A rechargeable 
alkali metal battery comprising: (a) an 
anode comprising an 
alkali metal layer and a 
dendrite penetration-resistant layer comprising an 
amorphous carbon or polymeric 
carbon matrix, an optional carbon or 
graphite reinforcement phase dispersed in this matrix, and a 
lithium- or 
sodium-containing species that are chemically bonded to the matrix and / or the optional carbon or 
graphite reinforcement to form an integral layer that prevents 
dendrite penetration, wherein the 
lithium- or 
sodium-containing species is selected from Li2CO3, Li2O, Li2C2O4, LiOH, LiX, ROCO2Li, HCOLi, ROLi, (ROCO2Li)2, (CH2OCO2Li)2, Li2S, LixSOy, Na2CO3, Na2O, Na2C2O4, NaOH, NaiX, ROCO2Na, HCONa, RONa, (ROCO2Na)2, (CH2OCO2Na)2, Na2S, NaxSOy, or a combination thereof, wherein X═F, Cl, I, or Br, R=a 
hydrocarbon group, x=0-1, y=1-4; (b) a 
cathode; and (c) a separator and 
electrolyte component; wherein the 
dendrite penetration-resistant layer is disposed between the 
alkali metal layer and the separator.