1819 results about "Methacrylate methyl" patented technology

The invention belongs to the technical field of flame retardants, and particularly relates to a high-thermal-stability polyphosphate flame retardant and a preparation method thereof. The DOPO is modified through the polyethylene glycol acrylate, methyl methacrylate and dicumyl peroxide composite solution, double bonds of the polyethylene glycol acrylate and P-H bonds of the DOPO can be subjected to nucleophilic addition to form stable C-P bonds, and thermal migration of the DOPO is hindered; dOPO has polymerization double bonds of methyl methacrylate and long carbon chains of polyethylene glycol acrylate, so that the compatibility of the polyphosphate flame retardant and a polymer substrate is improved, and phase separation is avoided; maleic anhydride grafted silicone oil is connected to the surface of an amino modified gamma-cyclodextrin-modified DOPO inclusion compound, so that the polyphosphate flame retardant has high thermal stability and high compatibility after long-chain alkyl modification; amino groups in the modified gamma-cyclodextrin react with maleic anhydride grafted silicone oil to generate an amido bond cross-linked network, so that the thermal migration of DOPO is reduced together, and the high thermal stability of the polyphosphate flame retardant is improved.

Provided are a water-resistant wood-plastic reinforced composite flooring and a manufacturing method therefor. Wood flour is boiled in boiling water for 3-4 hours, filtered and dried, to obtain dried wood flour; polypropylene, butyl acrylate, methyl methacrylate, maleic anhydride and dicumyl peroxide are mixed evenly, extruded and granulated, and dried to obtain a compatibilizer; the dried wood flour and polypropylene are mixed evenly, the compatibilizer is added and mixed evenly, then extrusion and granulation, and injection molded, are performed, to obtain a wood-plastic flooring blank; a composite resin emulsion and a photoinitiator are ultrasonically mixed evenly, and the wood-plastic flooring blank is immersed therein, then taken out and dried at room temperature, and then vacuum dried and UV cured, to obtain water-resistant wood-plastic reinforced composite flooring.

The invention belongs to the technical field of pyridone ethanolamine salt synthesis, and discloses an environment-friendly pyridone ethanolamine salt preparation process which comprises the following preparation steps: enabling isononanoyl chloride and 3, 3-methyl dimethacrylate to react under the catalysis of a solid acid catalyst to prepare 3, 7, 9, 9-tetramethyl-2-decene-5-keto acid methyl ester, and enabling the 3, 7, 9, 9-tetramethyl-2-decene-5-keto acid methyl ester to react under the catalysis of a solid acid catalyst to prepare 3, 7, 9, 9-tetramethyl-2-decene-5-keto acid methyl ester. The preparation method of the solid acid catalyst comprises the following steps: S1, taking water as a solvent, adding 14-16 parts by weight of zirconium oxychloride, 1-3 parts by weight of titanium sulfate, 0.1-0.5 part by weight of chloroplatinic acid and 0.05-0.4 part by weight of cerium chloride, adjusting the pH value to 10-11, and aging to obtain a precipitate; s2, roasting the precipitate obtained in the step S1 in an air atmosphere at 500-600 DEG C to obtain a solid acid catalyst; the method has the advantages that the catalyst is easy to recycle, and the reusability is high.

The invention relates to the field of coatings, and discloses an outer wall light radiation heat preservation and heat insulation decorative sheet and a preparation method thereof.A radiation refrigeration layer on the surface of the outer wall light radiation heat preservation and heat insulation decorative sheet comprises modified acrylate resin, silicon dioxide, ground calcium carbonate, talcum powder, modified hollow glass beads and auxiliaries; the modified acrylate resin is prepared by copolymerizing perfluorooctyl ethyl acrylate, methyl methacrylate, modified isocyano ethyl methacrylate and vinyltriethoxysilane, and the modified isocyano ethyl methacrylate is prepared by using salicylaldehyde and benzothiazole-2-formaldehyde as well as 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate as an initiator and using 2, 3, 4-trimethyl-1, 3-pentanediol monoisobutyrate as an initiator. The preparation method comprises the following steps: reacting amino groups at two ends of 1, 5-naphthylenediamine with DOPO, carrying out nucleophilic addition reaction with DOPO, and grafting with isocyano ethyl methacrylate. The modified hollow glass beads are prepared by using tetrabutyl titanate as a titanium source through a sol-gel method, and the prepared radiation refrigeration layer has the super-amphiphobic self-cleaning effect, the radiation refrigeration effect is good, and meanwhile the flame retardant property and the antibacterial effect are excellent.

The invention discloses high-strength concrete and a preparation method thereof in the field of concrete. The high-strength concrete is prepared from the following raw materials in parts by weight: superfine sulphoaluminate cement; coarse aggregate; quartz sand; silica fume; coal ash; nano metakaolin; silicon carbide whiskers; a graphene oxide; a pH responsive microcapsule; coating the steel fibers with liquid metal; a carbon nanotube; and a polycarboxylic acid water reducer. Release of the repairing agent is accurately regulated and controlled by adopting the pH response microcapsule, the interface performance is enhanced by combining with the liquid metal coating steel fiber, and the composite dispersion process of the nano material is optimized. Wherein the environment response efficiency of the microcapsule is remarkably improved through the collaborative design of a calcium oxide-slow release agent system and a methyl methacrylate / acrylic acid copolymerization shell layer; according to the gallium-based liquid metal coating, metallurgical bonding of fibers and a matrix is achieved through the low-melting-point characteristic, and traditional physical bonding limitation is broken through.

The invention discloses a phase change microcapsule modification method which comprises the following steps: S1, selecting a paraffin phase change material or a hydrated salt phase change material, and adding 0.5-1.5 wt% of a chemical stabilizer to modify the thermal stability of the phase change material; s2, compounding a microcapsule wall material by using polyurethane (PU) and nano silicon dioxide (SiO2), and adding 1wt% of carbon nanotubes (CNT) and 0.5-2wt% of nano silicon dioxide (SiO2); s3, the microcapsule wall material is subjected to surface hydrophobic coating treatment, polymethyl methacrylate (PMMA) is sprayed to form a waterproof isolation layer, the modified microcapsule phase change material is obtained, and in the step S1, 0.5-1.5 wt% of graphene oxide (GO) is added for modification when the paraffin phase change material is selected. The preparation method is reasonable in design, energy storage, heat preservation and mechanical properties of PCM-UHPC are remarkably improved through multi-layer composite modification of the PCM microcapsules and the nano-enhancement technology of the UHPC matrix, and the preparation method is suitable for the fields of energy-saving buildings, temperature control infrastructures and the like and has wide application prospects.

The invention discloses a super-hydrophobic anti-icing coating for a power transmission line and a preparation method, and belongs to the technical field of preparation of anti-icing coatings. The super-hydrophobic anti-icing coating for the power transmission line is composed of a coating wrapping the surface of the power transmission line, and the coating is composed of the following components in parts by weight: 34-45 parts of composite resin, 8-14 parts of a composite ice melting agent, 10-18 parts of deionized water, 1-3 parts of hexadecyl trimethoxy silane and 50-58 parts of tetrahydrofuran, the composite resin is prepared from carboxyl multi-walled carbon nanotubes, isopropanol, tetraethoxysilane, a silane coupling agent KH-550, perfluorodecyl trimethoxysilane, butyl acrylate, methyl methacrylate and dodecafluoroheptyl methacrylate, and the composite ice melting agent is prepared from pyridine-2, 6-dicarboxylic acid, thionyl chloride and nicotinic acid hydrazide. The coating prepared by the method has excellent hydrophobicity, wear resistance and anti-icing effect.

The invention discloses a flame-retardant PMMA (polymethyl methacrylate) plate and a preparation method thereof, and belongs to the technical field of acrylic plates. Comprising the following raw materials in parts by weight: 70-80 parts of methyl methacrylate, 8-12 parts of methyl acrylate, 5-15 parts of a synergistic flame retardant, 10-18 parts of modified nano silicon dioxide, 0.2-0.4 part of an initiator and 3-5 parts of a release agent. Wherein the modified nano silicon dioxide is high in surface hydrophobicity and better in compatibility with a PMMA matrix, so that the wear resistance and the mechanical property of the PMMA plate are greatly enhanced; wherein the synergistic flame retardant can enhance the mechanical property of the PMMA plate, in addition, molecules contain three elements of silicon, nitrogen and phosphorus, and the three elements can achieve a synergistic effect, so that the flame retardance of the plate is remarkably improved, and the stability is good; therefore, the PMMA plate prepared by the invention is good in wear resistance and excellent in mechanical property, also has stable and efficient flame retardance, and has important application value in the technical field of acrylic plates.

A carbon-coated current collector. The carbon-coated current collector comprises a foil and a conductive coating arranged on the surface of the foil. The conductive coating comprises a combination of a modified conductive carbon material and a binder. The binder is prepared from the following raw materials in parts by weight: 40-60 parts of methyl isobutyl ketone, 25-30 parts of a solvent, 20-25 parts of isobornyl methacrylate, 20-25 parts of methyl methacrylate, 20-25 parts of n-butyl acrylate, 20-25 parts of hydroxyethyl acrylate, 18-22 parts of silicone oil, and 50-55 parts of an initiator. The modified conductive carbon material is a fluorosilane-modified carbon material. The modified conductive carbon material and the binder can form silanols by means of hydrolysis reaction of respective alkoxy groups, then the silanols form new hydrogen bonds with OH groups, and covalent bonds are formed on the surface of the carbon material, thereby forming a highly cross-linked network structure, which further enhances water resistance, allowing for the ability to withstand 200 or more wiping operations.

The invention discloses a high-RAP-doping-amount cold-mixed asphalt regenerant, and particularly relates to the technical field of asphalt regenerant, the high-RAP-doping-amount cold-mixed asphalt regenerant comprises the following raw materials: hydrogenated extract oil, acetyl tributyl citrate, a low-temperature penetrant, pre-swelling SEBS master batch, a crosslinking catalyst and a microcapsule antioxidant. Molecular-level branched-chain alkyl sodium sulfonate can be wedged into aged asphalt microcracks at the temperature of 65 DEG C, lost light components are balanced and supplemented through hydrogenated extract oil, an SEBS micro-crosslinking network forms an in-situ reinforcement effect at the temperature of 90 DEG C, the triple regeneration effect of regenerated asphalt is achieved, and the service life of the regenerated asphalt is prolonged. Nano-zinc oxide is treated by a silane coupling agent and then is modified by using methyl methacrylate and potassium persulfate, so that the nano-zinc oxide is coated with polymethyl methacrylate, the compatibility of the microcapsule antioxidant and the recycled asphalt can be improved, and the anti-aging performance of the recycled asphalt is improved.

The invention relates to the technical field of cable materials, in particular to a thermoplastic low-smoke halogen-free flame-retardant polypropylene cable material and a preparation method thereof. The modified thermoplastic low-smoke halogen-free flame-retardant polypropylene cable material is prepared from the following components in parts by weight: 30 to 36 parts of polypropylene, 12 to 16 parts of toughening agent, 10 to 16 parts of POE (Polyolefin Elastomer) compatilizer, 88 to 102 parts of flame retardant, 0.5 to 0.9 part of antioxidant, 1 to 2 parts of lubricant and 3 to 6 parts of modified nano particles, the modified nano particles are prepared from nano silicon dioxide and methyl methacrylate through graft polymerization. By adding the modified nanoparticles, the performance of the cable material is remarkably improved, so that the cable material achieves better balance and effect in the aspects of mechanical property, flame retardant property, electrical property, aging property, low-temperature property and the like.

The invention relates to the technical field of electric wire materials, in particular to a preparation process of a high-strength halogen-free flame-retardant electric wire. According to the preparation method, the polyolefin flame-retardant microspheres are obtained by adding propenylated cyclotriphosphazene, propenylated phosphaphenanthrene, methyl methacrylate, lauroyl peroxide, polyvinyl alcohol and deionized water. The flame-retardant modified boron nitride nanosheet is prepared by the following steps: firstly, preparing a flame-retardant modified boron nitride nanosheet, and then adding hydroxylated boron nitride, gamma-glycidyl ether oxypropyl trimethoxy silane and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide, so as to obtain the flame-retardant modified boron nitride nanosheet. An ethylene-vinyl acetate copolymer, polyolefin flame-retardant microspheres, flame-retardant modified boron nitride nanosheets, an antioxidant and a lubricant are mixed and react, and the high-strength halogen-free flame-retardant protective sleeve is obtained. And wrapping the periphery of the copper core wire with the high-strength halogen-free flame-retardant protective sleeve to obtain a finished product. The finished product prepared by the invention has excellent flame retardant property and high strength, thereby having a wide application prospect in the technical field of electric wire materials.

The invention provides transparent high-impact-resistance heat-resistant MBS (methyl methacrylate-butadiene-styrene) resin and a preparation method thereof, and relates to the field of high polymer material preparation methods, the transparent high-impact-resistance heat-resistant MBS resin is prepared from the following raw materials: water, ethanol, maleic anhydride, an emulsifier, MBS resin grafted latex, potassium persulfate and an antioxidant; the MBS resin grafted latex is prepared from the following raw materials: water, modified styrene-butadiene latex, sodium hydrogen sulfite, potassium persulfate, methyl methacrylate and styrene, the modified styrene-butadiene latex is prepared from the following raw materials: a pre-emulsion, glycidyl methacrylate, ammonium persulfate, divinyl benzene and potassium persulfate; the pre-emulsion is prepared from the following raw materials: water, an emulsifier, butadiene and styrene. The product is good in heat resistance and good in PVC modification effect, and the modified PVC composite material is high in light transmittance, high in cantilever beam impact strength and resistant to aging.

The invention relates to the technical field of lithium battery diaphragms, and discloses a water-soluble gel electrolyte, a preparation method thereof, water-based slurry and application. The preparation method of the water-soluble gel electrolyte comprises the following steps: in the presence of an initiator, carrying out first polymerization reaction on methyl methacrylate and N-isopropylacrylamide to obtain an intermediate I; carrying out second polymerization reaction on the polymer solution A and the polymer solution B to obtain an intermediate I; the polymer solution A contains an intermediate I with the concentration of 8-12wt%; the polymer solution B contains neopentyl glycol diglycidyl ether with the concentration of 0.5 to 1.2 weight percent; and carrying out heating treatment on the intermediate I to obtain the water-soluble gel electrolyte. When the water-soluble gel electrolyte is applied to the battery diaphragm, the addition amount of the electrolyte can be reduced during electrolyte injection in a battery cell, and the cost is effectively reduced; battery leakage is reduced, and the safety performance of the battery cell is improved; and the internal resistance can be reduced, and the cycle performance of the battery cell can be improved.

The invention relates to the technical field of cables, and provides a tensile new energy charging pile cable which comprises a conductor, an insulating layer, a shielding layer and a sheath layer which are sequentially arranged from inside to outside. The sheath layer comprises the following components in parts by weight: 60-70 parts of chlorinated polyethylene, 15-20 parts of polyisoprene, 5-10 parts of an ethylene-methyl methacrylate copolymer, 8-18 parts of an acrylonitrile-butadiene-styrene copolymer, 20-30 parts of modified hydroxyapatite, 1-5 parts of a lubricant, 3-6 parts of a plasticizer, 30-40 parts of a flame retardant and 1-3 parts of an antioxidant; the raw materials of the modified hydroxyapatite comprise hydroxyapatite and a modifier; the modifier comprises maleic acid-acrylic acid copolymer sodium salt; the weight ratio of the hydroxyapatite to the modifier is 45: (1-7). According to the technical scheme, the problem that the cable sheath layer of the new energy charging pile is poor in tensile property and corrosion resistance in the prior art is solved.

The invention relates to the technical field of BOPP (biaxially-oriented polypropylene) films, in particular to a scratch-resistant adhesive-free matt film and a preparation method thereof, and the scratch-resistant adhesive-free matt film comprises a matt layer, a core layer and a thermal composite layer which are sequentially arranged, the matt layer comprises co-polypropylene, high-density polyethylene, 2.0-2.5 wt% of linear alkyl silicone (the weight-average molecular weight is 12-150 thousands, and the surface tension is 42-45 mN / m) taking maleic anhydride modified aziridine as a terminal group, and 2000-4000 ppm of spherical polymethyl methacrylate (the particle size D50 is 4.0-5.0 microns); the core layer comprises homo-polypropylene; and the thermal composite layer comprises an ethylene-vinyl acetate copolymer and 2000 to 4000 ppm of a spherical anti-blocking agent. According to the scratch-resistant adhesive-free matt film, through collaborative design of the components of the matt layer and the thermal composite layer, balance of scratch resistance, high surface tension (printing applicability) and winding and unwinding smoothness of the surface of the matt layer is achieved, and a solution for the scratch-resistant generality problem of the matt surface of the high-end BOPP matt film is provided.

The invention relates to an epoxy core-shell polymer particle and resin, a preparation method of the epoxy core-shell polymer particle and resin and application of the epoxy core-shell polymer particle and resin to epoxy resin. The preparation method of the epoxy core-shell polymer particle comprises the following steps: heating and mixing a polybutadiene seed emulsion, a reducing agent, an emulsifier and the like; adding methyl methacrylate and an initiator, and glycidyl methacrylate and an initiator, and heating to react; compared with the prior art, the core-shell particle with the outer layer of the synthesized shell containing the epoxy group can be used for toughening the epoxy resin, so that the toughness of the epoxy resin is effectively improved while the excellent heat resistance and mechanical properties of the epoxy resin are maintained.

The invention relates to the technical field of concrete structure repair, and particularly discloses a high-freezing-resistance and high-permeability concrete crack repair material and a preparation process thereof. The repairing material comprises the following components in parts by weight: 10-50 parts of acrylic acid, 12-50 parts of methyl methacrylate, 0.2-3.0 parts of a cross-linking agent, 0.05-2 parts of an oxidizing agent, 0.01-1 part of a reducing agent and 2-10 parts of watermelon leaf powder-saturated lime water suspension. The repairing material disclosed by the invention not only has good permeability, can penetrate into microcracks, but also has good frost resistance, so that the repairing material can be well applied to repairing of weight cracks of a concrete structure in a low-temperature environment.

The invention discloses a biodegradable polylactic acid composite material and a preparation method thereof, and relates to the technical field of polylactic acid materials. The method comprises the steps that firstly, chitosan activated through hydrochloric acid is subjected to graft modification through a KH550 silane coupling agent, meanwhile, nano-zinc oxide is subjected to surface modification through stearic acid, the chitosan and the nano-zinc oxide are mixed, spray drying is conducted, and antibacterial composite powder is prepared; the preparation method comprises the following steps: performing hydrochloric acid activation and KH570 silane coupling agent modification on nano silicon dioxide, performing hydroxypropylation modification on alkali lignin, and performing reflux crosslinking reaction on the modified alkali lignin, KH570 modified nano silicon dioxide, polycaprolactone, methyl methacrylate and azodiisobutyronitrile to prepare a heat-resistant reinforcer; uniformly mixing polylactic acid, poly (butylene succinate), the antibacterial composite powder, the heat-resistant reinforcer, tributyl citrate, polyethylene glycol and talcum powder, and extruding and granulating by using a twin-screw extruder to obtain the heat-resistant antibacterial material. The composite material prepared by the invention has excellent antibacterial property, heat resistance and biodegradability.

The invention relates to the technical field of bactericides, and discloses an oilfield flooding bactericide containing plant bactericidal components and a preparation method thereof. The preparation method comprises the following steps: loading the plant-based traditional Chinese medicine extract and the isothiazolinone-based corrosion inhibitor on the silver-loaded cyclodextrin metal organic framework to prepare an antibacterial agent / silver-loaded cyclodextrin metal organic framework composite material, and mixing the antibacterial agent / silver-loaded cyclodextrin metal organic framework composite material with methyl methacrylate to prepare the antibacterial agent / silver-loaded cyclodextrin metal organic framework composite material. The bactericide obtained by carrying out copolymerization reaction on modified hydroxyquinoline, vinyl quaternary phosphonium salt and methacrylic acid through an in-situ polymerization method can effectively kill and inhibit the breeding of sulfate reducing bacteria and other bacteria in oilfield reinjection water, and has a certain corrosion inhibition effect.

The invention provides an outdoor hard polyvinyl chloride material and a preparation method and a product thereof. The outdoor hard polyvinyl chloride material is prepared from the following raw materials in parts by weight: 80 to 100 parts of polyvinyl chloride resin, 15 to 50 parts of chlorinated polyvinyl chloride resin, 50 to 100 parts of acrylonitrile-styrene-acrylate terpolymer, 3 to 15 parts of impact modifier, 0.1 to 5.0 parts of processing aid, 0.1 to 5.0 parts of lubricant and 0 to 10 parts of other aids. The impact modifier comprises a methyl methacrylate-butadiene-styrene terpolymer and chlorinated polyethylene, and the processing aid comprises ACR acrylic resin. The lubricant includes a first lubricant and a second lubricant. The melting point of the first lubricant is 20-70 DEG C, and the melting point of the second lubricant is 100-115 DEG C. The outdoor rigid polyvinyl chloride material has the advantages of excellent compatibility of the components, high impact strength, high weather resistance and low specific gravity, and meets the use requirements of base station antenna housing materials.

The invention provides a solvent-free UV dielectric insulation protective coating as well as a preparation method and application thereof. The high-surface-energy and high-glass-transition-temperature UV-curable coating is prepared by combining flexible modified polyurethane acrylate, flexible acrylate, rigid acrylate with high glass transition temperature, a high-functionality acrylate cross-linking agent, methyl methacrylate with high dilutability and high glass transition temperature as well as a plurality of photoinitiators, auxiliaries, pigment and filler powder and the like. The invention relates to a dielectric insulation protective coating with high adhesive force. The prepared coating is a solvent-free 100% solid single component, is complete in mixing and dissolving, convenient to construct, high in light curing energy utilization rate, high in production efficiency and suitable for large-scale automatic large-scale flow line production, and compared with PSA back glue used for a traditional PET blue film, the outer surface of the coating has higher surface energy, and the coating has the advantages of being high in light curing energy utilization rate and high in production efficiency. And the film has considerable dielectric insulation performance and good edge covering protection performance, and meets the development requirements of a higher charging voltage platform of a fast-charging electric vehicle in the future.

The invention provides a composite diaphragm, a preparation method thereof and a lithium ion battery. The composite diaphragm comprises a base diaphragm and a solid electrolyte-water-soluble gel electrolyte composite coating, wherein the surface of the base diaphragm is coated with the solid electrolyte-water-soluble gel electrolyte composite coating by utilizing a roller coating process; the water-soluble gel electrolyte is obtained by co-polymerizing an intermediate I prepared from methyl methacrylate and N-isopropylacrylamide and neopentyl glycol diglycidyl ether. In the composite diaphragm provided by the invention, the water-soluble gel electrolyte can effectively improve the adhesion of the solid electrolyte on the base membrane, and ensure that the solid electrolyte can be effectively adhered to the surface of the base membrane; lithium titanium aluminum phosphate and the like can effectively promote transmission of lithium ions through the solid electrolyte, the hexagonal boron nitride composite coating can prevent direct contact between the lithium titanium aluminum phosphate solid electrolyte and the like and lithium, and the solid electrolyte is protected. And the interface stability of the composite diaphragm is relatively good, and a compact phase formed in the circulation process can effectively inhibit the permeation of lithium dendrites, so that the safety of the battery is improved.

The invention provides thiamethoxam water dispersible granules and a production process thereof, and belongs to the technical field of pesticide preparation. The production process comprises the following steps: modifying methyl methacrylate; preparing an anti-ultraviolet carrier; loading eugenol; and preparing the water dispersible granules. The water dispersible granule is prepared by mixing the uvioresistant carrier loaded with eugenol with thiamethoxam, the dispersing agent, the wetting agent, the disintegrating agent and the binder, when eugenol and thiamethoxam are combined for use, the pest killing effect can be synergistically enhanced, and in addition, eugenol can bypass the resistance mechanism of pests to thiamethoxam, so that the pest killing effect is improved. Even if pests have certain tolerance to neurotoxicity of thiamethoxam, eugenol can still play a role by destroying cell membrane structures and respiratory systems of the pests, so that the resistance of the pests is broken, and the overall insecticidal effect of the prepared water dispersible granule is enhanced.

The invention provides an additive composition containing a bioactive enzyme and a preparation method of the additive composition, and belongs to the technical field of biological enzymes. The preparation method comprises the following steps: fixing phytic acid and cyclodextrin on hydroxyapatite, modifying with tannic acid, reacting with dithiothreitol modified lysozyme to prepare an immobilized compound, adding 2, 2-dimethoxy-2-phenylacetophenone and methyl methacrylate, and carrying out irradiation reaction with an ultraviolet lamp to prepare the additive composition containing the bioactive enzyme. The broad-spectrum antibacterial property and the antiviral property of the lysozyme are greatly improved, the sterilization effect on gram negative bacteria is obviously improved, meanwhile, the stability of enzyme is greatly improved, the enzyme is not prone to inactivation, the preservation time of the enzyme is prolonged, the application effect of the enzyme is widened, meanwhile, the lysozyme has good killing capacity on oral bacteria and viruses, the addition of preservatives is reduced, and the cost is reduced. The cleaning effect and stability of the product are improved, tooth demineralization can be prevented, decayed teeth can be prevented, and wide application prospects are achieved.

The invention discloses a carbon dioxide injection and production well cementation cement paste and a preparation method and application thereof, the well cementation cement paste comprises the following components by weight: 95-105 parts of oil well cement, 44-48 parts of water, 4-6 parts of a polymer emulsion, 4-6 parts of a self-repairing material, 1.5-2.5 parts of a drag reducer, 0.5-1.5 parts of a fluid loss agent and 0.2-0.8 part of an antifoaming agent; wherein the polymer emulsion is an emulsion which is formed by taking methyl methacrylate, vinyl trimethoxy silane and propylene carbonate as monomers through polymerization; the self-repairing material is a microcapsule in which thiobacillus ferrooxidans thalli and bacillus amyloliquefaciens thalli are embedded. The well cementation cement paste keeps good strength and relatively low permeability in a carbon dioxide environment, is good in corrosion resistance and has self-repairing capability.

The invention relates to the technical field of coatings, in particular to an acrylate-epoxy resin composite coating and a preparation method thereof. According to the technical scheme, the coating is prepared from 25 to 35 parts of methyl methacrylate, 15 to 25 parts of butyl acrylate, 10 to 20 parts of epoxy resin E-5110, 8 to 15 parts of organic silicon modified acrylate prepolymer, 5 to 12 parts of fluorocarbon modified epoxy resin, 4 to 8 parts of core-shell structure corrosion inhibition nano container, 1 to 3 parts of functionalized graphene quantum dots and 4 to 10 parts of polyhedral oligomeric silsesquioxane maleimide modified amine curing agent. And 1-3 parts of a hindered amine light stabilizer. By integrating the core-shell structure corrosion inhibition nano container, the functionalized graphene quantum dots and the photo-thermal dual responsive curing agent component, the sensing, response and self-repairing of the coating on damage are realized, and long-acting corrosion resistance, weather resistance, bacteria resistance, mechanical property balance and intelligent maintenance are considered; and efficient and economical full-period protection is provided for equipment in an extreme environment.

The invention discloses a multi-hydrogen bond enhanced fluorine-containing core-shell water-based binder as well as a preparation method and application thereof, and relates to the technical field of lithium ion silicon-based negative electrode binders. The preparation method comprises the following steps: dissolving methyl methacrylate, acrylonitrile and an emulsifier in water, carrying out a polymerization reaction to obtain a rigid core emulsion, adding acrylic acid long-chain ester, a fluorine-containing monomer and acrylamide, carrying out a mixing reaction to obtain a core-shell structure emulsion, mixing the core-shell structure emulsion with a sodium alginate solution, adding nano SiO2, and carrying out a polymerization reaction to obtain the high-temperature-resistant water-based acrylic emulsion. And after the reaction is finished, obtaining the multi-hydrogen bond enhanced fluorine-containing core-shell water-based adhesive. Through core-shell structure design and introduction of a multiple hydrogen bond network, the problem of bonding caused by volume expansion of the silicon negative electrode material in the charging and discharging process is successfully solved, the cycle life and stability of the battery are remarkably prolonged, meanwhile, the environment-friendly characteristic and the process simplicity are considered, and the preparation method is simple and convenient. And an efficient and sustainable development solution is provided for the field of lithium ion batteries.

The invention relates to the technical field of fabric waterproofing agents, in particular to a polyurethane modified organic silicon fluoride-free waterproofing agent and a preparation method thereof. The polyurethane modified organic silicon fluoride-free waterproof agent is prepared from the following raw materials in parts by mass: 5 to 15 parts of hexamethylene diisocyanate, 5 to 15 parts of butyl acrylate, 1 to 5 parts of methyl methacrylate, 40 to 60 parts of octamethylcyclotetrasiloxane, 10 to 30 parts of alpha, omega-dihydroxy polydimethylsiloxane and 5 to 10 parts of gamma-aminopropyl methyl diethoxy silane. The invention relates to a silane coupling agent, which is prepared from the following raw materials in parts by weight: 1 to 5 parts of glycidyl ether oxypropyl trimethoxy silane, 0.1 to 1 part of tetramethylammonium hydroxide, 0.1 to 1 part of triethylamine, 2 to 5 parts of tetraethoxysilane, 0.2 to 0.75 part of ammonia, 0.1 to 1 part of silane coupling agent KH-570, 0.01 to 0.1 part of dibutyltin dilaurate, 1 to 5 parts of epsilon-caprolactam, 1 to 2 parts of emulsifier and 0.1 to 1 part of initiator. The fabric treated by the method has good softness and excellent hydrophobic effect.

The invention discloses an acrylate finishing emulsion and a preparation method thereof, and the acrylate finishing emulsion comprises the following components in parts by mass: 18-30 parts of styrene, 5-15 parts of methyl methacrylate, 1-5 parts of 2-ethylhexyl acrylate, 5-14 parts of butyl acrylate, 0.5-1 part of acrylic acid, 0.6-1.2 parts of acrylamide, 0.8-2 parts of a high-density crosslinking monomer, 0.2-0.5 part of an initiator, 0.7-1 part of an emulsifier and 50-60 parts of water. 0.1-0.5 part of an oxidant, 0.1-0.5 part of a reducing agent, 1-5 parts of a pH regulator and 10-20 parts of an inorganic material; after the emulsion is coated to form a film, the hardness, the water resistance, the stain resistance, the low-temperature stability and the temperature change resistance are remarkably improved, and the acrylate emulsion with high hardness, high water resistance and high stain resistance can be prepared.