The invention is a hole wall strengthening method and device based on laser shock wave technique, relating to the laser machining field. And the invention firstly determines the corresponding reflecting cone diameter according to the principle of cooperation of hole size and hole shaft of a to-be-machined workpiece, coating energy absorbing layer material on the concial surface of the reflecting cone and then inserting the reflecting cone in the workpiece, installing the workpiece on a clamp, injecting constraint layer in the to-be-machined hole; a laser generates a laser pulse which irradiates the energy absorbing layer through light guiding system and constraint layer, and the energy absorbing layer absorbs the laser energy to vaporize, ionize, form plasma explosion, generate high amplitude shock wave, and strengthen the hole wall. And the invention can strengthen the walls of holes with larger diameters and strengthen the walls of micropores. And the strength and hardness of the strengthened hole wall are remarkably improved, and the surface layer has helpful remaining compression stress and it can obtain higher size accuracy and lower surface roughness and directly act as the final procedure of hole machining.