1175 results about "Phthalic acid" patented technology

The invention discloses a preparation method of a fly ash-Al-MOF material loaded with sodium percarbonate and acid-containing ferrous sulfate, which comprises the following steps: carrying out heat treatment on fly ash, cooling, adding into a sulfuric acid solution, stirring and mixing, carrying out solid-liquid separation, adding sodium hydroxide into a liquid product to adjust the pH value to 4.5-6 to obtain an aluminum hydroxide precipitate, washing and roasting to obtain aluminum oxide, and drying to obtain the fly ash-Al-MOF material loaded with sodium percarbonate and acid-containing ferrous sulfate. The preparation method comprises the following steps: mixing fly ash-Al-MOF with a sulfuric acid solution to obtain an aluminum sulfate solution, uniformly mixing the aluminum sulfate solution with a phthalic acid solution, carrying out solid-liquid separation, washing a solid product, carrying out freeze drying to obtain fly ash-Al-MOF, and respectively loading sodium percarbonate and acid-containing ferrous sulfate on the fly ash-Al-MOF to obtain fly ash-Al-MOF loaded with sodium percarbonate and fly ash-Al-MOF loaded with acid-containing ferrous sulfate; and uniformly mixing the two components to obtain a finished product. Compared with the existing method, the material prepared by the invention can realize long-term, stable, effective and environment-friendly remediation of the organic polluted soil, and the remediation efficiency is high.

The invention relates to the technical field of cables, and provides an anti-aging insulated power cable. A conductor layer and an anti-aging outer sheath layer are sequentially arranged from inside to outside. The anti-aging outer sheath layer is prepared from the following raw materials in parts by weight: 55 to 65 parts of PVC (Polyvinyl Chloride) resin, 20 to 30 parts of ethylene propylene diene monomer, 10 to 15 parts of ethylene-vinyl acetate copolymer, 10 to 12 parts of modified kaolin, 18 to 20 parts of diisononyl phthalate, 4 to 5 parts of calcium-zinc composite stabilizer, 1.5 to 2 parts of antioxidant, 0.5 to 1 part of polyethylene wax and 0.5 to 0.7 part of calcium stearate; the modified kaolin is obtained by coating the surface of kaolin with nano silicon dioxide to obtain SiO2-coated kaolin and grafting the SiO2-coated kaolin with an ultraviolet absorbent. According to the anti-aging insulated power cable prepared in the invention, the problem that the ultraviolet absorbent may be decomposed, volatilized or migrated to fail in long-term use is solved, and the anti-aging stability of the insulating material in long-term operation is improved.

The invention belongs to the field of conductive paste preparation, and particularly discloses conductive paste containing ruthenium oxide and a preparation method of the conductive paste. The conductive paste is prepared from the following components in percentage by mass: 40 percent to 50 percent of ruthenium oxide, 3.8 percent to 5 percent of carbon nano tubes, 5 percent to 10 percent of PbO-B2O3-SiO2, 3 percent to 8 percent of ethyl cellulose, 21 percent to 28 percent of terpilenol, 9 percent to 12 percent of butyl carbitol, 0.7 percent to 1 percent of ammonium polyacrylate and 1 percent to 2 percent of dibutyl phthalate. According to the preparation method, ruthenium oxide is activated in vacuum, a mixed solvent is combined after dispersion, and a ball milling and ultrasonic dispersion synergistic process is adopted, so that the slurry is uniformly dispersed and has excellent stability. According to the invention, a ruthenium oxide-carbon nanotube-frit ternary synergistic system is constructed, and terpilenol and butyl carbitol in a specific mass ratio are taken as a mixed solvent, so that the problems of insufficient conductivity and easy agglomeration of traditional paste are effectively solved, and the method can be widely applied to manufacturing of high-precision electronic devices.

The invention discloses a quick-curing polyurethane seamless expansion joint material for roads and a preparation method, and belongs to the technical field of road engineering materials. The material is prepared from polyether polyol, polycaprolactone glycol, a bisphenol A epoxy-polyether block isocyanate terminated prepolymer, a methyl phenyl silicon-boron hybrid hydroxyl chain extender, diphenylmethane diisocyanate, calcium carbonate, wollastonite, a hindered amine anti-aging agent and dioctyl phthalate. Wherein the bisphenol A epoxy-polyether block isocyanate terminated prepolymer is prepared by the following steps: reacting bisphenol A with epoxy chloropropane to generate epoxy resin, reacting with polytetramethylene ether glycol, and introducing isophorone diisocyanate; the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation and ethylene glycol reaction on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester; and the methyl phenyl silicon-boron hybrid hydroxyl chain extender is prepared by carrying out hydrosilylation on methyl trimethoxy silane, 3-glycidyl ether oxypropyl trimethoxy silane and allylboronic acid pinacol ester. The material has the advantages of quick curing property, weather resistance and high-temperature stability, and is suitable for road seamless expansion joint scenes.

The invention relates to a photo-thermal aging resistant photovoltaic cable and a preparation method thereof, and belongs to the technical field of high polymer materials. The photo-thermal aging resistant photovoltaic cable is composed of a conductor wire core, and an insulating layer, a filling layer and an outer sheath which are sequentially coated on the outer side of the conductor wire core, the outer sheath is prepared from the following raw materials in parts by weight: 80-120 parts of polyvinyl chloride resin, 3-5 parts of a modified anti-aging agent, 2-8 parts of a modified flame retardant, 1-3 parts of dioctyl phthalate, 10-20 parts of nano silicon dioxide, 1-3 parts of butyl stearate and 3-5 parts of zinc stearate; the photo-thermal aging resistant photovoltaic cable prepared by the invention not only has good ultraviolet ray and thermal aging resistant effects, but also has an excellent flame retardant effect.

The invention relates to the technical field of ceramic substrates, in particular to a ceramic substrate blank powder coating and sintering process. Comprising the following steps: step 1, uniformly stirring boron nitride powder, terpilenol, ethyl cellulose, butyl benzyl phthalate and phosphate, and grinding to obtain coating powder; step 2, printing powder on the surface of the green body by using a silk-screen printing technology to form a powder pattern; a powder coating green body is obtained; step 3, stacking N powder-coated green bodies to obtain laminated green bodies; 4, the laminated green body is subjected to glue discharging sintering and sand blasting in sequence; and obtaining the ceramic substrate.

The invention discloses a normal-temperature bacteria liquid enteric-coated targeted colonization microcapsule and a preparation method thereof. The invention belongs to the technical field of biological medicine. The structure of the room-temperature bacterial liquid protection microcapsule is as follows: an inner layer is an activity maintaining layer and mainly consists of a sodium alginate-calcium chloride polyelectrolyte compound (the thickness is 50-100 microns); the middle layer is a pH response release layer and is mainly composed of hydroxypropyl methyl cellulose phthalate (HPMCP, dissolved at pH of 6.8 or above) and nano calcium carbonate particles (the particle size is 50nm, and the proportion is 10% w / w); the outer layer is a mucous membrane adhesion layer, and the main components of the mucous membrane adhesion layer comprise fucose modified chitosan (Fuc-CS, targeted colonic mucous membrane lectin protein) and carbomer 940 (pH sensitive adhesion polymer); the method is a microcapsule capable of preserving the bacterial liquid at normal temperature and accurately targeting colon release and adhesion colonization and a process thereof, the problem of flora activity loss caused by a freeze-drying process can be solved, in addition, the process does not need freeze-drying equipment, and the production cost is reduced.

The invention relates to the technical field of waterproof materials, and particularly discloses a self-adhesive polymer modified asphalt waterproof material as well as a preparation method and application thereof. The self-adhesive polymer modified asphalt waterproof material is prepared from the following raw materials in parts by mass: 45 to 55 parts of asphalt, 8 to 12 parts of softening oil, 10 to 15 parts of modifier, 8 to 12 parts of desulfurized rubber and 10 to 15 parts of filler, the modifier comprises the following raw materials: an ethylene-octylene copolymer, butadiene styrene rubber, coumarone resin and a functional modified material; the functional modified material is prepared from illite and phthalic acid ester. Through the design of the modifier and the proportion design of the raw material components, the synergistic interaction effect of the raw materials is fully played, the comprehensive performance of the waterproof material is improved, and the self-adhesive polymer modified asphalt waterproof coiled material prepared from the waterproof material has excellent high and low temperature properties, persistent adhesivity, peel strength, aging resistance and water resistance.

The invention relates to the technical field of alloys, and discloses a high-strength silver-copper alloy and a preparation method thereof. The acidified carbon nanotubes are subjected to functional modification, methylbenzene-2, 4-diisocyanate reacts with surface active groups of the methylbenzene-2, 4-diisocyanate to introduce-NCO groups, then through hydroxyl reaction of-NCO and 4-hydroxyphthalic acid, a plurality of carboxyl groups are grafted on the surfaces of the carbon nanotubes, the carboxyl groups can firmly adsorb lanthanum nitrate through a coordination effect, and meanwhile, the carboxyl groups can also adsorb lanthanum nitrate through a coordination effect. The rare earth elements are prevented from being separated from the raw materials in the ball milling process, uniform distribution is ensured, the agglomeration tendency of the carbon nanotubes can be reduced, and the dispersity of the carbon nanotubes in the silver-copper alloy is improved; the carbon nanotubes have extremely high axial strength and excellent conductivity, the mechanical and electrical properties of the alloy material can be enhanced through load transfer and a conductive network effect, rare earth lanthanum is segregated at a grain boundary to form a pinning effect to refine grains, the alloy strength is further improved, and finally collaborative improvement of the strength and the conductivity of the silver-copper alloy is achieved.

The invention relates to the technical field of rubber-plastic composite flame-retardant materials, and provides a graphite rubber-plastic composite flame-retardant material and a preparation method thereof.The preparation method comprises the following processes that nitrile rubber, polyvinyl chloride, dioctyl phthalate, modified expandable graphite, a stabilizer, sulfur and an anti-aging agent are added into a high-speed mixer and mixed to be uniform, and a premix is obtained; and feeding the premix into a double-screw extruder, and carrying out melt blending, extrusion and vulcanization to obtain the composite flame-retardant material. The preparation method has the beneficial effects that the modifier is combined with the expansible graphite and compounded with the nitrile rubber, the polyvinyl chloride and other base materials, so that the flame retardant property and the mechanical property of the prepared composite material are remarkably improved.

The invention discloses a low-temperature curing PVC plastisol composition for a vehicle and a preparation method of the low-temperature curing PVC plastisol composition. The invention relates to a low-temperature curing PVC plastisol composition for vehicles, which is prepared from the following raw materials in parts by weight. Comprising 5 to 15 parts of polyvinyl chloride-vinyl acetate copolymer resin, 5 to 15 parts of homopolymerized PVC paste resin, 1 to 10 parts of blended PVC paste resin, 30 to 40 parts of a compound plasticizer, 1 to 10 parts of a hydrocarbon solvent, 0.5 to 1.5 parts of terminated polyurethane, 0.5 to 2 parts of polyamide, 0.5 to 1 part of a thixotropic agent, 30 to 45 parts of an inorganic filler, 1 to 5 parts of a stabilizer and 1 to 5 parts of a moisture absorbent. The compound plasticizer is prepared from diethylene glycol dibenzoate, isodecyl benzoate and diisononyl phthalate. The PVC plastisol composition disclosed by the invention is a low-temperature and short-time curing material, and can be cured under the conditions that the baking temperature is 125 DEG C and the baking time is 20 minutes.

It is intended to provide a method for producing a catalyst for olefin polymerization which exhibits excellent catalytic activity in a polymerization treatment and permits production of a polymer excellent in stereoregularity, melt flowability, etc., even when the polymerization catalyst is prepared in an inert gas atmosphere by using a solid catalytic component comprising an electron-donating compound other than a phthalic acid ester. The method for producing a catalyst for olefin polymerization comprises performing a pre-contact treatment of bringing a solid catalytic component (A) comprising a magnesium atom, a titanium atom, a halogen atom and an electron-donating compound having no phthalic acid ester structure, a specific organoaluminum compound (B) and an external electron-donating compound (C) into contact with each other at a temperature of lower than 15° C. for a time of 30 minutes or shorter in the absence of the olefin.

The invention relates to the technical field of shield tunnel construction, and discloses a shield tunnel segment joint waterproof material and a waterproof structure, the shield tunnel segment joint waterproof material comprises a component A and a component B; the component A comprises the following component: 30-40 parts of liquid polysulfide rubber; 5 to 10 parts of a fluorinated polyurethane prepolymer; 1-5 parts of a silane coupling agent; 3-5 parts of fumed silica; 8-15 parts of hollow glass beads; 10 to 15 parts of nano calcium carbonate; 0.5 to 2 parts of polytetrafluoroethylene micro powder; 0.1 to 1 part of ettringite; the component B comprises the following component: 1-5 parts of manganese dioxide; and 5 to 10 parts of dioctyl phthalate. By utilizing the characteristics that the sealing gasket has excellent fluidity during injection and can be automatically cured into a high elastomer within a set time, a pre-installed sealing gasket can be replaced by adopting an innovative injection process, and the construction difficulty faced by high-precision shield segment assembly in a high-water-pressure environment is effectively solved.

The invention relates to the technical field of cables, and provides a flexible cable for a robot, which comprises a cable core and a sheath layer wrapping the cable core, the cable core comprises signal lines and power lines. Each signal line sequentially comprises a conductor, a belting layer and a shielding layer from inside to outside; the shielding layer sequentially comprises a first shielding layer and a second shielding layer from inside to outside; the first shielding layer is a bare copper wire mesh layer; the second shielding layer is a tinned copper wire mesh layer; the belting layer is a glass fiber tape layer; the sheath layer comprises the following raw material components in parts by weight: 80-90 parts of polyvinyl chloride resin, 20-30 parts of a plasticizer, 2-4 parts of an anti-aging agent, 2-4 parts of a calcium-zinc stabilizer, 1-4 parts of a lubricant and 6-16 parts of a flame retardant; the plasticizer is prepared from dioctyl phthalate, polyethylene glycol adipate and p-methoxyacetophenone. According to the technical scheme, the problem of low elongation at break of the flexible cable for the robot in the prior art is solved.

The invention discloses a method for detecting 18 phthalic acid ester substances in brewed sauce, which specifically comprises the following steps: step 1, obtaining a sample of the brewed sauce to be detected, adding a phthalic acid ester substance internal standard working solution containing deuterated isotope and water, uniformly mixing, adding sodium chloride and acetonitrile, continuously uniformly mixing, and detecting the content of the phthalic acid ester substances in the brewed sauce to be detected; carrying out ultrasonic extraction treatment for 5-15 minutes, adding an ultrasonic extracting solution into a mixture of PSA, C18 and MgSO4, and carrying out centrifugal treatment to obtain supernate; 2, carrying out nitrogen blowing on the supernate until the supernate is nearly dry, and fixing the volume by using normal hexane to obtain a sample to be detected; and step 3, detecting by adopting a gas chromatography-tandem mass spectrometer isotope internal standard method.

The invention relates to the technical field of cables, and provides a corrosion-resistant insulated power cable. The corrosion-resistant insulated power cable is sequentially provided with a conductor layer, an insulating layer and a sheath layer from inside to outside, and the insulating layer is prepared from the following raw materials in parts by weight: low-density polyethylene, magnesium hydroxide and calcium carbonate composite powder, an antioxidant, dicumyl peroxide, zinc stearate and polyethylene wax; the sheath layer comprises the following raw materials in parts by weight: PVC resin, magnesium hydroxide and calcium carbonate composite powder, diisononyl phthalate, a calcium-zinc composite stabilizer, an antioxidant, polyethylene wax and calcium stearate. According to the corrosion-resistant insulated power cable prepared in the invention, the corrosion resistance of the power cable in extreme corrosion environments such as strong acid, strong alkali, high-concentration salt mist and the like is improved, and the condition that a common cable sheath is easy to expand and crack in the extreme corrosion environments is improved.

Processes and systems for producing recycled content polyethylene terephthalate (r-PET) are provided. Integration of chemical recycling facilities with PET production facilities reduces energy consumption and helps minimize adverse environmental impacts, while providing valuable end products having up to 100 percent recycled content.

The invention discloses 1, 2-dibromo-6-tert-butyl-9-(4-tert-butylphenyl)-9H-carbazole and a synthesis method of the 1, 2-dibromo-6-tert-butyl-9-(4-tert-butylphenyl) The method comprises the following steps: taking 3-nitrophthalic acid as an initial raw material, reacting trichloroisocyanuric acid with liquid bromine to obtain 1, 2-dibromo-3-nitrobenzene, reducing by stannous chloride to obtain 2, 3-dibromoaniline, carrying out diazotization reaction to obtain 2, 3-dibromophenylhydrazine, reacting with p-tert-butyl cyclohexanone, and reacting by using 2, 3-dichloro-5, 6-dibromophenylhydrazine to obtain 2, 3-dibromophenylhydrazine. The preparation method comprises the following steps: carrying out dehydrogenation on 2, 6-dicyanobenzoquinone to obtain 1, 2-dibromo-6-tert-butyl-9H-carbazole, and finally reacting the 1, 2-dibromo-6-tert-butyl-9H-carbazole with 4-tert-butyl iodobenzene to obtain the 1, 2-dibromo-6-tert-butyl-9-(4-tert-butylphenyl)-9H-carbazole. Due to the existence of a bromine atom functional group on the 1, 2-dibromo-6-tert-butyl-9-(4-tert-butylphenyl)-9H-carbazole, the further conversion of the compound has expandability, and the compound can be used as a material / drug molecule precursor in the fields of organic light-emitting semiconductors, pharmaceutical chemistry and the like.

The invention relates to rosin modified resin and a preparation process thereof and low-odor printing ink, the rosin modified resin is prepared from maleic anhydride, sulfonate alkyd resin, rosin and a metal organic framework, and the sulfonate alkyd resin is prepared from neopentyl glycol, dibutyltin dilaurate, m-phthalic acid-5-sodium sulfonate, phthalic anhydride and pentaerythritol. The printing ink has the effect of improving the strength and smell of the printing ink.

The invention discloses Pseudomonas putida, a bacterial agent thereof and an application of the Pseudomonas putida in chemical wastewater treatment, the Pseudomonas putida is named as PH-20 and preserved in the China General Microbiological Culture Collection Center on March 17, 2025, and the preservation number of the strain is CGMCC No. 33831. The invention further discloses a preparation method of the Pseudomonas putida. The pseudomonas putida disclosed by the invention can be used for rapidly degrading polybenzoic acid such as terephthalic acid, phthalic acid, isophthalic acid, trimellitic acid, trimellitic acid and pyromellitic acid in wastewater under the conditions of high salt and low temperature, and the degradation effect is still excellent under the condition that various pollutants coexist.

The invention discloses a liquid treatment agent for red mud harmless treatment and a preparation method thereof.The liquid treatment agent comprises a treatment agent A and a treatment agent B. The treatment agent A is formed by mixing hydrochloric acid and sulfuric acid, and the treatment agent B is prepared from malic acid, acetic acid, phthalic acid monoester, a solvent and an adsorbent, the mass fraction of the malic acid is 20%-40%, the mass fraction of the acetic acid is 20%-40%, the mass fraction of the phthalic acid monoester is 15%-25%, the mass fraction of the solvent is 5%-15%, and the mass fraction of the adsorbent is 5%-15%. The red mud is subjected to primary treatment by using the liquid treatment agent A, and then the red mud subjected to primary treatment is treated again by using the liquid treatment agent B, so that the alkalinity of the red mud can be effectively reduced, and various heavy metals, fluorides, radioactive elements and trace toxic elements in the red mud can be effectively removed; the environment pollution caused by the loss of the harmful substances is avoided, so that the innocent treatment of the red mud is realized.

The invention discloses a whitening and antibacterial knitted fabric and a preparation method thereof, and belongs to the technical field of functional clothing, Zn (NO3) 2.6 H2O and 1, 4-phthalic acid (H2BDC) are fully dissolved and dispersed through N, N-dimethylformamide (DMF) and dried to prepare Zn-BDC MOF powder, then nicotinamide and chitosan with whitening, spot fading and antibacterial functions pass through N, N-dimethylformamide (DMF) through interaction of subjects and guests, and the functional clothing is obtained. And dissolving N, N-dimethylformamide, and embedding into MOF pores to obtain the whitening skin-care antibacterial functional MOF material. And finally, adding a polyvinyl alcohol solution to obtain a functional finishing agent, and finishing the finishing agent on knitted garments to obtain the knitted fabric with the whitening, skin-care and antibacterial composite functions. The obtained knitted fabric has good whitening, skin care and antibacterial effects and can be applied to sportswear worn in daily life, and knitted garments made of the knitted fabric have the whitening and skin care effects, are good in use comfort and efficiently resist bacteria.

The present disclosure relates to a flexible multi-layered material. An embodiment consistent with the disclosure has a plurality of poly(vinyl chloride)—PVC—layers, wherein at least one of the plurality of PVC layers is a foam layer, wherein each of the layers of the plurality of PVC layers comprises up to 60% (w / w) of a phthalate-free plasticizer, and wherein the phthalate-free plasticizer is selected from the group consisting of: phosphate, trimellitate, adipate, citrate, sebacate, polyester, vegetable oil, and mixtures thereof, and wherein the solubility of the phthalate-free plasticizer in the PVC is at least 13 (J·cm−3)1 / 2.

The invention discloses a rhodococcus ruber WM-5 strain, and the preservation number of the rhodococcus ruber WM-5 strain is CCTCC (China Center for Type Culture Collection) NO.M2025874. Research shows that the rhodococcus ruber WM-5 strain has the functions of resisting cadmium and degrading phthalic acid ester, has extremely high degradation efficiency on DBP (dibutyl phthalate), and is relatively wide in suitable degradation condition range; the Rhodococcus ruber WM-5 strain has strong tolerance to Cd < 2 + > and PAEs, when the Rhodococcus ruber WM-5 strain is applied to PAEs polluted solution systems under the condition of different initial concentrations of PAEs and Cd-PAEs composite polluted solution systems with different initial concentrations of Cd < 2 + >, high PAEs degradation efficiency can be maintained, and technical support is provided for remediation of Cd-PAEs composite pollution. In a word, the invention makes up the technical blank of Cd-resistant PAEs degrading strains, and the Rhodococcus ruber WM-5 strain or the microbial agent thereof has great application value in the aspects of degrading phthalate and repairing Cd-PAEs composite pollutants.

The invention discloses polyolefin artificial leather, a preparation method thereof and an automobile seat, and belongs to the technical field of polyolefin artificial leather. The polyolefin artificial leather comprises a base cloth layer, a high-elasticity and high-softness layer and a coating layer which are sequentially stacked, the high-elasticity and high-softness layer comprises the following raw material components: a polyolefin elastomer, a low-density polyolefin elastomer, modified high-elasticity resin, an assistant crosslinker, a coupling agent and an anti-aging agent; the low-density polyolefin elastomer comprises a modified polyolefin elastomer, inorganic microspheres and a silane coupling agent; the modified polyolefin elastomer is prepared by grafting 4-vinyl-1, 2-phthalic acid and maleic anhydride on a polyolefin elastomer by adopting a melt grafting method; the modified high-elasticity resin comprises a high-elasticity polyolefin elastomer, a rubber elastomer, a silane coupling agent and a peroxide cross-linking agent; the high-elasticity polyolefin elastomer is obtained by copolymerization of propylene, norbornene and cardanol; p-chlorophenyl trimethoxy silane is at least adopted as the coupling agent.

The invention discloses an anti-aging light-conversion silver black mulching film and a preparation method thereof, and belongs to the technical field of agricultural polymer films. The preparation method comprises the following steps: S1, mixing low-density polyethylene powder, aluminum paste, a complex light conversion agent, dioctyl phthalate and EVA (Ethylene Vinyl Acetate) to prepare silver light conversion master batches; s2, vinyl-terminated fluorosilicone oil, tert-butyl peroxybenzoate and linear low-density polyethylene powder are stirred for a reaction, and modified low-density polyethylene is obtained; the modified low-density polyethylene, maleic anhydride grafted polyethylene, a multi-effect light stabilizer and polyethylene wax are subjected to banburying granulation, and modified light-stable master batches are obtained; s3, carrying out banburying granulation on the low-density polyethylene powder, the polyethylene powder, carbon black, zinc stearate, ethylene bis-stearamide and the EVA powder to obtain black master batches; s4, blending the silver layer and the black layer, and performing double-layer co-extrusion to obtain the light-conversion silver-black mulching film. The light-conversion silver black mulching film provided by the invention has good mechanical properties and aging resistance.

The invention relates to a composite plasticizer, a silicon nitride green body, a preparation method of the silicon nitride green body and a silicon nitride ceramic chip, and relates to the technical field of ceramic materials. The first plasticizer comprises at least one of a glycol polymer and glycol polymer monomethyl ether, the glycol polymer is HO-(CaH2aO) b-H, the glycol polymer monomethyl ether is HO-(CaH2aO) b-CH3, a is greater than or equal to 2 and less than or equal to 6, and the molecular weight is 2000-10000. The molecular formula of the second plasticizer is R1-(CmH2mO) n-R2, m is greater than or equal to 2 and less than or equal to 6, m * n is greater than or equal to 2 and less than or equal to 30, R1 is one of hydroxyl, alkoxy or carboxylic ester group, and R2 is one of hydrogen, alkyl or alkyl carbonyl. The composite plasticizer provided by the embodiment of the invention can replace a phthalate plasticizer in related technologies, and reduces environmental and health risks while improving the plasticizing effect.

The invention discloses a bio-based flame-retardant coating based on ammonium polyphosphate, which is prepared by taking a chitosan / lignin / ammonium polyphosphate bio-based flame retardant CS / LS / APP (short for CLA) as a flame retardant, urea, formaldehyde and melamine as resin raw materials, dioctyl phthalate DOP as a plasticizer and tannic acid as a curing agent. The preparation method comprises the following steps: 1, preparing the chitosan / lignin / ammonium polyphosphate bio-based flame retardant CLA; 2, preparation of a melamine-urea formaldehyde resin emulsion MUF (Melamine-Urea Formaldehyde); and 3, preparing the bio-based flame-retardant coating MUF / CLA based on ammonium polyphosphate. When being used as a wood flame-retardant coating, the flame-retardant coating has a flame-retardant property and passes a UL-94V-0 grade test; a carbon residue layer formed after complete combustion is continuous and compact; the limit oxygen index is 32.6 + / -0.06%; the maximum heat release rate is 42.83 + / -1.51 kW / m < 2 >, the total heat release amount is 2.62 + / -1.25 MJ / m < 2 >, and the fire increase index is 0.37 + / -0.02 kW / m < 2 >. S.

The invention discloses a low-rank coal composite flotation reagent and a preparation method and application thereof, and belongs to the technical field of coal flotation of mineral processing. The agent specifically comprises a composite collecting agent and a composite foaming agent, and the composite collecting agent comprises kerosene, n-dodecane, oleic acid, dimer acid, sodium stearate, terpilenol, diethyl phthalate, alkylphenol ethoxylates, span-80, trioctyl phosphate and 2-ethylhexanol. The composite foaming agent is prepared from the following components: terpilenol, terpenic oil, sec-octyl alcohol and sodium alpha-olefin sulfonate. Compared with a traditional single flotation reagent combination, the composite flotation reagent has a remarkable effect in fine coal flotation, and particularly when coal with the particle size smaller than 0.5 mm is treated, the flotation efficiency, the clean coal yield and the combustible body recovery rate can be effectively improved. More importantly, the medicament is stable at normal temperature, the layering phenomenon is avoided, the long-term effectiveness is ensured, and the medicament has extremely high industrial application potential.

The invention provides a drilling fluid flow pattern regulator suitable for Antarctic subglacial drilling and a preparation method and application thereof, and belongs to the technical field of polar region drilling. The flow pattern regulator is prepared from the following raw materials: 4-tert-butyl styrene, carboxylic acid, an acrylate monomer, oleyl alcohol, concentrated sulfuric acid and an initiator. The carboxylic acid is one of ricinoleic acid or phthalic acid; the acrylic ester monomer is one of acrylic acid-2-hydroxyethyl ester or 2-acrylic acid-2-hydroxy-3-phenoxy propyl ester, and the acrylic ester monomer is one of acrylic acid-2-hydroxyethyl ester and 2-acrylic acid-2-hydroxy-3-phenoxy propyl ester; and the initiator is one of azodiisobutyronitrile or benzoyl peroxide. The flow pattern regulator is simple in raw material composition and preparation method and low in cost. The flow pattern regulator can effectively improve the ultralow-temperature rheological property of the drilling fluid, enables the drilling fluid to have the advantages of low viscosity, high dynamic shearing force, chip carrying (ice chips and rock chips), excellent suspension performance and the like at the ultralow temperature, and is suitable for under-ice drilling in the Antarctic pole.