14992 results about "Macromolecule" patented technology

The invention relates to a layered drug-loading microneedle patch as well as a preparation method and application thereof. The preparation method of the layered drug-loading microneedle patch comprises the following steps: S1, dissolving a drug and a soluble high-molecular polymer in a solvent according to a mass ratio of (2: 1)-(1: 12) to form a needle tip solution, then filling a needle tip cavity of a microneedle mold with the needle tip solution, drying, and removing redundant drug residues on the surface to form a drug-loading needle tip layer; and S2, filling a mold containing the drug-loading needle tip layer with a photocurable polymer, performing ultraviolet curing for 10-30 seconds under the wavelength of 365-405 nm, and then performing demolding to form a substrate layer, thereby obtaining the layered drug-loading microneedle patch. According to the method, one-time filling of the needle tip part is successfully achieved by combining needle tip auxiliary material proportion optimization, meanwhile, the curing process is rapid, the medicine utilization rate and the process stability are remarkably improved, the medicine stability is good, and the method is suitable for industrial production.

The invention discloses a pure bio-based PHA aqueous dispersion as well as a preparation method and application thereof, and belongs to the technical field of pure bio-based polymer aqueous dispersion. According to the dispersion, polyhydroxyalkanoate is used as a unique film forming matter, Pickering solid particles and a natural surfactant are adopted for synergistic stabilization, and a bio-based plasticizer can be selected. The emulsion or slurry with the polyhydroxyalkanoate content of 40-85wt% and the particle size of 0.2-3m is prepared through a melting high-pressure homogenization method, a low-temperature wet grinding method or a solvent replacement method. The coating does not contain petrochemical polymer protective colloid and perfluorinated and polyfluoroalkyl substances, and the bio-based content is greater than or equal to 99%. Due to the excellent stability, rheological property and film-forming property of the modified starch, the modified starch becomes an ideal basic material for constructing a multi-layer programmable controlled release and degradation functional coating system, can be used in the fields of paper-based barrier coatings, adhesives, advanced crop seed coats and the like, realizes excellent barrier, bonding and controlled release properties, meets the industrial compost and repulping property standards, and has wide application prospects. The method has green, environment-friendly and industrial potential.

A preparation method of a self-suspending proppant for hydraulic fracturing is characterized in that solid ceramsite is changed into a porous reinforced structure, a self-repairing function is introduced, bio-based macromolecules are adopted to replace a traditional surfactant, the environmental protection property is improved, nano-deposition and microwave technologies are introduced, the performance is improved, meanwhile, the energy consumption is reduced, and the compression resistance enhancement and self-repairing characteristics are newly added; and the method adapts to more complex stratum working conditions.

The invention discloses a preparation method of flame-retardant silicone rubber resistant to long-term thermal aging, and relates to the technical field of high-molecular compound composition anti-aging rubber. The flame-retardant silicone rubber is prepared from the following components in parts by mass: 75 to 100 parts of methyl vinyl silicone rubber raw rubber, 18 to 28 parts of fumed silica, 20 to 35 parts of aluminum oxide trihydrate, 0.5 to 3 parts of platinum flame-retardant synergist, 2 to 5 parts of heat-resistant additive, 1.5 to 2.5 parts of structured control agent, 1 to 2 parts of cross-linking agent, 2 to 10 parts of anti-aging agent and 8 to 13 parts of fluorinated silicone rubber. Through a synergistic flame-retardant system, the silicone rubber disclosed by the invention shows obvious advantages in flame-retardant capability, can reach a higher flame-retardant grade, effectively delays flame propagation, and reduces the risk of fire disasters. The weather resistance of the silicone rubber is remarkably improved due to the ultraviolet absorption function and the anti-oxidation function of the anti-aging agent, so that the silicone rubber can effectively resist ultraviolet rays and oxidation under the long-term outdoor solarization condition, and the performance reduction and the appearance deterioration are reduced.

The invention belongs to the technical field of high polymer material design and intelligent manufacturing, and discloses a machine learning driven epoxy resin based composite material thermal-mechanical property aided design method, which comprises the following steps: S1, data acquisition and feature construction; s2, performing feature screening; s3, constructing and training an interpretable prediction model; s4, carrying out reverse design and optimization; and S5, performing closed-loop verification and updating. According to the method, the quantitative relation of structure-process-performance is constructed through an interpretable machine learning model, and the contribution mechanism of each factor is revealed by means of SHAP analysis. And finally, reversely designing an optimal epoxy resin monomer structure and a matched curing process according to the performance target. The limitation of a traditional trial and error method is broken through, collaborative optimization of the material structure and the forming process can be achieved, and the development efficiency of the epoxy resin-based carbon fiber composite material is remarkably improved.

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The invention relates to the technical field of high polymer materials, in particular to ethylene-vinyl acetate copolymer modified polypropylene high-toughness plastic particles and a preparation process thereof. The composite material is prepared from the following raw materials in parts by weight: 60 to 80 parts of polypropylene, 15 to 30 parts of ethylene-vinyl acetate copolymer, 5 to 10 parts of maleic anhydride-2-ethylhexyl acrylate copolymer grafted ethylene-vinyl acetate copolymer, 3 to 8 parts of nano silicon dioxide / graphene quantum dot composite filler, 5 to 12 parts of polyolefin elastomer, 0.5 to 2 parts of antioxidant and 0.5 to 2 parts of lubricant. The content of vinyl acetate in the ethylene-vinyl acetate copolymer is 20-33 wt%, the composite filler is modified through a silane coupling agent KH-560, the grafting rate of the grafted ethylene-vinyl acetate copolymer is 1.5-3.5 wt%, and the composite filler is prepared through a melt grafting method. Through multi-component collaborative design and process optimization, the low-temperature toughness, rigidity, heat resistance and aging resistance of the material are improved, the problems of rigidity and toughness imbalance, low-temperature brittleness, poor stability and the like of a traditional modification system are solved, and the material is excellent in comprehensive performance and wide in application range.

The invention provides a PHA dispersion emulsion as well as a preparation method and application thereof, and belongs to the field of high polymer materials. The invention aims to solve the technical problem that the prior art cannot simultaneously meet the requirements of the polyhydroxyalkanoate water dispersion system on extremely low temperature natural film-forming property, excellent comprehensive performance after film formation and long-term storage stability. The method is characterized in that a polyhydroxyalkanoate polymer with specific molecular weight and polydispersity index range, a coalescing agent 2, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate with a specific chemical structure and a specific type of aliphatic polyisocyanate cross-linking agent compatible with water dispersion are strictly limited and combined. Through the synergistic effect generated by the unique ternary combination, the minimum film forming temperature of the prepared emulsion can be reduced to 6-10 DEG C, a film can be naturally formed without hot pressing, and the formed film has excellent mechanical property, water resistance and adhesive force and has excellent storage stability of at least one year.

The invention discloses a solvent-resistant foaming material and a preparation method thereof, and relates to the technical field of high-molecular compound rubber foaming materials. The solvent-resistant foaming material is prepared from the following raw materials in parts by mass: 90 parts of a basic polymer, 5-25 parts of a chemical foaming agent, 0.5-5 parts of a cross-linking agent, 0.5-8 parts of a foaming aid, 5-40 parts of filler, 10-30 parts of a solvent-resistant modifier, 0.5-5 parts of a processing aid and 0.5-1.5 parts of an anti-aging agent. Through the synergistic effect of the base polymer (the nitrile rubber and the butadiene rubber are mixed according to the ratio of 1: 1) and the solvent-resistant modifier (such as polytetrafluoroethylene powder), the problem that a traditional foaming material is easy to swell and deform in an organic solvent environment is solved. On the trend, the volume swelling rate and the mass change of the material in a solvent are effectively reduced, the infiltration resistance is enhanced, the structural integrity of the material is kept when the material is in contact with lubricating oil or an alcohol solvent for a long time, and therefore the service life of a sealing piece is prolonged.

The invention belongs to the technical field of flame-retardant macromolecules, and particularly relates to intrinsic heat-conducting flame-retardant recycled epoxy resin and a preparation method thereof. The preparation method comprises the following steps: (1) carrying out a reaction on diethanol amine and 9, 10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) to obtain an intermediate A; and (2) carrying out condensation polymerization on the intermediate A and phenylphosphonic acid to prepare the phosphate-terminated polyester flame retardant (PEF). And (3) carrying out epoxidation on 4, 4 '-biphenol to prepare the liquid crystal epoxy precursor LEP. And (4) mixing PEF, LEP and 3, 3 '-dithiodipropionic acid, and heating and curing to prepare the epoxy resin. The prepared epoxy resin has intrinsic heat conduction, flame retardance and efficient recoverability, and is a high polymer material with great potential.

The invention discloses reactive compatible ACR-PHA core-shell latex and application thereof, and belongs to the field of polymer chemistry and material science. The latex comprises composite particles with core-shell, gradient core-shell, raspberry-shaped or Janus heterostructure, interfaces of ACR phase and PHA phase of the latex are connected through covalent bonds, and the compatibility problem of physical blending is fundamentally solved. The latex particles have a Z-average particle size of 80-400 nm, a PDI of less than or equal to 0.30, and a minimum film formation temperature (MFFT) of-10 to 12 DEG C. The coating prepared by the invention has excellent high-humidity barrier stability (WVTR is less than or equal to 65g / m.d), low-temperature rapid heat sealability, water resistance, oil resistance and complete recoverability, does not contain PFAS, is an ideal alternative scheme of a traditional PE (Polyethylene) spraying film, and is suitable for the fields of food packaging paper, paper cups, bowls and the like.

The invention discloses a large-size green packaging carton and a preparation process thereof, and relates to the field of packaging box preparation. The environment-friendly composite material comprises the following raw materials in parts by weight: 50-80 parts of plant fiber slurry, 10-25 parts of a modified starch-based adhesive, 5-15 parts of a nanoscale inorganic reinforcing filler, 1-5 parts of a degradable water repellent agent, 0.5-3 parts of a cross-linking agent and 2-8 parts of starch and plant fiber composite buffer microspheres. According to the preparation method, full-environment-friendly raw materials such as plant fiber slurry and a modified starch-based adhesive are selected and matched with starch and plant fiber composite buffer microspheres, and optimized processes such as segmented temperature control pressurization molding, adhesive gelatinization treatment, stirring speed reduction and microsphere structure protection are combined; and through coating of the degradable polymer coating and micron-sized hydrophobic texture imprinting, synergistic improvement of high compressive strength, excellent buffering performance, excellent hydrophobic and damp-proof effects and high degradation rate of the carton is achieved.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PVB (Polyvinyl Butyral) film and a preparation method thereof. The PVB film provided by the invention is prepared from the following components in parts by mass: 100 parts of PVB resin, 33 to 36 parts of triethylene glycol di-2-ethylhexoate, 7 to 9 parts of integrated anti-radiation toughening filler, 1 to 2 parts of organic montmorillonite, 0.8 to 1.2 parts of composite coupling agent, 0.5 to 1 part of ultraviolet light absorber, 0.6 to 0.8 part of antioxidant and 0.8 to 1 part of heat stabilizer. The integrated anti-radiation toughening filler adopts a core-shell structure, the anti-radiation core is composed of bismuth oxide and tungsten oxide according to the mass ratio of 3: 1, and the elastic coating layer is maleic anhydride grafted modified POE. The preparation method comprises the steps of pre-dispersion treatment, component mixing, melt extrusion, film casting, graded cooling, two-way stretching and the like. Through the core-shell structure design of the integrated anti-radiation toughening filler and the optimized processing technology, the anti-radiation performance and the toughening performance are synergistically improved, and the prepared film has the advantages of excellent anti-radiation effect, high toughness and good transparency.

The invention discloses a biomass-based reinforcing agent for paper and application of the biomass-based reinforcing agent. The reinforcing agent comprises a biomass-based material, the biomass-based material comprises a micron-sized structure and a nano-sized structure distributed on the micron-sized structure. The reinforcing agent prepared by the invention has abundant nanostructures, is beneficial to physical crosslinking such as entanglement and bridging of fibers in paper pulp, and improves the wet strength of paper; the preparation of the reinforcing agent is a simple physical process, and a complex synthesis chemical process for synthesizing a polymer in a traditional organic reinforcing agent is avoided; the reinforcing agent is prepared by a dissolution regeneration method, so that the energy consumption is low, the solvent can be recycled and reused, no chemicals are consumed, and the reinforcing agent is environment-friendly; the reinforcing agent prepared by the invention can achieve a satisfactory wet strength effect at a lower content.

The invention discloses an extrusion process multi-parameter dynamic cooperative control method and system based on deep learning, and belongs to the technical field of high polymer material processing control, the extrusion process multi-parameter dynamic cooperative control method and system based on deep learning comprises the following specific steps: 1, data acquisition and preprocessing, the method comprises the following steps: acquiring multi-source time sequence data in an extrusion production process in real time through a sensor system, and preprocessing the data to form a standardized data set; the multi-source time sequence data comprises equipment operation parameters, process physical parameters and environment parameters. According to the method, the control system is endowed with powerful nonlinear time sequence prediction and multi-parameter collaborative decision-making capabilities through deep fusion of deep learning and reinforcement learning technologies, the quality trend can be accurately predicted, a collaborative control instruction can be given prospectively, and the problems of parameter coupling and control lag are effectively solved.

The invention discloses water-based anti-forgery ink, a preparation method thereof, an obtained printed matter and application thereof, and relates to the technical field of printing forgery prevention. The water-based anti-forgery ink comprises the following components in percentage by mass: 15%-30% of water-based resin, 5%-20% of acrylic resin, 0.5%-10% of an auxiliary agent, 2%-5% of a first fluorescent developing substance, 3%-10% of a first microcapsule and the balance of water, a capsule core of the first microcapsule contains a second fluorescent color developing substance, a capsule shell is made of a first temperature-sensitive high polymer material, and the first temperature-sensitive high polymer material is subjected to reversible phase transformation at a first threshold temperature T1; the second fluorescent color-developing substance is different from the first fluorescent color-developing substance. According to the invention, multiple hidden anti-counterfeiting mechanisms are arranged and can be triggered under specific conditions, so that the cracking difficulty is increased; and the anti-counterfeiting verification requirements in some important occasions can be met.

The invention discloses a heavy metal chelating agent for industrial wastewater and a preparation method of the heavy metal chelating agent, and belongs to the technical field of sewage treatment.The preparation method comprises the steps that 2-hydroxyphenylboronic acid is subjected to graft modification through acrylic acid and polymerized on the surface of activated biomass porous carbon powder with acrylic acid, boron-containing polymer modified porous carbon is obtained, and then ferric chloride hexahydrate serves as an iron source; a boron-containing polymer modified porous carbon surface and aminated magnetic adsorption nanospheres are obtained, B-N coordination is formed between the aminated magnetic adsorption nanospheres and the boron-containing polymer modified porous carbon surface, boron element fixation is achieved through modified copolymerization, loss caused by long-time use of the boron element is avoided, lasting and stable chelation is guaranteed, activated biomass porous carbon serves as a carrier, and macromolecular resin serves as a coating layer. The environment-friendly biochar has the advantages of favorable degradability, greenness, degradability, safety and high efficiency, and avoids the problem of secondary pollution caused by the use of a chelating agent.

The invention relates to double-layer integrated asymmetric viscous hydrogel as well as a preparation method and application thereof, and belongs to the technical field of hydrogel. The invention relates to a preparation method of double-layer integrated asymmetric viscous hydrogel, which comprises the following steps: adding natural macromolecular polysaccharide and a polymeric monomer into a salt solution, stirring at room temperature, then adding an initiator and a cross-linking agent, stirring and polymerizing to obtain the double-layer integrated asymmetric viscous hydrogel. Through a one-pot method, a salt component is introduced into a hydrogel system, and the hydrogel has a double-layer structure with asymmetric viscosity under the salting-out action; in addition, the hydrogel is doped with a carbon nanotube with the surface modified by polydopamine and silver nanoparticles, so that the mechanical property and the conductivity of the hydrogel are remarkably improved. The preparation method provided by the invention is simple, is suitable for various hydrogel systems, has good universality and is easy to popularize and apply.

The invention relates to a high-barrier polypropylene medical material and a preparation method thereof, and belongs to the technical field of high polymer materials. The medical material is prepared from the following components in percentage by weight: 2.2 to 3.5 percent of modified graphene, 0.35 to 0.4 percent of antioxidant, 0.6 to 0.8 percent of lubricant and the balance of polypropylene resin, the modified graphene induces polypropylene to generate a beta crystal extension area along the lamellar edge, an inorganic-organic barrier surface is formed, the shielding barrier effect is improved, the tortuosity degree of a permeation path is increased, and the core technical problems that large-lamellar graphene is difficult to disperse and small-lamellar graphene is difficult to form a large shielding barrier layer are solved; the beta-phase polypropylene formed at the edge of the graphene has excellent toughness, the toughness gradient of the graphene and a polypropylene matrix is weakened, the defects between interfaces are reduced, and the stability of the barrier property is improved.

The invention relates to an impact-resistant chlorinated polyvinyl chloride composite material and a preparation method thereof, and belongs to the technical field of polymer composite materials. The composite material comprises the following components: 100 parts of CPVC resin, 6.5 to 9.5 parts of a modified impact modifier, 2.6 to 3.2 parts of a heat stabilizer, 1.5 to 2 parts of a lubricant, 1.2 to 1.6 parts of a processing aid, 0.2 to 0.25 part of a light stabilizer and 8 to 11 parts of a filler, the modified impact modifier takes a POSS cage structure as a core, a branch chain sequentially contains thioamide-secondary amine-tertiary amine structures, a polarity gradient is formed and fully extends into a macromolecular chain of CPVC to transmit and dissipate impact energy, meanwhile, the amine structure interacts with chlorine groups in a molecular chain of CPVC to form molecular anchoring, expansion of crazes is inhibited, and the impact strength of the CPVC is improved. The continuity and the stability of a bonding interface are maintained, so that the composite material keeps relatively high mechanical strength and thermal stability.

The invention relates to the field of electromagnetic functional composite materials, and particularly discloses a multi-layer composite structure flexible frequency selective surface material and a preparation method thereof. The ultra-high molecular weight polymer fiber-reinforced polymer-based composite material thin-film mechanical enhanced band-pass frequency selection array sequentially comprises an acrylic acid polyvinylidene fluoride organic polymer coating environment-resistant layer, a metal oxide organic film isolation layer, an ultra-high molecular weight polymer fiber-reinforced polymer-based composite material thin-film mechanical enhanced layer, a band-pass frequency selection layer and a packaging protection layer from top to bottom, and the band-pass frequency selection layer is a hexagonal / circular ring nested band-pass frequency selection pattern array. The packaging protection layer is formed by printing a conductive coating composed of conductive filler / polymer resin matrix, and the packaging protection layer is an ink coating. The flexible frequency selective surface material has the characteristics of light weight, high strength, salt fog / rain / ultraviolet and other severe environments, frequency selective wave transmission and multiple functions, has good gas barrier property, is beneficial to maintaining the shape of an inflatable hangar made of a skin and ensuring normal operation of radar equipment, and has good practical engineering application value.

The invention relates to the technical field of coating surface preparation, in particular to an anticoagulant coating based on novel tick-derived anticoagulant protein Qinghaenin and a preparation method of the anticoagulant coating. The functional layer of the anticoagulant coating comprises the following components: anticoagulant protein Qinghaenin or a functional peptide fragment Qinghaenin 167-192 of the anticoagulant protein Qinghaenin, wherein the amino acid sequence of the functional peptide fragment is as shown in SEQ ID NO. 2. The preparation method of the anticoagulant coating comprises the following steps: by using a polydopamine coating as a substrate layer, covalently grafting through an amido bond, immobilizing anticoagulant protein Qinghaenin capable of inhibiting FXII factor activation or a functional peptide fragment Qinghaenin 167-192 thereof on the surface of a medical polymer material, and successfully constructing a novel anticoagulant coating. Compared with an unmodified medical polymer material, the modified coating can significantly enhance the hydrophilic performance of the material and inhibit platelet adhesion and activation, finally effectively prolongs the in-vitro blood coagulation time, and shows excellent anticoagulation performance.

The invention belongs to the technical field of polymer composite materials, and particularly relates to an oil-resistant interior material. The material comprises a porous base material layer, a fluorine-containing polymer and organic silicon resin blended oil-resistant functional layer and a micro-nano structure layer with a periodic micro-bulge array, surface modified nanoparticles are distributed in the functional layer in a gradient manner, and the micro-bulge surface is covered with a perfluoropolyether / fluorinated silicon dioxide composite coating; through a synergistic effect of a low-surface-energy oleophobic interface formed through chemical bonding and curing and a micro-structure capillary lifting effect, anti-permeation barrier of high-viscosity grease is realized, and meanwhile, mechanical wear resistance and thermal stability are improved by virtue of a nano-particle enhanced cross-linked network; and continuous imprinting and an ultraviolet-thermal dual-curing process are combined to achieve high-efficiency manufacturing with zero solvent residue, and finally the interior material with long-acting oil resistance, high environmental tolerance and industrial mass production feasibility is obtained.

The invention discloses an amphiphilic chitosan and plant nanocellulose composite coating fresh-keeping material, which is prepared from the following ingredients in percentage by mass: 0.5 to 20 percent of amphiphilic chitosan, 0.1 to 5.0 percent of plant nanocellulose, 0.5 to 10.0 percent of coalescing agents, 0.1 to 3.0 percent of antioxidants and the balance deionized water. Wherein the amphiphilic chitosan is prepared from chitosan, quaternary phosphonium salt and sorbic acid. Amphipathic chitosan of the material has hydrophilic groups such as amino and carboxyl and a sorbate hydrophobic group, has hydrophilicity and hydrophobicity at the same time, and is extremely easy to combine with substances such as a coalescing agent, plant nanocellulose and an antioxidant to form a stable polymeric membrane layer, so that the mechanical property after membrane formation is remarkably improved, and the material has a good application prospect. Meanwhile, the plant nanocellulose particles can be stably coated in the polymeric membrane material layer, so that the mechanical property of the material is enhanced, and lasting and efficient antibacterial and antioxidant effects are realized. The invention further discloses a preparation method and application of the amphiphilic chitosan and plant nanocellulose composite coating fresh-keeping material.

The invention provides coal-based porous carbon for preparing a silicon-carbon negative electrode material as well as a preparation method and application of the coal-based porous carbon, coal-based porous graphite is used as a matrix carbon material, polymer resin is used as a rigid bonding and coating material, heterogeneous elements such as B, N and P are used as doping materials, a carbon nanotube is used as a flexible conductive buffer material, and the materials are dispersed in a solvent to form slurry; through atomization granulation and high-temperature carbonization, heterogeneous element doped resin hard carbon is bridged with carbon nanotubes to construct a three-dimensional rigid-flexible conductive network to cooperatively coat the surface of the porous coal-based graphite, and doped heterogeneous elements are utilized to induce chemical-physical auxiliary activation to perform micro-mesoporous precise regulation and control pore forming on an inner core and a shell. The prepared novel coal-based porous carbon is high in porous framework particle strength and reasonable in pore distribution and has a three-dimensional rigid-flexible conductive network core-shell structure. The invention aims to solve the problems of unreasonable pore distribution of porous carbon, poor matrix strength and the like in the preparation process of a novel vapor deposition silicon-carbon negative electrode material.

The invention discloses a flame-retardant ABS (Acrylonitrile Butadiene Styrene) composition as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The flame-retardant ABS composition provided by the invention comprises the following components in parts by mass: 50-80 parts of ABS resin; 8 to 12 parts of styrene-acrylonitrile copolymer; 3 to 5 parts of styrene-acrylonitrile-maleic anhydride terpolymer; 2 to 6 parts of a fluorine-containing maleimide copolymer; 5 to 15 parts of graphite nanosheet modified high rubber powder; 12 to 18 parts of brominated flame retardant; 3-7 parts of a phosphorus-based flame retardant; 0.1-1 part of a processing aid; the phosphorus-based flame retardant is prepared from the following components in parts by mass: 80 to 95 parts of diethyl phosphinate; 0.3 to 3 parts of ethyl butyl phosphinate; 0.1 to 2 parts of ethyl phosphonate; and 5 to 20 parts of melamine polyphosphate. The flame-retardant ABS composition prepared by the invention is good in flame retardant property, good in welding strength and low in cost.

The invention discloses a degradable PHA / PU composite water-based barrier coating and a coated paper product, and belongs to the field of biodegradable polymer coatings. The coating composition comprises a high proportion of polyhydroxyalkanoates as a barrier phase and a bio-based polyurethane as a toughening and heat sealing phase. The key innovation lies in that the cooperation of rigid barrier and flexible functions is realized by accurately regulating and controlling the ratio of two phases and adopting bio-based crosslinking, and the problem that the barrier property, the heat sealability and the flexibility of a traditional single material are difficult to consider at the same time is solved under the condition of low coating amount. The invention provides a full-life-cycle green packaging solution, aims to replace a polyethylene spraying film and a fluorine-containing coating, and has a remarkable application value in the field of food packaging.

The invention relates to the technical field of tunnel engineering building materials, in particular to a double-slurry synchronous grouting material based on shield silty-fine sand and a preparation method of the double-slurry synchronous grouting material based on shield silty-fine sand. The liquid A is prepared from, by weight, 20%-30% of cement, 30%-50% of shield silty-fine sand, 5%-10% of bentonite, 5%-15% of mineral admixture, 0.1%-0.5% of stabilizer and 20%-30% of water, and the stabilizer is a water-soluble high-molecular polymer; the solution B is a water glass solution, and the volume ratio of the solution A to the solution B is (10-15): 1; the double-slurry synchronous grouting material further comprises a retarder and a coagulant, the retarder is citric acid, and the coagulant is a nano Ca (OH) 2 crystal nucleus. Bidirectional and gradient regulation and control of the gelation time between 5s and 100s can be realized through the coagulant and the retarder, and diversified requirements of different geological conditions and construction progress on slurry operation time are met.

The invention discloses a PHA-acrylic acid structural unit water-based dispersion based on interface engineering regulation and control, a preparation method thereof and application of a paper-based barrier coating, and belongs to the technical field of high polymer materials, interface engineering and water-based coatings. The stable interface layer is constructed in situ between the crystalline PHA and the acrylic resin through the amphiphilic polymer, so that the problems of poor compatibility and film forming defects of a bio-based material are effectively solved. The dispersion can realize excellent waterproof, oil-proof and gas barrier effects by only needing a relatively low coating weight, and the material consumption is remarkably reduced. The unique gradient structure of the coating has excellent mechanical adhesive force and efficient re-pulping and recycling characteristics, and the technical defect that a traditional barrier coating is difficult to recycle is overcome. And an ideal solution with high performance and high safety is provided for green packaging.

The invention relates to a phosphorus-free zinc-free seawater special-purpose scale and corrosion inhibitor, which comprises, by weight, 20-25% of sulfonic acid modified polyaspartic acid, 8-12% of quaternized chitosan, 5-10% of a sulfonate copolymer, 5-10% of polyepoxysuccinic acid, 1-3% of benzotriazole or methyl benzotriazole, 0.5-1% of sodium tungstate, and the balance of deionized water. According to the formula, traditional corrosion inhibitors such as phosphorus and zinc are completely abandoned, functions are achieved through natural polymer derivatives such as sulfonic acid modified polyaspartic acid and quaternized chitosan, and the scale and corrosion inhibitor has the following environmental protection advantages that the scale and corrosion inhibitor does not contain phosphorus and zinc elements at all, and water eutrophication and heavy metal accumulation caused by a traditional phosphorus and zinc formula are avoided.