916 results about "Chelation" patented technology

The invention belongs to the technical field of perovskite solar cells, and particularly discloses a self-assembly monomolecular film hole transport material based on diphosphoric acid and a preparation method and application thereof.The diphosphoric acid serves as an anchoring group, the chelation between the material and a conductive base can be effectively enhanced, the self-assembly characteristic of the material on the surface of a substrate is improved, and the hole transport efficiency is improved. The compact and smooth self-assembled monomolecular film is formed. Meanwhile, the electron and space effects of alkyl chains or benzene ring connecting units are regulated and controlled, so that the molecular stereo configuration and energy level matching are optimized. The material disclosed by the invention is simple in synthesis steps and low in preparation cost, and industrial synthesis of the material can be realized. When the material is applied to an inverted perovskite solar cell as a hole transport layer, photoelectric conversion efficiency exceeding 24.7% and excellent device stability performance can be obtained, and huge commercial prospects are shown.

The invention relates to the field of molecular photoelectric devices, and provides a single photon source based on an up-conversion photoelectric device and a preparation method thereof, and the preparation method comprises the steps: preparing a dielectric layer; preparing a graphene array electrode on the dielectric layer; constructing a graphene nano gap point electrode pair; placing the graphene nano gap point electrode pair in a two-neck flask, adding 1-(3-dimethylaminopropyl)-3-2-ethylcarbodiimide hydrochloride and an up-conversion luminescent molecule A part into the two-neck flask, adding anhydrous pyridine into the two-neck flask in a nitrogen environment, and stirring to obtain a graphene nano gap point electrode pair; and putting the device connected with an up-conversion luminescent molecule part A at two ends and an up-conversion luminescent molecule part B containing lanthanide metal into a tetrahydrofuran solution for molecular system chelation to obtain the single-molecule up-conversion photoelectric device containing the chiral group. A liquid metal Ga2O3 protective layer is plated on a single-molecule up-conversion photoelectric device, so that a single photon source is obtained, and the stability and the anti-interference capability of the single photon source are enhanced.

The present invention relates to a method and system for efficiently extracting lithium from a mixed salt solution. The method comprises: adding a chelating agent into a mixed salt solution to be treated, and regulating the pH to promote the chelating agent and divalent or multivalent cations in the mixed salt solution to form a stable chelate, so as to obtain influent water; subjecting the influent water to membrane separation, and using a membrane pore size sieving mechanism and electrostatic repulsion to achieve lithium-magnesium separation, so as to generate membrane-filtered concentrated water and membrane-filtered produced water; regulating the pH of the membrane-filtered concentrated water, and subjecting same to solid-liquid separation so as to obtain a high-value hydroxide having a high degree of dispersion and a chelating agent recovery liquid; and performing concentration and enrichment on the membrane-filtered produced water to obtain a lithium-rich concentrated liquid, the lithium-rich concentrated liquid being used for lithium precipitation. The solution of the present invention solves the technical problems of existing membrane process lithium extraction technologies of high requirements for influent water, limited adaptability, large consumption of fresh water, low lithium-magnesium separation factor, low concentration of produced water, low lithium recovery rate, etc.

The present disclosure provides a preparation method of a yak hide-derived oligopeptide ferrous chelate with a high antioxidant activity. The preparation method includes preparing a yak hide-derived oligomeric collagen peptide and subjecting the yak hide-derived oligomeric collagen peptide as a protein source to chelation with an iron source in water. A pretreated yak hide is subjected to enzymatic hydrolysis under a pH value of 7 at 50° C. for 4 h with an amount of an enzyme added at 2% to obtain a yak skin-derived collagen with a molecular weight of less than 2 kDa; the chelation is conducted in a peptide-to-iron mass ratio of 1:1 to 5:1 with a peptide concentration of 1% to 5% at 30° C. to 70° C. for 20 min to 60 min under a pH value of 3 to 8; and an iron chelating capacity is 42.72 mg / g under optimal preparation conditions.

The invention discloses inorganic modified core-shell structure water-based outdoor wood paint, a preparation method and a film forming method. The preparation method comprises the following steps: S1, pre-dispersing a GO-TiO2-ZnO composite material modified by a silane coupling agent KH570; s2, uniformly stirring the GO-TiO2-ZnO composite material modified by KH570, an acrylic acid core-shell emulsion, dipropylene glycol monomethyl ether, bentonite and an organic silicon flatting agent, and adjusting the pH (Potential of Hydrogen) of the materials to 8.0 to 8.5; and filtering to obtain the target inorganic modified core-shell structure water-based outdoor wood paint. A GO-TiO2-ZnO composite material modified by a silane coupling agent KH570 is dispersed in a self-crosslinking acrylic core-shell emulsion, an alkaline material effectively enhances formation of a high-bond-energy bidentate chelate ([R-COO] 2Zn < 2 + >) with resin carboxyl through ZnO loaded on GO, water molecule permeation channels are reduced, ultraviolet light is shielded in situ in cooperation with TiO2, and the water-resistant service life of an obtained film layer is long.

The invention relates to the field of organic fertilizer manufacturing, in particular to a preparation method of a humic acid-containing water-soluble organic fertilizer with chelated medium trace elements for synergism, and the preparation method comprises the following steps: S1, adding modified humic acid into deionized water, heating to 40-50 DEG C, stirring for 25-35 minutes, adding hydrated ferrous sulfate, introducing compressed air, and stirring for reaction for 30-50 minutes to obtain a chelating solution and the like; according to the invention, the environmental adaptability of humic acid is improved through molecular structure modification, a composite chelation system is constructed to enhance element stability, a multistage chelation sequence is optimized to prevent ion antagonism, and a physical barrier is innovated to realize a core process path of intelligent controlled release. The functional limitation of a traditional fertilizer in a complex agricultural ecological system is effectively broken through, the nutrient utilization efficiency and agricultural sustainability are remarkably improved, and the fertilizer has wide application prospects in soil remediation, precision agriculture and resource-saving planting systems.

The invention discloses a mine water fluorine removal agent and a preparation method and application thereof, and belongs to the technical field of wastewater treatment.The preparation method of the fluorine removal agent comprises the following steps that aluminum salt, calcium salt, magnesium salt and ferric salt are added into water to be stirred, then a chelating agent, a hydroxy carboxylic acid compound and a dispersing agent are added, the mixture is heated to 40-60 DEG C to be stirred and dispersed, and heat preservation is conducted. The preparation method gets rid of the constraint of traditional calcium salt, introduces the chelating agent, the hydroxy carboxylic acid compound and the dispersing agent on the basis of controlling the compatibility of the materials and the synthesis reaction process, and utilizes the excellent fluorine ion adsorption performance and flocculation settling performance of the aluminum-calcium-magnesium-iron-based quaternary metal material to improve the fluorine ion adsorption performance of the aluminum-calcium-magnesium-iron-based quaternary metal material. Quaternary metals are assembled into a long-chain porous structure through chelation, the specific surface area and the pore volume are further increased, the contact area with fluorine ions in mine water is increased, and the porous structure adsorbs complexing groups to achieve the purposes of rapid coordination, strong adsorption, precise chelation, flocculating settling and efficient removal of fluoride in mine water.

The invention discloses a preparation method and application of a positive electrode lithium supplement agent, the positive electrode lithium supplement agent is of a core-shell structure, and a core layer comprises lithium-rich metal materials such as lithium-rich lithium ferrite, lithium-rich lithium nickelate and lithium-rich lithium manganate; and a shell layer comprises organic lithium salt materials such as lithium bis (oxalato) borate, lithium bis (fluorosulfonyl) imide, lithium difluorophosphate and lithium difluorobis (oxalato) phosphate. The lithium-rich metal material lithium supplementing agent is coated with the organic lithium salt lithium supplementing agent which is also used as the lithium supplementing agent, so that the lithium-rich metal material is prevented from being in contact with air, and the environmental stability of the lithium-rich metal material is improved; through chelation of specific groups and transition metal ions, the structural stability of the lithium-rich metal material is improved, a lithium ion transmission path is fixed, the capacity of the lithium supplement agent for the lithium-rich metal material can be exerted to the maximum extent, and the organic lithium salt also has a lithium supplement effect, so that the migration rate of lithium ions can be further improved, and the lithium supplement effect is improved. The lithium supplementing effect of the two lithium supplementing agents greatly improves the energy density and the cycling stability of the battery.

The invention provides a green compound scale inhibitor for geothermal fluid. The compound scale inhibitor comprises modified polyaspartic acid, high-hydrolysis polymaleic anhydride, polyepoxysuccinic acid and polyacrylic acid. According to the environment-friendly compound scale inhibitor for the geothermal fluid, the modified polyaspartic acid, the high-hydrolysis polymaleic anhydride, the polyepoxysuccinic acid and the polyacrylic acid are compounded, a good synergistic effect is achieved, scale inhibition is achieved through chelation solubilization and lattice distortion, the scale inhibition advantage in actual geothermal water is obvious, and the environment-friendly compound scale inhibitor has a good actual popularization value.

The invention belongs to the technical field of inter-cooling water treatment, and relates to a system and method for cooperatively treating inter-cooling water through multi-stage bypasses. Comprising a gradient filtering unit, a modified adsorption unit and a composite adsorption unit which are sequentially connected, a bottom outlet of the gradient filtering unit is connected with a bottom inlet of the modified adsorption unit; a top outlet of the modified adsorption unit is connected with a top inlet of the composite adsorption unit; the gradient filtering unit sequentially comprises a manganese sand layer and a quartz sand layer from top to bottom; the modified adsorption unit is filled with a coal gangue modified straw biochar material; the composite adsorption unit is internally filled with a microcapsule-embedded calcium alginate-vinasse biochar composite material. According to the invention, three-stage cooperative treatment of iron suspended matter interception, sulfate radical adsorption and iron ion chelation is realized, and low-cost, green and sustainable indirect cooling water deep purification is realized by using the solid waste-based functional material.

The invention relates to a perovskite photovoltaic cell high-transmittance low-scattering coating material and a preparation method thereof, and belongs to the technical field of photovoltaic cells. The coating material is prepared from the following components in percentage by weight: 7.2 to 8.5 percent of PMMA (Polymethyl Methacrylate) resin, 0.17 to 0.22 percent of modified nano titanium dioxide, 0.09 to 0.11 percent of flatting agent, 0.03 to 0.04 percent of defoaming agent and the balance of solvent, the modified nano titanium dioxide is prepared into an intermediate through addition reaction of triallylamine and mercaptoethanol, and then a modifier with a network molecular structure is formed through substitution reaction of trifluoropropyl trichlorosilane and hydroxyl at the end part of an intermediate molecule; a thioether chain segment in a modifier molecule and similar nitrogen and oxygen elements form a strong chelation effect to coat the nano titanium dioxide; the introduction of the modified nano titanium dioxide makes up the problem of light transmission reduction caused by traditional titanium dioxide reinforcement.

The invention provides a polymer composite gel for heavy metal ion adsorption and a preparation method and application thereof, diatomite DE, chitosan CS, polyethyleneimine PEI and sodium alginate SA are used as raw materials, and polymer modification crosslinking is promoted through an ionic crosslinking method to form the composite gel. Compared with the prior art, SA is a biodegradable natural polysaccharide material, contains rich hydroxyl and carboxyl functional groups and is used as a controllable modification site, DE is used as an inorganic clay material, has a layered porous structure and contains rich active sites, and CS and PEI polymer surfaces have rich amino and hydroxyl groups and are used as ion adsorption sites. Meanwhile, PEI is used as a nucleation site and an ionic cross-linking agent to promote material modification and cross-linking to form composite gel. The composite gel is used as an ion adsorbent, can be adsorbed through chemical chelation between functional groups and ions, and can also be physically adsorbed through a porous structure, so that the composite gel shows efficient ion adsorption performance.

The invention provides a low-molecular soluble chelating collector as well as a preparation method and application thereof, and belongs to the technical field of mineral processing. According to the collecting agent, low-molecular-weight ethylene glycol terephthalate serves as a precursor, and isosorbide is introduced for a copolymerization reaction; glutamic acid is introduced as a branched chain unit, and the branching degree and reaction active site density of the molecular structure are remarkably improved by utilizing the polyfunctional group characteristic of glutamic acid. A rigid ring structure and an ether bond of the isosorbide endow the medicament with good water solubility and dispersity, and invalid curling of a macromolecular chain is avoided; the introduction of glutamic acid branched chains greatly increases the number of hydroxyl groups and amino groups capable of reacting with carbon disulfide, so that each molecule carries more xanthate groups, and the adsorption stability and coverage density of the molecule on the surface of arsenopyrite are enhanced. By means of the structure, xanthate functional groups are fully exposed, multi-tooth chelation is easily conducted on the xanthate functional groups and iron and arsenic ions on the surface of arsenopyrite, a strong hydrophobic surface layer is formed, and therefore the collecting selectivity is remarkably improved.

The invention relates to the technical field of wastewater treatment, in particular to modified cation exchange resin, a preparation method and application of the modified cation exchange resin in shale gas wastewater treatment. The modified cation exchange resin is characterized in that the modified cation exchange resin is obtained by compounding cation exchange resin and sodium alginate and then grafting N, N-dimethylacrylamide, and the surface of the modified cation exchange resin has an amido group; wherein the cation exchange resin is weakly acidic cation exchange resin taking carboxylic acid groups as exchange groups. The modified cation exchange resin provided by the invention simultaneously contains carboxyl, hydroxyl and amido, can simultaneously adsorb organic pollutants and metal ions through various mechanisms (such as ion exchange, hydrogen-bond interaction, chelation, hydrophobic interaction and the like), and remarkably improves the treatment capacity and efficiency of the resin on complex wastewater. In addition, the dispersibility of the modified resin in water is improved due to the hydrophilicity of the modified resin, so that the modified resin shows higher stability and efficiency in the treatment process.

The application discloses a light-controlled nitric oxide releasing hollow single-atom nanoscale enzyme, a preparation method and application, and belongs to the technical field of biomedical materials. In the application, spherical silica nanoparticles are used as a template, and a structure of copper ion-polydopamine coated silica nanoparticles is formed on the surface of the silica nanoparticles through self-polymerization of dopamine and chelation of copper ions, and the spherical structure is maintained with the support of the silica nanoparticles. The copper ion-polydopamine coated silica nanoparticles are pyrolyzed to obtain a copper-based single-atom nanoscale enzyme with a carbon skeleton, and a hollow spherical single-atom nanoscale enzyme is obtained after etching. Nitric oxide donor molecules are loaded into the hollow of the hollow spherical single-atom nanoscale enzyme to obtain the light-controlled nitric oxide releasing hollow single-atom nanoscale enzyme. The application can realize the synergistic treatment effect of photothermal therapy, nitric oxide gas therapy and biological catalytic therapy, is used for efficiently removing bacteria and biofilms at an infected wound site, and effectively promotes the healing of the bacteria-infected wound.

The invention provides a novel macrocyclic compound, a gadolinium chelate thereof, a method for preparing the compound and application of the compound as a magnetic resonance contrast agent. The compound has pertinence on magnetic resonance detection of liver focal lesions and can be used for liver specific imaging.

The invention discloses a microemulsion cleaning agent capable of rapidly and efficiently removing radioactive dirt, and belongs to the technical field of special decontaminants. The microemulsion cleaning agent for rapidly and efficiently removing radioactive dirt comprises the following components in percentage by mass: 15 to 20 percent of surfactant, 10 to 15 percent of oxidant, 10 to 15 percent of green chelating agent, 1 to 1.5 percent of assistant, 20 to 50 percent of oil, 0.001 to 0.5 percent of defoaming agent, 0.01 to 7 percent of corrosion inhibitor and the balance of water. The product obtained by the invention integrates oxidation, chelation and solvation, can effectively remove reduced dirt, quickly and efficiently capture and wrap nuclide ions, and is firmly combined to quickly and effectively remove radioactive dirt.

The invention discloses a preparation process of a rare earth precipitation resistant electrophoretic coating for an automobile body. The preparation process comprises the following steps: S1, preparing a stable solution; s2, preparing a rare earth chelating solution; adding lanthanum lactate into the stable solution for multiple times, and adding ammonium ceric sulfate for multiple times after the lanthanum lactate is completely dissolved; s3, preparing a resin base solution; s4, preparing mixed slurry; s5, adding a solvent and an auxiliary agent; a five-membered ring chelate with thermodynamic stability is formed by carboxyl, hydroxyl and rare earth elements in sodium citrate, rare earth ions can be tightly wrapped through strong coordination bonds, namely, empty orbits of the rare earth ions and lone pair electrons of a chelating agent form coordination bonds, so that the rare earth ions cannot be dissociated in a system, and the rare earth ions are prevented from being dissociated in the system. And a path of generating hydroxide precipitates by free rare earth ions is thoroughly blocked, so that rare earth elements are effectively ensured to be uniformly distributed in the electrophoretic paint, and the surface of a raw material treated by a subsequent electrophoresis process is more uniform.

The invention relates to the technical field of ore flotation, and discloses a preparation process of a foaming agent. The foaming agent is obtained by mixing fluorine-containing pyridine modified carboxyl betaine, sulfonic group modified polyoxyethylene ether and methyl isobutyl carbinol. Fluorine atoms can enhance the stability of the foaming agent and improve the flotation effect; sulfur atoms and metal ions form a stable chelate, and mineral separation and purification are achieved; pyridyl can generate electrostatic attraction with the surface of the mineral to form a hydrophobic membrane, so that the adhesive force of bubbles and the mineral is improved, and the flotation effect is enhanced; polar groups in the carboxyl betaine are adsorbed on the surfaces of the minerals, and non-polar groups face outwards, so that the surfaces of the minerals are hydrophobic, and a flotation effect is achieved; sulfonic groups can be adsorbed on the surfaces of minerals, so that the original hydrophilic surfaces of the minerals are changed into hydrophobic surfaces, and the floatability of the minerals is improved; the polyoxyethylene ether has good dispersing performance, so that the foaming agent is more uniformly distributed in ore pulp, and minerals can be better captured by bubbles and float upwards.

The invention specifically discloses a preparation method of a FeZn diatomic nano enzyme with adjacent double metal sites. The product is of a planar sheet structure, chitosan serves as a chelating support, and the product is prepared through in-situ doping of bimetallic precursors of Fe and Zn in a competitive coordination and high-temperature pyrolysis mode. The preparation method comprises the following steps: taking chitosan as a sacrificial template, taking ferric nitrate and zinc chloride as precursors, and carrying out in-situ conversion on the metal precursors into bimetallic atom sites by virtue of a high-temperature pyrolysis means, so as to prepare the FeZn diatomic nano-enzyme. FeZn diatoms exist in an adjacent state, the peroxidase-like activity of the FeZn diatoms is larger than that of monatomic Fe nano-enzyme and monatomic Zn nano-enzyme, the FeZn diatoms have excellent storage stability and high-temperature-resistant catalytic stability, and the preparation method has the advantages of being high in expandability, simple in process, green in raw material, stable in diatom structure and the like.

The invention relates to a water-based ball-milled passivated aluminum paste and a preparation method and application thereof, and the preparation method comprises the following steps: carrying out ball milling on aluminum powder, a surface modifier, a hydrophilic solvent and an inorganic passivator until the target particle size of the aluminum powder is reached, and obtaining preliminarily passivated aluminum paste; carrying out suction filtration on the primarily passivated aluminum paste, uniformly stirring and mixing, adding an organic passivator, continuously stirring to carry out a passivation reaction, adding an auxiliary agent, and continuously stirring to obtain aluminum paste; wherein the organic passivator is a combination of a micromolecular organic passivator and a macromolecular organic passivator. According to the method, the in-situ passivation technology is adopted, the aluminum sheet is passivated in the extension process, the influence of dissolution and auxiliaries on the aluminum sheet is small, a more compact protective film is formed through the synergistic effect of the inorganic passivator and the organic passivator and through the oxidation film layer, chelation and precipitation reaction, corrosion of aluminum powder is greatly inhibited, and the service life of the aluminum sheet is prolonged. And the water-based passivated aluminum paste and a water-based resin system maintain good compatibility, and can show good glossiness.

The invention belongs to the technical field of composite materials, and particularly relates to aldehyde aromatic compound crosslinked polyethyleneimine as well as a preparation method and application thereof. Amino groups in polyethyleneimine are combined with different substances, so that the adsorption capacity of the aldehyde aromatic compound crosslinked polyethyleneimine is improved; the polyethyleneimine has high cationic property in water and can neutralize and adsorb anions or chelate noble metal ions, so that the adsorbability of noble metal is improved; amino in a polyethyleneimine structure can be subjected to a cross-linking reaction with an aldehyde aromatic compound, and C = N double bonds are introduced into polyethyleneimine, so that the adsorption performance on noble metal ions is improved. The aldehyde aromatic compound cross-linked polyethyleneimine provided by the invention has a mesoporous structure, gold ions and platinum ions are adsorbed to the surface of a material and the inside of pore channels through various mechanisms such as electrostatic attraction, chelating coordination and oxidation reduction, and the adsorption capacity to metal ions, especially the gold ions and the platinum ions, is improved.

An aqueous pharmaceutical composition including compound having the formula of tetragadolinium [4,10-bis(carboxylatomethyl)-7-{-3,6,12,15-tetraoxo-16-[4,7,10-tris(carboxylatomethyl)-1,4,7,10-tetraazacyclododecan-1-yl]-9,9-bis({[({2-[4,7,10-tris(carboxylatomethyl)-1,4,7,10-tetraazacyclododecan-1-yl]propanoyl}amino)acetyl]amino}methyl)-4,7,11,14-tetraazaheptadecan-2-yl}-1,4,7,10-tetraazacyclododecan-1-yl]acetate wherein the stereochemistry at the chiral carbon of the four alanine substituents is selected from the group consisting of RRRR, SSSS, RSSS, RRSS, and RRRS stereoisomers, and racemic and diastereomeric mixtures of any thereof, or a tautomer, a hydrate, a solvate, or a salt thereof, or a mixture of same is described. The compounds may be used as an MRI contrast imaging agent.

The invention relates to the technical field of chitosan, and discloses a preparation method and application of a functional water-absorbing chitosan material, an aldehyde triazine quaternary ammonium salt cross-linking agent and amino of chitosan are subjected to a cross-linking reaction, hydrophilic quaternary ammonium salt and sulfonic acid are grafted into the chitosan material, and the hydrophilicity of chitosan is remarkably improved. And the aldehyde triazine quaternary ammonium salt cross-linking agent contains three aldehyde groups, and forms a porous structure of a space cross-linked network with the chitosan, so that the water absorption rate is greatly increased. The chitosan material contains functional quaternary ammonium salt cation groups which can form electrostatic interaction with Cr2O7 < 2-> anions, meanwhile, nitrogen atoms in sulfonic acid groups, nitrogen-rich triazine and imidazole structures can generate coordination chelation with metal ions such as Cu < 2 + >, and the equilibrium adsorption capacity of the chitosan material to Cu < 2 + > is improved. The method has a wide application prospect in the field of metal-containing sewage treatment.

The invention relates to the technical field of polypeptides, in particular to an enzyme-mimetic polypeptide, hydrogel, a preparation method and application, the enzyme-mimetic polypeptide selects a peptide fragment I and a peptide fragment II with biocompatibility and degradability as basic sequences, and the peptide fragment I and the peptide fragment II form a beta folding unit, so that the stability of a polypeptide structure can be enhanced; then, the peptide chain is driven to be self-assembled to form a regular nanofiber structure; according to the invention, the characteristic that the biomimetic polypeptide and metal ions are subjected to a complex reaction to form a chelate is utilized, the transparent and stable hydrogel can be rapidly formed without adding a gelatinizing agent, and TEM, SEM and rheological characterization are carried out on the hydrogel to find that the hydrogel containing the biomimetic polypeptide has a porous nanofiber network structure, so that the biomimetic polypeptide can be used for preparing the hydrogel. Meanwhile, the biomimetic polypeptide hydrogel has the same flexibility as natural tissues, and the characteristics indicate that the biomimetic polypeptide hydrogel is expected to have wide application prospects in the aspects of biomimetic materials, antibiosis, cell culture, drug carriers and the like.

The invention provides a composite extraction agent and a method for separating gold in electroplating wastewater by using the composite extraction agent, and belongs to the field of wastewater purification, the composite extraction agent comprises an extraction main agent and an extraction main agent stabilizer, the extraction main agent is a diallyl sulfide compound, and the extraction main agent stabilizer is dithiothreitol. The extraction main agent can form a stable complex with gold ions to enter an organic phase, and a nonlinear space structure of the extraction main agent can realize selective coordination with the gold ions, so that coordination reaction with other impurity metal ions is avoided; the sulfydryl in the dithiothreitol molecular structure has reducibility, so that the residual oxidant or dissolved oxygen in the solution can be prevented from oxidizing the extraction main agent, and the nonlinear polysulfide structure of the extraction main agent is kept. According to the method, the heterogeneous interface-coordination reaction of the activation sites in the molecular structure of the extracting agent and the gold ions in the inorganic phase is ensured by regulating and controlling the multi-component components of the composite extracting agent, efficient selective chelation of target metal is achieved, and the purpose of separating and enriching the gold ions in the gold-containing electroplating waste liquid is achieved.

The invention discloses an insect antibacterial peptide nutrient solution as well as a preparation method and application thereof, and belongs to the technical field of biology. Insect protein (fly maggot powder / hermetia illucens) and plant fiber (bran) are subjected to enzymolysis and then subjected to a pH gradient chelation process (5.0-7.0-8.5), metal ions (Fe < 2 + > / Mn < 2 + > / Zn < 2 + >) are added in stages for chelation, the chelation degree is larger than or equal to 91.4%, lentinan and alginate oligosaccharide are added for synergistic interaction, and finally the insect antibacterial peptide nutrient solution is obtained. Experiments prove that after the insect antibacterial peptide nutrient solution prepared by the invention is used for carrying out root irrigation treatment on plants, tomato yellow leaf curl virus or tomato spotted wilt virus can be remarkably prevented and treated, and the insect antibacterial peptide nutrient solution has high efficiency and persistence and conforms to the development direction of green plant protection.

The invention relates to the technical field of oil field yield increase and transformation, in particular to environment-friendly biological blockage removal liquid and application thereof, and aims to solve the problem that a current biological blockage removal product can only remove organic blockage. The environment-friendly biological unblocking liquid provided by the invention is prepared from the following components in percentage by mass: 2-5% of biological enzyme, 1-5% of surfactant, 1-5% of pH (Potential of Hydrogen) regulator and the balance of water. 1%-3% of a biological enzyme stabilizer; 3-5% of a chelating agent; 0.5%-1% of a surfactant; 0.5%-1% of a dispersion suspending agent; and the balance of water. The biological blockage removal liquid provided by the invention can effectively remove organic blockage of a stratum caused by wax and asphaltene precipitates, so that crude oil is released from the surfaces of rock particles, the flowing of the crude oil in pores of the stratum is improved by changing the wetting state of rock, and inorganic blockage is removed through permeation dispersion and chelation solubilization effects, so that the mechanical property of the stratum is improved. Mixed scales formed by mutual deposition of inorganic scales and organic matters (wax and asphaltene) are effectively removed, and the requirement for plugging removal of a complex scaling reservoir of an oil well is met.

The invention provides a gold leaching agent of a compound leaching aid system and a dump leaching process, and belongs to the field of hydrometallurgy, the gold leaching agent comprises an agent main body and the leaching aid system, the agent main body is sodium cyanide, the leaching aid system comprises an oxidizing agent, an oxidation synergist and a chelating gain agent, the chelating gain agent is a furan ring-shaped hydroxamic acid compound. According to the method, the high-selectivity leaching auxiliary is designed, the components of the dump leaching agent system are regulated and controlled, and efficient gold extraction of the dump leaching process is achieved through the synergistic effect of all the components in the system. Wherein the chelating gaining agent can form a stable chelate with metal ions in a solution through a special annular structure and chelating capacity, so that the metal ions are prevented from precipitating again, gold ions in the solution are kept in a free state, further reaction of sodium cyanide is facilitated, and the leaching rate of gold is increased. Meanwhile, the aromaticity of furan rings and oxygen heteroatoms enhance the solubility and stability of the furan rings in water, and the effect of the whole leaching process is improved.

The invention provides an environment-friendly chalcopyrite inhibitor and a copper-molybdenum separation method, and belongs to the technical field of copper-molybdenum separation. The environment-friendly chalcopyrite inhibitor is a sulfur-containing histidine derivative, a unique aromatic conjugated structure of the environment-friendly chalcopyrite inhibitor can be converted into sulfydryl through thiocarbonyl tautomerization, S in the sulfydryl and N atoms which contain lone pair electrons and do not participate in conjugation in an aromatic ring cooperate with each other, copper ions in chalcopyrite can be directionally chelated, a formed chelate is of an annular structure, and the chalcopyrite inhibitor can be used for inhibiting copper ions in chalcopyrite. Chelation with molybdenum in molybdenite is avoided, and excellent selectivity is shown. The environment-friendly chalcopyrite inhibitor contains carboxyl and tertiary amino at the same time, and it is guaranteed that the environment-friendly chalcopyrite inhibitor can efficiently inhibit target minerals in a wide pH window through the two hydrophilic functional groups of different structures. Based on the specific space structure of the environment-friendly chalcopyrite inhibitor, the types of functional groups and mutual cooperation of different functional groups, efficient selective inhibition of chalcopyrite in copper and molybdenum associated ores can be achieved safely and environmentally in a wide pH range.