240results about "Bismuth compounds" patented technology

The invention provides anti-ionizing radiation powder with a core-shell heterogeneous gradient structure and a preparation method and application of the anti-ionizing radiation powder, and belongs to the field of radiation protection.The preparation method of the anti-ionizing radiation powder with the core-shell heterogeneous gradient structure comprises the following steps that high-atomic-number metal salt is added into deionized water, aging, washing, drying and primary calcination are conducted in sequence, and the anti-ionizing radiation powder with the core-shell heterogeneous gradient structure is obtained; a core layer is obtained; the core layer and low-atomic-number metal salt are added into deionized water, aging, washing, drying and primary calcination are sequentially conducted, and preliminary wrapping powder with the high-atomic-number metal core layer wrapped by low-atomic-number metal is obtained; and adding the preliminarily wrapped powder and rare earth salt into deionized water, and sequentially performing aging, washing, drying, primary calcining, secondary calcining, airflow crushing and air rotation purging to obtain the anti-ionizing radiation powder with the core-shell heterogeneous gradient structure. Through cooperation of the core-shell heterostructure, the high-atomic-number oxide, the low-atomic-number oxide and the multi-element rare earth element, the shielding performance of the material is remarkably improved.

The invention relates to the field of inorganic material preparation, and provides a bismuth hydroxide material and a preparation method thereof. The bismuth hydroxide is sphere-like nano-particles with the particle size of 85-175 nm, the dispersity is good, and the purity exceeds 99.8%. The preparation method comprises the following steps: preparing a micelle solution from a polyethylene glycol-polylactic acid (PEG-PLA) block copolymer, adding bismuth salt into the micelle solution, carrying out a reaction, and carrying out centrifugation, washing and vacuum drying to obtain the product. Due to the unique amphipathy of the PEG-PLA micelle, bismuth ions are uniformly distributed, and the uniformity of particles is improved; the hydrophilic chain segment forms steric hindrance to inhibit particle aggregation; meanwhile, the reaction rate is slowed down, and high-concentration ammonia water is combined to ensure high purity of the product. The method overcomes the problems of uneven particle size and agglomeration in traditional preparation.

The present application relates to a kind of preparation method of bismuth trifluoride, belong to bismuth compound preparation technical field.The preparation method of bismuth trifluoride of the present application includes the following steps: bismuth-containing compound powder is hydrothermally reacted with hydrofluoric acid;The bismuth-containing compound is one or any combination of bismuth oxide, bismuth oxychloride, bismuth trichloride.The preparation method of bismuth trifluoride of the present application carries out hydrothermal reaction to bismuth oxide, bismuth oxychloride, bismuth trichloride and hydrofluoric acid, and the high temperature and high pressure generated by hydrothermal reaction are used to improve the reactivity, solve the problem that bismuth oxide, bismuth oxychloride and bismuth trichloride are not completely reacted with hydrofluoric acid under normal pressure, resulting in low yield and low purity, product can be obtained by one-step reaction.The preparation method of bismuth trifluoride of the present application is simple, and route is short, the solvent used is water, cost is low, yield is high, and it is economic and environmental protection.

The invention discloses a preparation method of stable in-situ 14: 24 AEC second-phase Bi-2212 powder, which comprises the following steps: preparing powder with specific components by controlling the components of a Bi-2212 precursor solution, and then adjusting by a fine heat treatment process to obtain the stable in-situ 14: 24 AEC second-phase Bi-2212 powder. According to the method disclosed by the invention, components of a Bi-2212 precursor solution are controlled, the components of Bi-2212 precursor powder after heat treatment and the molar ratio of Sr to Ca are monitored to be within a specific range, and a heat treatment process is matched for adjustment, so that stable generation of a 14: 24 AEC second phase in the Bi-2212 precursor powder is ensured; the self-generated 14: 24 AEC second phase can improve the critical current density of the Bi-2212 superconducting material; the method is easy to operate, low in cost, high in controllability and operability and suitable for being rapidly applied to the field of Bi-2212 superconducting material preparation.

The invention provides a Bi-doped SnO catalyst and a preparation method and application thereof, a gas diffusion electrode and a preparation method and application thereof, and belongs to the technical field of catalyst preparation. The preparation method comprises the following steps: mixing divalent metal tin salt, a regulator and bismuth salt in water to obtain a mixed solution; and mixing the mixed solution with a sodium hydroxide solution, and reacting to obtain the Bi-doped SnO catalyst. The preparation method is simple, rapid, low in cost, green and free of organic solvent or high-temperature treatment, and the prepared catalyst is stable in structure and lasting in performance. The Faraday efficiency of a gas diffusion electrode prepared by adopting the Bi-doped SnO catalyst for synthesizing formic acid through electrocatalytic reduction of CO2 at-850 mA / cm < 2 > is as high as 98%, the gas diffusion electrode can stably run for more than 140 h under N2 purging in a solid electrolytic tank, and the concentration of formic acid continuously produced exceeds 5 mol / L.

The invention discloses a preparation method of nuclear radiation protective clothing, and belongs to the technical field of nuclear radiation protection. The raw materials comprise, by weight, 80-100 parts of polyester chips, 15-29 parts of modified nanometer bismuth oxide, and 12-18 parts of tungsten boride. According to the prepared protective clothing, polyester serves as a base material, the comfort level is high, wrinkles are not prone to occurring, by adding tungsten boride and modified nanometer bismuth oxide, the protective clothing is endowed with excellent shielding performance, flame retardance and aging resistance, and the protective clothing is free of lead and toxicity and environmentally friendly; the weaving technology and the coating compounding technology are combined, the coating contains polypyrrole, the shielding performance of the protective clothing can be further improved, and in conclusion, the protective clothing has important application value in the technical field of nuclear radiation protection.

The invention discloses a bismuth oxide-based fuel cell electrolyte material and a preparation method thereof, and relates to the technical field of cell electrolyte materials. The material is composed of a trication-doped delta-Bi2O3 core and a zirconium oxide coating layer, the trication-doped delta-Bi2O3 core is co-doped with erbium, tungsten and aluminum ions, and the material comprises the following components in parts by mass: 75-80 parts of bismuth oxide (Bi2O3); 14 to 19 parts of erbium oxide (Er2O3); 1 to 3 parts of tungsten oxide (WO3); 1 to 3 parts of aluminum oxide (Al2O3); the zirconium oxide coating layer is formed by a coprecipitation method, and the thickness of the zirconium oxide coating layer is 5-20nm, so that the technical problems that the working temperature range of delta-Bi2O3 is difficult to broaden, and the low-temperature phase change and reduction under low oxygen partial pressure are difficult to inhibit are solved.

The invention provides a process for the preparation of a bismuth sodium titanate (BNT) compound of formula (I) wherein A is one or more of Bi, Na, Li, K, Mg, Ca, Sr, Ba, La, Al, Cu, Eu, Ag and Zn; B is one or more of Ti, Nb, Ta, Zr, Fe, Nd, Eu and Co; 0 < x < 0.8; 0 <y < 0.8; and -0.1 < z < 0.1; said process comprising spray pyrolysis of a solution comprising Bi ions, Na ions, Ti ions and, if present, metal (A) and / or metal (B) ions.

Preparation method and application of bismuth sulfide / zinc oxide heterojunction material, which solves the problem that the gas sensor prepared from Bi2S3-based heterostructure can only detect H2S gas under dark conditions, while there are still problems of low response value and poor selectivity under visible light conditions. Method: Synthesize Bi2S3 nanowires, and mechanically mix them with ZnO nanoparticles to form a Bi2S3 / ZnO heterostructure. Regulate the quantity of zinc oxide, change the electronic structure of bismuth sulfide, improve the surface adsorption active sites, and then improve the response value and selectivity for detecting H2S under room temperature visible light, and shorten the response time. After the surface of Bi2S3 nanowires is modified with ZnO in the present invention, it has a response value of 16.0 times for 500 ppb of H2S under room temperature visible light, the response time is only 51.6 s, and it has good selectivity, low cost and simple process, and is suitable for industrial production. It is used for rapid detection of H2S under room temperature and visible light conditions.

The invention relates to a preparation method and application of an ultra-efficient nitrate-based free radical activation catalyst, and the preparation method comprises the following steps: S1, dissolving bismuth nitrate Bi (NO3) 3.5 H2O and polyvinylpyrrolidone (PVP) in a mannitol solution; s2, adding potassium bromide into the solution in the step S1, and performing ultrasonic treatment to form a white suspension; s3, transferring the suspension into a high-pressure reaction kettle for hydrothermal reaction; and S4, after the reaction is completed, cooling, centrifugally collecting precipitates, washing, and carrying out vacuum freeze drying to obtain the bismuth oxybromide BixOBr nanosheet catalyst. According to the application of the super-efficient nitrate-based free radical activation catalyst in degradation of organic pollutants, the bismuth oxybromide BixOBr nanosheet catalyst is added into a water body containing nitrate, the nitrate is activated to generate free radicals by utilizing the piezoelectric effect induced by photoinduced deformation of the photocatalyst under the condition that an external electric field and an oxidizing agent are not needed, and the degradation efficiency of the nitrate-based free radical activation catalyst is improved. Therefore, organic pollutants are degraded.

Aspects of the present disclosure are directed towards a method for producing an activated carbon / bismuth oxy-iodide nanocomposite. The method includes heating a glycol solution including Bi(NO3)3·5H2O and activated carbon to 100° C. The method includes heating a glycol solution includes potassium iodide to 100° C. The method includes adding the glycol solution including Bi(NO3)3·5H2O and activated carbon and the glycol solution including potassium iodide to a reaction vessel including a solvent to form a reaction mixture. The method includes chilling the reaction mixture to ambient temperature. The method includes filtering the reaction mixture to obtain the activated carbon / bismuth oxy-iodide nanocomposite.

The invention relates to a preparation method and application of a monolayer assembled bismuth subcarbonate nanosheet catalyst precursor. The preparation method comprises the following steps: 1) dissolving bismuth salt in water, adding triethanolamine, and stirring and mixing to form a uniform white solution; 2) adding an alkaline substance into the solution obtained in the step 1), and adjusting the solution to be alkaline; 3) heating and reacting the solution obtained in the step 2) to obtain a suspension containing white bismuth subcarbonate nanosheets; 4) carrying out solid-liquid separation on the suspension obtained in the step 3), collecting a white solid product, washing and drying to obtain a monolayer assembled bismuth subcarbonate nanosheet precursor; the morphology is formed by orderly assembling small-size nanosheets in a single layer in the two-dimensional plane direction, stacking and gathering of the nanosheets can be effectively inhibited, and exposure and structural stability of effective active sites are remarkably improved. When applied to the field of electrochemical carbon dioxide reduction, the catalyst can continuously run for 300 hours at the current density of 100 mA. Cm <-2 >, and the average formic acid Faraday efficiency reaches 82.6%.

Aspects of the present disclosure are directed towards a method for producing an activated carbon / bismuth oxy-iodide nanocomposite. The method includes heating a glycol solution including Bi(NO3)3·5H2O and activated carbon to 100° C. The method includes heating a glycol solution includes potassium iodide to 100° C. The method includes adding the glycol solution including Bi(NO3)3·5H2O and activated carbon and the glycol solution including potassium iodide to a reaction vessel including a solvent to form a reaction mixture. The method includes chilling the reaction mixture to ambient temperature. The method includes filtering the reaction mixture to obtain the activated carbon / bismuth oxy-iodide nanocomposite.

The invention belongs to the technical field of electrochemical sensing, and discloses a preparation method and application of BiOCl and a bismuth membrane electrode. The preparation method of BiOCl comprises the following steps: heating and dissolving bismuth nitrate into concentrated nitric acid, then adding bismuth trioxide into the solution, then adding concentrated hydrochloric acid, fully stirring, standing and cooling to room temperature to obtain a solution A; preparing a 15-25 wt% sodium hydroxide solution as a solution B; the preparation method comprises the following steps: adding water into a reaction container, heating to 65-85 DEG C, then adding concentrated hydrochloric acid, then adding a non-sulfur non-phosphorus surfactant while stirring, stirring until the solution is clear, simultaneously dropwise adding the solution A and the solution B into the reaction container, reacting for 15-15.5 hours, then dropwise adding the solution B again, adjusting the pH value of the solution to 9-11, cooling to room temperature, and drying to obtain the target product BiOCl. The bismuth membrane electrode is obtained by modifying a carbon fiber electrode with BiOCl. The bismuth membrane electrode can be used for detecting one or two of Pb < 2 + > content and Cd < 2 + > content in a water body / blood, and can also be used for integrating a portable heavy metal detection device.

This invention relates to the field of inorganic photochromic materials, specifically to an inorganic photochromic material, its preparation method, and its applications. Compared with existing technologies, the preparation method provided by this invention uses potassium carbonate, bismuth oxide, and titanium dioxide in a molar ratio of potassium, bismuth, and titanium of 1:3:4-x as raw materials, where 0≤x≤1, and calcines at a high temperature of 900℃~1000℃ to prepare an inorganic photochromic material with good photochromic properties and reversibility. The preparation method of this invention is simple, the raw materials are readily available, and the preparation cost is low. Furthermore, the irradiation light source required for the prepared inorganic photochromic material is a common 365nm ultraviolet light source, resulting in low application cost. Therefore, it solves the technical problem that existing inorganic photochromic materials cannot be applied to large-scale industrial applications. Experimental results show that the inorganic photochromic material prepared by the method of this invention can be successfully used to prepare anti-counterfeiting and encryption materials.

The present invention relates to bismuth oxide nanoparticles that are surface-treated with a hydroxyl group-free carboxylic acid (a) and a hydroxyl group-containing carboxylic acid (b), as well as a production method for bismuth oxide nanoparticles, including a step of mixing and heating a hydroxyl group-free carboxylic acid (a), a hydroxyl group-containing carboxylic acid (b), and triphenylbismuthine (c).

The invention relates to a Bi2O3 / Bi-Nx co-doped carbon-based composite coating material as well as a preparation method and application thereof, the composite coating material is prepared by taking SiO2 nanospheres as a hard template and polyquaternium-7 as a nitrogen source, forming a three-dimensional carbon skeleton structure with hierarchical pores after alkali etching, and then performing acid pickling and secondary carbonization processes. According to the preparation method, a composite active center system of the atomic-scale dispersed bismuth and the Bi2O3 phase is successfully constructed, the zinc deposition behavior is optimized by precisely regulating and controlling the synergistic effect mechanism of the atomic-scale dispersed bismuth and the Bi2O3 phase, and the zinc anode coating with high zinc affinity and long cycle stability is prepared.

A particulate crystalline nanocomposite including: a monoclinic bismuth oxide (Bi2O3) crystalline phase; a calcium silicate (CaSiO3) crystalline phase; and, a graphitic carbon nitride (g-C3N4) crystalline phase, wherein at least a fraction of the g-C3N4 is in the form of mesoporous nanosheets.

This invention belongs to the field of photoelectric active materials and photoelectric sensing analysis technology, specifically relating to a Z-type heterojunction composite material, its preparation method, and its application. The composite material uses Ti-MOF as a precursor, annealing to obtain carboxyl-functionalized p-type 2DTiO2@C nanocakes. Chemical reduction forms AuNPs in situ on the surface of the 2DTiO2@C nanocakes, obtaining p-type 2DTiO2@C / Au nanocakes. Amino-modified p-type 3D peony-shaped BiOI is added to the p-type 2DTiO2@C / Au nanocakes, and electrostatic interaction yields the 2DTiO2@C / Au / 3DBiOI Z-type heterojunction composite material. This invention uses a metal-organic framework template-assisted calcination method, chemical reduction, and electrostatic interaction to design and prepare the Z-type heterojunction composite material, improving photoelectric activity and achieving rapid, highly sensitive, accurate, and reliable detection of hexavalent chromium ions.

The present invention belongs to the field of the development of new adsorbents and comprehensive utilization of resources, and discloses a preparation method of an inorganic tin sulfide adsorbent and its application in cesium extraction. The adsorbent is synthesized by a hydrothermal method and has a lamellar structure. It has excellent ion exchange performance for alkali metal cesium ions in an aqueous solution and exhibits excellent adsorption selectivity. The adsorbed material can be regenerated, thus realizing the recycling of the adsorption material. The preparation process of the adsorption material provided by the present invention is simple and low in cost. Therefore, the adsorption material prepared by the present invention can be used for the extraction of cesium in geothermal water, salt lake brine, and underground brine, and can also be applied to the separation and extraction of cesium in solid cesium ore or associated ore leaching solutions.

The application discloses a flower ball-shaped bismuth disulfide / tungsten disulfide composite material and a preparation method and application thereof. Tungsten hexachloride is added into anhydrous ethanol solution and fully stirred, then bismuth nitrate pentahydrate is added into the mixed solution and stirred to uniformly disperse the bismuth nitrate pentahydrate into the solution, then thioacetamide is added and stirred to be uniform, the obtained solution is moved into a reaction kettle, and the reaction kettle is sealed and placed into a homogeneous reactor; after the reaction is completed, the product is taken out, washed and fully dried in a vacuum oven to obtain the composite material. The composite material has a thickness of 20-30 nm, and nanosheets are vertically grown on a self-assembled flower ball-shaped structure with a diameter of 350-400 nm; the composite material can be applied to preparation of a potassium ion battery negative electrode material, and the structure is more stable, the conductivity is better, and the electrochemical performance is greatly improved.

The application provides a core-shell heterogeneous gradient structure anti-ionizing radiation powder and a preparation method and application thereof, and belongs to the field of radiation protection. The preparation method of the core-shell heterogeneous gradient structure anti-ionizing radiation powder comprises the following steps: adding a high-atomic-number metal salt into deionized water, sequentially performing aging, washing, drying and primary calcination to obtain a core layer; adding the core layer and a low-atomic-number metal salt into deionized water, sequentially performing aging, washing, drying and primary calcination to obtain a preliminary wrapped powder in which a low-atomic-number metal wraps a high-atomic-number metal core layer; adding the preliminary wrapped powder and a rare earth salt into deionized water, sequentially performing aging, washing, drying, primary calcination, secondary calcination, airflow pulverization and air rotation blowing to obtain the core-shell heterogeneous gradient structure anti-ionizing radiation powder. Through the synergy of the core-shell heterogeneous structure, high-atomic-number and low-atomic-number oxides and multiple rare earth elements, the shielding performance of the material is significantly improved.

The present invention relates to 2D bismuth material, also called bismuthene, with a sandwich-like sheet structure with at least two outer layers formed by organic molecules containing sulphur atoms that form Bi-S bonds and at least one inner layer formed by a crystalline network of Bi(0) atoms. These materials are useful in electronic, optoelectronic, catalytic applications or in energy storage and transformation. Furthermore, it relates to a process for producing this material from a bismuth salt that reacts with an amine and subsequently with a thiol by effect of the application of radiation and a subsequent reduction. This process has a colloidal approach to producing Bi(0) crystals based on a photocatalytic reduction of a soluble Bi(III) organometallic complex leading to the generation of said crystals.

Formula (I): L n D m (B x B’ 1-x ) r (Z t Z’ 1-t ) q M p A y A’ s (I) wherein n, m, x, r, t, q, p, y, s, L, D, B, B’, Z, Z’, M, A, and A’ are as defined herein. These compounds can exhibit superconductivity at high temperatures.

Systems and methods for generating radionuclides, such as radium-224. Systems herein may include a first cartridge having a first opening, a second opening, and a chamber therebetween having a first resin having affinity for thorium-228 and bismuth-212; a second cartridge having a first opening, a second opening, and a chamber therebetween having a second resin having affinity for thorium-228 and bismuth-212, a third cartridge having a first opening, a second opening, and a chamber therebetween comprising a third resin having affinity for thorium-228 and bismuth-212, a fourth cartridge having a first opening, a second opening, and a chamber therebetween having a third resin having affinity for lead-212; wherein a continuous flow path is formed from a top of the first cartridge though the second cartridge, through the third cartridge, and to a bottom of the fourth cartridge during system use.

The invention belongs to the technical field of photocatalytic plastic degradation, and particularly relates to a chlorine free radical photocatalyst, a preparation method thereof and application of the chlorine free radical photocatalyst to plastic degradation. The chlorine free radical photocatalyst is a bismuth oxychloride photocatalyst rich in oxygen vacancies; the bismuth oxide is obtained through solvothermal reaction of bismuth salt and halide, washing and drying. According to the photocatalyst, Cl <-> free radicals are generated in situ through photo-generated hole oxidation interlayer Cl <-> in a sodium chloride solution system, and a hydrogen atom transfer reaction of a polyolefin C-H bond is initiated; cl. Free radicals form carbon center free radicals by capturing hydrogen atoms of a polyethylene molecular chain, a beta-chain breakage mechanism is triggered in the presence of oxygen, and controllable cracking of a C-C bond is realized to generate a high-added-value liquid product; therefore, the photocatalyst is used for degradation of polyolefin plastics, and degradation products comprise carbon dioxide, alcohols, acids and other products with high added values. The photocatalyst has good chemical stability and photocatalytic activity, is free of additional photosensitizer and sacrificial agent, and is suitable for large-scale industrial application.

The invention discloses a nanometer long rod-shaped Bi2Ti4O11 / BiOCl composite photocatalyst and a preparation method of the nanometer long rod-shaped Bi2Ti4O11 / BiOCl composite photocatalyst. The preparation method specifically comprises the following steps: mixing raw materials such as B2O3, Bi2O3, R2O, TiO2 and the like according to a certain proportion, melting at a high temperature to prepare glass, crushing the glass into glass powder, and preparing the glass ceramic powder containing Bi2Ti4O11 long rod-shaped crystals by using a glass crystallization process. The preparation method comprises the following steps: preparing a Bi2Ti4O11 crystal, stirring and soaking glass ceramic powder in diluted hydrochloric acid for a period of time, carrying out acid pickling to remove a glass phase, and reacting the Bi2Ti4O11 crystal with hydrochloric acid to generate a BiOCl crystal on the surface of the Bi2Ti4O11 crystal, thereby obtaining the pure nano long rod-shaped Bi2Ti4O11 / BiOCl composite catalyst. The preparation method disclosed by the invention has the beneficial effects that the prepared nano long-rod-shaped Bi2Ti4O11 / BiOCl composite catalyst is relatively low in cost and high in photocatalytic degradation efficiency.

This invention discloses a composite modified lithium manganese oxide cathode material, its preparation method, and its applications, belonging to the field of cathode material technology. The structural formula of the composite modified lithium manganese oxide cathode material is: LiX a O b @LiYO2 / LiMn2O4, comprising: a core composed of LiYO2 and LiMn2O4, and LiX coating at least a portion of the surface of the core. a O b The coating layer; wherein: LiMn2O4 has a porous structure, and LiYO2 fills the channels of LiMn2O4. The cathode material in this invention uses lithium manganese oxide as a matrix, with LiYO2 filling the channels of the matrix, and LiX coated on the surface of the matrix. a O b Filling the pores with LiYO2 can reduce the Jahn-Teller effect of lithium manganese oxide without affecting the specific capacity of the cathode material. Moreover, LiYO2 can accelerate the lithium-ion diffusion rate, thereby improving the rate performance of the material.

The invention discloses a defect-engineered nanosheet material for an alkaline aqueous battery as well as a preparation method and application of the defect-engineered nanosheet material, and belongs to the technical field of nano materials and electrochemical energy storage. The method comprises the following steps: firstly, dissolving 1, 3, 5-benzene tricarboxylic acid and bismuth nitrate pentahydrate in methanol, and carrying out hydrothermal reaction to obtain a bismuth-based metal-organic framework precursor; and then dispersing the precursor and ammonium halide in deionized water, and carrying out ion etching reaction through oil bath heating to obtain the bismuth oxyhalide nanosheet material. The prepared material has a self-supported hierarchical porous nanosheet structure, the surface of the material has wrinkles and pore channels, and the material contains oxygen vacancies and low-valence bismuth defects. The material can be used as a negative electrode to be applied to an alkaline aqueous battery, and after the material, a positive electrode material and alkaline electrolyte are assembled into a battery, the battery has high specific capacity, excellent rate capability and good cycle stability. The preparation method is simple in process and mild in condition, and the material performance can be optimized by adjusting etching parameters.

The application relates to a preparation method and application of a multilayer shell-shaped bismuth oxide / bismuth / carbon composite material and belongs to the technical field of lithium ion batteries. Bismuth nitrate pentahydrate and ethylene glycol are added into an ethanol solvent and uniformly ultrasonically mixed, then are placed in a solvent thermal reaction at a temperature of 180-200 DEG C for 150-180 min, are cooled to room temperature, are subjected to solid-liquid separation, and the solid is sequentially washed by deionized water and ethanol and is dried to obtain multilayer shell-shaped bismuth oxide; glucose and the multilayer shell-shaped bismuth oxide are added into deionized water and uniformly ultrasonically mixed, then are placed in a hydrothermal reaction at a temperature of 180-200 DEG C for 120-180 min, are subjected to solid-liquid separation, and the solid is sequentially washed by deionized water and ethanol and is dried to obtain a precursor; the precursor is uniformly heated to a temperature of 400-600 DEG C under an argon atmosphere and is calcined at a constant temperature for 1-2 h to obtain the multilayer shell-shaped bismuth oxide / bismuth / carbon composite material. The multilayer shell-shaped bismuth oxide / bismuth / carbon composite material has a high specific surface area, and as a lithium ion battery negative electrode, can relieve the huge volume expansion of a lithium ion battery in a lithiumation process.