The invention discloses a FLiNaK fused salt and a preparation method, a reactor and a preparation device thereof. The contents of oxygen, sulfur, chlorine, silicon, nickel, iron, calcium, aluminum, barium, chromium, cobalt, cadmium, manganese, magnesium, copper, phosphorus, lead, zinc, vanadium, titanium, molybdenum, tungsten, zirconium, strontium, and stannum in the FLiNaK fused salt is lower than 0.01%, and the total content of impurity elements is not more than 0.1%; and the mass ratio of LiF, NaF and KF is 29.3:11.7:59.0. The preparation method includes mixing and drying; (2) heating and melting; (3) performing bubbling treatment with hydrogen for more than 8 hours at the temperature of 500-600 DEG C; (4) performing the bubbling treatment on the mixture gas of hydrogen fluoride and hydrogen with the ratio of 1:(4-9) for more than 36 hours at the temperature of 500-550 DEG C; and (5) performing retreatment with hydrogen. The FLiNaK fused salt has excellent material compatibility with Hastelloy N, GH3535 and SUS316Ti alloy.