The invention discloses a
solid electrolyte with high
ionic conductivity, which comprises the following components: a matrix material: a
halide super
ion conductor with a LiMXCl4 structure, M being selected from at least one of Ta, Nb and Hf, X being O or F, a chemical general formula being LiM1-aX1-6Cl4, a being equal to 0.1-0.3, and an
electrochemical window being regulated to 2.5-4.0 V through
fluorine-
chlorine mixed anion substitution; the second phase material is a core-shell structure compound, the core is Li3TiCl6, and the shell is a Li3PS4
interface layer; and the
sintering aid is a compound of Li3BO3 and LiF. Through
fluorine-
chlorine mixed anion regulation and control and MO2Cl4
octahedron synergistic tilting mechanism, the
ionic conductivity of the
solid electrolyte is remarkably improved, the
lithium ion conductivity at
room temperature is greater than or equal to 10mS / cm, the
activation energy is less than or equal to 0.2 eV and is superior to that of the traditional
halide electrolyte, and meanwhile, the free volume between chains is optimized through Zr < 4 + > / Sn < 2 + > gradient
doping, so that the performance of the
solid electrolyte is improved. The core-shell structure compound and the
silane coupling agent are combined for modification, so that the
electrochemical window is effectively widened to 2.5-4.0 V, the interface
side reaction is inhibited, and the
composite material is adaptive to a high-
voltage positive
electrode material.