5418results about "Solid electrolytes" patented technology

The invention relates to catalytically coated anion exchange membranes and their production. The catalytically active coated anion exchange membranes are used in electrochemical cells, in particular for water electrolysis. The object of the invention was to provide a process for producing an electrocatalytically active coated anion exchange membrane whose coating is porous and thus the electrocatalytically active centers located in the coating are easily accessible to the reactants. A basic idea of the process according to the invention is to incorporate particulate inorganic material into the catalyst coating as a placeholder, to solidify the coating, and then to leach the inorganic material out of the coating. The leaching converts the inorganic material into a water-soluble product that can be easily washed out of the coating.What remains are voids (pores) where the particulate inorganic material was previously located within the coating. The inorganic material therefore assumes the function of a structure-imparting agent within the coating composition, which is lost during the catalytically active coating process.

The invention relates to a composite solid electrolyte membrane with high ceramic content and a preparation method and application thereof. The preparation method comprises the following steps: mixing ceramic solid electrolyte particles activated by a silane coupling agent with an in-situ polymerization solution containing a cross-linking agent, an organic monomer, a plasticizer, a lithium salt, an ultraviolet light initiator and a thermal initiator to form solid electrolyte slurry, wherein the ceramic solid electrolyte particles account for 60-90% of the total mass of the composite solid electrolyte membrane; the preparation method comprises the following steps: coating a positive pole piece with solid electrolyte slurry, initiating shallow organic matter monomers and a cross-linking agent to generate in-situ polymerization through an ultraviolet light initiator, covering a negative pole piece for hot pressing treatment, initiating residual organic matter monomers and the cross-linking agent to generate in-situ polymerization through a thermal initiator, and forming a composite electrolyte membrane with high ceramic content. The invention also discloses an all-solid-state battery containing the composite solid electrolyte membrane. The solid-state battery containing the in-situ formed composite solid-state electrolyte membrane has relatively high cycling stability.

A solid electrolyte material and a preparation method therefor, a solid electrolyte, a semi-solid electrolyte, a positive electrode, and a battery. The solid electrolyte material comprises a compound represented by the following general formula: Aa(M1bM2c)Xd, wherein A comprises one or more of Li, Na, K, Cu and Ag, X is halogen, M1 is a main element, M1 is selected from among one of Ga, Y, In, Mg, Sr, Sc, Al, Fe, Zr, Hf, Ta, Nb, W, Mn, Zn, Co, Mo, Sn, Ca, Pb, Ti, Ru and a lanthanide metal element, M2 is a doping element, M2 comprises one or more elements of groups IIA, IIB, IIIA, IIIB, IVA, IVB, VA and VB, b is greater than the molar ratio of any element in M2, 0.5≤a≤5, 0.2≤b≤2, 0.2≤c≤2, d=a*ε1+b*ε2+c*ε3, ε1 is the weighted average valence of A, ε2 is the weighted average valence of M1, and ε3 is the weighted average valence of M2.

The present disclosure provides a solid electrolyte composition that can suppress deterioration in ion conductivity of an ionic solid electrolyte material. The solid electrolyte composition according to the present disclosure contains a sulfur element-free ionic solid electrolyte material and an organic solvent, where the organic solvent includes at least one selected from the group consisting of a hydrocarbon and a compound having a functional group; and the functional group is at least one selected from the group consisting of an ether group, a halogen group, and a Si—O—C group.

The present disclosure provides a solid electrolyte composition that can suppress deterioration in ion conductivity of an ionic solid electrolyte material. The solid electrolyte composition according to the present disclosure contains a sulfur element-free ionic solid electrolyte material and an organic solvent, where the organic solvent includes at least one selected from the group consisting of a hydrocarbon and a compound having a functional group; and the functional group is at least one selected from the group consisting of an ether group, a halogen group, and a Si—O—C group.

A positive electrode material of the present disclosure includes: a positive electrode active material; and a first solid electrolyte material coating at least partially a surface of the positive electrode active material, wherein the first solid electrolyte material includes Li, Ti, M1, and F, and the M1 is at least one element selected from the group consisting of Ca, Mg, Al, Y, and Zr.

The invention discloses a gel solid electrolyte, a preparation method thereof and a lithium ion battery, and relates to the technical field of batteries. The gel solid electrolyte comprises the following components: a solvent, a lithium salt, an inorganic salt or an organic small molecule additive, an ester cross-linking agent polymeric monomer, a silazane polymeric monomer, a diluent and an initiator, the invention also provides a lithium ion battery comprising the gel solid electrolyte and a preparation method of the lithium ion battery. The preparation method has the beneficial effects that by introducing the silazane polymeric monomer and the ester cross-linking agent polymeric monomer, the silazane polymeric monomer and the ester cross-linking agent polymeric monomer can be subjected to a copolymerization reaction, so that in-situ curing of the electrolyte is realized. The silazane fragment in the high-molecular polymer skeleton can effectively realize the constraint on strong Lewis acid substances such as PF5 and can also remove hydrofluoric acid and trace water so as to realize the protection of positive and negative active materials.

A method of manufacturing a free-standing, sheet-type solid-state electrolyte is provided. The method includes: mixing a sulfide ion conductor-containing material and a non-polar or low-polar binder in a solvent to obtain a slurry composition; disposing the slurry composition onto a planar substrate; spreading the slurry composition on the substrate to obtain a film; calendering the film to densify the film; and subsequently drying the film under vacuum. The binder may be polyisobutylene and may be present in the slurry composition in an amount of up to 10 wt. %, optionally between 1 and 5 wt. %. The sulfide ion conductor-containing material may be a lithium argyrodite having the chemical formula Li6PS5X in which X is Cl, Br, or I. The solvent may be toluene or xylene. The film may have a thickness of between 10 and 200 μm.

The invention discloses deep eutectic gel polymer electrolyte as well as preparation and application thereof, belongs to the technical field of battery electrolyte, solves the problems of low thermal stability, low ionic conductivity and poor mechanical property in the prior art, and comprises a bimetallic salt-eutectic solvent and a polymer chain which are dynamically crosslinked and constructed, the bimetallic salt-eutectic solvent comprises lithium ions, heterogeneous metal salt and Lewis base, and the polymer chain is formed by free radical polymerization, atom transfer radical polymerization (ATRP) or reversible addition-fragmentation chain transfer radical polymerization (RAFT). According to the invention, the deep eutectic solvent is introduced as a reaction solution, so that the organic gel monomer is subjected to photopolymerization or thermal polymerization in the solution, the elongation at break can reach more than 500%, the organic gel has excellent mechanical stretchability, a polymer network is formed by utilizing a long-chain molecular formula of a polymer chain, the deep eutectic solution is wrapped in the polymer network, and the organic gel has excellent thermal stability; and the good ionic conductivity of the electrolyte is ensured.

The present invention relates to a method of manufacturing an electrode of an all-in-one battery comprising the steps of mixing an electrode active material, a solid electrolyte and a first binder with a first solvent to prepare a primary slurry; drying the primary slurry to prepare a mixture powder; mixing the mixture powder, a conductive agent, and a second binder with a second solvent to prepare a secondary slurry; and coating the secondary slurry on a current collector.

The invention discloses a solid electrolyte, a preparation method thereof and an all-solid-state battery, and belongs to the technical field of solid electrolytes. According to the preparation method, a nano inert oxide and a solid electrolyte raw material are compounded through mechanical grinding, and the solid electrolyte with a core-shell structure is prepared; the device comprises an inner core, an interface layer and a shell from inside to outside, the inner core is a solid electrolyte matrix, the interface layer is a transition layer generated by reaction of the solid electrolyte matrix and a nano inert oxide, and the shell is a nano inert oxide layer. The material combines the advantages of high moisture resistance and wide electrochemical window of the nano inert oxide and the characteristics of high ionic conductivity and excellent mechanical property of the solid electrolyte, and the comprehensive performance of the material is remarkably improved through the synergistic effect of the components. The composite structure design not only solves the problem of performance limitation of a single material system, but also realizes collaborative optimization of ionic conductivity, environmental adaptability and electrochemical stability while ensuring the material stability.

To provide cathode mixture that can restrain an increase in resistance that accompanies an increase in the potential of a cathode active material layer.SOLUTION: A cathode mixture includes a cathode active material, a first solid electrolyte, a first conductive material that is a particulate carbon material, and a second conductive material that is a fibrous carbon material. The D / G ratio of the first conductive material is 1.0 or less, the D / G ratio of the second conductive material is 0.5 or less, and the proportion of the first conductive material relative to the total of the first and second conductive materials is 5 mass% or more and 30 mass% or less.SELECTED DRAWING: Figure 1

The invention discloses an iodine compound coated sulfide solid electrolyte as well as a preparation method and application thereof, and relates to the technical field of batteries. The preparation method comprises the following steps: mixing and ball-milling coating liquid and sulfide solid electrolyte powder to obtain a mixture; carrying out solid-liquid separation on the mixture to obtain a solid, washing the solid, drying, and carrying out heat treatment to obtain a sulfide solid electrolyte coated with an iodine compound on the surface; wherein the coating liquid comprises the following components in percentage by mass: 0.1-10% of an iodine compound coating agent and 90-99.9% of a coating auxiliary agent. The surface of the particle can be modified, the dispersion condition of the sulfide electrolyte is improved, and the reaction activity between the sulfide electrolyte and the iodine compound is regulated and controlled; and shear force is provided through ball milling, and uniform liquid phase coating can be realized, so that the forming process of the coating layer is optimized, the thickness and compactness of the coating layer are regulated and controlled, and the interface stability of the sulfide solid electrolyte and the metal lithium negative electrode is improved.

The invention provides a composite sulfide solid electrolyte, a preparation method thereof and a lithium ion battery. The composite sulfide solid-state electrolyte comprises a sulfide solid-state electrolyte matrix and a composite layer coating the surface of the sulfide solid-state electrolyte matrix, the composite layer comprises an interface reaction layer and a coating layer from inside to outside, the coating layer comprises a halide material, and the interface reaction layer comprises an interface reactant obtained after the halide material and the surface of the sulfide solid electrolyte matrix are subjected to an interface reaction. According to the invention, under the action of the specific surface composite layer, the electrochemical window and mechanical property of the sulfide solid electrolyte are widened, the mechanical stability and electrochemical stability of the sulfide solid electrolyte and a positive electrode material are improved, and the interface reaction of the sulfide solid electrolyte is further inhibited.

The invention relates to an organic solid electrolyte for an in-situ curing high-voltage positive electrode, a battery and a preparation method. The organic solid electrolyte is formed by in-situ polymerization of ether monomers, ester monomers, a lithium salt and a solvent through synergistic thermal initiation of double initiators. The electrolyte disclosed by the invention has the advantages that the ester polymer monomer and the ether polymer monomer are blended, and then the two monomers are respectively polymerized in a thermal initiation manner to form mutually crossed macromolecular long chains. The strategy can improve the interface stability of the electrode and the electrolyte and reduce the interface impedance of the electrode and the electrolyte. In the formed polymer network structure, the ester chain segment enhances the mechanical strength and widens the electrochemical window; and the ether chain segment provides flexible and lithium ion transmission channels. Due to the chemical complementarity of the ester monomers and the ether monomers, the overall performance of the composite polymer electrolyte is improved.

The invention discloses an all-solid-state battery based on a high-performance silicon negative electrode and a conversion type positive electrode and a dynamic compensation method for volume expansion of the all-solid-state battery, and belongs to the technical field of all-solid-state lithium ion batteries. The battery is composed of conversion type positive electrode materials such as a Si negative electrode, an S positive electrode and a Se positive electrode and a solid electrolyte; the active material of the negative electrode is LixSi alloy; the reaction equation is (x / 2) S / Se + LixSi = Si + (x / 2) Li2S / Li2Se, wherein 0 lt; x is smaller than or equal to 4.4; a Si negative electrode is matched with a conversion type positive electrode material such as an S positive electrode or a Se positive electrode, and the conversion type positive electrode material such as the S positive electrode or the Se positive electrode has relatively large volume expansion and shrinkage in a battery circulation process, so that a part of volume change of the Si negative electrode in the battery circulation process is made up, and the internal stress change of the battery is reduced; therefore, the problems of falling and inactivation of active substances, internal stress damage to solid electrolyte and the like caused by volume change of the alloying negative electrode and the conversion type positive electrode in the all-solid-state battery in the charging and discharging process are effectively solved, and the cycling stability, coulombic efficiency, economical efficiency and safety of the battery under the ultrahigh loading capacity are effectively improved.

The invention discloses a composite solid electrolyte and a preparation method and application thereof, and belongs to the technical field of solid lithium batteries. The composite solid electrolyte comprises a polymer matrix, a lithium salt and a lithium ion modified ionic metal organic framework (MOF) material. The metal center of the ion-conducting MOF material can be selected from Zr, Ti, Hf and the like, and the organic ligand can be selected from organic acids containing sulfydryl, sulfo groups and the like. The MOF material can effectively inhibit crystallization of a polymer matrix and increase the proportion of an amorphous region, Lewis acid sites on the surface of the MOF material can promote dissociation of lithium salt, and a lithium ion coordination channel formed in the MOF material can provide an extra rapid transmission path for lithium ions. When the electrolyte is applied to the solid-state lithium battery, the growth of lithium dendrites can be effectively inhibited, and the rate capability, the cycling stability and the safety of the battery can be remarkably improved.

Provided are: a negative electrode composite material for a negative electrode for a solid-state battery, the negative electrode composite material being capable of being used even when a high-capacity negative electrode active material having a large volume change rate and a sulfide-based solid electrolyte that is reactive with an ionic liquid are used in the negative electrode composite material; and a solid-state battery using the negative electrode composite material. As a result, it is possible to achieve a solid-state battery in which loss of an ion conduction path during charging and discharging of the solid-state battery is suppressed, and a decrease in capacity during a charging and discharging cycle is suppressed. The negative electrode composite material contains a specific ionic liquid. Specifically, in a negative electrode composite material containing a negative electrode active material, a solid electrolyte, and an ionic liquid, the negative electrode active material is a silicon-based negative electrode active material, the solid electrolyte is a sulfide-based solid electrolyte, and the ionic liquid contains an anion having a donor number of 9 or less as determined from the half-wave potential of a noble metal.

A solid-state battery, preferably a pouch cell, includes a cathode including cathode active material comprising Li ions, graphene, and optionally a binder; an electrolyte; and an anode, preferably a lithium anode, wherein said electrolyte is positioned in between said cathode and said anode.

The invention provides a composite solid electrolyte layer and a preparation method and application thereof. The composite solid electrolyte layer comprises a lithium dendrite inhibiting layer and a sulfide electrolyte layer at least located on the surface of one side of the lithium dendrite inhibiting layer; the lithium dendrite inhibiting layer comprises a first electrolyte and a second electrolyte; the first electrolyte comprises a sulfide electrolyte; the second electrolyte comprises one or more of an oxide electrolyte, a halide electrolyte and an M-doped electrolyte; m comprises one or more of In, F, I, Sn and Ga. Compared with the prior art, the composite solid electrolyte layer provided by the invention adopts the lithium dendrite inhibiting layer with specific components to be compounded with the sulfide electrolyte layer, so that relatively good overall interaction is realized, the electrolyte membrane can be prevented from being punctured by lithium dendrites, the cycling stability of the battery is improved, separation of a heterogeneous structure is avoided, and the service life of the battery is prolonged. The internal resistance of the battery is lower than that of single-layer electrolyte.

The invention provides a safe flame-retardant gel electrolyte and a lithium ion battery. The gel electrolyte is obtained by heating, cross-linking and polymerizing a gel electrolyte solution; the gel electrolyte comprises a basic electrolyte, a gel polymerization monomer, a cross-linking agent and an initiator; the basic electrolyte comprises a lithium salt, an organic solvent and an additive; the gel polymerization monomer comprises a phosphorus-containing flame-retardant monomer and a fluorine-containing flame-retardant monomer. Aiming at the pain point of the current liquid electrolyte, a phosphorus-containing flame-retardant element and a fluorine-containing flame-retardant element are innovatively introduced by forming the gel electrolyte through an in-situ polymerization means, so that the two-element synergistic flame retardance and the electrochemical performance are considered, and the defect that the electrochemical performance is reduced due to the introduction of a flame-retardant additive into the existing gel electrolyte is overcome; the compatibility of the gel electrolyte and the electrode is improved, the safety performance of the battery is enhanced, and the cost is reduced.

The present invention relates to a positive electrode for an all-solid-state battery, and the positive electrode for an all-solid-state battery comprises a positive electrode layer including a positive electrode active material, a sulfide-based solid electrolyte, a positive electrolyte layer including a plasticizer and a lithium salt that is a solid at room temperature and liquid at 60 °C or higher, and a current collector supporting the positive electrode layer.

The invention provides a sulfide solid electrolyte and a preparation method and application thereof, and relates to the technical field of lithium ion batteries. The preparation method comprises the following steps: S1, carrying out dry ball milling treatment on raw materials Li2S, P2S5 and LiX according to a required stoichiometric ratio, so that the raw materials are amorphized; s2, adding a solvent into the non-crystallized raw material obtained in the step S1, and carrying out wet ball-milling treatment to obtain a precursor with the particle size of 0.05-0.5 mu m; s3, the solvent is removed from the precursor slurry, the sulfide solid electrolyte is obtained through solid-phase sintering, all the steps are carried out in an inert atmosphere, and X is a halogen element. According to the present invention, the non-crystallization of the raw material is achieved through the dry ball milling, the uniform precursor slurry with the small particle size is obtained by combining the wet ball milling, and the sub-micron / nano-scale pure phase electrolyte material can be obtained after the sintering treatment, such that the electrode / electrolyte interface contact is improved, the impedance is reduced, and the battery performance is significantly improved.

A new polyelectrolyte multilayer coated proton-exchange membrane for electrolysis and fuel cell applications has been developed for electrolysis and fuel cell applications. The polyelectrolyte multilayer coated proton-exchange membrane comprises: a cation exchange membrane, and a polyelectrolyte multilayer coating on one or both surfaces of the cation exchange membrane. The polyelectrolyte multilayer coating comprises alternating layers of a polycation polymer and a polyanion polymer. The polycation polymer layer is deposited on and is in contact with the cation exchange membrane. The top layer of the polyelectrolyte multilayer coating can be either a polycation polymer layer or a polyanion polymer layer.

The invention provides a modified sulfide solid electrolyte and a preparation method and application thereof.The modified sulfide solid electrolyte comprises lithium thioborate crystals, composite grain boundaries are contained between the lithium thioborate crystals, and lithium iodide is contained in the composite grain boundaries. The structures of crystal lattices and composite crystal boundaries in the modified sulfide solid electrolyte are stable, so that the lithium ion migration capability of the modified sulfide solid electrolyte can be improved, and the ionic conductivity of the modified sulfide solid electrolyte is obviously improved.

According to the lithium battery and the preparation method thereof provided by the invention, dual mechanisms of free radical polymerization and ring-opening polymerization are combined, a stable double-crosslinking structure gel electrolyte constructed by two polymers can be obtained in an in-situ polymerization process, and the mechanical strength and the thermal stability are improved; by regulating and controlling the ratio of an epoxy monomer to an acrylate monomer, firstly, room-temperature ring-opening polymerization is performed, so that part of in-situ gel is formed before formation, smooth formation of a gel interface is ensured, the first coulombic efficiency of the battery is not influenced, and meanwhile, the dosage of the acrylate monomer and a corresponding thermal initiator is reduced; high-temperature treatment is carried out after formation, so that the interface aging of the battery is stable, the cycle life of the battery is prolonged, the acrylate monomers are polymerized, the high temperature continues to promote the polymerization of the residual epoxy monomers, the polymerization conversion rate is favorably increased, and the high-pressure resistance and oxidative decomposition resistance of the gel electrolyte are improved.

Solid electrolyte compositions and solid-state batteries are disclosed, which comprise a solid electrolyte layer including a sulfide-containing solid-state electrolyte material and a compound of Chemical Formula 1. The sulfide-containing solid-state electrolyte material includes but is not limited to Li6PS5Cl (“LPSC”), an LPS-based glass or glass ceramic of formula xLi2S·yP2S5, wherein x+y=1, or an argyrodite-based sulfide-based solid electrolyte or formula Li6PS5X, wherein X═Cl, Br, or I) or Li6-yPS5-yCl1+y, where y is <1. In some aspects, the compound of Chemical Formula 1 is sodium 3-mercapto-1-propanesulfonate (3M1P).

The invention discloses an amphiphilic imidazole sulfonate ionic liquid, a synthetic method thereof and a solid-state battery, and belongs to the technical field of ionic liquid synthesis. The amphiphilic imidazole sulfonate ionic liquid comprises an acceptable combined salt which is formed by imidazole cations and sulfonic acid anions in pharmacy, and the amphiphilic imidazole sulfonate ionic liquid has an ionic conduction characteristic in a solution or solid state; the amphiphilic imidazole sulfonate ionic liquid can be obtained through simple synthesis, and the amphiphilic imidazole sulfonate ionic liquid has good ionic conduction characteristics in a solution or solid state, and is suitable for preparing an electrolyte of a solid-state battery.

The invention discloses a lithium ion battery, a preparation method thereof and a lithium ion battery module. The lithium ion battery comprises a positive electrode, a first solid electrolyte membrane and a negative electrode which are sequentially stacked in the thickness direction, the lithium ion battery also comprises a second solid electrolyte membrane; the second solid electrolyte membrane is positioned between the positive electrode and the first solid electrolyte membrane; wherein the second solid electrolyte membrane is provided with a plurality of first through holes, and the first through holes are filled with a positive electrode lithium supplement agent. The lithium ion battery disclosed by the invention is provided with the double-layer composite solid electrolyte membrane, and the positive electrode lithium supplementing agent is filled in the through hole formed in the solid electrolyte membrane in contact with the positive electrode, so that active lithium consumed when the lithium ion battery is charged for the first time can be effectively supplemented, the total capacity and the energy density of the lithium ion battery are improved, and the cycle life of the lithium ion battery is prolonged.

The invention discloses a multilayer composite solid electrolyte membrane, a preparation method and a prepared solid-state battery, the multilayer composite solid electrolyte membrane sequentially comprises a three-dimensional polymer networked solid electrolyte, a LiPON layer and a polydopamine layer, the thickness of the three-dimensional polymer networked solid electrolyte is 20-40 [mu] m, and the thickness of the polydopamine layer is less than 100 nm. By adopting the synergistic effect of the silane coupling agent modified LLZO and the degraded chitosan, a better ion transmission coordination effect can be provided, and the efficiency of an ion channel is improved. The dendritic crystal inhibition efficiency is improved, obvious cracks are avoided after 1000 times of circulation, the composite material is applied to a solid-state battery, the cycle life of the battery is prolonged, and the capacity retention rate is 95% after 1000 times of circulation. The mechanical toughness of the solid electrolyte is improved, and the elongation at break can reach 130%. A water-phase solvent is used in the whole preparation process, use of an organic solvent is avoided, energy consumption is reduced by 40%, no VOC is discharged in the whole process, and the method is green, safe and environmentally friendly.