The invention discloses a method for enriching platinum group metal secondary resource with high efficiency. The technology comprises the following steps: a platinum group metal secondary resource material, a trapping agent, a reducing agent, a slagging agent, a binder and moisture are put in a bowl mill for wetting grinding, after the materials are uniformly mixed, a granulator is used for preparing the pellets, the pellets are dried to obtain the composite pellets; a graphite crucible is used for putting the composite pellets, the composite pellets are molten in a reduction furnace, after melting for a while, the composite pellets are dumped into the graphite crucible, then cooled, an upper layer is the melting slag, a lower layer is a platinum metal alloy sulfonium phase, the high efficiency trapping of the platinum group metal is realized; elements such as copper, iron, nickel and sulfur in the alloy phase can be leached by employing pressure acid leaching in a selective mode, after filtering and washing, the platinum group metal concentrate is obtained, and the high efficiency enrichment of the platinum group metal is realized. The method has the advantages of simple operation, high platinum yield, high enrichment ratio, environmental protection, low cost, low energy consumption, and good industrialization prospect.