1920 results about "Reaction rate" patented technology

The invention provides a continuous preparation system and method of pyroxasulfone. The continuous preparation system comprises a mixing device, a continuous oxidation reaction device, a continuous quenching device, a continuous devitrification device, a continuous solid-liquid separation device and a continuous drying device. Compared with intermittent preparation of pyroxasulfone, the continuous preparation system disclosed by the invention has the advantages that the reaction can be more stable, and the reaction temperature can be more accurately controlled, so that the problems of large heat release and high process risk in batch reaction can be effectively solved. Moreover, compared with a tank reactor, the continuous oxidation reaction device filled with the catalyst bed layer can improve the oxidation reaction rate, shorten the oxidation reaction time and improve the yield and selectivity of oxidation products.

The invention provides a waste glass activity rapid comprehensive evaluation method based on dissolution kinetics analysis. According to the method, the silicon ion dissolution characteristic of the waste glass in an alkaline environment is measured, the particle size effect and kinetic parameter analysis are combined, the corresponding relation with the 28-day compressive strength activity index is established, and rapid evaluation of the activity of the waste glass is achieved. The method comprises the steps of dissolution test, kinetic analysis and activity evaluation. Research finds that a power function relationship exists between the reaction rate constant and the particle size, and good linear correlation exists between the dissolution characteristic and the activity index. According to the invention, a complete evaluation system of particle size-reaction rate-activity index is established, the goal of predicting the 28-day activity index from the 24-hour dissolution characteristic is realized, and the error between the prediction result and the measured value is less than 2%. The method is short in evaluation period and accurate and reliable in result, and has important engineering application value.

The invention relates to the technical field of chemical engineering and machine learning, and provides a Fischer-Tropsch reactor strengthening method based on microsystem catalyst screening and kinetic research. The method comprises four main steps of catalyst screening, kinetic model establishment, reactor size optimization and performance verification. The method comprises the following steps: firstly, screening Fe9Cr3 as an optimal bimetallic catalyst through molecular dynamics simulation; then, establishing a kinetic model by utilizing an Arrhenius equation, and calculating a reaction rate constant and activation energy; secondly, optimizing the length-diameter ratio L / D of the reactor through macroscopic simulation and computational fluid dynamics (CFD) simulation; finally, the performance of the optimized reactor is verified through experiments, it is ensured that the activity and the synthesis rate of the catalyst reach expected targets, and CO2 emission reduction is achieved. According to the method, microscopic simulation and macroscopic simulation are combined, so that the overall efficiency and performance of F-T synthesis are improved, and meanwhile, the research and development cost is reduced, and the research and development time is shortened.

The invention provides an MHP precipitation method based on a compound alkali precipitator and application of the MHP precipitation method, and the MHP precipitation method comprises the following steps: mixing laterite-nickel ore iron and aluminum removed liquid and a compound alkali solution for precipitation reaction to obtain cobalt nickel hydroxide slurry; the compound alkali in the compound alkali solution comprises a mixture of sodium carbonate and sodium hydroxide; and carrying out post-treatment on the cobalt nickel hydroxide slurry, and separating to obtain the MHP. According to the method, a sodium hydroxide and sodium carbonate compounded system is used as a precipitator, the MHP is prepared under the cooperation of sodium carbonate and sodium hydroxide, the content of manganese in the obtained MHP is remarkably reduced, the content of nickel and cobalt in the MHP is increased, the method has important significance for reducing the cost for preparing crystals through subsequent MHP refining, meanwhile, the reaction rate is more controllable, the obtained MHP is better in filtering performance, and the method is suitable for industrial production. The water content is lower.

The invention belongs to the technical field of ferrous metallurgy, and particularly relates to a steel billet surface defect detection method which comprises the following steps: controlling the moving speed of a roller way to be synchronous with the reaction rate of flame cleaning, and performing continuous scanning type cleaning and removal on an oxide layer on the surface of a steel billet through a flame cleaning device; the flame cleaning device comprises a flame nozzle and an air source; and then the surface of the steel billet is detected after flame cleaning, surface defects are recognized, and the defects comprise cracks and air holes. The flame cleaning device is adopted to remove the oxide layer on the surface of the steel billet, so that the surface of the steel billet can be quickly and effectively cleaned, tedious pretreatment processes such as acid pickling and shot blasting are avoided, expensive chemicals and shot blasting equipment are avoided, the chemical treatment and equipment maintenance cost is saved, and the production cost is remarkably reduced. The speed and efficiency of billet surface defect detection are greatly improved, and the dead time and manual intervention of a production line are reduced.

The invention provides a process for preparing cyclohexane-1, 2-dioctyl phthalate, which adopts a loop reaction process to perform hydrogenation reaction of dioctyl phthalate, and comprises the following steps: under the condition of excessive hydrogen atmosphere, firstly putting a catalyst, a solvent and a target product into a reaction tank to form a circulating material; when reaction liquid passes through the Venturi ejector, hydrogenation reaction can be carried out, the Venturi reactor can provide a high gas-liquid mixing ratio, the reaction rate is high, and the production efficiency is high. The catalyst and the reaction mixed liquid are separated by combining a membrane separation process, so that the catalyst is recycled, and the cost is reduced. The target product is added into the system to maintain material balance in the system, so that stable production is ensured. Compared with the traditional technical process, the method has the advantages that the reaction time is shortened, the energy consumption of the device and the investment cost are reduced, the high conversion rate of reactants and the high selectivity of target products can be kept, the operation period of the device is long, and continuous and stable production is realized.

The invention relates to the technical field of aluminum electrolyte recovery, in particular to a waste aluminum electrolyte resource utilization method. The waste aluminum electrolyte resource utilization method comprises the following steps that waste aluminum electrolyte and a reactant are subjected to a reaction in a closed container, a product obtained after the reaction is completed is washed in water, then first solid-liquid separation is carried out to obtain a solid, aluminum fluoride is obtained after drying, and aluminum fluoride is obtained after second solid-liquid separation is carried out. The reactant is selected from one or two of anhydrous aluminum chloride and polyaluminum chloride, and the reaction temperature is not lower than 200 DEG C. By utilizing the physical characteristic that the melting point of the reactant is higher than the boiling point, the reactant forms a solid phase-liquid phase-gas phase three-phase coexistence system in a closed space at the temperature higher than the melting point and the boiling point, so that the reactant can more efficiently perform molecular collision and mutual diffusion at an interface, thereby accelerating the reaction rate and improving the conversion rate.

The invention belongs to the technical field of acyclic compounds, and particularly relates to a preparation method of tert-butyl peroxyisobutyrate. Stirring and cooling a solvent, a tert-butyl hydroperoxide aqueous solution and deionized water to obtain a mixed solution A; adding liquid caustic soda and a solid base catalyst into the mixed solution A under a stirring condition, and continuously stirring for reaction to obtain a mixed solution B; under the stirring condition, isobutyryl chloride and a water-soluble distributing agent are added into the mixed solution B, stirring reaction continues to be conducted, and a mixed solution C is obtained; standing and layering the mixed solution C, separating to obtain a tert-butyl peroxyisobutyrate crude product, and refining the tert-butyl peroxyisobutyrate crude product to obtain the tert-butyl peroxyisobutyrate. According to the method, the raw material utilization rate is increased, the reaction speed is increased, the reaction time is shortened, and the product yield is high.

The invention discloses a micro-channel jet reactor. The micro-channel jet reactor comprises a sample introduction unit, a main mixing unit and a reaction unit which are sequentially communicated, the main mixing unit comprises a first inner pipe and a first outer pipe arranged outside the first inner pipe in a sleeving manner; a first annular space is formed between the first inner pipe and the first outer pipe; the sample introduction unit is communicated with the first inner pipe; a second sample inlet is formed in the first annular space, and a plurality of through holes are formed in the first inner pipe; the reaction unit comprises a second inner pipe and a second outer pipe arranged outside the second inner pipe in a sleeving manner; a second annular space is formed between the second inner pipe and the second outer pipe; the first inner pipe is communicated with the second inner pipe; during use, condensate is arranged in the second annular space. The reactor can effectively improve the mixing uniformity degree of reaction liquid, meanwhile, the reaction temperature is controlled, and the reaction rate and selectivity are ensured.

The invention discloses an intelligent control and optimization system in aluminum hydrolysis hydrogen production, and relates to the technical field of automatic control, the system comprises a reaction kinetics analysis unit, a fluid field optimization unit and a self-adaptive intelligent control unit; the reaction kinetic analysis unit is used for obtaining the reaction rate of the aluminum powder according to the aluminum powder activity characterization parameters of the aluminum powder; according to the aluminum powder reaction rate, a hydrogen prediction rate is obtained, a bubble growth equation is constructed, and a bubble growth rate is obtained; the fluid field optimization unit is used for analyzing the mass transfer and heat transfer coupling effect in the reaction process, analyzing the influence of stirring on fluid movement, obtaining flow field speed distribution and predicting the reaction progress; and the self-adaptive intelligent control unit is used for dynamically adjusting the stirring speed according to the reaction progress, the reaction pressure, the hydrogen prediction speed, the flow field speed distribution and the aluminum powder activity characterization parameters. The utilization rate and the hydrogen production rate of the aluminum powder are improved.

The invention relates to the technical field of industrial flue gas purification, and discloses a desulfurization control method based on blast furnace gas sulfur concentration prediction, which comprises the following steps: step 1, acquiring real-time sulfur concentration, flow velocity, temperature, pressure and current desulfurizer feeding rate of blast furnace gas, denoising and normalizing acquired data, and storing the data in a database; step 2, based on the blast furnace gas sulfur concentration convection-diffusion model and the reaction rate equation, constructing a physical constraint prediction model in combination with a long-short term memory network, and outputting future predicted sulfur concentration; and 3, predicting a result based on the sulfur concentration. According to the method, the physical constraint prediction model based on the long and short term memory network is adopted, the technical effect of accurately predicting the sulfur concentration of the blast furnace gas is achieved, and compared with a prediction method purely based on experience or a traditional time sequence model in the prior art, the defects of low prediction precision and poor generalization ability under complex working conditions are overcome.

The invention discloses an automatic quality monitoring system based on a nickel hydrazine nitrate manufacturing technology, and relates to the technical field of nickel hydrazine nitrate manufacturing. The system has the functions of integrating a multi-wavelength filter wheel module, a process stability monitoring module and the like, and full-parameter real-time monitoring of the reaction process is realized. A Savitzky-Golay filtering algorithm is adopted to calculate a reaction rate, an XGBoost model is combined to predict a quality grade, and a hierarchical control strategy is designed to cope with different quality risks. And the risk assessment module simulates a crystal growth process by using a reaction kinetic model, identifies key risk factors, constructs a risk matrix to divide production areas, and generates an assessment report. Spectral data are corrected through a three-dimensional compensation matrix, the type of a quality problem is judged by adopting a double-layer fusion algorithm, and closed-loop control is realized in combination with a PID controller and an emergency emission program. A monitoring interface displays key parameters and early warning information in real time, dynamic adjustment of process parameters is supported, the production process is optimized, and the product quality and the production efficiency are improved.

The invention discloses a method for controlling ion concentration and volume balance in an electrolyte by using nickel hydroxide. The method comprises the following steps: preparing a reaction base solution containing a first complexing agent and a first alkali; the first anolyte, a second complexing agent solution and a second alkali solution are simultaneously added to the bottom of the reaction base solution for stirring reaction, solid-liquid separation is performed after nickel hydroxide reaches the target particle size, and filtrate and a filter cake are obtained; washing the filter cake, and slurrying the filter cake by using a second anolyte to obtain a nickel hydroxide slurrying material; and adjusting the sodium ion concentration, pH and nickel ion concentration of the third anolyte by adopting a sodium hydroxide solution, a nickel hydroxide slurrying material and a nickel sulfate solution to obtain the catholyte. According to the invention, a feeding mode of feeding at the bottom is adopted, and a complexing agent is matched, so that crystals can stably grow and are convenient to filter; in the preparation process, aging and too high pH conditions are not needed, operation is simpler, labor intensity is small, the reaction rate is higher, and continuous treatment of the anolyte can be achieved.

The invention relates to retarded acid for a carbonate rock reservoir and application thereof, and aims to solve the problems of poor high temperature resistance and too high acid rock reaction rate of the current retarded acid for the carbonate rock reservoir. The retarded acid for the carbonate rock reservoir comprises an acid agent, a functional aid and water; the acid agent comprises inorganic acid, organic acid, a chelating agent and organic ester in a mass ratio of 1: (10-13): (5-6): (3-4). According to the retarded acid provided by the invention, the acid agent is specifically designed, and the inorganic acid, the organic acid, the chelating agent and the organic ester in a specific ratio are matched, so that the retarded acid has high temperature resistance, and meanwhile, the problem that the acid-rock reaction rate is too high is avoided. And the deep transformation of the acid liquid in the reservoir is realized under the clamping of a low acid rock reaction rate. And by means of the high resistance reduction capacity after weight increasing, it is guaranteed that the construction operation pressure is reduced in the deep well and ultra-deep well reservoir transformation process, and therefore the efficient reservoir transformation capacity is achieved.

The invention discloses a reaction kettle device for synthesis of an iron phosphate material, and particularly relates to the technical field of synthesis of battery materials, and the device comprises a kettle body, a driving motor, a transmission disc and a turbo-type paddle. A sealing cover is arranged at the top of the kettle body, a driving motor is connected with a rotating shaft, an anchor blade is arranged below the rotating shaft, and the bottom realizes turbine blade lifting and sleeve guide limiting through transmission of a piston cavity and compressed gas; and a ratchet wheel on the outer wall of the rotating shaft is meshed with a pawl in the transmission disc in a one-way mode, and intermittent wall scraping is achieved. According to the device, dead angles are broken through synergistic stirring of the double blades, the mixing uniformity and the reaction rate are improved, materials adhering to the wall are efficiently removed through intermittent wall scraping, the stable reaction environment is guaranteed through multiple sealing, the structure is flexible to adjust, maintenance is convenient and fast, efficient and high-quality synthesis of the iron phosphate material can be achieved, and the device is suitable for industrial large-scale production.

The invention relates to the field of waste polymer material recovery and resource utilization, and particularly discloses a method for realizing ultra-fast recovery of fluorine-containing organic waste through a self-propagating reaction. According to the method, liquid sodium-potassium alloy (NaK) is used as a reaction medium, under the protection of inert atmosphere, fluorine-containing organic solid waste is in contact with NaK, electron transfer is induced through mechanical friction, C-F bond breakage is catalyzed and induced, a defluorination reaction is triggered, reaction heat is released, a self-propagating combustion reaction is initiated, and finally, carbon materials and metal fluoride products are recycled. The method is rapid in reaction, does not need external heating, can efficiently recover fluorine-containing waste and prepare high-added-value materials, and is suitable for green large-scale treatment of waste fluoropolymers and preparation of functional materials.

The invention relates to the technical field of nano particle heterogeneous reaction kinetic research, in particular to a nano single particle reaction rate measuring system and method based on optical surface wave dark field imaging. The method comprises the following steps: preparing a nano single particle sample; the humidity of the environment where the nano single particles are located is adjusted; starting a heterogeneous reaction of the nano single particulate matter, performing in-situ dark field imaging on the nano single particulate matter in the reaction process, and collecting scattering hot spot imaging data under different reaction times and different humidity; and based on the acquired imaging data, the reaction rate of the nano single particulate matter is inversed in combination with a kinetic model. According to the invention, the defects in the existing nano-particle reaction rate measurement technology can be overcome, and the reaction rate of a single particle as low as 50 nanometers in the heterogeneous reaction process can be accurately measured and inverted under the high-humidity standard atmospheric pressure condition.

The invention relates to the related technical field of neodymium-iron-boron recovery, in particular to a neodymium-iron-boron waste recovery parameter optimization method and system capable of predicting the recovery rate, and the method comprises the steps: determining a physical characteristic index, simulating and configuring a pyrolysis parameter set in combination with a pyrolysis temperature gradient, uploading an acid leaching concentration parameter, configuring an acid leaching parameter combination, and carrying out coupling analysis and iteration. And collecting parameters to establish a recovery parameter feedback adjustment mechanism. The technical problems that fixed pyrolysis parameters are difficult to adapt to different waste characteristics, the characteristic change of the pyrolyzed waste directly affects the acid leaching efficiency, a compact inert layer is generated on the surface of part of the pyrolyzed waste, and the dissolution bottleneck is caused are solved, the recovery process under different temperature gradients is analyzed, and the recovery efficiency is improved. The method has the advantages that recycling process parameter sets corresponding to different pyrolysis temperature intervals are accurately configured, the coupling relation between acid leaching and pyrolysis is fully considered, it is guaranteed that the dissolution efficiency, the impurity dissolution amount and the reaction rate of rare earth elements under different acid leaching concentrations reach the optimal balance, and the recycling efficiency is improved.

The invention relates to a supergravity adiponitrile production system and method, the system comprises a supergravity nitrile reactor, a separation tower, a semi-nitrile evaporator and a refining device, the middle part of the supergravity nitrile reactor is communicated with the lower part of the separation tower through a main pipeline, and the top of the supergravity nitrile reactor is communicated with a main ammonia gas pipeline; the top of the separation tower is respectively communicated with an ammonia recovery pipeline and a water recovery pipeline, and the upper part of the separation tower is communicated with the refining device through a pipeline; and the top of the semi-nitrile evaporator is respectively communicated with the bottom of the separation tower, the main pipeline and the main ammonia gas pipeline through pipelines. The reactor has the beneficial effects that the characteristics of structure, technology and the like of the supergravity reactor are utilized, the reverse concentration gradient of ammonia gas and molten adipic acid is formed in the radial direction of the rotor from inside to outside, the gas-liquid contact specific area is increased, the mass transfer driving force is increased, the reaction rate is increased, reaction products are separated out in the reaction process, and the reaction is accelerated and pushed.

The invention belongs to the technical field of flue gas acid making, and particularly discloses a dynamic model-based non-equilibrium flue gas acid making conversion rate prediction method, which comprises the following steps of: acquiring smelting flue gas parameters, processing and storing; constructing an SO2 catalytic oxidation reaction rate kinetic equation; in combination with a gas mass transfer process, the influence of a diffusion efficiency factor on mass transfer from SO2 to the surface of the catalyst is considered; integrating the temperature, the concentration and the diffusion effect, and establishing a macrodynamic model under the non-equilibrium condition; introducing a correction factor optimization model, and comparing the actual conversion rate with a model prediction result to adjust a correction factor; comparing a model prediction result with production data to verify the model accuracy; evaluating the generalization ability of the model by adopting cross validation; optimizing model parameters according to a verification result; and inputting the acquired data into the verified and optimized model to obtain a conversion rate prediction result, and adjusting process parameters according to the result to enable the flue gas acid making to be better. The method has the characteristics that the prediction result is accurate and reliable, the acid making efficiency can be improved, and the energy consumption can be reduced.

The invention relates to the technical field of in-situ leaching mining of low-permeability sandstone type uranium ore, in particular to a prediction method for the in-situ leaching effect of the low-permeability sandstone type uranium ore. And constructing a single-hole blasting physical model, and simulating the change of the radiuses of the crushed region and the fractured region of the uranium mine by updating a non-coupling coefficient. Thirdly, constructing a multi-physics field coupling model, including a geometric model, rock parameter definition, initial and boundary condition setting, introduction of a fracture geometric model, and simulation of in-situ leaching uranium concentration and uranium recovery rate change curves after blasting permeation enhancement; the multi-physical field model covers a dilute material transfer field, a Darcy seepage field and a chemical field. And based on the uncoupling coefficients corresponding to the uranium concentration and the uranium recovery rate peak value, determining the optimal uncoupling coefficient, further constructing an HJC field scale blasting model, adjusting blasting parameters, and optimizing the uranium mine crack expansion condition and the in-situ leaching effect. And finally, in combination with the optimal blasting parameter, analyzing the influence of different in-situ leaching parameters on the in-situ leaching process, and optimizing the reaction rate, so that the whole process optimization is realized, and the in-situ leaching efficiency is improved.

The invention provides a method for recovering Cu or EDTA ligand in Cu (II)-EDTA wastewater by one-step complex breaking, which comprises the following steps: adding manganese powder wrapped by a proton exchange membrane into Cu (II)-EDTA-containing wastewater for ultrasonic reaction, keeping the wastewater free of dissolved oxygen and the pH value below 3 in the reaction process, and obtaining Cu0 on the surface of the proton exchange membrane after the reaction is completed. According to the method provided by the invention, the Cu and the EDTA can be recycled respectively, the reaction rate is high, the treatment process is simple, the copper and the EDTA are converted into resources which can be directly recycled, and the time and the economic cost are saved.

The invention relates to the technical field of gas-solid phase catalytic reaction equipment, and discloses a gas-solid phase catalytic reactor, which comprises a reactor body and a plurality of catalyst bed layers arranged in the inner cavity of the reactor body, the plurality of catalyst bed layers are arranged at intervals along the flowing direction of reaction raw materials, the discharge side of each catalyst bed layer is provided with a quenching filler layer, and the discharge side of each catalyst bed layer is provided with a quenching filler layer. The quenching filler layer is arranged to be capable of quenching flames generated by the reaction raw materials; according to the invention, through a plurality of catalyst bed layers arranged at intervals, the intensity of gas-solid phase catalytic reaction is directly reduced, so that combustion explosion of combustible gas in reaction raw materials caused by release of excessive heat is avoided; the quenching filler layer is used for quenching flames possibly generated by reaction raw materials, so that combustible gas and oxygen can be subjected to a gas-solid phase catalytic reaction within the explosion limit, the reaction rate is increased, the reaction efficiency is improved, the economic benefits are further improved, and the device has the advantages of being safe and reliable.

The invention provides a method for preparing a spinel type catalyst rich in oxygen vacancies under the assistance of magnetization treatment and application of the spinel type catalyst. The synthesis method of the catalyst comprises the following steps: (1) preparing a precursor of the catalyst by adopting a hydrothermal method: putting a metal foam carrier into a mixed solution of metal salt ions such as ferric nitrate, manganous nitrate and cobalt nitrate, adding ammonium fluoride and urea, carrying out hydrothermal reaction, repeating the hydrothermal reaction for several times, and washing and drying to obtain the precursor; and (2) putting the catalyst precursor into a magnetization reactor, putting the magnetization reactor in the center of an alternating magnetic field coil, and carrying out magnetization treatment on the catalyst precursor in an air or oxygen atmosphere to obtain the spinel type catalyst rich in oxygen vacancies. The method is simple in process and low in cost, and the obtained product is uniform in morphology and good in repeatability and has high photo-thermal catalytic oxidation toluene performance. Through a clean, pollution-free and in-situ directional heating electromagnetic induction auxiliary technology, removal of oxygen atoms on the surface of the spinel catalyst is promoted, so that rich oxygen vacancies are introduced into cobalt-manganese spinel, the exchange effect between the catalyst and oxygen molecules is accelerated, and the reaction rate of catalytic oxidation of VOCs is promoted. When the intensity of simulated sunlight is 500 cm <-2 >, the concentration of toluene is 1000 ppm, the air speed is 45000 mL.gcat <-1 >. H <-1 >, the conversion rate of toluene reaches 86% or above, and high-efficiency oxidation of toluene can be realized under the driving of the simulated sunlight.

The invention discloses a reactive polyurethane hot melt adhesive for laminating and compounding a PVC (Polyvinyl Chloride) film and a preparation method of the reactive polyurethane hot melt adhesive, so that a product prepared by the invention is very suitable for laminating and compounding a soft PVC film rich in a plasticizer. According to the invention, by designing specific raw materials and proportions, especially polyester polyol with a specific glass transition temperature, and selection and compounding design of a catalyst A and a catalyst B, the polyurethane hot melt adhesive system prepared by the invention can effectively improve the reaction rate in the actual use curing process, a compact structure can be formed more quickly, and the service life of the polyurethane hot melt adhesive system is prolonged. And the bonding strength is not influenced by migration of the plasticizer. Meanwhile, the preparation method provided by the invention is simple, easy to control, good in condition culture and suitable for large-scale industrial production.

The invention relates to a high-selectivity continuous synthesis method of dipentaerythritol. According to the invention, pentaerythritol is introduced, so that more dipentaerythritol intermediates can be effectively generated at the initial stage of reaction, and the selectivity of dipentaerythritol is greatly improved. The reaction product solution can be separated through a conventional separation method, the separation cost is low, the obtained crude product pentaerythritol can serve as an additive to participate in the reaction again and be recycled, and high selectivity of dipentaerythritol is guaranteed. Besides, a continuous reactor is used for condensation reaction under the high-temperature condition, compared with a conventional method, the reaction rate is higher, the reaction time can be shortened to be within 1 hour, the selectivity of dipentaerythritol is improved, and the yield even reaches 30% or above.

The invention discloses a preparation method of a high-entropy phosphide nanotube, which successfully prepares a nanotube phosphide with a high-entropy structure by adopting a hydrogen bond organic framework (HOF)-metal organic framework (MOF) template conversion method. In the preparation process of the material, a core-shell structure (HOF (MOF)) is firstly formed, the core gradually disappears through a diffusion mechanism, and finally, the material is converted into a hollow nanotube structure which is uniform and controllable in size. According to the hollow structure, the specific surface area is remarkably increased, more active sites are provided, the transmission path of reactant molecules is optimized, and the electro-catalytic performance is greatly improved. Besides, the overall tubular morphology of the material is uniform, the size is controllable, and compared with a traditional granular material, the specific surface area is remarkably increased, so that more reaction sites are exposed in the external environment, and the catalytic efficiency and the reaction rate of the material in an electro-catalytic reaction are greatly improved.

The invention belongs to the technical field of deep sea manganese nodule treatment, and particularly relates to a method for microwave treatment of manganese nodules. When manganese nodules are treated in the prior art, the defects that an additional reducing agent needs to be added, a large amount of by-product gas polluting the environment exists in products, the reaction rate is low, the treatment time is long, energy consumption is high, pollution is large, and the separation efficiency of gangue components in minerals is low exist. In order to solve the problems, the method for microwave treatment of the manganese nodule comprises the following steps of microwave preheating activation, ore grinding premixing, microwave reduction acid leaching, sulfuration precipitation, microwave sulfuration smelting, oxygen-enriched blowing, microwave roasting oxygen pressure leaching, multi-stage extraction and microwave treatment. And the structure of the manganese-containing aggregate in the raw ore is destroyed, and gas-phase components in the raw ore overflow, so that the leaching rate and the recovery rate of valuable metals are greatly improved.

The invention discloses a preparation method of diiodosilane, and belongs to the technical field of material synthesis. The preparation method of diiodosilane comprises the following steps: adding a first iodine source and a second iodine source into a closed reactor in an inert gas atmosphere, and dissolving the first iodine source and the second iodine source in a solvent to form a uniform solution; and reducing the temperature, and adding liquid dichlorosilane. Raising the temperature to 30 to 80 DEG C and reacting; and after the reaction is finished, heating at reduced pressure, rectifying and purifying to obtain the high-purity electronic-grade diiodosilane. The first iodine source is lithium iodide, the second iodine source is at least one of sodium iodide or potassium iodide, and the solvent comprises at least one of acetonitrile, acetone, diethyl ether or ethanol. Lithium iodide and sodium iodide or potassium iodide are compounded, a specific solvent is matched, and a one-step method is used for testing, so that the input cost of raw materials is reduced, the experimental steps are simplified, the reaction rate of a reaction system can be improved, and the purity of a diiodosilane product is improved.

The invention relates to a preparation method and system of high-molecular-weight polyethylene glycol oxalate, and the preparation method comprises the following steps: adding oxalic acid diester, ethylene glycol and a first catalyst, and carrying out transesterification to obtain an ester; adding a second catalyst, and carrying out a pre-polycondensation reaction on the esterified product to obtain a glycol oxalate oligomer; polymerizing the ethylene glycol oxalate oligomer, and carrying out final polymerization reaction to obtain polyethylene glycol oxalate; the molar ratio of the oxalic acid diester to the ethylene glycol is (1.05-1.3): 1. Compared with the prior art, by controlling excessive oxalic acid diester in the raw material ratio, namely controlling the molar ratio of oxalic acid diester to ethylene glycol to be greater than 1, the reaction rate of ethylene glycol is improved, self-polycondensation of ethylene glycol is prevented, further increase of molecular weight is facilitated, and meanwhile, the thermal performance of the product is improved.