2195 results about "Benzenesulfonic acid" patented technology

The room temperature ionic liquid containing unsaturated double bond has the general expressino of A+B-, where A+ contains R1 being hydroxyl with 1-4 carbon atoms and R2 containing 2-20 carbon atoms and at least one double bond; and B- is one of anions, including chlorate radical, bromate radical, iodate radical, acetate radical, sulfate radical, nitrate radical, tetrafluorobromate radical, etc. Its preparation is to mixture and react olefin halide R1X and N-alkyl imidazole to obtain ionic liquid dialkyl imidazolium halide. The present invention also relates to the application of the ionic liquid in dissolving cellulose and preparing cellulose derivative.

A composition and associated method for chemical mechanical planarization (or other polishing) are described. The composition contains an abrasive, benzenesulfonic acid compound, a per-compound oxidizing agent, and water. The composition affords tunability of removal rates for metal, barrier layer materials, and dielectric layer materials in metal CMP processes. The composition is particularly useful in conjunction with the associated method for metal CMP applications (e.g., step 2 copper CMP processes).

The invention provides a method for preparing high base number (TBN400) synthetic calcium alkyl-benzene sulfonate. The method comprises the following steps of: adopting a mixed acid of long-chain linear alkyl-benzene sulfonic acid and high-boiling heavy alkyl-benzene sulfonic acid, calcium oxide and/or calcium hydroxide, low-carbon alcohol, alkaline-earth metal halide or nitrate, and a mixture of alkaline-earth metal alkylphenol or alkaline-earth metal alkylphenate and polyisobutylene succinic anhydride for a neutralization reaction in the presence of a solvent and cutback oil at a temperature of between 40 and 80 DEG C; then, passing through carbon dioxide to a product of the neutralization reaction at a temperature of between 40 and 60 DEG C for a carbonation reaction; and producing high base synthetic alkyl-benzene sulfonate with a total base number (TBN) of 400mgKOH/g by adopting a process of a one-step method. The product is divided into high-base number (TBN400) synthetic alkyl-benzene sulfonate containing chlorine and high-base number (TBN400) synthetic alkyl-benzene sulfonate without the chlorine. The product produced by adopting the method with low viscosity, small turbidity, easy filtration, light color and no skin formation has the advantages of excellent high-temperature detergency, excellent anti-foaming property and excellent heat storage stability.

The invention relates to agricultural pesticide with essential oil and an application thereof. The agricultural pesticide comprises the following components: 5-90% of the essential oil with insecticidal active components, and 5-90% of solvent, 5-90% of pesticide adjuvant. The essential oil is one or mixture made one from wintergreen oil, camphor tree oil, clove oil, peppermint oil, eucalyptus oil, citronella oil or tea tree oil. The solvent is one or a mixture made of formic acid, acetic acid, propionic acid, methyl alcohol, ethyl alcohol or propyl alcohol. The pesticide adjuvant is one or mixture made of dodecyl benzenesulfonic acid, Tween-80, Span-80 (SPAN) or OP-10. The invention has low toxin for animals, safety for environment, efficiency for pests at each life stage and good effects for killing mites and pests. The agricultural pesticide has simple use method and low manufacturing cost, and is suitable for killing the mites and the pests in agriculture and forestry.

The invention discloses a spherical montmorillonite mesoporous composite carrier and a preparation method thereof, a supported benzenesulfonic acid catalyst and a preparation method thereof, an application of the catalyst in an esterification reaction, and a preparation method of ethyl acetate. The spherical montmorillonite mesoporous composite carrier contains montmorillonite and a mesoporous molecular sieve material, average particle size of the spherical montmorillonite mesoporous composite carrier is 30-60 micrometers, the specific surface area is 150-600 square meters/gram, pore volume is 0.5-1.5 milliliters/gram, aperture distribution is trimodal distribution, most probable apertures corresponding to three peaks are 2-4 nanometers, 5-15 nanometers and 10-40 nanometers respectively. The provided supported benzenesulfonic acid catalyst has the advantages of high catalytic activity and repeated usage.

The invention discloses a water-based environment-friendly finishing paint, which is prepared from the following compositions in part by weight: 20 to 70 parts of water borne acrylic resin solution of which the solid content is 30 to 80 percent and/or 20 to 70 parts of water borne epoxy resin solution of which the solid content is 30 to 80 percent, 4 to 10 parts of water borne amino resin solution of which the solid content is 60 to 98 percent; 1 to 5 parts of organic amine, 0.2 to 2 parts of wetting and leveling agent, 0.2 to 2 parts of thickener, 0.1 to 0.8 part of defoaming agent, 1 to 5 parts of adhesion promoter, 0.2 to 5 parts of catalyst, 10 to 30 parts of alcohol diluting solvent and/or 1 to 5 parts of nontoxic ether diluting solvent, and 20 to 50 parts of deionized water, wherein the catalyst is one or more of ammonias, alcohols and benzenesulfonic acids. The water-based environment-friendly finishing paint has the advantages of wide applicable range, high hardness, good flexibility, strong adhesion, good scratchproof performance, and environmental protection. Simultaneously, the invention also discloses a method for preparing the water-based environment-friendly finishing paint.

The invention relates to a preparation method for electroactive aniline oligomer-modified graphene. The preparation method comprises the following steps of: reducing graphite oxide by a reducing agent, cooling the reduced graphite oxide to the room temperature, centrifuging and drying the cooled graphite oxide to obtain the reduced graphene; ultrasonically dispersing the reduced graphene and the aniline oligomer into an organic solvent; adding dicyclohexyl carbodiimide and 4-dimethylamino-pyridine to the mixed solution; stirring and heating up the mixture for reacting; washing the mixture by a plurality of times by using acetone, alcohol and distilled water in sequence after the reaction is completed; and drying the mixture to obtain the aniline oligomer-modified graphene; doping the aniline oligomer-modified graphene by hydrochloric acid or dodecylbenzene sulfonic acid to obtain the electroactive aniline oligomer-modified graphene. The preparation method has the beneficial effects that the solubility in the organic solvent is improved and the specific capacitance reaches 160 F/g, so that the electroactive aniline oligomer-modified graphene has a broader application prospect in the fields such as super capacitors, solar cells and the like.

The invention relates to a method for preparing calcium sulfonate with high base number. In the method, alkyl benzene sulfonic acid and/or petroleum sulfonic acid serve as raw materials, low molecular alcohol serves as accelerating agent, calcium oxide and/or calcium hydroxide serve as calcifying agent; firstly, neutralization reaction is carried out to generate calcium sulfonate; then carbonation reaction is carried out for twice, post-treating agent is added for reaction; finally, alcohol, water, solvent and solid residue are removed to obtain the calcium sulfonate with high base number. The product of the invention is especially suitable for preparing lubricating grease, can shorten conversion time of calcium sulfonate crystal form, improve high-temperature bproperty and anti-moisture performance of the lubricating grease and satisfy the demands of high-performance lubricating grease.

A rigid, rod liquid crystal polymer includes a a poly(phenylene sulfonic acid).

The invention relates to a method for preparing cabazitaxel, particularly relates to a method for preparing the cabazitaxel by taking 10-deacetylate-baccatin III as a raw material and belongs to the technical field of drug synthesis. The method comprises the following steps: firstly, reacting 10-DAB with chlorocarbonate-2,2,2-trichloro ethyl ester, thereby obtaining a product; reacting the product with DMAP (dimethylamino pyridine), DCC (dicyclohexylcarbodiimide) and (4S, 5R)-2,2-dimethyl-4-phenyl-3-tert-butoxycarbonyl-3.5-oxazolidine formic acid, thereby obtaining a product; reacting the product with acetic acid and zinc powder, and then methylating the product; and lastly, adding a p-methyl benzenesulfonic acid, thereby reacting and obtaining a cabazitaxel product. The cabazitaxel prepared according to the method can be widely applied to the treatment of prostate cancer. Compared with a traditional technique for preparing the cabazitaxel, the method has the advantages that the preparation quantity is greatly increased, the operation steps are simplified, the manpower is saved and the method has industrial application value and prospect.

The invention relates to a composite phosphating solution of P-Ca-V on the surface of a magnesium alloy and a method for chemical conversion treatment. The solution is characterized in that each liter of the composite phosphating solution comprises the following compositions: 4 to 20 milliliters of 85 percent phosphoric acid of, 5 to 30 grams of sodium dihydrogen phosphate, 10 to 40 grams of calcium nitrate, 0.5 to 10 grams of benzene sulfonic acid sodium salt, 0.5 to 5 grams of ammonium metavanadate, and the balance being water. The method comprises the following steps: pre-degreasing, degreasing, secondary water washing, acid washing, secondary water washing, alkaline etching, secondary water washing, chemical transformation, secondary water washing, pure water washing, and drying. Taking an AZ91D magnesium alloy as an example, 48 hours after a corrosion resistance salt spray test after the treatment by the method of the invention, the corrosion area of the AZ91D magnesium alloy is less than 1 percent; the paint film adhesive force is at 0 level by a grid method and is obviously superior to the performance of a chromate conversion coating; and the formed chemical conversion coating does not contain crystal water. The composite phosphating solution has the synergistic reaction of Ca and V, as well as the functions of a corrosion inhibitor and a wetting agent of the benzene sulfonic acid sodium salt.

The invention provides a novel synthesis method for pimavanserin. The method comprises the steps that a compound formula (1a) is adopted as a raw material for preparing an active urea compound formula (1) and then subjected to a reaction with a compound formula (2) under an alkaline system to obtain a pimavanserin free alkali formula (3), and then pimavanserin free alkali forms a salt with tartaric acid to obtain a pimavanserin half tartrate formula (4). The method is simple in technological path, low in cost and suitable for industrial production. The formula is shown in the description, wherein HmA is the general formula of m-basic acid, HnA is the general formula of n-basic acid, m and n are 1 or 2 or 3, and the m-basic acid and the n-basic acid are selected from sulfuric acid, hydrochloric acid, phosphoric acid, p-toluenesulfonic acid, benzenesulfonic acid, methanesulfonic acid, methanoic acid, acetic acid, trifluoroacetic acid, oxalic acid, citric acid or tartaric acid.

The invention discloses benzene sulfonic acid levo-amlodipine pills and a preparation method thereof. On the basis of 1000 pills, the benzene sulfonic acid levo-amlodipine pill comprises 1-10g of benzene sulfonic acid levo-amlodipine, preferably 2.5g; 50-100g of lactose, preferably 67-87g and most preferably 80g; 5-55g of low-substituted hydroxy propyl cellulose, preferably 20-40g and particularly preferred 30g; 2-20g of crosslinked polyethylene ketopyrrolidine, preferably 5g; and 0.5-2.5g of magnesium stearate, preferably 1.5g. The benzene sulfonic acid levo-amlodipine pills have more than 95 percent of dissolution rate and good production stability.

Pigmented inks are disclosed comprising an aqueous medium, a pigment, a dispersant, and a humectant. Inks are disclosed where the humectant is a sulfonated polyethylene oxide which provides long decap times and fast drying of the printed image. Inks are further disclosed where the dispersant is an alkyl(sulfophenoxy)benzenesulfonic acid or its salt. Such dispersants reduce the agglomeration of pigment particles and reduce or eliminate the deposition of foreign substances on heater elements during the jetting process. A variety of pigments, dispersants, humectants, and aqueous media can be used. Combinations of a sulfonated polyethylene oxide humectant and an alkyl(sulfophenoxy)benzenesulfonic acid (salt) dispersant provide inks with good stability, few kogation problems, long decap times and relatively fast drying times.

The invention discloses a spherical montmorillonite mesoporous composite carrier and its preparation method, a supported benzenesulfonic acid catalyst and its preparation method, a use of the supported benzenesulfonic acid catalyst in an esterification reaction, and a preparation method of ethyl acetate. The spherical montmorillonite mesoporous composite carrier contains montmorillonite and a mesoporous molecular sieve material having a three-dimensional tunnel structure. The spherical montmorillonite mesoporous composite carrier has the average particle size of 20-50 microns, a specific surface area of 150-600 m<2>/g and a pore volume of 0.5-1.5ml/g, and has a bimodal pore diameter distribution mode and most probable pore diameters of 2-8nm and 20-50nm corresponding to two peaks. The supported benzenesulfonic acid catalyst has high catalytic activity and can be recycled.

The invention relates to a water body, a method for rapidly detecting the residue of malachite green and colorless malachite green in an aquatic product, belonging to the technical field of residue detection in a water body and an aquatic product. The method comprises the following steps: oscillating and mixing a sample to be detected and an extractant I uniformly; adding an extractant II, oscillating and mixing and then standing still; taking and adding an supernatant to an enrichment column; observing color change of a chromogenic reagent on the lowest layer; and determining that the sample contains the malachite green and colorless malachite green if a green circular strap is formed. The extractant I is a mixed solution of acetonitrile, dichloromethane, n-hexane and paratoluenesulfonic acid, the extractant II is a mixture of lead dioxide and acid alumina, and the sample to be detected is a water body sample to be detected or an aquatic product sample to be detected. The invention has the advantages of simple operation and fewer steps, does not need expensive instruments and equipment and can embody the convenience and the flexibility to on-site detection.