecting the desalination rate of the reverse osmosis membrane or sacrificing the thickness of the skin layer, thereby resolving the trade-off between flux and desalination in the current technology. At the same time, the micron-scale prism structure can be designed into different shapes according to performance requirements, thereby achieving precise control of the flux performance of the reverse osmosis membrane.

The invention relates to the technical field of water purifiers, and provides a water purifier control method, device and equipment and a storage medium, and the method comprises the following steps: when an instruction of starting water production is received, obtaining any random number from a preset random number range; if the random number is within a preset first range, firstly filtering tap water flowing in from a main water inlet through a first reverse osmosis membrane, then enabling wastewater output by the first reverse osmosis membrane to flow into a second reverse osmosis membrane for secondary filtration, and then enabling the wastewater to flow out from a main water outlet; if the random number is within a preset second range, firstly filtering the tap water flowing in from the main water inlet through a second reverse osmosis membrane, then enabling the wastewater output by the second reverse osmosis membrane to flow into the first reverse osmosis membrane for secondary filtration, and then enabling the wastewater to flow out from the main water outlet. According to the invention, the first reverse osmosis membrane or the second reverse osmosis membrane can be prevented from being invalid in advance due to overuse, so that the service life of each osmosis membrane in the reverse osmosis filter piece is prolonged.

The invention provides a preparation method of super absorbent resin, and relates to the technical field of super absorbent resin. The preparation method comprises the following steps: diluting acrylic acid with water, and adding alkali liquor for neutralization to obtain a neutralized solution; mixing an emulsifying agent, a thickening agent and foaming carbonate to obtain a foaming promoting auxiliary agent; adding a cross-linking agent, a photoinitiator and a temperature initiator into the neutralization solution to obtain a polymerization mother solution; uniformly mixing a foaming promoting auxiliary agent with the polymerization mother liquor, and initiating polymerization of the polymerization mother liquor under a UV illumination condition to obtain acrylate polymer gel; drying the acrylate polymer gel, and crushing and screening to obtain basic particles; and spraying a surface cross-linking treatment liquid on the surfaces of the basic particles, initiating a surface cross-linking reaction of the basic particles through heat treatment, and adding an inert filler after the surface cross-linking reaction to prepare the super absorbent resin finished product particles. The super absorbent resin disclosed by the invention has the characteristics of high reaction efficiency, high liquid absorption speed, good liquid passing performance, excellent reverse osmosis resistance and the like.

The present invention provides a system and method for extracting lithium from salt lake brine and preparing battery-grade lithium carbonate. The system includes a coagulation and precipitation system, a filtration system, an adsorption and desorption system, a calcium and magnesium removal system, a boron removal system, a concentration system, an evaporation system, and a lithium precipitation system connected in sequence. The calcium and magnesium removal system includes a first-stage reverse osmosis concentration unit, a first-stage nanofiltration calcium and magnesium removal unit, a second-stage reverse osmosis concentration unit, a multi-stage nanofiltration calcium and magnesium removal unit, and a calcium and magnesium ion exchange unit connected in sequence. The boron removal system includes a first-stage nanofiltration boron removal unit, a multi-stage nanofiltration boron removal unit, and a boron ion exchange unit connected in sequence. After the lithium precipitation system, there are also a precision filtration system and a water washing and drying system connected in sequence. By adopting the process of the present invention, the lithium recovery rate is improved, and the product is battery-grade lithium carbonate, greatly improving the resource utilization and recovery rate of the lithium extraction system, reducing the amount of externally added water and the consumption of sodium carbonate in the process of the lithium precipitation system.

The invention relates to the technical field of membrane separation, in particular to a high-flux high-salt rejection rate reverse osmosis membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: sequentially contacting a porous base membrane with a water phase solution and an oil phase solution to generate an interfacial polymerization reaction to form a primary reverse osmosis membrane, and sequentially contacting the primary reverse osmosis membrane with a nitrous acid or salt solution thereof and a hydrosulfite solution to obtain the reverse osmosis membrane with high flux and high salt rejection rate, the water-phase solution contains a water-phase cosolvent, and the oil-phase solution contains an oil-phase cosolvent. According to the preparation method, cosolvents are creatively added into a water-phase solution and an oil-phase solution in an interfacial polymerization reaction process to regulate and control the microstructure of a polyamide layer, and a diazo reaction promotes further crosslinking of residual aniline groups, so that in-situ densification regulation and control of a polyamide network structure are realized; the trade-off effect of the water flux and the salt rejection rate of the traditional reverse osmosis membrane is successfully broken through.

This disclosure relates to the fabrication of high-performance thin film composite (TFC) reverse osmosis (RO) membranes comprising a thin polyamide rejection layer (thickness of 100-200 nanometer), a porous substrate including polysulfone (PSf) layer (thickness of 40-50 micron) cast on polyester nonwoven fabric (thickness of ˜100 micron). Hydrophilic and antibacterial TFC polyamide RO membranes were developed by incorporating green Lignin and nanostructured silver-based metal organic frameworks (MOFs) into the selective layer. The polyamide layer of TFC RO membranes was fabricated on the porous PSf substrate by interfacial polymerization between aqueous monomer solutions containing MPD, and adequate additives in water and organic monomer solutions containing TMC in the mixture of hexane and co-solvents. The optimized produced RO membranes were provided water flux of 95-100 LMH and sodium chloride (NaCl) salt rejection of 98.5-99.0% during filtration of 2000 ppm NaCl solution at 225 psi pressure, and water flux of 55-60 LMH and sodium chloride (NaCl) salt rejection of 98.6-98.9% during filtration of 35000 ppm NaCl solution at 800 psi pressure. This disclosure also relates to developing a roll-to-roll PSf membrane as a substrate for making TFC RO membranes for water desalination

The invention relates to the technical field of water treatment, in particular to a reverse osmosis membrane and a preparation method thereof. The preparation method of the reverse osmosis membrane comprises the following steps: soaking a base membrane in a water phase solution, taking out the base membrane, drying the surface of the base membrane, coating the base membrane with an oil phase solution, carrying out interfacial polymerization reaction, curing, coating with a modifier solution, and drying to obtain the reverse osmosis membrane, the modifying agent comprises 2, 4, 6-tri (4-aminophenyl)-1, 3, 5-triazine-1, 3, 5-tri (4-methyl phenyl) benzene. The successfully grafted COFs can improve the water permeability of the membrane to a certain extent, and also can improve the pollution resistance, acid resistance and oxidation resistance of the membrane, so that the service life of the membrane is prolonged. According to the invention, different effects of the same type of imino COFs introduced to the reverse osmosis membrane are further compared, so that the excellence of the selected imino COFs is highlighted.

The present invention relates to the field of water treatment technology, and more particularly to a kind of reverse osmosis membrane and preparation method thereof.The preparation method of the reverse osmosis membrane includes:Basement membrane is soaked in aqueous phase solution, after taking out surface drying, oil phase solution is coated on basement membrane and carries out interfacial polymerization reaction, after solidification, coating modifier solution, after drying, obtain reverse osmosis membrane;The modifier includes 2,4,6-tris (4-aminophenyl) ‑1,3,5-triazine ‑1,3,5-tris (4-methylphenyl) benzene.The COFs successfully grafted by the present invention can improve the water permeability of membrane to a certain extent, and can also improve the anti-pollution property, acid resistance and oxidation resistance of membrane, and then improve the service life of membrane.The present invention further compares the different effects that the same type of imino COFs are introduced into reverse osmosis membrane, so as to highlight the excellence of the imino COFs selected by the present invention.

The invention relates to the technical field of water treatment, and provides a reverse osmosis membrane cleaning method, a cleaning agent composition and application. According to the method, whether cleaning is needed or not is determined by comparing initial operation parameters and current operation parameters of a system; the pollutant type is accurately judged by observing the appearance characteristics of the membrane surface and detecting related index parameters; and selecting a corresponding cleaning agent formula according to the pollutant type, and sequentially performing physical washing and chemical cleaning. The cleaning agent composition comprises a biological pollution cleaning agent, an organic pollution cleaning agent and / or an inorganic scaling cleaning agent. By establishing a scientific pollution diagnosis system and a targeted cleaning strategy, the problems of fixed cleaning scheme and low pertinence in the prior art are solved, the pressure difference recovery rate after cleaning can reach 90% or above, the desalination rate recovery rate can reach 99% or above, the cleaning efficiency is remarkably improved, the operation cost is reduced, and the service life of the membrane is prolonged.

According to the efficient water treatment system based on the reverse osmosis membrane and the control method provided by the invention, gradient anti-pollution membrane arrangement and reconfigurable intelligent waterway design are creatively combined, so that a foundation is laid for high-flux and low-pollution operation from a physical structure; meanwhile, a full-closed-loop intelligent control system is constructed, and by fusing fuzzy logic, an optimization algorithm and a neural network prediction model, the system can integrate multi-dimensional information such as inlet water quality, membrane pressure difference and water yield, judge pollution risks in real time and adaptively and seamlessly switch among a high recovery mode, a segmented flushing mode and a prediction cleaning mode, so that the system is high in recovery efficiency and high in reliability. Meanwhile, parameters such as pump frequency and valves are dynamically optimized to find an optimal balance point of recovery rate and energy consumption; according to the invention, the recovery rate can be stably improved, the membrane pollution rate is greatly reduced, the chemical cleaning period and the service life of the membrane element are prolonged, and finally, the comprehensive operation and maintenance cost of the system is remarkably reduced while the water treatment efficiency and the water quality safety are improved.

The invention relates to the technical field of wastewater treatment, in particular to water treatment plant reverse osmosis wastewater treatment equipment and method.The water treatment plant reverse osmosis wastewater treatment equipment comprises a precipitation barrel used for wastewater precipitation, a drainage opening is formed in the annular barrel wall of the precipitation barrel, and a sewage outlet used for discharging precipitates is formed in the bottom wall of the precipitation barrel; the filter pressing unit is arranged in the precipitation barrel, is used for separating the wastewater from the precipitation, and comprises a filter pressing part which can move up and down and is arranged in the precipitation barrel. The filter pressing unit adopted by the invention can filter precipitates generated after wastewater treatment, the precipitates do not need to stand, the wastewater treatment efficiency is effectively improved, the treated wastewater can be discharged in real time in the filtering process, and the step of discharging the wastewater through a water pump is reduced.