3006results about "Solid electrolytes" patented technology

The present disclosure provides a solid electrolyte composition that can suppress deterioration in ion conductivity of an ionic solid electrolyte material. The solid electrolyte composition according to the present disclosure contains a sulfur element-free ionic solid electrolyte material and an organic solvent, where the organic solvent includes at least one selected from the group consisting of a hydrocarbon and a compound having a functional group; and the functional group is at least one selected from the group consisting of an ether group, a halogen group, and a Si—O—C group.

A positive electrode material of the present disclosure includes: a positive electrode active material; and a first solid electrolyte material coating at least partially a surface of the positive electrode active material, wherein the first solid electrolyte material includes Li, Ti, M1, and F, and the M1 is at least one element selected from the group consisting of Ca, Mg, Al, Y, and Zr.

The present invention relates to a method of manufacturing an electrode of an all-in-one battery comprising the steps of mixing an electrode active material, a solid electrolyte and a first binder with a first solvent to prepare a primary slurry; drying the primary slurry to prepare a mixture powder; mixing the mixture powder, a conductive agent, and a second binder with a second solvent to prepare a secondary slurry; and coating the secondary slurry on a current collector.

The invention discloses a solid electrolyte, a preparation method thereof and an all-solid-state battery, and belongs to the technical field of solid electrolytes. According to the preparation method, a nano inert oxide and a solid electrolyte raw material are compounded through mechanical grinding, and the solid electrolyte with a core-shell structure is prepared; the device comprises an inner core, an interface layer and a shell from inside to outside, the inner core is a solid electrolyte matrix, the interface layer is a transition layer generated by reaction of the solid electrolyte matrix and a nano inert oxide, and the shell is a nano inert oxide layer. The material combines the advantages of high moisture resistance and wide electrochemical window of the nano inert oxide and the characteristics of high ionic conductivity and excellent mechanical property of the solid electrolyte, and the comprehensive performance of the material is remarkably improved through the synergistic effect of the components. The composite structure design not only solves the problem of performance limitation of a single material system, but also realizes collaborative optimization of ionic conductivity, environmental adaptability and electrochemical stability while ensuring the material stability.

The invention discloses a composite solid electrolyte and a preparation method and application thereof, and belongs to the technical field of solid lithium batteries. The composite solid electrolyte comprises a polymer matrix, a lithium salt and a lithium ion modified ionic metal organic framework (MOF) material. The metal center of the ion-conducting MOF material can be selected from Zr, Ti, Hf and the like, and the organic ligand can be selected from organic acids containing sulfydryl, sulfo groups and the like. The MOF material can effectively inhibit crystallization of a polymer matrix and increase the proportion of an amorphous region, Lewis acid sites on the surface of the MOF material can promote dissociation of lithium salt, and a lithium ion coordination channel formed in the MOF material can provide an extra rapid transmission path for lithium ions. When the electrolyte is applied to the solid-state lithium battery, the growth of lithium dendrites can be effectively inhibited, and the rate capability, the cycling stability and the safety of the battery can be remarkably improved.

A solid-state battery, preferably a pouch cell, includes a cathode including cathode active material comprising Li ions, graphene, and optionally a binder; an electrolyte; and an anode, preferably a lithium anode, wherein said electrolyte is positioned in between said cathode and said anode.

The invention discloses a lithium ion battery, a preparation method thereof and a lithium ion battery module. The lithium ion battery comprises a positive electrode, a first solid electrolyte membrane and a negative electrode which are sequentially stacked in the thickness direction, the lithium ion battery also comprises a second solid electrolyte membrane; the second solid electrolyte membrane is positioned between the positive electrode and the first solid electrolyte membrane; wherein the second solid electrolyte membrane is provided with a plurality of first through holes, and the first through holes are filled with a positive electrode lithium supplement agent. The lithium ion battery disclosed by the invention is provided with the double-layer composite solid electrolyte membrane, and the positive electrode lithium supplementing agent is filled in the through hole formed in the solid electrolyte membrane in contact with the positive electrode, so that active lithium consumed when the lithium ion battery is charged for the first time can be effectively supplemented, the total capacity and the energy density of the lithium ion battery are improved, and the cycle life of the lithium ion battery is prolonged.

The invention discloses a multilayer composite solid electrolyte membrane, a preparation method and a prepared solid-state battery, the multilayer composite solid electrolyte membrane sequentially comprises a three-dimensional polymer networked solid electrolyte, a LiPON layer and a polydopamine layer, the thickness of the three-dimensional polymer networked solid electrolyte is 20-40 [mu] m, and the thickness of the polydopamine layer is less than 100 nm. By adopting the synergistic effect of the silane coupling agent modified LLZO and the degraded chitosan, a better ion transmission coordination effect can be provided, and the efficiency of an ion channel is improved. The dendritic crystal inhibition efficiency is improved, obvious cracks are avoided after 1000 times of circulation, the composite material is applied to a solid-state battery, the cycle life of the battery is prolonged, and the capacity retention rate is 95% after 1000 times of circulation. The mechanical toughness of the solid electrolyte is improved, and the elongation at break can reach 130%. A water-phase solvent is used in the whole preparation process, use of an organic solvent is avoided, energy consumption is reduced by 40%, no VOC is discharged in the whole process, and the method is green, safe and environmentally friendly.

The electrochemical device includes: a case including a recessed container having a bottom and a side wall, and a cap covering the opening of the recessed container; a power generation element including a laminate having an electrode layer, an electrode layer and a solid electrolyte layer laminated together and contained in the interior space of the case such that the bottom and electrode layer face each other; and a conductive plate located adjacent to the opening of the recessed container and positioned between the electrode layer and cap. The recessed container includes insertion holes with openings in the upper end surface of the side wall. The conductive plate includes elastic locking portions located on edges thereof and corresponding in position to the insertion holes. With each elastic locking portion inserted in an insertion hole, the tip portion of the elastic locking portion presses a side surface of the insertion hole.

A battery cell includes C cathode electrodes, A anode electrodes, and S separators, where A, C, and S are integers. Each of the A anode electrodes includes an annealed aluminum foil layer and a lithium aluminum layer arranged on one side of the annealed aluminum foil layer.

The invention provides a sulfide solid electrolyte with an MOF structure, and a preparation method and application thereof, the process is designed from a molecular level, and lithium ions and sulfur elements are used as basic components for constructing an MOF skeleton through in-situ combination of excellent ion conduction capability of the sulfide electrolyte and structural advantages of an MOF material; the bulk sulfide electrolyte with a regular three-dimensional multi-channel crystalline MOF structure is directly synthesized and constructed by taking a sulfur element as an inherent component of an MOF skeleton in a breakthrough manner, so that the intrinsic design of the sulfide MOF skeleton electrolyte is realized, and the problems of interface bonding, performance stability and ion transmission path are fundamentally solved; a sulfur element in the electrolyte is derived from sulfur atoms (such as-SH and-S-) of a ligand and participates in construction of an MOF skeleton, the electrolyte has the advantages of good interface stability, regular ion transmission channels, adjustable mechanical properties and the like, and the problems of poor interface stability, irregular ion transmission paths and the like of a sulfide electrolyte in the prior art are solved.

The present invention provides a composition for forming a gel polymer electrolyte which includes a lithium salt; an organic solvent; and a crosslinking compound represented by Formula 1. wherein in Formula 1, L1, L2, L3, and L4 are each independently selected from a direct bond or an alkylene group having 1 to 3 carbon atoms, L5 and L6 are each independently an alkylene group having 1 to 20 carbon atoms in which at least one methylene group is optionally substituted with an ether group and at least one hydrogen is substituted with fluorine, and R1 and R2 are each independently selected from hydrogen, an alkyl group having 1 to 3 carbon atoms, or a halogen.

This application relates to the field of hydrogel electrolyte technology, specifically disclosing a modified sodium alginate crosslinked hydrogel electrolyte, its preparation method, and its applications. This application reduces environmental toxicity and pollution by introducing modified sodium alginate as a crosslinking agent into the hydrogel electrolyte. The interaction between sodium alginate and zinc ions inhibits zinc dendrite formation, regulates the interfacial growth between the negative electrode and the electrolyte, and thus extends battery life; it also has a certain inhibitory effect on hydrogen evolution reaction. This application can prepare the modified sodium alginate crosslinked hydrogel electrolyte using a simple free radical polymerization method. Furthermore, compared to conventional aqueous batteries, the hydrogel electrolyte can better control the interfacial growth of the positive and negative electrodes.

Example embodiments include electrode assemblies and all-solid-state batteries. The electrode assembly includes a first solid electrolyte layer, a positive electrode layer, a second solid electrolyte layer, and a negative electrode layer that are disposed along a radial direction of the electrode assembly. The positive electrode layer includes a positive electrode current collector, a first positive electrode active material layer on a first surface of the positive electrode current collector and in contact with the first solid electrolyte layer. A first width of the first positive electrode active material layer is less than a second width of the first solid electrolyte layer, a first buffer structure adjacent to a first side of the first positive electrode active material layer, and a second buffer structure adjacent to a second side of the first positive electrode active material layer.

Provided is a battery including a positive electrode layer, a negative electrode layer, and an electrolyte layer disposed between the positive electrode layer and the negative electrode layer, in which the electrolyte layer contains a polymer having an ability to preferentially conduct metal ions, and a thickness ratio between the positive electrode layer and the electrolyte layer is 10:1 to 0.5:1.

The present invention relates to a method for preparing lithium sulfide, according to the present invention, when preparing lithium sulfide by a reaction between a lithium raw material and hydrogen sulfide, the reaction is carried out under relatively mild conditions compared to the prior art, so that frequent maintenance or replacement due to corrosion and failure of a reactor and various pipes is not required, thereby improving the economical efficiency of the process. Further, by reusing the unreacted hydrogen sulfide from which moisture has been removed and the solvent, process costs can be reduced, and economical efficiency can be ensured during mass production. Furthermore, moisture and water vapor generated in the lithium sulfide generation reaction are effectively removed, thereby preventing a reverse reaction for generating lithium hydroxide, promoting a positive reaction, and producing high-quality lithium sulfide with high purity and high yield. In addition, the particle size can be adjusted in units, and a separate pulverizing space or pulverizing table is not required, so that convenience and mass productivity are excellent.

Provided are a wide-temperature-range solid-state electrolyte, a preparation method thereof and use thereof in solid-state lithium metal batteries. The preparation method includes: dissolving a lithium salt and a magnesium salt in a solvent to obtain a mixed salt solution; and mixing the mixed salt solution with an ammonia fluoride solution, subjecting a resulting mixture to reaction, and subjecting a resulting reaction product to centrifugation, washing, and drying in sequence to obtain magnesium-doped lithium fluoride nanoparticles; and mixing the magnesium-doped lithium fluoride nanoparticles, a liquid plasticizer, a polymer monomer and a thermal initiator to obtain a liquid precursor, and subjecting the liquid precursor to curing to obtain the wide-temperature-range solid-state electrolyte, where the polymer monomer is a mixture of ethoxylated trimethylolpropane triacrylate and hexafluorobutyl methacrylate.

The invention provides a Li7P3S11 doped solid electrolyte design and optimization method based on artificial intelligence. According to the method, at least 50 variant crystal structures containing Cl, Br and other doped elements are generated through a GAN or diffusion model; synchronously predicting an ionic conductivity sigma and an air stability score S by using a GNN model of a CGCNN or M3GNet architecture; and screening at least five optimal structures according to a'double-high 'principle for experimental synthesis, updating the model through data closed-loop feedback, and achieving a performance target through 3-5 rounds of iteration. The method breaks through the limitation of the traditional technology, is high in prediction precision, and shortens the research and development period from 3-5 years to 6 months. The room temperature ionic conductivity gt of the prepared solid electrolyte; the capacity retention rate gt after being exposed for 48 hours at 25 DEG C under the conditions of 20 mS / cm, 50% relative humidity and 20 mS / cm; the method is suitable for all-solid-state lithium batteries, and the performance of the batteries is remarkably improved.

The present invention provides an electrode assembly including a plurality of electrode structures each including a positive electrode, a negative electrode, and a solid electrolyte layer disposed between the positive electrode and the negative electrode, the electrode assembly including a polymer layer on both ends of the electrode assembly, and a secondary battery including the electrode assembly.

The application discloses a kind of full solid-state battery and its preparation method and application, it is related to solid-state battery technical field.The edge of positive active layer is attached with solidified insulating glue, so as to use the solidified insulating glue to fill the size difference between the positive active layer and the negative active layer, and the end of the positive active layer and the negative active layer is flush, the insulating glue plays a supporting role under extrusion, avoids the problems such as collapse and short circuit caused by the size difference between the positive active layer and the negative active layer;The insulating glue at the edge can be bonded with the negative electrode under high pressure, and when the positive electrode is charged and discharged, the cycle performance difference caused by the volume change of the positive electrode during charging and discharging can be effectively alleviated, and the cycle of the battery is improved;It can also effectively avoid the occurrence of problems such as the edge of the positive electrode dropping material.By setting electrolyte film between the positive active layer and the negative active layer, the impedance between the electrolyte film and the electrode sheet is reduced by using the ionic liquid treatment layer on the electrolyte film, and the battery performance is improved.

Provided is an all-solid-state lithium batteries (ASSLBs), Li-based cathode materials and structures incorporated therein and to methods of producing said materials, structures and batteries.

The invention relates to the technical field of batteries, in particular to sulfide solid electrolyte, a preparation method thereof and a solid-state battery. The sulfide solid electrolyte comprises sulfide and polyvinylpyrrolidone at least partially coating the periphery of the sulfide. According to the sulfide solid-state electrolyte, the surface of the sulfide is coated with a layer of polyvinylpyrrolidone, so that the risk of agglomeration of the sulfide solid-state electrolyte is reduced, and the electronic conductivity of the sulfide solid-state electrolyte is reduced.

The application provides a modified lithium-rich manganese-based material, a modification method of the lithium-rich manganese-based material, a secondary battery and an electric device. The modified lithium-rich manganese-based material comprises a lithium-rich manganese-based material co-doped with anions and cations and a fast ion conductor material, and a chemical formula of the lithium-rich manganese-based material is xLi2MnO3·(1-x)LiNi y Co z Mn a O2, wherein 0

A coated active material 130 according to the present disclosure comprises: an active material 110; and a coating layer 111 that coats at least some of the surface of the active material 110. The coating layer 111 contains a first coating material. A coarse powder and a fine powder, which are contained in a powder of the coated active material 130, are classified by air classification so as to be classified at a mass% ratio of coarse powder to fine powder of 9:1. The value of R2 / R1 is less than 7.1, where R1 is defined as the mass% content ratio of the first coating material in the coarse powder, and R2 is defined as the mass% content ratio of the first coating material in the fine powder.

Provided is a negative electrode comprising a current collector with tensile strength ranging from about 1,000 MPa to 2,000 MPa and an active material layer. The current collector may be a Fe—Ni alloy foil containing nickel (Ni) from about 10 wt % to 60 wt % with an average grain size of less than 10 nm. An all-solid-state battery including this negative electrode and a method for its preparation are also described. The method involves stacking and isostatic pressing, with specific parameters for pressure, temperature, and time.

The present disclosure provides an electrolyte composition containing an organic solvent and a polymer having an ability to conduct alkali metal ions, the electrolyte composition being characterized in that the total number of donors of the organic solvent contained in the electrolyte composition is 16.5 or more (wherein n is the total number of organic solvents contained in the electrolyte composition and is 1 or more, n is an integer of 1 or more, and n is an integer of 1 or more). DNi is the donor number of the ith organic solvent, and fi is the mass fraction of the ith organic solvent.

Provided is a composite active material that is capable of more suppressing deterioration of an active material caused by the moisture of the composite active material than a conventional composite active material by increasing a permissible water content of a layer of the composite active material. The composite active material that is used for solid-state batteries includes: an active material; a first coat layer that contains a fluoride-containing first solid electrolyte, the first coat layer coating at least part of a surface of the active material; and a second coat layer that contains a sulfide-containing second solid electrolyte, and a solvent, the second coat layer coating at least part of the first coat layer, wherein a water content of the composite active material at 200° C. measures at most 823 ppm on a Karl Fischer titrator.

A moisture electric generating device comprising: a first electrode and a second electrode; and disposed between the first electrode and the second electrode and a functional layer which releases electrical charge carriers; the functional layer includes at least two sub layers; a first sub layer acting as a moisture reservoir to a second sublayer, to provide moisture to the second sublayer; the second sub layer which produces electrical charge carriers as a function of moisture available from the first sub layer.

Provided is an all solid state battery with excellent productivity. An all solid state battery according to the present invention relates to goals 3, 7, 11, and 12 of the SDGs.　An all solid state battery according to the present invention is characterized in comprising a laminated body provided with a positive electrode, a negative electrode, and a solid electrolyte sheet between the positive electrode and the negative electrode, wherein: the solid electrolyte sheet includes a porous base material and a solid electrolyte; the solid electrolyte is held in voids in the porous base material; the solid electrolyte covers both surfaces of the porous base material; in the solid electrolyte sheet, the porous base material is positioned offset to the positive electrode side in the thickness direction of the solid electrolyte sheet; and the thickness of the solid electrolyte sheet is not more than 50 μm.

The invention discloses a preparation method of a sulfide solid electrolyte, and relates to the field of solid-state batteries, the preparation method comprises the following steps: preparing Li2S-coated LiCl core-shell nanoparticles, and carrying out airflow collision grinding on the Li2S-coated LiCl core-shell nanoparticles and P2S5 nanopowder to obtain composite powder; the composite powder is placed in a reaction furnace for heating deposition, then heating crystallization is carried out, and Li6PS5Cl nanoparticles are obtained; the Li6PS5Cl nanoparticles are placed in a ball milling tank to be treated, then annealing treatment is conducted, and the sulfide solid electrolyte is obtained after treatment is completed. Through combination of the core-shell structure precursor and the vapor deposition technology, the core contradiction that nanocrystallization and high ionic conductivity are difficult to consider at the same time in the sulfide solid electrolyte field is effectively solved, and the problems of interface contact defects caused by micron-sized particles and crystal defects caused by mechanical refinement in a traditional process are effectively solved; the problem is solved through construction of Li2S-coated LiCl core-shell nanoparticles and activation treatment of airflow on collision and grinding.