703 results about "Polypyrrole" patented technology

The invention belongs to the technical field of gel materials, and particularly relates to aerogel powder for polyolefin modification and a preparation method and application thereof. The preparation method of the aerogel powder comprises the following steps: (1) preparing aramid nanofiber dispersion liquid; (2) preparing a polypyrrole coated aramid nanofiber dispersion liquid; (3) mixing polyamide acid and the polypyrrole coated aramid nanofiber dispersion liquid, and then carrying out partial imidization and solvent exchange to prepare hydrogel; and (4) carrying out freeze drying, thermal imidization and crushing to obtain the aerogel powder for polyolefin modification. The aerogel powder is a porous solid material formed by forming one-dimensional composite fibers from aramid nanofibers and polypyrrole and combining the one-dimensional composite fibers with polyimide resin. The aerogel powder and polyolefin resin are compounded to obtain the polyolefin resin composite material with high strength and antistatic property, and the polyolefin resin composite material can be widely applied to the fields of pipes, plates, grouting equipment parts, grouting bags and the like.

The invention belongs to the technical field of fiber materials, and particularly relates to a modified aramid nanofiber as well as a preparation method and application thereof. The preparation method comprises the following steps: (1) preparing an aramid nanofiber dispersion liquid; (2) modifying the aramid nanofiber by using POSS; and (3) carrying out in-situ polymerization on polypyrrole on the surface of the aramid nanofiber. POSS (polyhedral oligomeric silsesquioxane) has a relatively large volume exclusion effect, the template effect of long-chain alkyl quaternary ammonium salt can be influenced by scattered adhesion of POSS on the surface of aramid nanofiber, uneven polymerization of pyrrole monomers is caused, and formation of a rough structure on the surface of the fiber is facilitated. According to the invention, the polypyrrole-coated aramid nanofiber with a coarse structure is used as a polyolefin modified material, so that the problem of low interfacial force existing in a common filler is solved, and the polyolefin resin composite material with high strength and antistatic property is obtained and can be widely applied to the fields of pipes, plates, grouting equipment parts, grouting bags and the like.

The invention discloses a preparation method of a degradable transparent conductive polymer film, and belongs to the technical field of film preparation. Preparing dispersion liquid I through graphene oxide quantum dots; preparing a dispersion liquid II from polyaniline nanofibers; dissolving pyrrole and toluenesulfonic acid in N, N-dimethylformamide to prepare a reaction solution, adding the dispersion liquid I and the dispersion liquid II, stirring, and adding ferric chloride hexahydrate to obtain a reaction solution; adjusting the pH value of the reaction solution to 1.5, and heating to obtain a polypyrrole solution; preparing cellulose acetate, polyvinyl alcohol and N, N-dimethylformamide to obtain a cellulose acetate solution; mixing the polypyrrole solution and the cellulose acetate solution, adding glutaraldehyde to obtain a mixed solution, and pouring the mixed solution into a mold to prepare a composite wet film; and putting the composite wet film into a hot-pressing forming machine for hot-pressing to generate the polymer film. The conductive polymer film prepared by the invention can be applied to the fields of supercapacitor electrode materials, electromagnetic shielding materials, flexible sensors and the like, and provides a new high-performance material choice for the development of related fields.

The invention belongs to the technical field of fuel cell electrode material preparation, and particularly relates to a carbon electrode material for a polypyrrole modified bio-based fuel cell and a preparation method of the carbon electrode material. Comprising the following steps: modifying rice hull low-temperature carbonized powder by sequentially adopting POSS (Polyhedral Oligomeric Silsesquioxane) containing unipolar functional groups and POSS containing polypolar functional groups to obtain modified low-temperature carbonized powder; and carrying out in-situ polymerization on a pyrrole monomer on the surface of the modified low-temperature carbonized powder, and carrying out high-temperature carbonization and hydrofluoric acid corrosion to obtain the polypyrrole modified bio-based fuel cell carbon electrode material. The polypolar functional group POSS not only is beneficial to the in-situ polymerization reaction of pyrrole, but also can form a continuous macromolecular chain, and a net structure is formed on the surface of the whole material. The effect of the unipolar functional group POSS is to improve the stability of the low-temperature carbonized powder in the high-temperature carbonization process, and more importantly, the unipolar functional group POSS is to provide a channel for subsequent hydrofluoric acid corrosion, etch away non-conductive substances and improve the conductivity and specific surface area of the carbon electrode material.

The invention discloses a preparation method and application of a pH-responsive controllable oil-water separation material, polyurethane sponge is used as a substrate, polypyrrole is attached to the sponge substrate through an in-situ polymerization method, a pH-responsive polymer is introduced into the sponge substrate through a soaking method, and finally the pH-responsive controllable oil-water separation material is obtained. The controllability of the material in the oil-water separation process is reflected as follows: due to the introduction of the pH responsive polymer, the surface of the material has pH responsiveness, the surface of the material has different wettability by adjusting the pH value, different types of oil-water mixtures can be controllably separated in a targeted manner, and the adsorption and desorption of oil products can be realized. Due to the introduction of polypyrrole, the material has good photo-thermal conversion capacity, the viscosity of crude oil can be effectively reduced, and the absorption rate of the crude oil can be improved. The material with pH responsiveness has wide application prospects in the fields of oil-water separation, oil product adsorption and desorption and crude oil absorption.

The invention discloses a preparation method and application of a conductive polypyrrole compound. The preparation method comprises the following steps: (1) preparing an emulsion system; (2) adding an oxidizing agent; (3) diluting and dropwise adding monomer pyrrole, and reacting for 6-24 hours; and (4) washing the product, and applying the product to preparation of the foamed conductive polyurethane foam. Comprising the following steps: 1, filtering a conductive polypyrrole compound; 2, carrying out synthesis post-treatment on the conductive polypyrrole compound; 3, effectively mixing the polypyrrole compound with a commercial polyurethane foaming component (firstly premixing with an isocyanate-containing component or a polyol-containing component, and then effectively mixing with another polyol-containing component or an isocyanate-containing component); and 4, carrying out one-time forming foaming to obtain the conductive product. The preparation method has the advantages that better dispersion can be realized by synthesizing the conductive polypyrrole compound which is microcosmically in a nano-scale dendritic shape, and the use amount of a conductive material is reduced; the foamed conductive polyurethane foam is simple and convenient to construct, can be foamed instantly, has high foaming rate, retains the original mechanical properties by more than 50%, and has good conductivity.

The invention discloses a polypyrrole / cobalt / nitrogen-doped carbon composite material with a coaxial hollow structure and a preparation method thereof, and belongs to the technical field of advanced functional composite materials. The method comprises the following steps: firstly, synthesizing a hollow polypyrrole nanotube by a soft template method; secondly, cobalt / nitrogen-doped carbon is synthesized by adopting a template guiding method; and finally, secondarily coating the outer surface of the cobalt / nitrogen-doped carbon with a polypyrrole layer by adopting an in-situ oxidative polymerization method to construct the polypyrrole / cobalt / nitrogen-doped carbon composite material with a coaxial hollow heterostructure, and the polypyrrole / cobalt / nitrogen-doped carbon composite material has a coaxial sandwich structure: the inner core is a nitrogen-doped carbon hollow tube, the middle layer is a nitrogen-doped porous carbon matrix embedded with cobalt nanoparticles, and the outer surface of the cobalt / nitrogen-doped carbon composite material is a porous carbon matrix embedded with cobalt nanoparticles. And the outer layer is a conductive polypyrrole coating layer. The preparation method provided by the invention can successfully realize in-situ confinement growth and stable combination of ZIF-67, and has the advantages of high repetition rate, high yield and simple method; by adjusting the proportion of polypyrrole in the composite material, good impedance matching and large dielectric loss can be realized, and excellent electromagnetic wave absorption performance can be obtained.

The invention relates to the technical field of high polymer materials, in particular to a high-entropy alloy modified polyvinyl alcohol / polypyrrole composite hydrogel material as well as a preparation method and application thereof. Firstly, a polypyrrole aqueous solution is prepared through chemical oxidative polymerization, and high-entropy alloy nanoparticles are synthesized through a Joule thermal technology; and then mixing a polypyrrole aqueous solution, the high-entropy alloy nanoparticles and a polyvinyl alcohol aqueous solution, and adding a cross-linking agent and a catalyst to prepare the high-entropy alloy modified polyvinyl alcohol / polypyrrole composite hydrogel material. According to the composite hydrogel, under the synergistic effect of the high-entropy alloy, the light absorption performance is remarkably improved, wide-spectrum efficient absorption of ultraviolet rays, visible light and near-infrared light in a solar spectrum is achieved, and meanwhile the mechanical strength and chemical stability of the material are enhanced. The preparation process is simple, the cost is low, and the prepared composite hydrogel has wide application prospects in the fields of seawater desalination, wastewater treatment and the like as a solar interface evaporator.

The invention discloses a preparation method of a cellulose acetate / thermoplastic polyurethane / polypyrrole composite conductive nanofiber aerogel composite pressure sensing material. The preparation method comprises the following steps: (1) preparing a cellulose acetate and thermoplastic polyurethane spinning solution; (2) preparing a cellulose acetate / thermoplastic polyurethane composite nanofiber membrane; (3) preparing cellulose acetate / thermoplastic polyurethane short nano dispersion liquid; (4) preparing a cellulose acetate / thermoplastic polyurethane / polypyrrole polymerization solution; and (5) preparing the cellulose acetate / thermoplastic polyurethane / polypyrrole composite conductive nanofiber aerogel. According to the preparation method, a high-temperature thermal annealing process is not needed, and the prepared nanofiber composite aerogel has high conductivity, ultralow volume density, high compression deformation performance and high pressure resistance sensing sensitivity.

The invention discloses a preparation method of a broadband heat-conducting and wave-absorbing gasket and the broadband heat-conducting and wave-absorbing gasket, and relates to the technical field of wave-absorbing materials. The preparation method of the broadband heat-conducting wave-absorbing gasket comprises the following steps: S300, adding pretreated Fe-Si-Al powder into a reaction system of polypyrrole under the protection of nitrogen, and continuously stirring until polypyrrole forms a coating layer on the surface of the pretreated Fe-Si-Al powder; s400, after the reaction in the step S300 is finished, separating a reaction mixture in the step S300 to obtain polypyrrole coated Fe-Si-Al powder, and washing and drying the polypyrrole coated Fe-Si-Al powder; and S500, mixing the dried polypyrrole coated Fe-Si-Al powder with a polymer matrix material, a heat-conducting filler, a curing agent, a dispersing agent, an inhibitor and a catalyst to obtain a mixture, pressing the mixture into sheets, and curing the sheets to obtain the broadband heat-conducting wave-absorbing gasket. By the adoption of the technical scheme, the advantages of being capable of effectively absorbing electromagnetic waves in a broadband and good in heat conduction performance are achieved.

The invention belongs to the technical field of aerogel, and particularly relates to high-conductivity aerogel powder as well as a preparation method and application thereof. The preparation method comprises the following steps: firstly preparing a graphene / polypyrrole nanosheet composite material with a three-dimensional structure, and then preparing the polyimide / graphene / polypyrrole ternary hybrid conductive aerogel by taking a polyamide acid solution as a precursor through a solution dipping and freeze drying process. Polyimide is used as a framework of high-conductivity aerogel powder, excellent mechanical strength and structural integrity are provided, the common brittleness problem of a pure graphene carbon material or polypyrrole conductive polymer aerogel is solved, and the three-dimensional graphene / polypyrrole nanosheet composite material has excellent elasticity and toughness and can be used for preparing a composite material with high conductivity. The polyimide aerogel prepared by the method can be dispersed in a polyimide matrix as a nano reinforcement, can effectively transfer stress and prevent crack propagation, and endows the aerogel with higher mechanical properties.

The embodiment of the invention relates to the field of energy storage, and provides a secondary battery and a preparation method thereof, an energy storage system and electric equipment. The negative electrode active material comprises a silicon-based material, honeycomb porous graphite and a polypyrrole layer, the surface of the honeycomb porous graphite is coated with the polypyrrole layer, the silicon-based material is embedded in pores of the honeycomb porous graphite, and the silicon-based material comprises silicon particles, a poly N-isopropylacrylamide layer and a disulfide bond-containing polyaniline layer. The poly (N-isopropylacrylamide) layer and the disulfide bond-containing polyaniline layer are coated on the surfaces of the silicon particles, the poly (N-isopropylacrylamide) layer is positioned between the silicon particles and the disulfide bond-containing polyaniline layer, and the honeycomb porous graphite comprises a graphite flake and a carbon layer which is positioned on the surface of the graphite flake and is of a honeycomb pore structure. The secondary battery formed by assembling the negative electrode active material disclosed by the invention has relatively high cycling stability, high temperature resistance, rate capability, gram volume and safety.

The invention is suitable for the technical field of photocatalyst preparation, and provides a modified tubular g-C3N4 loaded Ni-CoP photocatalyst and a preparation method thereof. The preparation method comprises the following steps: calcining a carbon nitride precursor in stages to obtain tubular carbon nitride, stirring the tubular carbon nitride with a cobalt and nickel-containing compound and an alkaline compound, washing and drying to obtain a precipitate, calcining, mixing and grinding with a phosphorus-containing compound, calcining again, and modifying the product with polydopamine and polypyrrole to obtain the composite material. The photocatalyst modified by the polydopamine and the polypyrrole and loaded with the Ni-CoP by taking the tubular g-C3N4 as the carrier is obtained. According to the invention, three-in-one synergistic integration of'carrier-modifier-cocatalyst 'is realized, the prepared photocatalyst still keeps tubular morphology and has a larger specific surface area, the requirements of anode oxygen evolution reaction (OER) on rapid charge separation and transmission can be met, meanwhile, the light absorption range is widened, the solar energy utilization rate is increased, and a foundation is laid for efficient OER reaction.

The invention relates to the technical field of functional composite probe material preparation, in particular to a three-core spinning technology-based bio-compatible gel probe and a preparation method thereof, and the three-core spinning technology-based bio-compatible gel probe comprises a composite skin layer and three functional core layers; the composite skin layer is composed of a sodium alginate-polydopamine-chitosan grafted copolymer in a mass ratio of 2: 1: 0.5, and contains # imgabs 0 # chondroitin sulfate and # imgabs 1 # polyoxyethylene; the three core layers are respectively a carbon nanotube-polyaniline # imgabs2 # hybrid material, a graphene-polypyrrole-boron nitride hybrid material and a # imgabs3 # polythiophene-hydroxyapatite hybrid material, and the mass ratio of the carbon material to the conductive polymer to the newly added nano material in each core layer is 1: 2: 0.3; and the diameter ratio of the skin layer to the three core layers is 1: 0.28: 0.22: 0.17. According to the invention, multichannel signal transmission is realized, the impedance is reduced by the hybrid material, and the conductivity is improved; the composite skin layer is matched with soft tissue mechanical properties, and interface bonding is stable; and the biocompatible component reduces inflammation, is suitable for acquiring nerve electrophysiological signals, and is easy for large-scale production.

The invention belongs to the technical field of conductive polymer materials, and particularly relates to a three-dimensional polypyrrole conductive material and a preparation method and application thereof. The preparation method of the three-dimensional polypyrrole conductive material comprises the following steps: (1) preparing a metal copper quantum dot and graphene oxide mixed dispersion liquid; (2) adding an oxidizing agent to obtain a reaction solution; (3) adding a pyrrole monomer, and carrying out a polymerization reaction to obtain a graphene oxide / polypyrrole composite dispersion liquid; and (4) adding a reducing agent to reduce the graphene oxide to obtain the three-dimensional polypyrrole conductive material. After the metal copper quantum dots are loaded on the graphene oxide sheet layer, the graphene oxide sheet layer becomes a structure-oriented core in subsequent polymerization, and finally the stable three-dimensional conductive composite material with graphene as a framework and polypyrrole nanosheets as connection points is formed. Compared with a traditional three-dimensional material formed by overlapping and integrating a two-dimensional graphene sheet layer and a conductive nanowire / nanorod, the three-dimensional material with the structure can form an efficient conductive path more easily under the condition of low filler content.

The invention discloses a preparation method of an electrochemical biosensor based on neuraminidase, and relates to the field of electrochemical sensors. The method comprises the following steps: preparing N-Gr / MWCNTs, preparing N-Gr / MWCNTs (at) GCE, preparing Ppy / N-Gr / MWCNTs (at) GCE, and preparing NA / Ppy / N-Gr / MWCNTs (at) GCE. According to the electrochemical biosensor based on neuraminidase, MWCNTs and N-Gr are compounded to form an N-Gr / MWCNTs composite material, high-conductivity polypyrrole is polymerized on the N-Gr / MWCNTs composite material through pyrrole, the biosensor without a mediator is prepared, electrons can be directly transmitted between an electrode and a bioactive substance, and the electrochemical biosensor can be used for detecting neuraminidase. The response performance of the sensor is obviously improved; the electrochemical biosensor is based on the NA inhibition principle, is mainly used for rapidly screening antiviral components in traditional Chinese medicines, can realize rapid screening and evaluation of the antiviral components in the traditional Chinese medicines, belongs to a convenient, efficient and low-cost means, and also provides scientific basis and technical support for discovery and evaluation of active components.

The invention belongs to the technical field of solar-driven interface evaporation, and particularly relates to a solar-driven interface evaporation aerogel material based on gradient modification and a preparation method and application thereof. The preparation method specifically comprises the following steps: performing cross-linking reaction on chitosan and a cross-linking agent in an organic acid aqueous solution, and performing freeze drying to obtain a chitosan matrix with a three-dimensional network structure; a pyrrole monomer is uniformly dispersed in a network structure of a chitosan matrix, then the chitosan matrix is immersed in an ammonium persulfate solution, and by controlling the oxidative polymerization degree of ammonium persulfate to the pyrrole monomer, concentration gradient distribution gradually decreasing from the surface to the inside of polypyrrole is formed in the chitosan matrix, so that the polypyrrole / chitosan composite material is obtained. The solar-driven interface evaporation aerogel material based on gradient modification is obtained. The aerogel material provided by the invention combines a photothermal effect with interface evaporation, and achieves the purpose of reasonably and efficiently utilizing solar energy resources to carry out seawater desalination.

The invention provides a flexible electrochemical sensor, a preparation method and application. The flexible electrochemical sensor comprises a flexible substrate, three electrodes, a conductive strip, an external wire and a multi-cavity polypyrrole film, the three electrodes comprise a working electrode, a reference electrode and an auxiliary electrode and are printed on the flexible substrate; the conductive strip is connected with the three electrodes, the conductive strip is packaged through an insulating tape, and only working areas of the three electrodes are exposed; the external wire is pasted on the conductive strip through conductive silver adhesive. The multi-cavity polypyrrole film is modified on the surface of the working electrode. The technical problems that existing equipment is insufficient in portability, cannot meet the requirements of on-site rapid screening and real-time analysis of large-batch samples, and is difficult to realize on-site mobile detection are solved. The invention provides a feasible technical means for portable, mobile and on-site rapid detection of high-harm heavy metal ions such as Hg < 2 + > and Cd < 2 + >, and the method is simple to operate and extremely low in cost.

The invention discloses an anti-ultraviolet automobile window film and a preparation method thereof, and relates to the field of high polymer materials. When the anti-ultraviolet automobile window film is prepared, methylcyclotetrasiloxane, octamethylcyclotetrasiloxane, 3-glycidyl propyl (dimethoxy) methylsilane and 1, 3-bis (3-aminopropyl)-1, 1, 3, 3-tetramethyldisiloxane are subjected to a reaction, and modified polysiloxane is prepared; the preparation method comprises the following steps: reacting benzo [1, 2-d: 5, 4-d '] bis (oxazole)-2, 6-dithiol with 4-aminobenzoyl chloride to prepare a modified ultraviolet absorbent; isophorone diisocyanate, polytetrahydrofuran ether glycol, the modified polypyrrole particles, the modified polysiloxane and the modified ultraviolet absorbent are subjected to a reaction, and the reaction product is spread in a mold. The anti-ultraviolet automobile window film prepared by the invention has good anti-ultraviolet, heat-insulating, flame-retardant and anti-aging properties and good mechanical properties.

The invention provides a positive pole piece, a preparation method thereof and a lithium ion battery. The positive pole piece comprises a current collector, a positive active layer located on the surface of one side of the current collector and a coating layer located on the surface, away from the current collector, of the positive active layer; wherein the material of the coating layer comprises a titanium dioxide nanotube material coated with polypyrrole. Under the synergistic effect of all structures in the polypyrrole-coated titanium dioxide nanotube material in the coating layer, the positive pole piece can improve the loading capacity and the compaction density of the active material, and further improve the stability and the safety performance of the lithium ion battery in complex environments such as a high-heat environment and an overcharge condition at the same time. Meanwhile, due to the existence of the coating layer, the wettability of the positive pole piece with high loading capacity and high compaction density can be improved, the internal resistance of the battery is reduced, and the polarization phenomenon in the charging and discharging process of the battery is relieved. The prepared lithium ion battery not only has relatively high energy density and cycling stability, but also has good safety performance.

The invention relates to the technical field of conductive film substrate materials, in particular to a preparation method and application of a super-flexible stretchable conductive film substrate material. In order to solve the problems that an existing flexible conductive film is prone to fracture in the stretching process, a conductive layer is prone to stripping, and the conductive performance is seriously attenuated along with deformation, the invention provides a composite polyrotaxane enhanced matrix film which is capable of meeting the ultra-flexible and stretchable requirements. And an MXene-silver nanowire-polypyrrole ternary synergistic conductive network is combined, so that the problem that the conductivity is sharply attenuated in the deformation process is solved.

The application provides an octadecane-loaded cellulose-based composite phase change material evaporator and a preparation method and application thereof in seawater desalination, and belongs to the fields of photo-thermal conversion materials and separation technologies. Nanocellulose and polyvinyl alcohol are mixed to prepare an aerogel, octadecane is encapsulated in the pores of the aerogel by a vacuum impregnation method to obtain a composite phase change material aerogel, and the composite phase change material aerogel is coated with a non-woven fabric loaded with polypyrrole to obtain the octadecane-loaded cellulose-based composite phase change material evaporator. The evaporator is a composite phase change material evaporator based on the coupling of interfacial evaporation and phase change energy storage, solves the problems of discontinuous evaporation and low solar energy utilization rate caused by day and night alternation, has excellent light absorption performance, good heat insulation performance and sufficient water supply and the like, can be used for seawater desalination, and has the advantages of high evaporation rate, high energy conversion efficiency, salt precipitation prevention and the like.

A nitrogen-doped graphitized carbon material and a preparation method thereof are provided. The preparation method includes the following steps: adding graphitized carbon, pyrrole, concentrated hydrochloric acid and a non-noble metal ion compound into water sequentially in that order and mixing uniformly to obtain a mixture, and finally adding an ammonium persulfate solution into the mixture to prepare polypyrrole-coated graphitized carbon, and performing high-temperature annealing treatment and washing on the polypyrrole-coated graphitized carbon to prepare the nitrogen-doped graphitized carbon material. The prepared nitrogen-doped graphitized carbon material includes a coating layer and a substrate, the coating layer is coated on a surface of the substrate, the coating layer is epitaxially grown graphitized nitrogen-doped carbon, and the substrate is graphitized carbon. The substrate and the coating layer of the nitrogen-doped graphitized carbon material have higher graphitization degree as a whole, and the stability of the carbon material is improved.

The application discloses a carbon nitride / carbon felt electrode for a vanadium redox flow battery and a preparation method thereof, and belongs to the technical field of battery materials. The preparation method comprises the following steps: (1) soaking carbon felt in an ethanol solution containing an iron salt compound and then drying; (2) suspending the dried carbon felt in a closed container, adding a pyrrole monomer, and reacting at a constant temperature under an inert atmosphere to obtain a polypyrrole / carbon felt, which is cleaned and dried; (3) soaking the polypyrrole / carbon felt in an ethanol solution containing a zinc salt compound and then drying; (4) gradually increasing the temperature of the dried polypyrrole / carbon felt under an inert atmosphere to perform high-temperature carbonization, and obtaining carbon nitride / carbon felt; and (5) performing pickling and water washing on the carbon nitride / carbon felt, and obtaining the carbon nitride / carbon felt electrode after drying. In the application, the iron salt is used to catalyze the polymerization and deposition of pyrrole on the surface of the carbon felt, and finally high-temperature carbonization is performed to form various nitrogen-doped structures on the surface of the carbon felt, so that the liquid affinity and the electrochemical reaction activity of the electrode surface are significantly improved, and the energy efficiency of the battery is improved.

The invention discloses a preparation method and a test method of In2O3-rGO-PPy aerogel for rapidly detecting hydrogen at room temperature. The preparation method comprises the following specific steps: mixing CO (NH2) 2, In (NO3) 3.4. 5H2O and NH4F, reacting in a reaction kettle, washing and purifying after the reaction is completed, and annealing at 400 DEG C for 1-2 hours to prepare indium oxide (In2O3) nanoparticles; the preparation method comprises the following steps: preparing methyl orange, FeCl3. 6H2O and pyrrole into a mixed solution, standing to obtain a product, washing and purifying, and finally freeze-drying to obtain a polypyrrole (PPy) tube; the preparation method comprises the following steps: dissolving graphene oxide, polypyrrole and indium oxide in deionized water, carrying out ultrasonic treatment in an ice bath, carrying out a hydrothermal reaction to obtain composite hydrogel, washing and purifying the composite hydrogel, and finally carrying out freeze drying to obtain the three-dimensional In2O3-rGO-PPy aerogel. The innovative overall testing method is used for testing the sensor, a metal sheet and a wire are connected to the two ends of aerogel, the aerogel is integrally placed in a gas chamber, the introduction amount of hydrogen and air is controlled, a hydrogen environment with a certain concentration is kept, and the sensor is tested under the condition.

The invention discloses a low-temperature-resistant lithium iron phosphate positive electrode material and a preparation method thereof. The low-temperature-resistant lithium iron phosphate positive electrode material comprises the following raw material components in parts by weight: 90-120 parts of a lithium iron phosphate active material, 10-15 parts of a conductive agent, 8-12 parts of a binder, 5-8 parts of an additive and 60-70 parts of a solvent, the lithium iron phosphate active material is lithium iron phosphate coated with a carbon layer on the surface, and at least one metal element of aluminum, magnesium, chromium, vanadium and cobalt is doped in the lithium iron phosphate active material. The additive comprises nitrogen-doped carbon fibers compounded with titanium dioxide and titanium dioxide fibers coated with a polypyrrole layer; wherein the titanium dioxide fiber coated with the polypyrrole layer is obtained by firstly loading a first pyrrole monomer on a porous titanium dioxide fiber and then polymerizing with a second pyrrole monomer. The low-temperature-resistant lithium iron phosphate positive electrode material disclosed by the invention has excellent low-temperature resistance and conductivity, and the electrochemical performance of a battery at a low temperature can be improved.

The invention relates to the technical field of papermaking, in particular to a preparation method of high-definition electronic screen protection paper. According to the method, regenerated cellulose fibers serve as main raw materials, functional composite fibers of a core-shell structure are constructed, a core layer is the regenerated cellulose fibers, a shell layer is a polypyrrole / graphene composite conductive layer, and the lasting antistatic performance is achieved; meanwhile, the surface-modified nano silicon dioxide aerogel particles are introduced, so that the optical performance and the mechanical strength are improved; then compounding with polyimide fibers modified by a silane coupling agent, adding a bio-based wet strength agent and a fluorocarbon defoaming agent, and carrying out the steps of plasma pretreatment, pulping, on-net papermaking, controllable drying, magnetron sputtering surface treatment and the like to prepare the protective paper. The obtained protective paper has the characteristics of being ultrathin, high in strength, high in light transmittance, lasting in antistatic property and the like, and is suitable for protection of high-end liquid crystal display screens and OLED screens.

The invention belongs to the technical field of medical wound materials, and relates to conductive nanofiber aerogel for preventing and treating stress injury and a preparation method thereof. The conductive nanofiber aerogel comprises nanofiber aerogel, a polypyrrole conductive network and a polydopamine hydrophilic layer, wherein the polypyrrole conductive network and the polydopamine hydrophilic layer are deposited in the nanofiber aerogel; the nanofiber aerogel is composed of nanofibers containing a first methylacryloylated polymer and polylactic acid and a second methylacryloylated polymer, the nanofibers are in staggered lap joint to form a three-dimensional skeleton, and the lap joint is wrapped by the second methylacryloylated polymer. The preparation method comprises the following steps: preparing nanofiber aerogel, and sequentially infiltrating the nanofiber aerogel into a pyrrole / FeCl3. 6H2O solution and a dopamine hydrochloride / Tris-HCl solution to react. The conductive nanofiber aerogel has good structural stability, biological safety, hydrophilic imbibition and pressure / seepage sensing capability, and can play an efficient role in prevention and treatment of pressure injury.

The invention discloses a 0.1 mu m ultra-fine filtering material as well as a preparation method and application thereof, relates to the technical field of filtering materials, and solves the problems of insufficient precision and high maintenance cost of an existing oil filtering technology. Lignocellulose is bleached after being subjected to alkali treatment, nano cellulose fibers are obtained through a high-pressure homogenization method or an enzymolysis method, and the nano cellulose fibers are dispersed in water to be subjected to ultrasonic treatment to obtain main slurry; modifying the surface of the mesoporous SiO2 by using a silane coupling agent; adding chopped aramid fibers, surface-modified mesoporous SiO2 and nano-silver into the main slurry, and uniformly mixing with stirring and ultrasonic treatment; performing vacuum filtration on the crude fiber slurry to obtain a supporting layer; performing vacuum filtration on the slurry to obtain a middle layer; performing vacuum filtration on the main slurry to obtain a surface layer, pressing the three layers together, and sequentially performing pre-freezing, freeze-drying and chemical crosslinking; carrying out hot-pressing wrinkle treatment, and then spirally winding; a polypyrrole coating is electrostatically sprayed on the surface, and then a fluorosilane oleophobic coating is subjected to vapor deposition. The device can be applied to lubricating oil filtration and has a wide application prospect.

The invention provides a lightweight flexible composite micro-energy storage module, which comprises a flexible substrate, a composite electrode layer, a solid electrolyte layer and a packaging layer, and is characterized in that the flexible substrate is made of a polyurethane-graphene composite material, the thickness of the flexible substrate is 50-200 [mu] m, and the surface of the flexible substrate is provided with a micro-crack structure; the composite electrode layer is formed by alternately stacking MXene / silicon carbon composite nanosheets and polypyrrole conductive polymers, wherein the mass ratio of MXene to silicon carbon is 3: 1 to 5: 1. According to the invention, through the mechanical interlocking design of the microcrack structure of the flexible substrate and the composite electrode layer, the interlayer binding force is significantly enhanced, and the structural integrity under dynamic bending is improved; the root-shaped ion transmission channel of the solid electrolyte layer and the vertical orientation transition layer realize electron-ion dual-channel cooperative transmission and reduce the interface impedance; the gradient hydrophobic structure of the packaging layer is matched with mechanics through chemical bonding, the sealing performance, the flexibility and the environmental tolerance are balanced, and the service life of the module is prolonged.