3749results about "Solid electrolytes" patented technology

The invention relates to a composite solid electrolyte membrane with high ceramic content and a preparation method and application thereof. The preparation method comprises the following steps: mixing ceramic solid electrolyte particles activated by a silane coupling agent with an in-situ polymerization solution containing a cross-linking agent, an organic monomer, a plasticizer, a lithium salt, an ultraviolet light initiator and a thermal initiator to form solid electrolyte slurry, wherein the ceramic solid electrolyte particles account for 60-90% of the total mass of the composite solid electrolyte membrane; the preparation method comprises the following steps: coating a positive pole piece with solid electrolyte slurry, initiating shallow organic matter monomers and a cross-linking agent to generate in-situ polymerization through an ultraviolet light initiator, covering a negative pole piece for hot pressing treatment, initiating residual organic matter monomers and the cross-linking agent to generate in-situ polymerization through a thermal initiator, and forming a composite electrolyte membrane with high ceramic content. The invention also discloses an all-solid-state battery containing the composite solid electrolyte membrane. The solid-state battery containing the in-situ formed composite solid-state electrolyte membrane has relatively high cycling stability.

The present disclosure provides a solid electrolyte composition that can suppress deterioration in ion conductivity of an ionic solid electrolyte material. The solid electrolyte composition according to the present disclosure contains a sulfur element-free ionic solid electrolyte material and an organic solvent, where the organic solvent includes at least one selected from the group consisting of a hydrocarbon and a compound having a functional group; and the functional group is at least one selected from the group consisting of an ether group, a halogen group, and a Si—O—C group.

The present disclosure provides a solid electrolyte composition that can suppress deterioration in ion conductivity of an ionic solid electrolyte material. The solid electrolyte composition according to the present disclosure contains a sulfur element-free ionic solid electrolyte material and an organic solvent, where the organic solvent includes at least one selected from the group consisting of a hydrocarbon and a compound having a functional group; and the functional group is at least one selected from the group consisting of an ether group, a halogen group, and a Si—O—C group.

A positive electrode material of the present disclosure includes: a positive electrode active material; and a first solid electrolyte material coating at least partially a surface of the positive electrode active material, wherein the first solid electrolyte material includes Li, Ti, M1, and F, and the M1 is at least one element selected from the group consisting of Ca, Mg, Al, Y, and Zr.

The present invention relates to a method of manufacturing an electrode of an all-in-one battery comprising the steps of mixing an electrode active material, a solid electrolyte and a first binder with a first solvent to prepare a primary slurry; drying the primary slurry to prepare a mixture powder; mixing the mixture powder, a conductive agent, and a second binder with a second solvent to prepare a secondary slurry; and coating the secondary slurry on a current collector.

The invention discloses a solid electrolyte, a preparation method thereof and an all-solid-state battery, and belongs to the technical field of solid electrolytes. According to the preparation method, a nano inert oxide and a solid electrolyte raw material are compounded through mechanical grinding, and the solid electrolyte with a core-shell structure is prepared; the device comprises an inner core, an interface layer and a shell from inside to outside, the inner core is a solid electrolyte matrix, the interface layer is a transition layer generated by reaction of the solid electrolyte matrix and a nano inert oxide, and the shell is a nano inert oxide layer. The material combines the advantages of high moisture resistance and wide electrochemical window of the nano inert oxide and the characteristics of high ionic conductivity and excellent mechanical property of the solid electrolyte, and the comprehensive performance of the material is remarkably improved through the synergistic effect of the components. The composite structure design not only solves the problem of performance limitation of a single material system, but also realizes collaborative optimization of ionic conductivity, environmental adaptability and electrochemical stability while ensuring the material stability.

The invention provides a composite sulfide solid electrolyte, a preparation method thereof and a lithium ion battery. The composite sulfide solid-state electrolyte comprises a sulfide solid-state electrolyte matrix and a composite layer coating the surface of the sulfide solid-state electrolyte matrix, the composite layer comprises an interface reaction layer and a coating layer from inside to outside, the coating layer comprises a halide material, and the interface reaction layer comprises an interface reactant obtained after the halide material and the surface of the sulfide solid electrolyte matrix are subjected to an interface reaction. According to the invention, under the action of the specific surface composite layer, the electrochemical window and mechanical property of the sulfide solid electrolyte are widened, the mechanical stability and electrochemical stability of the sulfide solid electrolyte and a positive electrode material are improved, and the interface reaction of the sulfide solid electrolyte is further inhibited.

The invention discloses a composite solid electrolyte and a preparation method and application thereof, and belongs to the technical field of solid lithium batteries. The composite solid electrolyte comprises a polymer matrix, a lithium salt and a lithium ion modified ionic metal organic framework (MOF) material. The metal center of the ion-conducting MOF material can be selected from Zr, Ti, Hf and the like, and the organic ligand can be selected from organic acids containing sulfydryl, sulfo groups and the like. The MOF material can effectively inhibit crystallization of a polymer matrix and increase the proportion of an amorphous region, Lewis acid sites on the surface of the MOF material can promote dissociation of lithium salt, and a lithium ion coordination channel formed in the MOF material can provide an extra rapid transmission path for lithium ions. When the electrolyte is applied to the solid-state lithium battery, the growth of lithium dendrites can be effectively inhibited, and the rate capability, the cycling stability and the safety of the battery can be remarkably improved.

A solid-state battery, preferably a pouch cell, includes a cathode including cathode active material comprising Li ions, graphene, and optionally a binder; an electrolyte; and an anode, preferably a lithium anode, wherein said electrolyte is positioned in between said cathode and said anode.

The invention provides a sulfide solid electrolyte and a preparation method and application thereof, and relates to the technical field of lithium ion batteries. The preparation method comprises the following steps: S1, carrying out dry ball milling treatment on raw materials Li2S, P2S5 and LiX according to a required stoichiometric ratio, so that the raw materials are amorphized; s2, adding a solvent into the non-crystallized raw material obtained in the step S1, and carrying out wet ball-milling treatment to obtain a precursor with the particle size of 0.05-0.5 mu m; s3, the solvent is removed from the precursor slurry, the sulfide solid electrolyte is obtained through solid-phase sintering, all the steps are carried out in an inert atmosphere, and X is a halogen element. According to the present invention, the non-crystallization of the raw material is achieved through the dry ball milling, the uniform precursor slurry with the small particle size is obtained by combining the wet ball milling, and the sub-micron / nano-scale pure phase electrolyte material can be obtained after the sintering treatment, such that the electrode / electrolyte interface contact is improved, the impedance is reduced, and the battery performance is significantly improved.

The invention discloses a lithium ion battery, a preparation method thereof and a lithium ion battery module. The lithium ion battery comprises a positive electrode, a first solid electrolyte membrane and a negative electrode which are sequentially stacked in the thickness direction, the lithium ion battery also comprises a second solid electrolyte membrane; the second solid electrolyte membrane is positioned between the positive electrode and the first solid electrolyte membrane; wherein the second solid electrolyte membrane is provided with a plurality of first through holes, and the first through holes are filled with a positive electrode lithium supplement agent. The lithium ion battery disclosed by the invention is provided with the double-layer composite solid electrolyte membrane, and the positive electrode lithium supplementing agent is filled in the through hole formed in the solid electrolyte membrane in contact with the positive electrode, so that active lithium consumed when the lithium ion battery is charged for the first time can be effectively supplemented, the total capacity and the energy density of the lithium ion battery are improved, and the cycle life of the lithium ion battery is prolonged.

The invention discloses a multilayer composite solid electrolyte membrane, a preparation method and a prepared solid-state battery, the multilayer composite solid electrolyte membrane sequentially comprises a three-dimensional polymer networked solid electrolyte, a LiPON layer and a polydopamine layer, the thickness of the three-dimensional polymer networked solid electrolyte is 20-40 [mu] m, and the thickness of the polydopamine layer is less than 100 nm. By adopting the synergistic effect of the silane coupling agent modified LLZO and the degraded chitosan, a better ion transmission coordination effect can be provided, and the efficiency of an ion channel is improved. The dendritic crystal inhibition efficiency is improved, obvious cracks are avoided after 1000 times of circulation, the composite material is applied to a solid-state battery, the cycle life of the battery is prolonged, and the capacity retention rate is 95% after 1000 times of circulation. The mechanical toughness of the solid electrolyte is improved, and the elongation at break can reach 130%. A water-phase solvent is used in the whole preparation process, use of an organic solvent is avoided, energy consumption is reduced by 40%, no VOC is discharged in the whole process, and the method is green, safe and environmentally friendly.

The invention relates to a composite solid-state electrolyte membrane and a preparation method thereof, a lithium ion battery and an electric device, the composite solid-state electrolyte membrane comprises a lithium phosphorus oxygen nitrogen solid-state electrolyte, the general formula of the lithium phosphorus oxygen nitrogen solid-state electrolyte is LixPOyNz, x is greater than 2.7 and less than or equal to 3, zlt; 0.45, 3 < (y + z) < 4; along the thickness direction of the solid electrolyte membrane, the nitrogen doping ratio of the lithium-phosphorus-oxygen-nitrogen solid electrolyte in the composite solid electrolyte membrane is gradually increased, and the corresponding oxidation stoichiometric number is gradually reduced. According to the composite solid electrolyte membrane, the capacity retention ratio, the cycling stability and the safety of the lithium ion battery are improved.

The invention belongs to the technical field of solid-state batteries, and provides a lithium-ion solid-state electrolyte and a preparation method and application thereof. The lithium ion solid electrolyte comprises a polymer matrix, a lithium salt, a polar organic compound, a polymer monomer (comprising a first monomer and a second monomer) and an anion acceptor. The preparation method comprises the following steps: mixing a lithium salt and a polar organic compound to obtain a eutectic mixture; mixing a polymer matrix, a first monomer, a second monomer and an anion acceptor with the eutectic mixture to obtain a precursor solution; and coating a substrate with the precursor solution, curing and drying. The invention also discloses a solid-state lithium ion battery comprising the lithium-ion solid-state electrolyte and a manufacturing device of the solid-state lithium ion battery. The lithium ion solid electrolyte disclosed by the invention is high in room-temperature ionic conductivity, excellent in tensile strength, tensile elongation and high in breaking strength and incombustibility, and the lithium ion transference number is increased; therefore, the battery has long-term cycle stability, and the problem of electrode stress failure under low stacking pressure is solved.

The electrochemical device includes: a case including a recessed container having a bottom and a side wall, and a cap covering the opening of the recessed container; a power generation element including a laminate having an electrode layer, an electrode layer and a solid electrolyte layer laminated together and contained in the interior space of the case such that the bottom and electrode layer face each other; and a conductive plate located adjacent to the opening of the recessed container and positioned between the electrode layer and cap. The recessed container includes insertion holes with openings in the upper end surface of the side wall. The conductive plate includes elastic locking portions located on edges thereof and corresponding in position to the insertion holes. With each elastic locking portion inserted in an insertion hole, the tip portion of the elastic locking portion presses a side surface of the insertion hole.

A battery cell includes C cathode electrodes, A anode electrodes, and S separators, where A, C, and S are integers. Each of the A anode electrodes includes an annealed aluminum foil layer and a lithium aluminum layer arranged on one side of the annealed aluminum foil layer.

The invention provides a sulfide solid electrolyte with an MOF structure, and a preparation method and application thereof, the process is designed from a molecular level, and lithium ions and sulfur elements are used as basic components for constructing an MOF skeleton through in-situ combination of excellent ion conduction capability of the sulfide electrolyte and structural advantages of an MOF material; the bulk sulfide electrolyte with a regular three-dimensional multi-channel crystalline MOF structure is directly synthesized and constructed by taking a sulfur element as an inherent component of an MOF skeleton in a breakthrough manner, so that the intrinsic design of the sulfide MOF skeleton electrolyte is realized, and the problems of interface bonding, performance stability and ion transmission path are fundamentally solved; a sulfur element in the electrolyte is derived from sulfur atoms (such as-SH and-S-) of a ligand and participates in construction of an MOF skeleton, the electrolyte has the advantages of good interface stability, regular ion transmission channels, adjustable mechanical properties and the like, and the problems of poor interface stability, irregular ion transmission paths and the like of a sulfide electrolyte in the prior art are solved.

The present invention provides a composition for forming a gel polymer electrolyte which includes a lithium salt; an organic solvent; and a crosslinking compound represented by Formula 1. wherein in Formula 1, L1, L2, L3, and L4 are each independently selected from a direct bond or an alkylene group having 1 to 3 carbon atoms, L5 and L6 are each independently an alkylene group having 1 to 20 carbon atoms in which at least one methylene group is optionally substituted with an ether group and at least one hydrogen is substituted with fluorine, and R1 and R2 are each independently selected from hydrogen, an alkyl group having 1 to 3 carbon atoms, or a halogen.

The invention relates to the technical field of batteries, and provides a flexible lithium metal battery based on a dynamic self-repairing electrolyte and a gradient artificial SEI membrane and a preparation method of the flexible lithium metal battery. The battery comprises a battery cell and a flexible packaging shell, wherein the battery cell comprises a negative electrode structure, a diaphragm and a positive electrode structure which are stacked in sequence; the negative electrode structure comprises a three-dimensional fiber cloth current collector, a lithium metal negative electrode active layer, a gradient artificial SEI film and a dynamic self-repairing solid electrolyte layer; the positive electrode structure comprises a positive electrode current collector and a positive electrode active layer loaded on the positive electrode current collector. Wherein the positive electrode active layer and the lithium metal negative electrode active layer are loaded in a segmented coating mode, and flexible hinges are correspondingly formed in segmented interval areas of the positive electrode active layer and the lithium metal negative electrode active layer. The invention has the advantages that crack repair and high ionic conductivity are realized through the dynamic self-repairing electrolyte, the gradient SEI film improves the interface stability, the structure is optimized, the problems of interface failure and the like under the bending of the traditional battery are solved, and high flexibility, safety and energy density are realized at the same time.

This application relates to the field of hydrogel electrolyte technology, specifically disclosing a modified sodium alginate crosslinked hydrogel electrolyte, its preparation method, and its applications. This application reduces environmental toxicity and pollution by introducing modified sodium alginate as a crosslinking agent into the hydrogel electrolyte. The interaction between sodium alginate and zinc ions inhibits zinc dendrite formation, regulates the interfacial growth between the negative electrode and the electrolyte, and thus extends battery life; it also has a certain inhibitory effect on hydrogen evolution reaction. This application can prepare the modified sodium alginate crosslinked hydrogel electrolyte using a simple free radical polymerization method. Furthermore, compared to conventional aqueous batteries, the hydrogel electrolyte can better control the interfacial growth of the positive and negative electrodes.

A nanocomposite electrode including a substrate, a binding compound, a conductive additive, and NiO / Fe2VO4 nanoparticles. The NiO / Fe2VO4 nanoparticles have a substantially spherical shape. A mixture of the binding compound, the conductive additive and the NiO / Fe2VO4 nanoparticles, is at least partially coated on a first surface of the substrate. A method of making the NiO / Fe2VO4 nanoparticles is described.

Example embodiments include electrode assemblies and all-solid-state batteries. The electrode assembly includes a first solid electrolyte layer, a positive electrode layer, a second solid electrolyte layer, and a negative electrode layer that are disposed along a radial direction of the electrode assembly. The positive electrode layer includes a positive electrode current collector, a first positive electrode active material layer on a first surface of the positive electrode current collector and in contact with the first solid electrolyte layer. A first width of the first positive electrode active material layer is less than a second width of the first solid electrolyte layer, a first buffer structure adjacent to a first side of the first positive electrode active material layer, and a second buffer structure adjacent to a second side of the first positive electrode active material layer.

Provided is a battery including a positive electrode layer, a negative electrode layer, and an electrolyte layer disposed between the positive electrode layer and the negative electrode layer, in which the electrolyte layer contains a polymer having an ability to preferentially conduct metal ions, and a thickness ratio between the positive electrode layer and the electrolyte layer is 10:1 to 0.5:1.

The present invention relates to a method for preparing lithium sulfide, according to the present invention, when preparing lithium sulfide by a reaction between a lithium raw material and hydrogen sulfide, the reaction is carried out under relatively mild conditions compared to the prior art, so that frequent maintenance or replacement due to corrosion and failure of a reactor and various pipes is not required, thereby improving the economical efficiency of the process. Further, by reusing the unreacted hydrogen sulfide from which moisture has been removed and the solvent, process costs can be reduced, and economical efficiency can be ensured during mass production. Furthermore, moisture and water vapor generated in the lithium sulfide generation reaction are effectively removed, thereby preventing a reverse reaction for generating lithium hydroxide, promoting a positive reaction, and producing high-quality lithium sulfide with high purity and high yield. In addition, the particle size can be adjusted in units, and a separate pulverizing space or pulverizing table is not required, so that convenience and mass productivity are excellent.

Provided are a wide-temperature-range solid-state electrolyte, a preparation method thereof and use thereof in solid-state lithium metal batteries. The preparation method includes: dissolving a lithium salt and a magnesium salt in a solvent to obtain a mixed salt solution; and mixing the mixed salt solution with an ammonia fluoride solution, subjecting a resulting mixture to reaction, and subjecting a resulting reaction product to centrifugation, washing, and drying in sequence to obtain magnesium-doped lithium fluoride nanoparticles; and mixing the magnesium-doped lithium fluoride nanoparticles, a liquid plasticizer, a polymer monomer and a thermal initiator to obtain a liquid precursor, and subjecting the liquid precursor to curing to obtain the wide-temperature-range solid-state electrolyte, where the polymer monomer is a mixture of ethoxylated trimethylolpropane triacrylate and hexafluorobutyl methacrylate.

The invention belongs to the field of polymer electrolyte. Polyurethane (PU) which is high in strength, good in elasticity, convenient to form and capable of being self-repaired is selected as a substrate of the solid electrolyte. A deep eutectic solvent (DES) which can be copolymerized with the lithium salt is selected to enhance the polarity of the system and promote dissociation of the lithium salt, so that the conductivity of the solid electrolyte is improved. The invention provides a preparation method of a DES copolymerization modified self-repairing polyurethane-based solid electrolyte. The preparation method comprises the following steps: preparing a long-chain polyurethane prepolymer; preparing a self-repairing prepolymer; performing double-bond modification on the self-repairing prepolymer; preparing DES containing lithium salt and double bonds; uniformly mixing the self-repairing polyurethane prepolymer with the end capped by double bonds and DES (diethylbenzene sulfonate); pouring into a mold and curing to obtain the DES / polyurethane-based solid electrolyte membrane; and preparing the solid-state lithium battery. The solid electrolyte disclosed by the invention is free from slag falling and liquid leakage, capable of self-repairing, high in ion mobility, simple in preparation process, low in cost and outstanding in performance, and has a wide market application prospect.

The invention provides a Li7P3S11 doped solid electrolyte design and optimization method based on artificial intelligence. According to the method, at least 50 variant crystal structures containing Cl, Br and other doped elements are generated through a GAN or diffusion model; synchronously predicting an ionic conductivity sigma and an air stability score S by using a GNN model of a CGCNN or M3GNet architecture; and screening at least five optimal structures according to a'double-high 'principle for experimental synthesis, updating the model through data closed-loop feedback, and achieving a performance target through 3-5 rounds of iteration. The method breaks through the limitation of the traditional technology, is high in prediction precision, and shortens the research and development period from 3-5 years to 6 months. The room temperature ionic conductivity gt of the prepared solid electrolyte; the capacity retention rate gt after being exposed for 48 hours at 25 DEG C under the conditions of 20 mS / cm, 50% relative humidity and 20 mS / cm; the method is suitable for all-solid-state lithium batteries, and the performance of the batteries is remarkably improved.

The present invention provides an electrode assembly including a plurality of electrode structures each including a positive electrode, a negative electrode, and a solid electrolyte layer disposed between the positive electrode and the negative electrode, the electrode assembly including a polymer layer on both ends of the electrode assembly, and a secondary battery including the electrode assembly.

The application discloses a kind of full solid-state battery and its preparation method and application, it is related to solid-state battery technical field.The edge of positive active layer is attached with solidified insulating glue, so as to use the solidified insulating glue to fill the size difference between the positive active layer and the negative active layer, and the end of the positive active layer and the negative active layer is flush, the insulating glue plays a supporting role under extrusion, avoids the problems such as collapse and short circuit caused by the size difference between the positive active layer and the negative active layer;The insulating glue at the edge can be bonded with the negative electrode under high pressure, and when the positive electrode is charged and discharged, the cycle performance difference caused by the volume change of the positive electrode during charging and discharging can be effectively alleviated, and the cycle of the battery is improved;It can also effectively avoid the occurrence of problems such as the edge of the positive electrode dropping material.By setting electrolyte film between the positive active layer and the negative active layer, the impedance between the electrolyte film and the electrode sheet is reduced by using the ionic liquid treatment layer on the electrolyte film, and the battery performance is improved.

Provided is an all-solid-state lithium batteries (ASSLBs), Li-based cathode materials and structures incorporated therein and to methods of producing said materials, structures and batteries.