This invention relates to an In2S3 / In2MnS4 photoelectrocatalyst for the production of H2O2 or HClO and its preparation method, belonging to the field of high-value-added chemicals and catalyst production technology. In2S3 hollow hierarchical microtubes are obtained through a solvothermal method, and Mn is converted into
hydrogen through
ion exchange. 2+ Partial exchange In 3+ An In2S3 / In2MnS4 photocatalyst was obtained. An In2S3 / In2MnS4 / PVDF / NF
photocathode was obtained by loading In2S3 / In2MnS4 onto PVDF-modified
nickel foam, and an In2S3 / In2MnS4 / CP photoanode was obtained by drop-
coating In2S3 / In2MnS4 onto
carbon paper. Under
visible light irradiation and a specific additional bias
voltage, the yields of H2O2 and HClO produced by the catalytic process reached 2107.8 μmol / L and 28.5 mg / L, respectively, within 90 min. This invention is simple, efficient, and low-cost, and can be applied to the photoelectric production of H2O2 and HClO.