2159results about "Hybrid capacitor electrodes" patented technology

The invention discloses a preparation method and application of three-dimensional intercalation multidirectional conductive MXene-based aerogel, and relates to the technical field of advanced electrochemical energy storage materials and devices. According to the MXene / conductive polymer and nanofiber composite aerogel developed by the invention, the two-dimensional conductive material, the pseudocapacitance polymer and the high-performance nanofiber are integrated in a three-in-one manner, so that collaborative optimization of conductivity, the number of active sites and structural stability is realized, and inherent defects of a single-component material are fundamentally avoided; and a universal solution is provided for solving the industrial problem of unbalanced performance of the electrode material.

A nanocomposite electrode and a supercapacitor device including said nanocomposite electrode. The nanocomposite electrode includes a mixture of at least one binding compound, at least one conductive additive, and at least one molybdenum doped carbon material coated onto a substrate. The supercapacitor device includes two nanocomposite electrodes disposed facing one another, wherein the substrate of each nanocomposite electrode is coated with the mixture on an inside facing surface and the outer surfaces of the nanocomposite electrodes are not coated with the mixture, and the inside facing surfaces are separated by at least one electrolyte.

To provide a positive electrode active material with high capacity and good cycle characteristics.SOLUTION: A positive electrode active material exhibits minimal change in crystal structure between the charged and discharged states. For example, a positive electrode active material that has a layered rock-salt crystal structure in the discharged state and a pseudo-spinel crystal structure in the charged state at a high voltage of about 4.6 V exhibits less change in crystal structure and volume between charge and discharge than known positive electrode active materials. When this pseudo-spinel crystal structure is present, diffraction peaks appear at 2θ=19.30±0.20° and 2θ=45.55±0.10° when analyzed by XRD.SELECTED DRAWING: Figure 1

The invention discloses a lithium ion capacitor negative electrode based on an MXene carbon nanotube composite material and a preparation method thereof, and the main points of the technical scheme are that the lithium ion capacitor negative electrode based on the MXene carbon nanotube composite material is composed of an MXene sheet layer, a hydroxyl modified carbon nanotube and a binder; the MXene sheet layer is Ti3C2Tx, the interlayer spacing is 1.0-1.3 nm after the MXene sheet layer is etched by hydrofluoric acid, and the content of-OH functional groups on the surface accounts for 40-60% of the total functional groups; the diameter of the hydroxyl-modified carbon nanotube is 10 to 30 nm, the length of the hydroxyl-modified carbon nanotube is 500 to 2000 nm, and the hydroxyl modification degree of the hydroxyl-modified carbon nanotube is 2.5 to 4.0 mmol / g; the mass ratio of the MXene sheet layer to the hydroxyl modified carbon nanotube is 7: 3-8: 2, and the MXene sheet layer and the hydroxyl modified carbon nanotube are combined through hydrogen bonds to form a layered porous structure.

The invention belongs to the field of electrochemical energy storage material and device manufacturing, and particularly relates to a method for preparing super-capacitor carbon through ultrasonic atomization, the super-capacitor carbon and a super-capacitor electrode. The method comprises the following steps: preparing a carbonized material, a bridging conductive agent and a composite binder into slurry, performing ultrasonic atomization to form spherical liquid drops, and performing drying, pre-activation and CO2 etching to prepare the supercapacitor carbon with an integrated three-dimensional network. Through a synergistic process of spherical template construction-networked reconstruction-etching modification, controllable transformation of a material structure is realized, and the tap density, a pore channel system and a conductive network of the electrode are optimized, so that the electrode with high specific capacity, excellent rate capability and cycling stability is obtained, and the process is environment-friendly and coherent and is suitable for large-scale production.

The invention relates to the technical field of preparation of porous carbon materials, in particular to a carbon material with an ultrahigh specific surface area and a preparation method and application thereof, and the preparation method comprises the following steps: ball-milling and mixing a carbon precursor and a chemical activator to obtain a homogeneous mixture; synchronously carbonizing and activating the homogeneous mixture to obtain a carbonized compound; washing and drying the carbonized compound to obtain a carbon material with an ultrahigh specific surface area; the carbon precursor is waste phenolic resin. The waste phenolic resin is efficiently converted into the high-specific-surface-area porous carbon material (super activated carbon) through ball-milling-assisted homogenization and a synchronous carbonization / activation process, and the method has remarkable advantages in the aspects of environmental protection, process efficiency, material performance, application value and the like, not only solves the problem of thermosetting resin recovery, but also improves the recovery efficiency of the thermosetting resin. And the waste resin is converted into a high-added-value carbon material, so that the development of circular economy is promoted, and the dual-carbon strategic target is met.

A system and methods for manufacturing a dry electrode for an energy storage device are disclosed. The system includes a first dry electrode material delivery system configured to deliver a dry electrode material, a first calendering roll, a second calendering roll, and a controller. The second calendering roll is configured to form a first nip between the first calendering roll and the second calendering roll. The first nip is configured to receive the dry electrode material from the first dry electrode material delivery system, and form a dry electrode film from the dry electrode material. The controller is configured to control a rotational velocity of the second calendering roll to be greater than a rotational velocity of the first calendering roll. The method may include providing a multi-roll calender system comprising a first calender roll, a second calender roll; rotating the first calendering roll at a first rotational velocity; rotating the second calendering roll at a second rotational velocity; providing a first dry electrode material to a first nip between the first calendering roll and the second calendering roll to form a dry electrode film. The second rotational velocity may be greater than the first rotational velocity.

The invention discloses a method for preparing mesoporous Bi2O3 through block polymer micelle induced self-assembly and application, and relates to the field of supercapacitor electrode materials. The method comprises the following steps: dissolving P123 in a solvent, adding an acidic reagent, then adding Bi (NO3) 3.5 H2O or BiCl3, and uniformly stirring to form a mixed solution; preparing KOH into a KOH solution, adding the KOH solution into the mixed solution, stirring, and standing to obtain the mesoporous Bi2O3. Mesoporous Bi2O3 is synthesized by adopting a micelle-induced self-assembly method, the microtopography and particle size of the mesoporous Bi2O3 can be regulated and controlled, the mesoporous structure enables the Bi2O3 material to have higher specific surface area and porosity, more active sites are exposed, the stability and electrochemical performance of the Bi2O3 electrode material are improved, and the preparation method is suitable for industrial production. The problems of poor conductivity and poor cycling stability are solved.

The invention discloses a fluidized bed reactor for preparing porous carbon through collaborative graded activation of water vapor and CO2 and a method for preparing the porous carbon through collaborative graded activation of the water vapor and the CO2, and belongs to the technical field of material chemical engineering. The fluidized bed reactor is composed of a shell, a fluidization section, a sedimentation section, a porous distribution plate, a gas distribution chamber, a stirring device and a temperature control system, and uniform fluidization and multi-section temperature control of superfine powder are achieved. According to the activation method, steam and CO2 collaborative graded etching pore-forming is adopted, specifically, in the first stage, quick pore-forming is conducted mainly through steam at the temperature of 500-800 DEG C, in the second stage, pore-expanding is conducted cooperatively through steam and CO at the temperature of 700-900 DEG C, and in the third stage, fine control is conducted mainly through CO2 at the temperature of 850-1050 DEG C; the continuous preparation of the high-performance porous carbon with the specific surface area of 1500-2500m < 2 > / g, the pore volume of more than or equal to 0.8 cm < 3 > / g and the 2-10nm mesopores accounting for 20-60% is realized by adjusting the gas velocity, the activation temperature, the activation time and the ratio of water vapor to CO2, the bottlenecks of low specific surface area, single pore diameter, large batch difference and the like of physical activation are solved, and the method is suitable for green and low-cost production of high-end energy storage carbon materials such as supercapacitors, lithium / sodium ion batteries and the like.

Disclosed herein are methods for producing electrodes comprising single-layer 1T′-transition metal dichalcogenide (TMD) nanosheets. The method includes filtering a suspension of single-layer 1T′-TMD nanosheets over a polymeric substrate to produce the electrode, wherein, the single-layer 1T′-TMD nanosheets of the electrode are no more than 1,000 nm in thickness; the electrode comprises at least 70% 1T′-phase; and the electrode has a calculated electrochemical active surface area (ECSA) that is about 10-fold higher than that of a control electrode, which comprises 2H-TMD nanosheets. Also disclosed herein are methods for deionizing a fluid. The method includes steps of discharging the fluid in an electrochemical capacitor at a constant voltage of no more than 0.5 V to deionize the fluid, wherein the electrochemical capacitor is characterized in having the electrode comprising single-layer 1T′-TMD nanosheets produced by the present method.

A moisture electric generating device comprising: a first electrode and a second electrode; and disposed between the first electrode and the second electrode and a functional layer which releases electrical charge carriers; the functional layer includes at least two sub layers; a first sub layer acting as a moisture reservoir to a second sublayer, to provide moisture to the second sublayer; the second sub layer which produces electrical charge carriers as a function of moisture available from the first sub layer.

Method for creating an electrode on a substrate using a laser assisted deposition process. A metal paste is printed and dried on the substrate to form a conductive layer, and by 2D or 3D inspection, the dimensions of the conductive layer are measured. The substrate is subject to a pretreatment process so as to increase adhesion and / or conduction of the conductive layer to the substrate. An electrode that is produced according to the present method may be used in flexible devices.

A system and methods for manufacturing a dry electrode for an energy storage device are disclosed. The system includes a first dry electrode material delivery system configured to deliver a dry electrode material, a first calendering roll, a second calendering roll, and a controller. The second calendering roll is configured to form a first nip between the first calendering roll and the second calendering roll. The first nip is configured to receive the dry electrode material from the first dry electrode material delivery system, and form a dry electrode film from the dry electrode material. The controller is configured to control a rotational velocity of the second calendering roll to be greater than a rotational velocity of the first calendering roll. 62385256

The embodiment of the invention provides a self-supporting integrated composite electrode and a preparation method thereof, and the self-supporting integrated composite electrode comprises a supporting layer which comprises a conductive carbon skeleton and a three-dimensional porous carbon network structure which is integrally molded with the conductive carbon skeleton; the active layers are uniformly distributed in internal pores of the three-dimensional porous carbon network structure and the surface of the conductive carbon skeleton; and a coating layer, wherein the coating layer covers the active layer and the three-dimensional porous carbon network structure. According to the self-supporting integrated composite electrode and the preparation method thereof provided by the embodiment of the invention, by constructing the self-supporting integrated composite electrode structure, the core problems of high internal resistance of a binder, weight increment of a current collector, interface stripping, complex preparation process and the like in a traditional electrode are effectively solved.

Provided are a carbon sheet having excellent performance in terms of inhibiting lithium dendrite growth and a method of producing this carbon sheet. Also provided are a laminate and an electrical storage device that include a carbon sheet having excellent performance in terms of inhibiting lithium dendrite growth. The carbon sheet is a carbon sheet containing carbon nanotubes, wherein the carbon nanotubes and the carbon sheet each have pores, and the distribution states of these pores satisfy specific requirements.

To provide a novel positive electrode active material, a positive electrode, and a lithium ion secondary battery.SOLUTION: A lithium ion secondary battery includes a positive electrode, a negative electrode, and an electrolyte. The positive electrode includes a positive electrode active material including a complex oxide containing lithium and cobalt. The positive electrode active material contains barium, magnesium, and aluminum in a surface layer part. In the analysis of the surface layer part, it is preferable to include a region where a first point at which the concentration of barium is the maximum and a second point at which the concentration of magnesium is the maximum exist on a surface side of the positive electrode active material relative to a third point at which the concentration of aluminum is the maximum.SELECTED DRAWING: Figure 3

The invention relates to the technical field of supercapacitors, and particularly discloses a spherical hollow multi-layer high-entropy metal oxide and a preparation method and application thereof. The spherical hollow multi-layer high-entropy metal oxide is prepared by the following steps: cross-linking metal cation nitrate comprising iron nitrate nonahydrate, zinc nitrate hexahydrate, copper nitrate hexahydrate, cobalt nitrate hexahydrate and nickel nitrate hexahydrate with dextrose monohydrate to generate spherical high-entropy metal hydroxide FeZnCuCoNi-HO with a solid core structure, and annealing to induce the metal hydroxide. And the spherical hollow multi-layer high-entropy metal oxide is formed. Compared with the prior art, the high-entropy metal oxide is prepared through a low-energy-consumption and simple synthesis method, the problem of volume change of the high-entropy metal oxide serving as an electrode material in the circulation process is solved, more reaction active sites are provided, an ion diffusion path is improved, and the specific capacitance of the composite material is improved while the specific capacitance of the composite material is improved. And the stability of the material is maintained, so that the energy storage performance of the supercapacitor is improved.

The invention provides an anisotropic ion transmission supercapacitor based on topological insulator electrolyte. Relates to the technical field of energy storage devices, and comprises an electrolyte module, the electrolyte module comprises an electrolyte, the electrolyte is a network formed by Bi2Se3 nanowires, and the Bi2Se3 nanowires form an anisotropic ion transport channel through a surface modification method of sodium dodecyl benzene sulfonate and vertical orientation arrangement. According to the anisotropic ion transmission supercapacitor based on the topological insulator electrolyte, an electrolyte module with anisotropic ion transmission characteristics is formed by adopting a network formed by topological insulator electrolyte Bi2Se3 nanowires and a surface modification technology. The electrode performance of the electrode module is enhanced through a vertical heterojunction structure, laser reduction, plasma etching and other processes, and therefore the excellent performance of the solid-state supercapacitor in the aspects of high energy density, low-temperature stability and structural stability is achieved.

According to the prepared MXene / C electrode material based on PAN carbonization, a nitrogen-doped carbon layer generated through polyacrylonitrile (PAN) in-situ carbonization serves as a supporting spacer to be inserted between MXene nanosheet layers, the MXene nanosheet layers are tightly bridged, the interlayer spacing of MXene is effectively enlarged, re-stacking of nanosheets is inhibited, and in the carbonization process, the MXene / C electrode material can be used for preparing the MXene / C electrode material based on PAN carbonization. Abundant mesopores and fissure holes are generated in the composite material by introducing and decomposing a sacrificial template (PMMA nanosphere), and a three-dimensional through ion transmission channel is constructed; the nitrogen-doped carbon layer not only serves as a supporting spacer to be inserted between MXene nanosheet layers, but also coats the surfaces of the MXene nanosheets,-F end groups on the surfaces of the MXene nanosheets are weakened, and C-O (H) and C-N functional groups are enriched, so that the interface wettability, the conductivity and the anti-oxidation stability of the material are improved, and the material can be widely applied to the technical field of electrochemical energy storage materials.

An energy storage device according to an aspect of the present invention includes an electrode assembly in which a positive electrode including a positive active material layer and a negative electrode including a negative active material layer are stacked with each other with a separator interposed therebetween, in which the positive active material layer contains a positive active material particle, and the positive active material particle has an internal porosity of 15% or less, and the negative active material layer contains a graphite particle, and the graphite particle has an internal porosity of 2% or less.

The preparation method comprises the following steps: (1) dissolving a zinc salt in a mixed solvent of ethanol, DMF (Dimethyl Formamide), ammonia water and water, dropwise adding triazole, carrying out stirring reaction at room temperature for 5-10 hours, then carrying out aging treatment for 20-30 hours, obtaining a solid product, washing the solid product, and drying the solid product to obtain zinc-triazole MOF; (2) heating the zinc-triazole MOF to 800-850 DEG C under the protection of inert gas, calcining for 2-4 hours, cooling, washing to remove metal ions, and drying to obtain MOF-derived porous carbon; and (3) adding the MOF-derived porous carbon into an aniline hydrochloride solution, uniformly dispersing, adding an ammonium persulfate solution, stirring and reacting for 5-10 hours, and washing and drying a product to obtain the MOF-derived porous carbon composite electrode material. The MOF-derived porous carbon composite electrode material is used as a negative electrode material to prepare the supercapacitor, and the supercapacitor has very excellent electrochemical performance and cycling stability.

The invention relates to the technical field of electronic component manufacturing, solves the technical problem that interface contact resistance bounces and rises due to thermal stress mismatch, and particularly relates to an electronic component preparation parameter optimization method and system. Generating a gradient layer of which the thermal expansion coefficient continuously changes; and calculating a target thermal expansion coefficient for eliminating the interface thermal stress and an actual thermal expansion coefficient of the in-situ monitoring gradient layer based on the metal and ceramic concentration distribution function. According to the method, component continuous transition is achieved through metal / ceramic precursor dynamic flow control, continuous gradual change from metal to ceramic components is achieved, the coefficient of thermal expansion is in smooth transition in the thickness direction, and internal stress accumulation caused by material expansion difference is blocked from the source; and dynamic deposition regulation is combined to ensure that the thermal expansion gradient at any position is lower than a critical threshold value, and stripping or cracking caused by stress concentration in thermal circulation is avoided.

The invention discloses a supercapacitor with a honeycomb structure and a preparation method thereof, the supercapacitor comprises a positive current collector, a negative current collector and a honeycomb energy storage layer, and the positive current collector and the negative current collector respectively cover two opposite surfaces of the honeycomb energy storage layer; the honeycomb energy storage layer is formed by folding, stacking and fixing a plurality of composite films, each composite film comprises a first electrode layer, an electrolyte layer and a second electrode layer, and the first electrode layer, the electrolyte layer and the second electrode layer are sequentially stacked and are respectively compounded and fixed through a bonding layer. The preparation method comprises the following steps: firstly, sequentially compounding and fixing the first electrode layer, the electrolyte layer and the second electrode layer to form a composite membrane with a sandwich structure, coating an adhesive on the single side surface of each composite membrane at intervals, and then stacking and stretching a plurality of composite membranes to form a honeycomb core structure; after folding, a positive current collector and a negative current collector are compounded on the two sides of the honeycomb core structure. An energy storage structure and a force bearing structure are organically combined, and the energy storage performance and the mechanical performance are synergistically improved.

The invention discloses coal pitch-based super capacitor carbon and a preparation method and application thereof, and the preparation method of the super capacitor carbon comprises the steps: dissolving coal liquefaction refined pitch in an organic solvent, and adding ZnCl2, KCl and potassium citrate to obtain a pitch solution containing an ionic hot molten salt activator; the preparation method comprises the following steps: soaking a biomass template in a dopamine aqueous solution, and then mixing with an asphalt solution to obtain a biomass template-asphalt compound; and oxidizing, carbonizing, activating, washing and drying the compound to obtain the capacitor carbon. And mixing and heating the capacitor carbon, a nitrogen source and a phosphorus source, and carrying out graphitization doping. The pitch-based super capacitor carbon with high specific surface area, excellent electrochemical performance and environmental protection advantages is prepared through a biomass template method, and the preparation process has great potential in the field of energy storage.

The invention provides a method for eliminating residual alkali on the surface of a positive active material and generating a functional film-forming pre-metallization agent in situ and application thereof, and the method comprises the following steps: dissolving halogenated carboxylic acid in an organic solvent to obtain a mixed solution; mixing a positive electrode active material with the mixed solution, and reacting to obtain a positive electrode active material with a pre-metallization agent attached to the surface; wherein the pre-metallization agent is halogenated carboxylic acid metal salt, and the chemical general formula of the pre-metallization agent is Xm-R-(COOM) n; the chemical general formula of the active substance is LiNi < y > Co < z > Mn Q O < 2 > or M 'Li < x > Ni < y > Co < z > Mn Q O < 2 >; through treatment by the method, residual alkali on the surface of the positive electrode active material can be eliminated, and meanwhile, a pre-metallization agent is generated in situ on the surfaces of particles; the pre-metallization agent can be used as an alkali metal supplementing agent to improve the energy density of the electrochemical energy storage device, and MX generated by reaction with the electrolyte can be functionally formed into a film, so that the cycling stability of the electrochemical energy storage device is improved.

The invention relates to a fluoropolymer coating composition that can be used, for example, in coating electrodes and / or separators in electrochemical devices. The fluoropolymer coating composition preferably contains multiple fluoropolymer phases. The coated electrodes and / or separators have both excellent wet adhesion, excellent dry adhesion, and low leachables. Each of the fluoropolymer phases contains polymers having at least 10 weight percent, of a common fluoromonomer, making the polymer phases compatible with each other, and allowing for the phases to be distributed fairly homogeneously on a macroscopic level throughout the composition and dried coating formed from the composition.

A power storage device includes a power storage element, a case having a bottomed cylindrical shape with an opening at one end, and housing the power storage element, a sealing member sealing the opening, and a current collecting plate. The current collecting plate has a first region electrically connected to an external terminal that the sealing member or the case has, a second region joined to the power storage element, at least one first conductive part linking the first region to the second region, and at least one second conductive part linking the first region to the second region. The electrical resistance of the first conductive part is different from the electrical resistance of the second conductive part.

The invention provides a purification method and application of a coal-based hard carbon material, belongs to the technical field of lithium / sodium ion battery negative electrode materials, and overcomes the defects that according to an existing purification method, the ash content is lower than 3%, the iron content is lower than 400 ppm, and the requirements are difficult to meet. Turning over the materials and reacting for 3.8-4.2 hours in a boiling state; acidizing: mixing an acid solution, and reacting for 2-8 hours at the temperature of 60-100 DEG C; the mixed acid solution comprises hydrochloric acid with the volume concentration of 10%-30% and hydrofluoric acid with the volume concentration of 0.5%-8%; according to the high-purity coal-based hard carbon material and the preparation method thereof, purification and deep impurity removal can be cooperated, the original coal ash content higher than 8% can be reduced to lower than 1%, and the iron content of the high-purity coal-based hard carbon material is lower than 100 ppm.

The invention relates to the field of electrode materials, in particular to a preparation method of a silicon-carbon composite electrode material. The method comprises the following steps: carrying out crushing pretreatment on the silicon-containing agricultural residues, and mixing the silicon-containing agricultural residues with tetraethyl orthosilicate according to a mass ratio of (3-5): 1; raising the temperature to 200-800 DEG C at the speed of 5 DEG C / min in a nitrogen atmosphere, and performing constant-temperature pyrolysis for 30-60 minutes; in the pyrolysis process, the TEOS is decomposed to generate a SiO2 nano-template to regulate and control a pore structure, part of the SiO2 nano-template is reduced into SiO nano-particles, and a SiO (at) C core-shell structure material with microporous and mesoporous graded pores is formed in situ; the product, conductive carbon and polyvinylidene fluoride are prepared into slurry according to the ratio of (6-7): (1.5-3): (1-1.5), the slurry is coated on activated carbon cloth, and the activated carbon cloth is freeze-dried to prepare the electrode. According to the preparation method, through design of the green activating agent, synchronous silicon-based compounding, pore regulation and control and pyrolysis process optimization, the defects of the traditional technology in the aspects of environmental protection, pore regulation and control accuracy and functional compounding are effectively overcome, and the electrochemical performance of the agricultural residue-based electrode material is remarkably improved.

The invention provides multifunctional energy storage concrete, application thereof and an energy storage concrete member, and belongs to the technical field of concrete. The multifunctional energy storage concrete is prepared from the following components in parts by weight: 300 to 600 parts of ordinary Portland cement, 30 to 100 parts of mineral admixture, 300 to 700 parts of quartz sand, 5 to 60 parts of conductive material, 4 to 8 parts of admixture and 120 to 250 parts of water. The conductive material is added into the concrete, and a conductive network can be formed in the concrete material, so that the concrete has electric energy storage and conduction functions. The energy storage concrete provided by the invention can be used as a structural member for energy storage, and can also be combined with other energy technologies (such as solar energy and wireless charging) to realize integration of power generation, storage and utilization.