95results about How to "High modulus" patented technology

The invention relates to an integrally-formed hollow-structure Pick racket and a preparation method thereof, and belongs to the technical field of Pick rackets. The hollow cavity shell is filled with the foam core layer, an opening is formed in the hollow cavity shell, and the foam core layer is obtained by conducting heat treatment foaming on a foaming raw material; the method further comprises the following steps that an integrally-formed hollow cavity shell with an opening is obtained through a blow molding technology; the hollow cavity shell is filled with foaming raw materials; the filled hollow cavity shell is subjected to heat treatment, so that the foaming raw materials are foamed, expanded and fused in the shell, and a foam core layer tightly combined with the shell is formed; according to the Pick racket, an adhesive interface existing in a traditional spliced racket is structurally and thoroughly eliminated, the risk of adhesive failure and layering after long-term use or damp is fundamentally avoided, the structural integrity of the racket is greatly improved, and the durable life of the racket is greatly prolonged.

The invention relates to injectable cross-linked collagen gel and a preparation method thereof. Two crosslinking strategies of self-crosslinking and crosslinking agent crosslinking are fused together for the first time, and two types of amido bonds, namely amido bonds of a collagen-collagen structure (A) and amido bonds of a collagen-fatty amine-collagen structure (B), are respectively constructed through two crosslinking paths, namely catalysis of collagen polypeptide self-crosslinking and catalysis of fatty amine crosslinking, so that a hard / soft dual crosslinking network is obtained. The relative proportion of the structure A and the structure B in the final product is adjusted through a proper cross-linking process, so that the strength and the stability of the final product are adjusted and controlled, and the use requirements of different injection parts can be met.

The invention provides a production process of a high-wear-resistance and impact-resistance aramid fiber material, and relates to the technical field of material preparation, and the production process comprises the following steps: S1, raw material preparation: selecting a para-aramid fiber prepolymer, a hydroxylated boron nitride nanosheet, N-methyl pyrrolidone, a wear-resistance enhancer and an impact-resistance modifier according to a preset proportion, S2, mixing, S3, polymerization reaction, S5, extrusion molding, S6, extrusion molding, and S7, molding. Transferring the mixed system into a reaction kettle, introducing nitrogen for 35-55 minutes, and replacing air in the reaction kettle to form an aramid polymer; s4, molding processing: cooling the nylon polymer to room temperature, then putting the nylon polymer into spinning solution storage equipment, and winding the stretched fibers; s5, auxiliary treatment, wherein the wound fibers are washed with water and dried; according to the invention, the aramid polymer has a good crystal structure and high molecular weight, the wear resistance of the material is improved, the interface bonding force between the fiber and the matrix can be improved, and the impact resistance of the material is further improved.

The utility model relates to the field of textile fabric, especially a kind of high-strength wear-resistant fabric, including wear-resistant surface layer and antibacterial substrate layer, wear-resistant surface layer and antibacterial substrate layer between being equipped with hot melt gauze, antibacterial substrate layer is made of fiber with antibacterial function, hot melt gauze top and bottom respectively with wear-resistant surface layer and antibacterial substrate layer fixed connection, hot melt gauze is woven from hot melt fiber;Wear-resistant surface layer is woven from first fiber bundle and second fiber bundle, and the first fiber bundle includes main wear-resistant fiber as core line, and auxiliary wear-resistant fiber around core line, the weaving density of first fiber bundle in wear-resistant surface layer is 60-90 per square centimeter Root;Second fiber bundle includes main tensile fiber as core line, and auxiliary tensile fiber around core line, the weaving density of second fiber bundle in wear-resistant surface layer is 50-70 per square centimeter Root. Its solved the technical problem that existing fabric cannot consider wear resistance and tensile property.

This application relates to the field of polymer materials technology, providing a PET elastomer, composite material, dynamic covalent network polymer, and its preparation method and application. The elastomer is prepared by in-situ self-assembly of crown ether-primary amide dual-functionalized PET through melt blending. Its molecular network integrates a quasi-rotaxane supramolecular crosslinking network. This structure is formed by the host-guest interaction between the crown ether and the primary amide, and can act as a sliding crosslinking point to dissipate energy through the sliding of cyclic components. This application employs a two-step end-capping-in-situ self-assembly process to overcome the technical obstacles of low PET chain-end activity and poor compatibility between polyrotaxane and PET, achieving molecular-level dispersion of quasi-rotaxane in the PET matrix. This fully utilizes the molecular pulley effect to achieve breakthrough toughening of the elastomer. Simultaneously, it combines rigid nanofillers modified with aminosilane coupling agents to form a soft-hard synergistic network, enabling the PET composite material to maintain high toughness while simultaneously improving strength, modulus, and thermal properties.

The present application relates to the technical field of tire overall preparation, and proposes a variable stiffness tire and a tire overall preparation device, which can adapt to various driving conditions and realize the collaborative optimization of comfort and control performance, and the structure can effectively disperse flexural stress, and is not prone to heat accumulation, bulging and cracking, thereby significantly improving high-speed durability and load capacity, and the matching tire overall preparation device can adapt to the molding process of the tire body, effectively improve tire production efficiency and manufacturing precision, and comprises a tire body and a triangular rubber ring, wherein the tire body comprises a tread, a sidewall and an inner tire ring, the sidewall is divided into a shoulder section, a sidewall middle section and a bead section in the radial direction, the stiffness of the bead section, the shoulder section and the sidewall middle section decreases in turn, the sidewall middle section is a main flexible deformation area, the shoulder section provides lateral restraint, the bead section provides high stiffness support, the tread is fixedly connected with the shoulder section, and the inner tire ring is fixedly connected with the triangular rubber ring.

This invention proposes an impact-resistant seawall repair adhesive and its preparation method, belonging to the field of adhesive technology. The impact-resistant seawall repair adhesive is prepared from the following raw materials in parts by weight: 70-100 parts water glass, 30-40 parts sodium fluorosilicate, 5-10 parts ammonium chloride, 10-15 parts curing agent, 30-50 parts dimethyl silicone oil, 5-7 parts metal oxide, 2-4 parts emulsifier, and 100-120 parts water. This impact-resistant seawall repair adhesive is a silicate inorganic adhesive that can withstand extremely high temperatures and large tensile and shear forces. It boasts advantages such as high bonding strength with the substrate and abundant raw material sources, good stability, and convenient operation.

The invention relates to a high-hardness polyurethane adhesive as well as a preparation process and application thereof, and belongs to the technical field of polyurethane materials. The high-hardness polyurethane adhesive comprises a component A and a component B. The component A comprises the following raw materials in parts by weight: 30-50 parts of polyether polyol, 10-20 parts of a cross-linking agent, 5-10 parts of a composite filler, 0.5-1 part of a catalyst and 0.5-1 part of an antioxidant; and the component B is polyisocyanate. The adhesive prepared by the invention has high hardness and good toughness.

The invention relates to a Sudoku three-dimensional fabric forming process which comprises the following steps: constructing a three-dimensional skeleton with at least 3 * 3 array cavities by adopting first warp yarns, second warp yarns and weft yarns of a skin-core structure; a first type of orthogonal interaction locking structure is adopted at a central node, and a second type of surrounding bundling structure is adopted at peripheral nodes, so that the overall stability is enhanced; then, functional materials are injected into the cavities, the first warp skin layer is melted or dissolved in a heat or solvent mode and then solidified, and therefore the functional materials are sealed in the cavities of all the units; and finally binding knots by using weft yarns and applying hot pressing for reinforcement. The process can realize differentiated design of the cavity structure and stable packaging of the functional material, and is suitable for preparing the composite material preform with thermal management, sensing or bearing functions.

The invention relates to a high-strength antibacterial spandex fabric and a preparation method thereof, and belongs to the technical field of functional textile materials. The spandex fiber comprises a spandex fiber matrix and a functional polymer layer grafted on the surface of the matrix through a covalent bond, and the functional polymer layer is a polymer of an unsaturated derivative of natural phenolic acid and is prepared by introducing carbon-carbon unsaturated bond groups such as acryloyloxy and the like into the natural phenolic acid through esterification or etherification. During preparation, the spandex fiber is subjected to plasma pretreatment, and then the spandex fiber and the natural phenolic acid-containing unsaturated derivative monomer are subjected to thermal initiation or photo-initiation graft polymerization to form the functional layer. The lasting and stable antibacterial function is achieved through covalent bond grafting, the natural phenolic acid derivative endows the fiber with the environment-friendly and non-dissolution type antibacterial property, the functional layer can improve the modulus and breaking strength of the fiber, the intrinsic elasticity of spandex is considered, the comfortable fitting characteristic of the composite fabric is reserved, and the composite fabric is endowed with the high strength and the antibacterial function.

This invention provides a photoresponsive, deformable liquid crystal polyurethane material containing cyanostilbene, its preparation method, and its applications, belonging to the field of intelligent polymer materials technology. This invention introduces cyanostilbene liquid crystal units into a polyurethane system via short-chain spacer groups. Utilizing the characteristics of cyanostilbene under ultraviolet light irradiation (requiring trans / cis isomerization), its photothermal effect, the stability of the cis isomer structure, and the ability of the cis isomer to lower the glass transition temperature of the polymer, as well as the strong coupling effect between the cyanostilbene liquid crystal units and the main chain, a photoresponsive, deformable liquid crystal polyurethane material with high mechanical properties, high processability, high deformation rate, large deformation degree, and strong photostress can be prepared. This photoresponsive, deformable liquid crystal polyurethane material has wide applications in fields such as micro-optically driven robots, artificial muscle flexible actuators, and 4D-printed programmable deformable structures.

The invention relates to the technical field of building waterproof composite materials, in particular to an organic silicon modified resin building waterproof composite material and a preparation method thereof. Comprising a waterproof roll and a waterproof coating arranged on the surface of the waterproof roll, the waterproof coating is prepared from the following components in parts by weight: 20 to 32 parts of silane modified polyether, 15 to 30 parts of organic silicon modified resin, 5 to 10 parts of polysaccharide-based composite polylactic acid, 8 to 12 parts of plasticizer, 1 to 3 parts of curing agent, 0.5 to 2 parts of titanium dioxide and 0.5 to 3 parts of water removal agent. An organic silicon structure in the prepared waterproof composite material has the characteristic of low surface energy, so that the surface of a coating presents strong hydrophobicity, and liquid water permeation is effectively blocked; the waterproof coating can be matched with a compact cross-linked network structure to form a continuous and seamless waterproof film, realizes high hydrostatic pressure resistance and low water absorption, and is suitable for key waterproof parts such as roofs, basements and toilets.

This invention discloses a method for preparing high-temperature resistant polyimide foam material, comprising: preparing a foamable precursor powder using aromatic dianhydride and diamine; performing bilayer extrusion and foaming molding using two single-screw extruders, wherein one extruder extrudes and foams the foamable precursor powder, and the other extrudes fiber-reinforced thermoplastic resin; the two are compounded at a co-extrusion die, and shaped by a shaping die to obtain a polyimide foam composite material with a fiber-reinforced resin layer on the surface; cutting and collecting polyimide foam strips or foam particles of equal length, filling them into a die, and then hot-pressing to obtain the polyimide foam composite material. This invention significantly improves the operability of polyimide foam preparation and simplifies subsequent molding processes. This invention also provides a high-temperature resistant polyimide foam material obtained by the above preparation method, which can simultaneously provide high compressive strength, high modulus, and low density, and is easy to scale up for production.

The invention discloses a piezoelectric film with bionic textures and a preparation method and application thereof, the piezoelectric film is formed by directionally stacking and depositing fibers with core-shell structures, the piezoelectric film has a gully-bulge alternating bionic morphology imitating human skin surface textures, and the aperture of the piezoelectric film is gradually increased from an attachment surface in the thickness direction; the fiber having the core-shell structure comprises: a core layer having a porous structure and containing modified molybdenum disulfide and polyester; the shell layer wraps the core layer, and the shell layer contains collagen; the piezoelectric film comprises a sensing unit area and a flexible connection area, the collagen crosslinking degree of the sensing unit area is larger than 75%, and the collagen crosslinking degree of the flexible connection area is 40%-55%. Under the synergistic effect of materials and structures, the piezoelectric film not only has a high piezoelectric constant, but also shows excellent mechanical properties, air permeability and moisture penetrability, and has wide application prospects in the fields of electronic skin, health monitoring and the like.

The invention relates to the technical field of composite films, in particular to a flame-retardant composite film and a preparation method thereof. The composite film is of an ABA type symmetrical three-layer co-extrusion structure, and functional division and synergistic interaction are achieved by concentrating a main flame-retardant function on a core layer (B layer) and distributing hydrolysis resistance and mechanical enhancement functions on a surface layer (A layer). The layer A comprises crystalline polyester, reinforcing master batch and an interface reinforcing agent; the layer B comprises crystalline polyester and composite flame-retardant master batch; the preparation method mainly comprises the following steps: respectively preparing the reinforced master batch and the composite flame-retardant master batch; respectively mixing the raw materials of the layer A and the layer B, drying and melting; co-extruding and casting through a three-layer co-extrusion die head with gradient temperature field control, and quenching a cast sheet; and preheating the cast sheet, and then carrying out synchronous two-way stretching, heat setting and cooling rolling. The film prepared by the invention has excellent halogen-free flame retardance, outstanding damp-heat aging resistance and high mechanical strength, and is suitable for the field with strict requirements on safety and durability.

This invention discloses a method for preparing high-entropy ceramic matrix composites using a reactive infiltration process, belonging to the technical field of ceramic matrix composites. The steps are as follows: at least four single-component carbides are ball-milled and mixed with a carbon source, then dispersed in a dispersion liquid to obtain a slurry; continuous fibers are woven into a preform, and an interface layer and a matrix layer are deposited to obtain a semi-dense composite material; the slurry is introduced through vacuum or pressure impregnation; and a high-entropy carbide matrix is ​​generated in situ and densified by reactive infiltration after embedding with a transition metal and its alloy. This invention solves the problems of long process cycles, high porosity, high cost, and insufficient introduction of high-entropy ceramics in existing processes, achieving rapid densification and improving the material's high-temperature stability, oxidation resistance, and ablation resistance. It is suitable for the large-scale production of thermal protection materials for hypersonic vehicles.

The present application relates to a kind of light and thin embroidery fabric and its preparation method, belong to fabric technical field, the preparation method includes: S1, preparation modified polyurethane emulsion, cotton fiber and polyester fiber are immersed in modified polyurethane emulsion, dry, the cotton fiber and polyester fiber after treatment are obtained, for standby;S2, take the cotton fiber and polyester fiber after treatment, prepare light and thin yarn using the way of Siro compact spinning, plain weave, obtain light and thin base cloth;S3, preparation finishing liquor;S4, light and thin base cloth is soaked in finishing liquor according to bath ratio, take out, lay on the calender roll, roll liquid, take out the fabric, dry, obtain light and thin embroidery fabric.The sulfonic acid group and polyethylene glycol segment introduced in modified polyurethane, cotton fiber and polyester fiber are immersed in modified polyurethane emulsion, microcrystalline cellulose and chitosan are added in finishing liquor, improve the tensile resistance, hydrophilicity and dyeing rate of light and thin embroidery fabric.

The present invention provides a reinforced core material for a fan blade, comprising a core material and reinforcements distributed inside the core material. The reinforcements comprise one or more first reinforcements and one or more second reinforcements that are spaced apart from each other and alternately distributed, wherein the first reinforcement and the second reinforcement extend transversely to the length direction of the reinforced core material, the tensile modulus and tensile strength of the first reinforcement are greater than the tensile modulus and tensile strength of the second reinforcement respectively, the first reinforcement is formed via resin infiltration on one or more fibers of the same or different shapes, and the second reinforcement is a synthetic high polymer.

The invention relates to the technical field of alloy materials, and discloses an alloy material component screening method, system and equipment and a medium. The method comprises the following steps: constructing an alloy component performance data set; constructing a multi-model performance prediction model, and training the multi-model performance prediction model according to the alloy component performance data set to screen out a performance prediction reference model; performing global search according to a genetic algorithm and the performance prediction reference model to obtain an alloy component scheme and a corresponding performance prediction result; according to the alloy component scheme and the performance prediction result, weighted assignment sorting is carried out to screen out a target alloy combination; and performing simulation verification and process analysis on the target alloy combination to optimize the performance prediction reference model. According to the method, deviation of a single model is avoided through a multi-model performance prediction model, the genetic algorithm is introduced to ensure global search and avoid local optimization, the closed-loop process design is formed by combining simulation verification and process analysis, the target alloy combination meeting the requirements is rapidly and accurately screened, and the development efficiency is improved.

This invention discloses a method for preparing a modified chitosan whisker-reinforced and toughened PBAT microfoamed composite material. Biodegradable and high-modulus chitosan whiskers are selected as the reinforcing agent, enabling the composite material to achieve full biodegradability. Through surface modification technology, PBAT segments with the same composition as the PBAT matrix are introduced onto the surface of the chitosan whiskers. This design ensures good compatibility between the chitosan whiskers and the matrix, resulting in thorough dispersion within the matrix and achieving a more efficient reinforcement and toughening effect than traditional reinforcing agents. Simultaneously, the grafted and modified chitosan whiskers can increase the melt viscosity and melt strength of the PBAT matrix, thereby improving its foaming properties.

The application relates to the technical field of high polymer materials, and discloses a high-temperature-resistant PETG blister box and a preparation method thereof. The PETG blister box disclosed by the application comprises the following raw materials in parts by weight: PETG 50-70 parts, PET 10-15 parts, a composite modifier 8-12 parts, POE-g-GMA 12-16 parts, an antioxidant 0.5-1.5 parts, a lubricant 1-1.5 parts and a heat stabilizer 1-3 parts. The PET and the composite modifier are introduced into the blister box, and the two components synergistically improve the high-temperature resistance of the blister box. Therefore, the product can be widely used in the blister packaging field with high requirements for heat resistance, such as hot filling and high-temperature sterilization.

The utility model belongs to the technical field of self-adhesive labels, in particular to a flexible self-adhesive label suitable for curved surface adhesion, which comprises an outer layer, and a printing layer and a protective layer are sequentially coated on the upper surface of the outer layer from bottom to top. According to the flexible self-adhesive label suitable for curved surface pasting, the flexible self-adhesive label suitable for curved surface pasting is arranged and can adapt to curved surface pasting, the middle layer is made of silicon rubber, and controllable and local deformation (such as groove widening / deepening) can be generated when the label is subjected to bending or stretching stress through the stress release groove microstructure; therefore, stress is efficiently absorbed and dissipated, failure caused by the fact that the stress is transmitted to the edge of the label or the interface of the bonding layer is prevented, the stressed stress can be dispersed through the wave grooves, and the situation that the middle layer of the label is broken after being bent multiple times due to stress concentration is avoided.

The invention discloses a high-strength acrylic structural adhesive and a preparation method thereof, and belongs to the technical field of structural adhesives. The high-strength acrylic structural adhesive comprises a component A and a component B, the component A comprises an acrylate monomer, a first cross-linking agent, an antioxidant, a polyacrylate elastomer, a polymerization inhibitor, a reducing agent and modified mesoporous silica; the component B comprises an acrylate monomer, a first cross-linking agent, a polyacrylate elastomer, a polymerization inhibitor, an oxidizing agent and modified mesoporous silica; the acrylic ester monomers comprise ethyl methacrylate and lauryl methacrylate; 2, 4, 6-triallylphenol is adopted as the antioxidant; the polyacrylate elastomer is obtained by carrying out composite reaction on 2-acrylamido-2-methyl-1-propane sulfonic acid polymer particles, ethyl acrylate, vanillin methacrylate, an initiator and a second cross-linking agent; the second cross-linking agent is prepared from ethylene glycol dimethacrylate and triallyl phosphite ester.

The application discloses a resin composition and application thereof, and the resin composition comprises, in terms of solid weight, 10-70 parts of a benzoxazine resin containing unsaturated bonds, and 20-100 parts of a maleimide resin; wherein the benzoxazine resin containing unsaturated bonds is a mixture of a benzoxazine resin containing double bonds and a benzoxazine resin containing triple bonds. Compared with the prior art, the resin composition and application thereof can not only control the reactivity between the maleimide resin and the benzoxazine resin, improve the crosslinking network density, but also is beneficial to controlling the production speed of prepreg, and the prepreg has good apparent quality, and meanwhile has excellent high heat resistance, high modulus, low water absorption, low thermal expansion coefficient and low curing shrinkage.

The invention discloses a preparation method of a low-cost polyacrylonitrile-based carbon fiber. The preparation method comprises the following steps: preparing a high-viscosity low-solid-content polymerization stock solution, carrying out dry-jet wet spinning on a precursor, carrying out gradient heating pre-oxidation, carrying out graded reduced-pressure carbonization combined with pulsed magnetic field treatment and carrying out surface treatment. Wherein the step-by-step decompression carbonization treatment comprises the following steps: in a low-temperature carbonization stage, the system pressure is programmatically reduced to-200Pa from-5Pa, and pyrolysis byproducts are mildly discharged to reduce defects; in the high-temperature carbonization stage, a certain constant negative pressure within the range of-200Pa to-500Pa is maintained, a pulsed magnetic field parallel to the axial direction of the fiber is synchronously applied, and the axial arrangement degree of graphite microcrystals is improved by utilizing the magnetic orientation effect so as to remarkably improve the modulus. Through a matched multi-stage gradient vacuum dynamic sealing system, the consumption of protective gas is reduced by 50%-80% while continuous closed operation of fibers is realized. And the prepared fiber is better in performance and lower in production cost.

This invention discloses a solid asphalt based on ultrafine rock asphalt, a high-performance asphalt mixture prepared from the solid asphalt, and a preparation method thereof. The solid asphalt includes ultrafine rock asphalt, desulfurized rubber powder, binder, interface reinforcing agent, filler, and exothermic accelerator, wherein the exothermic accelerator is selected from dicyandiamide, 4,4'-diaminodiphenyl sulfone, phthalic anhydride, or pyromellitic dianhydride. The asphalt mixture includes solid asphalt, aggregate, and blending oil, wherein the blending oil includes epoxy resin blending oil and blending oil B. In preparing the asphalt mixture, after determining the aggregate gradation, the aggregate is preheated to 170-180°C, and then solid asphalt is added and mixed for 8-12 seconds to obtain the mixture. Then, the epoxy resin blending oil is preheated separately, and then blending oil B and epoxy resin blending oil are added to the mixture sequentially, and mixed for 30-60 seconds. The present invention, based on solid asphalt, not only changes the existing liquid asphalt mixing system, but also enables rapid liquefaction of asphalt within aggregates in a short time and improves the interfacial adhesion between asphalt and aggregates.

The invention provides a special-shaped child-mother rod intelligent composite bar based on microscopic modification and a preparation method of the special-shaped child-mother rod intelligent composite bar. The special-shaped child-mother rod intelligent composite bar is used for solving the problems that an existing intelligent composite bar is poor in toughness, fatigue resistance and stability. Comprising a metal sleeve and a special-shaped child-mother sensing core rod which are coaxially arranged, the metal sleeve is a metal sleeve, the space between the metal sleeve and the special-shaped child-mother sensing core rod is filled with an interface function layer, the interface function layer is made of a microcosmic modified high-molecular binder, the microcosmic modified high-molecular binder comprises a high-molecular material, and the surface of the high-molecular material is coated with a coating. Hard micro-nano particles used for improving toughness and fatigue resistance are uniformly dispersed in the high polymer material. Microscopic particle mechanical anchoring, microcosmic special-shaped geometric occlusion and macroscopic structure interlocking are organically combined, a seamless anti-sliding system from the nanometer / micrometer level to the millimeter level is constructed, and the toughness and fatigue resistance of the composite rib and the stability of signal transmission are improved.

The invention discloses a creep-resistant magnesium alloy with high elasticity modulus and high damping and a preparation method thereof, and the creep-resistant magnesium alloy with high elasticity modulus and high damping comprises the following components in percentage by mass: 1.2%-3.5% of Zn element, 2.5%-12% of Gd element, 0.5%-6% of Yb element, 0.15%-1.2% of Ni element, 0.3%-0.8% of Mn element, 0-0.5% of Cu element, 0.1%-5% of HRE element and the balance of Mg element. The HRE element is one or more of a Dy element, a Sm element and a Tb element, and the mixing enthalpy delta H of the creep-resistant magnesium alloy with the high elastic modulus and the high damping is-1.1 kJ / mol to-0.2 kJ / mol. The creep-resistant magnesium alloy with high elastic modulus and high damping is suitable for the fields of aerospace, precise instruments, transportation, 3C electronics and the like, and has remarkable technical and economic values.

The invention discloses a thermoplastic composite material prepared based on a waste composite material pyrolysis product and a preparation method of the thermoplastic composite material, and particularly relates to the technical field of fiber reinforced composite material reutilization, and the thermoplastic composite material comprises a matrix phase, a first-stage reinforcement phase and a second-stage reinforcement phase. The preparation method of the thermoplastic composite material comprises the following steps: crushing the waste carbon fiber composite material, and controlling the pyrolysis temperature to be 450-600 DEG C and the pyrolysis time to be 30-60 minutes to obtain a pyrolysis solid product; separating the obtained pyrolysis solid product to respectively obtain a fraction A and a fraction B; premixing the fraction A and cracked carbon micro powder according to the mass ratio of (2: 1)-(5: 1) to obtain a mixed reinforcement; and carrying out melt blending on the mixed reinforcement and the thermoplastic resin matrix, and carrying out extrusion molding to obtain the thermoplastic composite material. The thermoplastic composite material prepared by the scheme aims to synchronously reinforce an interface and a matrix by constructing a multi-stage reinforcing structure and realize all-component high-value utilization of a pyrolysis product of the waste carbon fiber composite material.

The invention discloses a forming method combining pultrusion and mould pressing of a bow slice, basalt fiber and glass fiber are guided and mixed, and then the mixture and a prepared gum dipping material are pultruded to form the bow slice, and the pultrusion process comprises the steps of feeding materials on a basalt fiber yarn roll and a glass fiber yarn roll which are respectively arranged on a creel; glue feeding is completed through the resin pre-soaking tank, then the glue sequentially passes through the pre-forming pultrusion die and the forming die, the glue is pulled to the cutting device to be cut by the traction device, and finally the glue is placed in the mold pressing device to be subjected to mold pressing forming. By means of high-efficiency production of the pultrusion process and combination of the mold pressing process, the modulus and strength of the bow piece are effectively improved, the porosity of the bow piece is reduced, and meanwhile the defect problems that the surface of the bow piece is sunken, and the center of the bow piece cannot be infiltrated thoroughly are solved.