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30results about How to "Abundant and cheap" patented technology

Method for preparing pentanol through hydrogenation of 2-methylfuran by using platinum-based catalyst

The invention provides a continuous-flow preparation method for a platinum-based catalyst. Compared with an impregnation method with the defects that time is long, selectivity is low, the manipulation of operators is depended, uneven mixing is easy to cause and the like, the continuous-flow preparation method of the platinum-based catalyst has the advantages of being simpler and more efficient and capable of realizing one-step and continuous production. According to the method, a pipe diameter of several millimeters is adopted, so the specific surface area of reaction liquid is greatly increased, mass and heat can be quickly transferred, and reaction liquid can be better mixed uniformly. Secondly, different amounts of solvents and reaction temperatures are screened, and a solvent dosage and an optimal reaction temperature are determined, so the conversion rate of pentanol prepared through hydrogenation of 2-methylfuran can reach 100% and the selectivity of pentanol is 70%, but however the selectivity of pentanol prepared through hydrogenation of 2-methylfuran by using a platinum-based catalyst prepared through the impregnation method is 53%; and the catalytic efficiency of the catalyst prepared by using the method can be improved by nearly 20% compared with the catalytic efficiency of the catalyst prepared by using the impregnation method. Mechanical operation can avoid human errors, so a result is easier to repeat, production efficiency is improved, and a new way is provided for preparing alcohol compounds by catalytic hydrogenation of furan derivatives.
Owner:NANJING UNIV OF TECH

Clinoenstatite microcrystalline glass prepared by talcum and process for same

The invention relates to clinoenstatite microcrystalline glass prepared by talcum and a process for the same, wherein the process comprises the following preparation steps of: 1) weighing raw materials containing talcum, quartz, clay and sodium carbonate; 2) uniformly mixing the raw materials, heating in a silicon-molybdenum electric furnace, taking out a crucible from the electric furnace, pouring the molten glass obtained in the crucible in a pre-heated mould to mould, and then transferring into a muffle furnace, insulating for 1-2 hours at 600 DEG C, and cooling with the furnace to obtain base glass; and 3) heating the base glass obtained in the step 2) in a silicon carbide rod electric furnace with a heating speed of 5-8 DEG C / min, insulating for 1-2 hours at 950-1000 DEG C according to the thickness of a test sample, and cooling with the furnace to obtain the microcrystalline glass. The clinoenstatite microcrystalline glass prepared by talcum and the process for the same disclosed by the invention have the following advantages that: 1) the used raw materials containing talcum, quartz and clay are raw mineral materials very rich in resource and low in price; 2) preparation process is simple; and 3) crystallization for glass has no need of additional nucleating agent, and crystallization velocity is fast.
Owner:WUHAN UNIV OF TECH +1

Method for preparing hierarchical pore SAPO-20 molecular sieve from illite

The invention belongs to the technical field of chemical material synthesis, and relates to a method for preparing a hierarchical pore SAPO-20 molecular sieve from illite. The method comprises the following steps: 1) calcining illite minerals and sodium carbonate to obtain activated illite; 2) mixing the activated illite with hydrochloric acid according to a mass-volume ratio of 1g to 13.5 mL, and stirring, centrifuging, washing and drying the mixture to obtain activated illite silicon slag; 3) mixing deionized water, a phosphorus source, an aluminum source, a microporous template agent, a mesoporous template agent, the acid-washed activated illite silicon slag and ethanol to obtain reactant gel, and crystallizing, centrifuging, washing, drying and calcining the reactant gel to obtain molecular sieve raw powder; and 4) calcining the molecular sieve raw powder in flowing air, and cooling the powder to obtain the hierarchical pore SAPO-20 molecular sieve. The hierarchical pore SAPO-20 molecular sieve is synthesized by taking the natural illite mineral as the raw material, so that the raw material source of the hierarchical pore SAPO-20 molecular sieve is broadened; the method has the advantages of short production process and low energy consumption, and the synthesis cost is greatly reduced.
Owner:XIAN UNIV OF SCI & TECH

Non-isocyanate polyurethane and preparation method thereof

The invention discloses non-isocyanate polyurethane and a preparation method thereof, and belongs to the technical field of adhesives, and the preparation method comprises the following steps: mixinga trifunctional aziridine polymer, a double-terminal allyl compound, hydrogen type macroporous cation exchange resin containing hydrogen ions and a catalyst, and introducing CO2 for reaction under a vacuum condition; adding a difunctional aziridine polymer, a double-terminal allyl compound, 2, 3-epoxysuccinic acid and a solvent, and introducing CO2 under a vacuum condition to react; and filteringthe macroporous cation exchange resin, distilling the solvent, and adjusting the solid content to obtain the non-isocyanate polyurethane. According to the preparation method, isocyanate is not used inpolyurethane preparation, CO2 and an aziridine polymer are used as raw materials for reaction synthesis of polyurethane, CO2 is non-toxic, rich in resource and low in price, the aziridine polymer islow in volatility and friendly to operators and the environment in the production process, and the preparation method is a safe and environment-friendly production mode, the polyurethane prepared by the preparation method is excellent in performance and can replace the existing isocyanate polyurethane.
Owner:福建华夏蓝新材料科技有限公司

Clinoenstatite microcrystalline glass prepared by talcum and process for same

The invention relates to clinoenstatite microcrystalline glass prepared by talcum and a process for the same, wherein the process comprises the following preparation steps of: 1) weighing raw materials containing talcum, quartz, clay and sodium carbonate; 2) uniformly mixing the raw materials, heating in a silicon-molybdenum electric furnace, taking out a crucible from the electric furnace, pouring the molten glass obtained in the crucible in a pre-heated mould to mould, and then transferring into a muffle furnace, insulating for 1-2 hours at 600 DEG C, and cooling with the furnace to obtain base glass; and 3) heating the base glass obtained in the step 2) in a silicon carbide rod electric furnace with a heating speed of 5-8 DEG C / min, insulating for 1-2 hours at 950-1000 DEG C according to the thickness of a test sample, and cooling with the furnace to obtain the microcrystalline glass. The clinoenstatite microcrystalline glass prepared by talcum and the process for the same disclosed by the invention have the following advantages that: 1) the used raw materials containing talcum, quartz and clay are raw mineral materials very rich in resource and low in price; 2) preparation process is simple; and 3) crystallization for glass has no need of additional nucleating agent, and crystallization velocity is fast.
Owner:WUHAN UNIV OF TECH +1

A kind of method that utilizes platinum-based catalyst to be used for the hydrogenation of 2-methylfuran to prepare pentanol

The invention provides a continuous flow preparation method of a platinum-based catalyst. Compared with the impregnation method, the time is long, the selectivity is low, and it depends on the operator's technique and the problems of easy mixing and unevenness. The method is simpler and more efficient, and can be produced in one step and continuously . The method adopts a pipe diameter of several millimeters, which greatly increases the specific surface area of ​​the reaction liquid, and can quickly transfer heat and mass, and the reaction liquid can be better mixed evenly. Secondly, this method has screened different amounts of solvents and reaction temperatures, determined the amount of solvent and the optimal reaction temperature, and can make 2-methylfuran hydrogenation to prepare amyl alcohol conversion rate can reach 100%, and the selectivity of amyl alcohol is 70%. %, while the platinum-based catalyst prepared by the impregnation method has a selectivity of 53% for the hydrogenation of 2-methylfuran to pentanol, and the catalytic efficiency can be improved by nearly 20% compared with the impregnation method. The mechanized operation can avoid human error, make the results more repeatable, improve the production efficiency, and provide a new way for the catalytic hydrogenation of furan derivatives to prepare alcohols.
Owner:NANJING TECH UNIV
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