1898 results about "Acid hydrolysis" patented technology

A method is disclosed for the acid hydrolysis of carbohydrates in or from biomass, using a solvent system including an aqueous ether, where the ether form a majority of the system, which affords high yields to the platform chemicals such as 2-furfural and 5-hydroxymethylfurfural (5-HMF). The later can also undergo a domino reaction to chemicals including levulinic acid, particularly with oxygenated anions and greater water content. A total dissolution and reaction of biomass occurs under a range of relatively mild conditions (combined Severity range ˜2.2-2.6). Lignin and lignin derived products can be easily separated by precipitation.

The invention discloses a method for efficiently hydrolyzing lignocellulosic biomass and synchronously preparing multi-component liquid glucose and lignin. The method comprises the steps that: the lignocellulosic biomass through physical crushing is added with phosphoric acid to perform acid hydrolysis; then organic solvent is added to extract the lignin, the layering and the phase separation are performed, then the lignin is extracted out while the organic solvent is reclaimed under the condition of pressure reduction and distillation; phosphoric acid can be reclaimed through steps such as neutralization, filtration, acidification and so on, hemicellulose hydrolyzed liquid glucose is obtained at the same time; and the remained cellulose undergoes the zymohydrolysis to prepare cellulosic hydrolyzed liquid glucose. The method can separate lignin, hemicellulose and cellulose, remarkably decreases the degree of crystallinity of the cellulose hydrolyzed by phosphoric acid, and remarkably improves the zymohydrolysis efficiency; and the prepared hydrolyzed liquid glucose does not contain fermentation inhibitors. The method has mild treatment conditions, simple process and less side reactions; the phosphoric acid and the organic solvent can both be reclaimed and circularly used; and the method is environment-friendly, and has broad social and economic benefits.

The invention relates to a method for recycling titanium dioxide in a waste SCR (Selective Catalytic Reduction) denitration catalyst. The method comprises the following steps of: firstly removing dust from the waste denitration catalyst, pulverizing, then adding concentrated sulfuric acid so as to carry out acid hydrolysis on the waste denitration catalyst to obtain a concentrated titanyl sulfate solution, and adding water for dilution; adding a non-ionic emulsifier serving as a flocculating agent and a sulfonate surface active agent or a polycarboxylate surface active agent as a coagulant aid, and adding water-solubility methyl silicone oil; pumping into a plate-and-frame filter press for filter pressing, carrying out vacuum concentration on filtrate, then heating to 90 DEG C to 98 DEG C, and maintaining for 5.5 hours so as to hydrolyze the filtrate; cooling a hydrolysis product to 40 DEG C, and carrying out vacuum filtration so as to sediment out metatitanic acid; rinsing with sand-filtered water and deionized water, and adding potassium carbonate or phosphorous acid to obtain metatitanic acid filter cakes; and drying the filter cakes, calcining at 500-800 DEG C, and then pulverizing to obtain a titanium dioxide finished product. The method has the advantages of being capable of reducing disposal amount of the waste denitration catalyst, recycling the waste denitration catalyst and reducing the production cost of the waste denitration catalyst.

The invention provides a method for extracting small molecule oligopeptides from bird's nests by hydrolysis, which is to obtain a small molecular nano oligopeptide containing composition by hydrolyzing the bird's nests through the combination of enzymolysis and acid hydrolysis. The bird's nest oligopeptide composition is characterized in that: the molecular weight of the nano oligopeptides mainlyranges from 180 to 1,000D; preferably, the percentage of Gaussian distribution peak area of the nano oligopeptides with a molecular weight ranging from 180 to 1,000D in the composition is over 40 percent. The Cordyceps militarisoligopeptide extract provided by the invention retain other active ingredients such as polysaccharide, bird's nest sialic acid, micro elements and the like. The invention also relates to the use of the nano oligopeptide containing composition extracted from bird's nests in the preparation of medicines, health-care products and cosmetics.

The invention relates to a method for removing cadmium in rice protein, belonging to the technical field of further processing for rice. The method comprises the following steps of: taking rice protein powder, adding hot water for size mixing, uniformly mixing, and obtaining size with the concentration being 12-13 percent; and conducting an acid hydrolysis reaction, removing impurities, sterilizing, dewatering, drying, and obtaining a rice protein powder finished-product. The method has the beneficial effects that the content of cadmium in the rice protein can be effectively reduced, the appearance of the rice protein cannot be influenced, and the nutritional ingredients in the rice protein cannon be reduced.

Provided is a process for producing biomass-based product from straw hemicellulose and utilizing the components thereof thoroughly. Steam-explosion and acid-hydrolysis are combined in the pre-treatment of straw in the process, thus a higher concentration of a sugar liquid can be obtained, and furfural and acetic acid can be recovered. The hemicellulose obtained by the pre-treatment can be used directly as ferment materials for producing butanol, succinic acid, butylene glycol, lactic acid, hydrogen and firedamp, which reduces the cost of these biomass-based products. The cellulose and lignin obtained by extracting the straw with an alkaline solution can produce products, such as sodium hydroxymethyl cellulose etc. In the process, all components in the straw can be utilized thoroughly and waste and pollutant will not be produced.

The invention discloses a method for preparing 2-methyltetrahydrofuran from waste biomass, which comprises the following steps: carrying out acid hydrolysis reaction on the waste biomass to obtain furfural and levulinic acid; sequentially carrying out first hydrogenation reaction and second hydrogenation reaction on the furfural to obtain the 2-methyltetrahydrofuran; and carrying out hydrogenation reaction on the levulinic acid to obtain the 2-methyltetrahydrofuran. The method provided by the invention more sufficiently utilizes the waste biomass, and adopts non-noble metal catalysts, thereby lowering the production cost.

The invention provides a method for preparing liquid alkane fuel by upgrading bio-oil in an aqueous phase catalytic mode. The method comprises the following steps of: 1) pretreating the bio-oil to obtain a water-soluble component and a water-insoluble component; 2) performing a pressurized acid hydrolysis process on a furan compound of the water-insoluble component to prepare the furan compound; 3) performing a reforming and hydrogen production reaction on the water-soluble component; 4) mixing the furan compound with a liquid-phase product separated from the step 3) to perform an aldol condensation reaction to increase carbon chains; and 5) performing a hydrogenation and dehydration reaction on an aldol condensation product to obtain liquid linear alkane. The method has the advantages that: an upgrading process, which is performed in a double-phase system, can effectively contribute to the desorption of an intermediate product from the surface of a catalyst and the mass transfer of an upgraded product, and can reduce the risk of carbon deposition on the surface of the catalyst; the quality of oil obtained by the method is high; the energy density and the energy grade of the bio-oil are improved greatly; and the liquid alkane fuel can be obtained from all kinds of bio-oil so as to partially substitute for the conventional widely-used fossil gasoline and diesel oil fuel.

The invention relates to a preparation method of a human milk fat substitute. The method comprises the steps of: step 1) conducting an acid hydrolysis reaction on a raw material of high melting palm stearin subjected to chemical interesterification and alcohol leaching, and an acyl donor of rapeseed oil fatty acid by using Lipozyme RM IM as a catalyst, so as to reduce the total palmitic acid content and increase the relative content of site-two palmitic acid of the raw material; and step 2) deacidifying an intermediate product; and at the same time, calculating the amount of sunflower seed oil, rapeseed oil, palm kernel oil, algae oil and microbial oil added to the intermediate product according to the composition and distribution of fatty acids in human milk fat, by a grease adding model, so as to ensure composition and distribution of fatty acids in a final product meeting requirements of a human milk fat substitute, as well as realize a maximum addition amount. The invention adopts two steps to produce the human milk fat substitute, in order to reduce usage amount of free fatty acids in the acid hydrolysis reaction; meanwhile, two times of oil additions increase yield. Therefore, the invention greatly reduces the cost, and achieves a more than doubled yield compared with a similar products with a similar cost.

The invention discloses a method for concentrating waste sulfuric acid by utilizing waste heat of a titanium dioxide calcinator, comprising the following steps: at normal temperature and pressure, proper amount of water absorbent is added to titanium dioxide waste acid, liquid water is dissolved out in the form of solid crystal water through the water absorbent, filtrate after solid-liquid separation is cooled, iron vitriol in the solution is crystallized and dissolved out, and the acid liquid is further concentrated; the two steps are repeatedly carried out until the concentration of sulfuric acid in the final filtrate reaches more than 60%, and then the final filtrate is utilized in the acid hydrolysis procedure; and the water absorbent is dehydrated and dried to be regenerated by taking dustproof tail gas of the calcinator, and the steam generated in the drying and regeneration is cooled and flows back to technological process as washing water in titanic acid rinsing or is drained. The method provided by the invention solves the problems of more equipment, long flow and easy blockage in the existing technology, and the equipment investment and operating cost are reduced; and the water absorbent is recycled after being regenerated, so that the energy is saved, the consumption is reduced, and the efficiency is obvious; no wastewater, waste gases and residues are generated in the whole technology, the operability is strong, the productivity of equipment is high, the flow is simple, the investment is less, the cost is low, energy is saved, emission is reduced, and the benefit is obvious.

The invention relates to a method for hydrolyzing methyl chlorosilane with concentrated acids to obtain hydrolysate, wherein, the methyl chlorosilane and the acidic oil-contained aqueous solution separated from the primary phase separator and the secondary phase separator from the hydrolysate are mixed, pass through a preheater, enter a concentrated-acid hydrolysis reaction system and undergo a circular reaction operation; the hydrogen chloride generated in the hydrolysis reaction is released from the top of a tower, goes through a defroster and a condensator and then becomes qualified HCI gas to be used in the production of methyl chloride. Qualified hydrolysate used for decomposition process is obtained after the hydrolysate of methyl chlorosilane goes through four phase separators and a steam tower.

The invention discloses a method for preparing nano-cellulose crystal/polyaniline composite material and a product thereof. In the method, firstly, the cellulose is hydrolyzed by acid to obtain nano-cellulose crystals, and the suspension of the nano-cellulose crystals spontaneously forms lyotropic cholesteric liquid crystals at a certain concentration. Then, the nanocellulose crystal/polyaniline composite material product with reversible redox properties is prepared by in-situ polymerization reaction of the polyaniline conductive monomer in the nanocellulose crystal cholesteric liquid crystal. The invention has the advantages of low cost, simple synthesis method, high production efficiency and the like.

The present invention provides for a method of hydrolyzing a cellulose, hemicellulose, or ligno-cellulose comprising: (a) contacting (i) an ionic liquid (IL) or ionic liquid-aqueous (ILA) phase comprising cellulose, hemicellulose, or ligno-cellulose, or a mixture thereof, and (ii) an acid, such that the cellulose, hemicellulose, or ligno-cellulose is hydrolyzed into sugar, and (b) optionally adding water to the IL or ILA phase wherein the proportion of water in the IL or ILA phase does not exceed about 60% by weight. The present invention also provides for a method of recovering a sugar comprising contacting an IL or ILA phase and an organic phase comprising an organic acid.

This invention relates to a process for making dimensionally stable reconstituted composite products from lignocellulosic material. By treating lignocellulose with high pressure steam to decompose and hydrolyse the hemicellulose, cellulose and lignin fractions of the lignocellulose and using those decomposition products as both a bonding and bulking agent, it converts, under heat and pressure in a moulding operation, the treated lignocellulose into moulded composite products such as panel boards and moulded articles. The composite products thus produced possess good physical and mechanical properties. Specifically, the dimensional stability in terms of the thickness swelling and linear expansion of panel boards such as fibreboards and particleboard, can be minimized to very low levels when the panel boards are made in high density. The adhesive bond developed from thermosetting of the decomposition products of hemicellulose, cellulose and lignin is strong and stable, and resistant to boiling water and acid hydrolysis, and is free of formaldehyde emissions. Thus, the reconstituted panel boards and moulded products are suitable for exterior and particularly for indoor applications. The absence of free formaldehyde emissions makes the product very suitable for interior applications. The manufacturing cost for the reconstituted products is significantly lower in comparison to the conventional process because expensive synthetic resin is not used.

The invention discloses a method for preparing nano cellulose by simultaneous assistance of ultrasonic waves and microwaves, belonging to the field of biomass nano materials. According to the nano material, liquid acid is taken as a catalyst, and the high-efficiency hydrolysis at the amorphous area of cellulose is promoted due to the simultaneous assistance of the ultrasonic waves and microwaves, so that the nano cellulose is rapidly prepared by plant fiber raw materials. The preparation method comprises the steps of acid hydrolysis of plant cellulose, centrifugal recovery of liquid acid and centrifugal separation of nano cellulose. According to the method, the mechanical dispersion action and ultrasonic cavitation effect of the ultrasonic waves, microwave uniform heating effect, catalytic action of the liquid acid and the synergistic effect of the ultrasonic waves and microwaves are utilized sufficiently, and the hydrolytic process of cellulose is enhanced, so that the high-efficiency and rapid preparation of the nano cellulose can be realized. The prepared nano cellulose material can be used for food additives, drug excipients, engineering material additives, specialty paper additives and the like.

The invention relates to a co-production method of calcium sulfate whisker and phosphoric acid. The method comprises the following technical steps of: (1) acid-hydrolyzing phosphate rock powder by hydrochloric acid with the mass concentration of 15 to 26% or nitric acid with the mass concentration of 20 to 90%, filtering the acid-hydrolyzed slurry into the acid hydrolysis solution containing Ca2<+>; (2) using the acid hydrolysis solution containing Ca2<+> and the sulfuric acid with the mass concentration of 20 to 90% as the raw materials, wherein the use level of the sulfuric acid is 100% of the needed theoretical amount of the sulfuric acid when the Ca2<+> in the acid hydrolysis solution and the sulfuric acid react completely, adding the sulfuric acid to the acid hydrolysis solution containing Ca<2+> under the stirring condition, reacting the sulfuric acid with the acid hydrolysis solution containing Ca2<+> at the normal pressure and at 50 to 90 DEG, filtering and separating the calcium sulfate whisker after the reaction is finished, and then washing and drying the calcium sulfate whisker; and (3) carrying out the counter-current extraction on the filtrate obtained in the step (2), wherein the extracted water phase is the phosphoric acid, and acid-hydrolyzing the phosphate rock powder by using the hydrochloric acid obtained by the counter-extraction of the soft water to the extracted organic phase which is separated in the counter-current extraction.

The microwave catalytic biomass cracking process for preparing biological oil with rich furfural features using ferric sulfate as catalyst, silicon carbide as microwave absorbing medium, microwave source as heat source for cracking biomass, and ice water mixture for cooling volatile component to obtain biological oil with rich furfural. The present invention can obtain liquid product with furfural content of 35-55 % and raise the utilization value of furfural greatly. The present invention uses solid ferric sulfate catalyst and is superior to acid hydrolysis process with corrosion and pollution problems.

The invention relates to a production process for producing biomass based natural gas, lignose and microcrystalline cellulose by utilizing bamboo-curing waste, which solves the problem that the bamboo-curing waste is utilized economically and effectively. The production process comprises the following steps: performing steam exploded pretreatment to the bamboo-curing waste, lixiviating and separating the steam exploded materials by water, producing marsh by the anaerobic fermentation of liquid phase materials, obtaining bamboo cellulose filter residue and black liquid by the alkali treatment of solid phase materials, separating the black liquid from the lignose, and obtaining the microcrystalline cellulose by the acid hydrolysis of the bamboo cellulose filter residue. The production process has high transition heat energy and can realize energy regeneration of the marsh; the joint lignose and microcrystalline cellulose realizes the energy regeneration utilization of the waste. The production process belongs to a closed circulating system which has high economic benefit and environment-protection without pollution.

The invention provides II-type collagen joint cartilage fluid and a preparation method thereof. Bacteria, viruses and other hazardous substances of the joint cartilage are removed through degreasing-> serum removing-> surfactant treatment-> oxidant treatment-> disinfection and other links. Hybrid protein and other denatured protein of the cartilage are removed through acid hydrolysis, salt precipitation, dialysis and other processes, and high-purity and high-activity II-type collagen solution is prepared. Non-toxin and non-heat raw materials and auxiliary materials and isotonic solution are mixed in an appropriate ratio, and filled in a sterile non-heat disposable injector, to prepare II-type collagen joint cartilage fluid for disposable injection. Other components of the II-type collagen joint cartilage fluid comprise the auxiliary materials and the isotonic solution. The II-type collagen joint cartilage fluid can play the roles of lubrication, pain relieving and joint activity degree improving to the injured joints, fundamentally realizes the internal repair to the cartilage tissue, and is applicable to a patient with various joint cartilage injuries and all types of arthritis.

An energy-efficient cycle for the production of ethanol and optionally natural gas from sunlight and biomass comprising first producing or obtaining biomass, for example by planting and harvesting of either an annual or perennial crop or both, and optionally tilling, fertilizing and obtaining wood wastes or paper wastes on-site or from a secondary site, for example, to supplement the on-site production of biomass, or for use as the sole source of biomass. The biomass is then converted to fermentable sugars through enzymatic conversion, acid hydrolysis, thermal cracking, or other processes that reduce cellulosic and hemi-cellulosic compounds to simple sugars. The reduced product is then fermented, producing ethanol in an intermediate beer product followed by recovery of ethanol from the resulting fermentation beer, wherein liquids are concentrated and recovered as fuel grade product. Recovery of ethanol may be by any suitable means including distillation, membrane separation or similar methods, and chromatographic rectification

Disclosed are acid-stable compounds of Formula I: as well as pharmaceutical compositions containing the compounds as active ingredients, and methods to treat cancers in mammal, including humans, by administering one or more of the compounds to a subject in need thereof. The compounds are resistant to acid hydrolysis.