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2614 results about "Polypyrrole" patented technology

Polypyrrole (PPy) is a type of organic polymer formed by the polymerization of pyrrole. It is a solid with the formula H(C₄H₂NH)ₙH. Upon oxidation, polypyrrole converts to a conducting polymer.

Graphene-based nitrogen-doped hierachical-pore carbon nanosheet/sulfur composite material for cathode of lithium sulfur battery, as well as preparation method and application of graphene-based nitrogen-doped hierachical-pore carbon nanosheet/sulfur composite material

The invention discloses a graphene-based nitrogen-doped hierachical-pore carbon nanosheet / sulfur composite material for a cathode of a lithium sulfur battery, as well as a preparation method and application of the graphene-based nitrogen-doped hierachical-pore carbon nanosheet / sulfur composite material. The carbon nanosheet is a graphene-based nitrogen-doped hierachical-pore carbon nanosheet, and is prepared by the steps of growing poly-pyrrole on graphene oxide in situ, performing carbonization at high temperature, activating by using potassium hydroxide and forming pores, wherein the graphene oxide and nano-silicon dioxide serve as double templates; the thickness of the carbon nanosheet is 10 to 25 nm; the specific surface area is 800 to 1,600 m<2> / g; the pore diameter of the carbon nanosheet is distributed into the range of 0.8 to 6 nm in a concentrated way; the structure of the carbon nanosheet is a sandwich-like type which adopts graphene as the interlayer of the carbon nanosheet. The carbon nanosheet with abundant micro-pores, meso-pores and large specific surface area can load more sulfur active substances and can effectively inhibit dissolution of polysulfide. The ultrathin nanosheet, and the micro-pores and meso-pores guarantee diffusion of electrolyte and transmission of ions. According to the structure, the capacity, the cycling stability, the coulombic efficiency and the rate performance of the carbon nanosheet / sulfur composition material applied to the lithium sulfur battery are improved synergistically.
Owner:WENZHOU UNIVERSITY

Preparation method of foamed porous graphene/polypyrrole composite oil absorption material

The invention relates to a preparation method of a foamed porous graphene/polypyrrole composite oil absorption material, belonging to the technical fields of environmental protection and composite materials. The method is characterized by comprising the following steps: carrying out KH570 functionalization on graphite oxide prepared from graphite; carrying out ultrasonic treatment on the functionalized graphite oxide product to obtain a graphene oxide aqueous solution with a certain concentration, adding certain amounts of pyrrole, styrene or butyl methacrylate or lauryl methacrylate and an initiator (ammonium persulfate or potassium persulfate); carrying out thermostatic reaction in a hydrothermal reaction kettle for 10 hours, thereby obtaining a black solid; and carrying out freeze-drying on the black solid to obtain the foamed porous graphene/polypyrrole composite oil absorption material in a three-dimensional structure. The graphene/polypyrrole composite oil absorption material ina three-dimensional structure is prepared by a chemical process, so the material has hydrophobicity and large specific area of the graphene, can contain abundant oil molecules, and has high oil adsorbability. The preparation method is simple to operate, and has the advantage of mild reaction conditions.
Owner:DALIAN UNIV OF TECH

High-magnetic heavy-metal ion adsorbent carrying conductive high molecules and preparation method thereof

The invention discloses a high-magnetic heavy-metal ion adsorbent carrying conductive high molecules and a preparation method thereof. The adsorbent comprises high-magnetic microspheres carrying conductive high molecules, each of which comprises a Fe3O4 polycrystal sphere cluster, an amorphous SiO2 protective layer and a polypyrrole adsorption outer layer from inside to outside. The preparation method of the adsorbent is realized in a way that: carrying out a solvent thermal reduction reaction on soluble ferrites to obtain the Fe3O4 magnetic sphere cluster; carrying out the basic hydrolysis by using tetraethoxysilane to obtain the Fe3O4-SiO2 nuclear shell sphere cluster; and finally, carrying out the free radical polymerization reaction on the pyrrole monomers to obtain the Fe3O4-SiO2-polypyrrole functional particles. The heavy-metal ion adsorbent has the characteristics of stable property, high adsorption rate and reproducibility, has favorable adsorption and recovery properties on dichromic ions, and has the advantages of simple preparation process, low material price and no environmental pollution. Compared with the normal chemical absorbent, the product of the invention is convenient to use and achieves the effects of waste water treatment, pollution abatement and environment protection.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

Sulfur-carbon composite material with nitrogen-doped porous carbon nanofiber net-shaped structure, as well as preparation method and application of composite material

The invention belongs to the technical field of lithium sulfur batteries, specifically relates to a sulfur-carbon composite material with a nitrogen-doped porous carbon nanofiber net-shaped structure, as well as a preparation method and an application of the composite material. By taking a polypyrrole net-shaped structure which is synthesized by virtue of a soft template method as a raw material, taking the potassium hydroxide as a pore forming agent, and taking the nitrogen-doped carbon nanofiber net-shaped structure which is synthesized through high-temperature carbonization under nitrogen atmosphere and is in a porous structure as a precursor, the sulphur-carbon composite material which can be used as the anode of the lithium sulfur battery can be prepared through heat treatment with elemental sulfur. The preparation method provided by the invention is simple, and good in reproducibility, and the prepared composite material is uniform in structure distribution, and can be used as the anode of the lithium sulfur battery. Due to the nitrogen doping and the tridimensional net-shaped structure, for the material, the conductivity can be improved, a transmission path of lithium ions is shortened, meanwhile, the dissolving of the sulfur and intermediate product in an electrolyte can be prevented, the electrochemistry performance of a positive material of the lithium sulfur battery is improved, good specific discharge capacity, cycle performance and rate performance can be achieved.
Owner:FUDAN UNIV

Fabric coating finishing agent with electromagnetic shielding function and preparation method thereof

InactiveCN102154832ABoth electromagnetic shieldingBoth electromagnetic shielding and stealth performanceFibre treatmentPolypyrroleElectromagnetic shielding
The invention aims to provide a fabric coating finishing agent with electromagnetic shielding function and a preparation method thereof. The method comprises the following steps: preparing fabric supported by nano ferroferric oxide particles by an in-situ chemical method; synthesizing nano ferroferric oxide/polypyrrole composite material by an emulsification and oxidation method; and adding matrix resin, auxiliaries, film forming auxiliary and the like to synthesize the fabric coating finishing agent with electromagnetic shielding function. The fabric coating finishing agent has relatively high electric conductivity and magnetic conductivity, relatively high electromagnetic shielding absorption performance and relatively wide shielding frequency band; by coating the fabric coating finishing agent on fabric, a relatively good electromagnetic wave shielding and hiding effect is realized, and pollution of electromagnetic wave radiation is reduced as well; the fabric coating finishing agent has good handfeel smoothness, good anti-wrinkle performance and good antistatic, anti-corrosion and weather resistant effect, and is an environment-friendly product; and moreover, the process is simple and convenient, the production cost is relatively low, and the product performance is excellent.
Owner:QUANZHOU JIANENG MACHINERY MFG

Super-hydrophobic washable conductive fabric and preparation method thereof

The invention relates to a super-hydrophobic washable conductive fabric and a preparation method thereof. The conductive fabric comprises a substrate fabric and a conductive polymer layer coated on the surface of the substrate fabric; the conductive polymer layer is polyaniline, polypyrrole, poly(3,4-ethylenedioxythiophene), polythiophene or their derivative polymer; and the substrate fabric is a blend fabric with the surface having cracks and the cross section having a cross shape, wherein the blend fabric is obtained by blending a heterotypic polyester synthetic fiber and a cotton fiber. The preparation method comprises the following steps: processing the substrate fabric with plasma, compositing the conductive polymer with the substrate fabric through utilizing an in situ polymerization method, and adjusting the molar ratio of a fluorine-containing doping agent and a polyaniline monomer and other reaction conditions to obtain conductive fabrics with different conductivities. The prepared conductive fabric which has the characteristics of high conductivity, rapid pH responsiveness, reversible super-hydrophobic performance, excellent washability and the like can be widely applied to development of wettability switching of acidity control, automatically cleaning fabrics, acidity detection and the like, so there are enormous business opportunities.
Owner:BEIJING INSTITUTE OF CLOTHING TECHNOLOGY
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