The invention relates to the technical field of adsorption materials, in particular to a functional
polymer material for high-selectivity n-
heptane adsorption separation and a preparation method of the functional
polymer material. During preparation, hydroxypropyl-beta-
cyclodextrin is used as a core
raw material, polymerizable double bonds are introduced through in-situ esterification, and then the functional
polymer material is prepared from hydroxypropyl-beta-
cyclodextrin, perfluorooctyl
ethyl acrylate and
divinyl benzene through an
emulsion dispersion-
emulsion polymerization process. According to the material, impurities are included in a hydrophobic cavity of modified hydroxypropyl-beta-
cyclodextrin, and the hydrophobic synergistic effect of a perfluoro
side chain is combined, so that the impurities are adsorbed, and a three-dimensional network constructed by
divinyl benzene can fix functional sites and inhibit swelling of chain segments. The
functionalized polymer material for high-selectivity n-
heptane adsorption separation is high in n-
heptane separation selectivity, excellent in
solvent expansion resistance and long-term stable in functional sites, the preparation process does not need special monomers, conditions are mild, large-scale production is easy, and the
functionalized polymer material can be efficiently applied to n-heptane purification in the fields of
petrochemical engineering and the like.