The invention belongs to the field of
water pollution treatment, and particularly relates to a method for degrading
chlorophenol organic pollutants in water by activating
persulfate with a
cobalt-
cerium dioxide monatomic catalyst in the presence of
bicarbonate radicals. According to the invention,
cerium nitrate hexahydrate is calcined in a
muffle furnace to obtain
cerium dioxide. A catalyst precursor is prepared by a traditional isovolumetric impregnation method. The prepared catalyst precursor is annealed at different temperatures to obtain a series of catalysts, the catalytic performance of Co1-CeO2-700 is optimal, and the Co1-CeO2-700 has more excellent catalytic performance in the presence of
bicarbonate radicals. The preparation method provided by the invention has the advantages of simple steps, convenience in operation, quick effect of treating
chlorophenol, high product yield and low cost, and has good economic value and social benefit. The prepared monatomic catalyst has the advantages of being high in atom
utilization rate, good in stability, excellent in
catalytic effect and the like, and is expected to become a key technology for solving actual
water environment organic
pollution.