2992 results about "Bonding strength" patented technology

The invention discloses a high-bonding-strength flame-retardant composite current collector base film and a preparation method thereof. The high-bonding-strength flame-retardant composite current collector base film is prepared from the following raw materials in parts by weight: 100 parts of PP resin, 1.5 parts of a lubricant, 0.8 part of an antioxidant and 16 parts of reinforced flame-retardant composite particles, the reinforced flame-retardant composite particles are prepared by the following steps: S1, preparing amidated porous carbon microspheres; s2, compounding the amidated porous carbon microspheres with mica powder to prepare a composite carrier; s3, loading a flame retardant to prepare a flame-retardant compound; s4, in-situ grafting of maleic anhydride grafted polypropylene is carried out, and the reinforced flame-retardant composite particles are obtained. By adding the reinforced flame-retardant composite particles into the PP resin, the flame retardance and mechanical strength of the PP-based composite current collector base film and the interface bonding force between the PP base film and the metal conductive layer can be comprehensively improved.

The invention discloses an integrated preparation method of a SiC-based composite material environment barrier coating in the technical field of aviation thermal structure materials, which comprises the following steps: cleaning a substrate, carrying out vacuum impregnation of phenolic resin and curing, coating Si slurry to form a bonding layer, coating rare earth silicate slurry to form a barrier layer, and drying to obtain the SiC-based composite material environment barrier coating. And finally carrying out high-temperature heat treatment in an inert atmosphere. According to the method, through an integrated slurry coating and gradient curing process, the performance of a base body is protected, and meanwhile efficient preparation of the coating is achieved; by adopting an integrated slurry coating and gradient curing technology and combining with an optimized medium-temperature sintering process, the matrix performance is effectively protected while the compactness of the coating is ensured, the bonding strength and interface stability of the coating are improved through the design of the phenolic resin transition layer and the silicon bonding layer in cooperation with the rare earth silicate barrier layer, and the bonding strength of the coating is improved. And the coating shows excellent protection performance in a high-temperature corrosion environment.

The invention provides a self-repairing EVA adhesive film and a preparation method thereof, and relates to the technical field of solar photovoltaic module packaging. According to the self-repairable EVA adhesive film disclosed by the invention, through Diels-Alder reactive group grafting and silane coupling agent microencapsulation technologies, a dual self-repairing mechanism of a photovoltaic module packaging adhesive film is realized, and the dual self-repairing mechanism comprises physical rearrangement repairing and chemical bonding repairing; while high light transmittance (more than or equal to 90%) and bonding strength (more than or equal to 96 N / cm) are maintained, the aging resistance (delta YI is less than or equal to 3) of the EVA adhesive film is remarkably improved, the service life of the EVA adhesive film is remarkably prolonged, and the problems that a traditional EVA adhesive film is easy to age in an extreme environment and is easy to suffer from micro damage caused by mechanical stress are solved; the preparation process disclosed by the invention is compatible with the existing production line, and has a relatively high industrial application value.

The invention discloses a high-refractive-index nano-composite optical adhesive and a preparation method thereof, and belongs to the technical field of optical transparent adhesives. The optical adhesive is prepared by taking a polyurethane acrylate oligomer with a specific structure as matrix resin, introducing surface-modified barium titanate and zirconium oxide core-shell nanoparticles as a functional filler, and matching with an active diluent, a photoinitiator and a silane coupling agent in a specific proportion. Through the design of the core-shell structure, the core problems that the high-refractive-index nanoparticles are easy to agglomerate in an organic resin matrix, the dispersion stability is poor and the bonding force with a matrix interface is weak are effectively solved. The prepared optical adhesive has a refractive index of more than 1.65, a light transmittance of more than 99% and a haze of less than 0.3% after being cured, has excellent bonding strength, weather resistance and long-term use stability, and is especially suitable for precise lamination of high-end display devices (such as OLEDs (Organic Light Emitting Diodes) and micro-lens arrays).

The invention discloses a high-strength wear-resistant self-lubricating drill bit for a coal mine and a preparation method of the high-strength wear-resistant self-lubricating drill bit. The preparation process comprises the steps that a drill bit blank is prepared from low-alloy carbon structural steel, a high-strength and high-toughness matrix is obtained through thermal refining, and then sand blasting activation is conducted to clean and coarsen the surface. After diamond particles are subjected to acid pickling pretreatment, metal modified diamond composite powder is obtained through salt bath metal and reduction prefabrication. The preparation method comprises the following steps: mixing MoS2 with the carbon dioxide, spraying the mixture on the surface of a matrix through high velocity oxy-fuel to form a wear-resistant coating, and then improving the density and interface bonding strength of the coating through high-frequency induction instantaneous remelting, thereby finally obtaining the coal mine drill bit with high hardness, strong bonding force and self-lubricating performance. The metal modified diamond composite coating containing the metal transition layer and the MoS2 lubricating phase is constructed on the steel substrate, and a high-frequency remelting process is combined, so that the wear resistance, the bonding strength and the self-lubricating performance of the drill bit are synergistically improved, and the drill bit has the advantages of high strength and toughness matching and low cost.

The invention relates to the technical field of organic polymer adhesives, and particularly discloses a modified castor oil-based polyurethane adhesive as well as a preparation method and application thereof. The adhesive comprises two components, and the component A comprises the following components in parts by weight: 30.0-50.0 parts of modified castor oil and 0.0-30.0 parts of refined castor oil; the component B is prepared from the following components in parts by weight: 30.0 to 50.0 parts of polyisocyanate or a polyisocyanate modifier and 0.00 to 0.05 part of a dewatering agent; the modified castor oil is prepared from refined castor oil and cysteamine through a sulfydryl-alkene addition reaction. Amido of the modified castor oil is alkalescent, and the reaction speed of the modified castor oil and isocyanate groups is high; hydrogen bonds are easily generated between urea bonds generated by the reaction of amino groups and isocyanate groups, so that the adhesive is endowed with thixotropy and high strength. The adhesive disclosed by the invention is simple in composition, high in reaction speed and good in thixotropy and bonding strength.

The invention relates to the technical field of 3D printing, and discloses a fiber reinforced composite material 3D printer and a printing method, current deposition tows are heated / cooled under the action of a preset interlayer pressing force through an interlayer pressing device, interlayer fusion can be promoted, the interlayer bonding strength can be improved, the heat history in the wire cooling process can be eliminated, and the 3D printing quality of the fiber reinforced composite material is improved. The crystallization behavior, the grain size and the grain distribution of a polymer in a printing wire material are controlled, and the microscopic uniformity of a composite material printing product is improved. The side face and the upper surface of the current deposition tow are subjected to hot-pressing shaping through the inter-channel pressing device, meanwhile, secondary hot-pressing is conducted on the adjacent printing layer deposition tow, resin of the current deposition tow and resin of the adjacent printing layer deposition tow can be melted and flow, so that the inter-channel gap between the adjacent printing layers is filled, and the printing effect is improved. And the inter-track bonding strength is improved.

The invention provides a thermal barrier coating with an interface three-dimensional bionic structure and a preparation method and application of the thermal barrier coating, and belongs to the technical field of thermal barrier coatings. By means of 3D printing, preparation of a complex, special and arrangement-distribution-controllable three-dimensional texture component with a complex geometrical shape and an internal structure can be achieved, and therefore the coating interface residual stress, the contact area and the pinning effect are improved; 3D printing can avoid internal oxidation of the bonding layer, and meanwhile it is ensured that the structure of the multi-level interface is uniform and stable; and then the ceramic layer is prepared by combining the spraying technology, preparation of the interface three-dimensional bionic structure thermal barrier coating is achieved, interface mechanical engagement of the bonding layer and the ceramic layer can be increased through the structure, an interlocking mechanism is achieved, the coating interface structure and residual stress are improved, and therefore the service life of the coating is greatly prolonged, and the bonding strength of the coating is greatly improved.

The invention belongs to the technical field of building materials, and particularly relates to a micro-expansion anti-cracking waterproof composite deep groove filler and a preparation method thereof. The micro-bulking anti-cracking waterproof composite deep groove filler provided by the invention comprises cement, gypsum, mineral powder, nano silicon oxide, coarse aggregate, fine aggregate, modified fibers, an expanding agent, a polycarboxylate superplasticizer and water. According to the invention, polyacrylamide, calcium sulphoaluminate and magnesium oxide are adopted to jointly form an expanding agent, and early-stage-late-stage full-period shrinkage compensation is jointly formed in a concrete hydration process, so that the density of the concrete is effectively improved, and the waterproof performance of the concrete is further improved; according to the invention, sodium dodecyl benzene sulfonate and propylene glycol block polyether are adopted to carry out compound modification on graphene oxide, and gamma-aminopropyltriethoxysilane is connected to the surface of basalt fiber, so that the bonding strength of basalt fiber and a cement matrix and the compactness of the cement matrix are improved, and the waterproof and anti-cracking properties of concrete are further improved.

The present invention relates to the technical field of tackified adhesive films and specifically to a tackified adhesive film. The tackified adhesive film comprises a substrate layer and a UV-tackified adhesive layer applied onto the substrate layer. The UV-tackified adhesive layer is prepared by using a modified polyester resin, which is obtained by the graft polymerization of a hydroxyl-terminated polyester resin, butyl methacrylate, and isocyanatoethyl methacrylate, as a main resin and mixing the main resin with a tackifying resin, a photo-curing agent and the like. The UV-tackified adhesive layer has relatively high cohesive strength and relatively good adhesion to a PET substrate. Before a UV-induced tackification reaction, an initial peel force is not significantly increased with the extension of standing time, so that an adhesive tape can be easily removed without causing damage and contamination such as residual adhesive to an adherend . After the UV-induced tackification reaction, the modified polyester resin can improve the bonding strength between the adhesive tape and the adherend.

The invention relates to the technical field of automobile parts, in particular to an automobile rubber sealing part and a preparation method thereof. A metal framework base material is stamped in a numerical control mode, and a framework blank is obtained by controlling deviation through a positioning pin; after being slightly roughened, the blank is phosphatized, coated with a special rubber prime coat adhesive and subjected to infrared drying; weighing the raw materials according to the ratio, feeding into an internal mixer by stages, and mixing at controlled temperature and speed to obtain a rubber compound; feeding the mixed rubber into a double-roller open mill to press a continuous rubber sheet in a step-by-step distance-adjusting manner; performing hydraulic cutting by a special cutting die to obtain a slightly large formed rubber sheet; sticking the molded film to the framework into a mold with a positioning boss, exhausting, boosting and vulcanizing to obtain a semi-finished product; feeding the semi-finished product into a hot air oven and introducing nitrogen for secondary vulcanization; and carrying out laser thickness measurement and visual inspection, packaging qualified products in an anti-static manner, and sealing in a corrugated carton. The framework precision and the rubber bonding strength are improved, and degumming is avoided; stable rubber material performance and uniform rubber sheet thickness are guaranteed, and material shortage is reduced; vulcanization displacement and bubbles are prevented, rubber oxidation and aging are inhibited, and the durability and stability of the product are improved.

The invention belongs to the technical field of thermal power heating surface treatment, and provides a gradient functional composite coating applied to a boiler heating surface and a preparation method of the gradient functional composite coating in order to solve the technical problems that an existing protective coating of the boiler heating surface is prone to abrasion and oxidation and high in cost. Collaborative design is formed, and gradient matching of mechanical properties and environmental failure resistance is achieved. The low-melting-point glass powder is combined with the rare earth catalytic effect, low-temperature ceramization is achieved, and thermal damage to a matrix is avoided. After the metal ceramic transition layer is sprayed, high-frequency induction remelting treatment is carried out, meanwhile, laser cladding is carried out on the surface of the ceramic surface layer, a nanocrystalline-amorphous composite structure is formed, and the bonding strength of the coating is improved.

The invention belongs to the technical field of thermal power heating surface treatment, and provides a multi-layer composite self-repairing anti-oxidation coating for a boiler heating surface and a preparation method of the multi-layer composite self-repairing anti-oxidation coating aiming at the technical problems that a thermal power boiler heating surface protective coating is insufficient in bonding strength, insufficient in long-term anti-oxidation capacity and concentrated in interface stress among multi-layer structures. Comprising a bonding layer, a gradient transition layer, a self-repairing functional layer and a ceramic surface layer which are sequentially arranged from inside to outside. The self-repairing functional layer is made of NiCoCrAlY alloy, the bonding layer is made of NiCrAlY alloy, the gradient transition layer comprises four layers of gradient transition layer units, each layer of gradient transition layer unit comprises a gradient composite structure of NiCrAlY and nano Al2O3, the self-repairing functional layer comprises NiCoCrAlY serving as a base body, thermal response type microcapsules are embedded in the NiCoCrAlY base body, and the ceramic surface layer comprises a nano ceramic material composed of Cr, Co, Ni, Fe, Al, Ti and B elements.

The invention discloses a basalt fiber reinforced ceramic tile binder and a preparation method thereof, and belongs to the technical field of ceramic tile binders. The basalt fiber reinforced ceramic tile binder is prepared from the following raw materials in parts by weight: 30 to 35 parts of cement, 40 to 50 parts of quartz sand, 1 to 2 parts of basalt fiber, 5 to 8 parts of calcium formate, 1 to 3 parts of redispersible latex powder, 1 to 1.5 parts of organic silicon modified polyurethane and 0.2 to 0.5 part of cellulose ether. The basalt fiber reinforced ceramic tile binder prepared by the invention has the advantages of relatively low slippage distance, good tensile bonding strength, water resistance, high temperature resistance and freeze thawing resistance stability.

The invention discloses a full-automatic vehicle film laminating machine and a hot-pressing compounding process thereof, and aims to improve the production efficiency of a vehicle film and the adhesive force of a film layer. The laminating machine comprises an electrostatic spraying chamber and a hot pressing chamber, and efficient compounding of membrane materials is achieved through the synergistic effect of the electrostatic spraying chamber and the hot pressing chamber; a film material is automatically fed into a laminating machine through an upper-layer film leading-in roller and a base material film leading-in roller, after the film material enters an electrostatic spraying chamber, the surface of the film material is subjected to corona treatment, and a nano coating solution is uniformly sprayed on the surface of an upper-layer film through an atomizer; meanwhile, redundant charged particles on the surface of the substrate film are collected through an electrostatic collection plate; the sprayed membrane material enters a hot-pressing chamber, and is heated and pressurized under the action of a hot-pressing roller, so that the two layers of membranes are tightly combined, and the high bonding strength between the membrane layers is ensured; and finally, the finished product film material is wound through a finished product storage roller, and a high-quality vehicle film product is formed.

The invention relates to the field of building materials, and discloses high-toughness and high-energy-absorption polymer emulsion modified mortar and a preparation method thereof, and the mortar is composed of ordinary Portland cement, river sand, a polymer emulsion, water, an active admixture and chopped fibers. Wherein the polymer emulsion is selected from styrene-acrylic emulsion (SBR), ethylene-vinyl acetate (EVA), polyurethane emulsion or a combination thereof; the mixing amount is 5-20wt% of the mass of the cementing material. According to the invention, a viscoelastic network is formed in a cement matrix through the polymer emulsion, and the synergistic effect of the active admixture and the chopped fibers is combined, so that the bonding strength, the crack resistance, the impact resistance and the stress wave dissipation capability of the mortar are remarkably improved. Test results show that the mortar provided by the invention is obviously superior to ordinary mortar in the aspects of 28d breaking strength, impact toughness and stress wave attenuation performance, and is suitable for high-performance constructional engineering and protective engineering.

The invention discloses a high-temperature-resistant high-stripping organic silicon pressure-sensitive adhesive and a preparation method thereof, and relates to a pressure-sensitive adhesive and a preparation method thereof. The invention aims to solve the problems of insufficient temperature resistance, low peel strength and poor binding force with a base material of the existing organic silicon pressure-sensitive adhesive. According to the invention, phenyl siloxane rubber, hydroxyl-terminated polysiloxane and methyl vinyl MQ silicon resin are used as basic raw materials, and polysilazane is used as a heat-resistant modifier to carry out heat-resistant modification on the chemical structure of the pressure-sensitive adhesive; a trifunctional allyl silane monomer is added in the film preparation process, so that the crosslinking density of the system is improved, and the heat resistance of the pressure-sensitive adhesive is further improved; the bonding force between the pressure-sensitive adhesive and a polyimide substrate is improved by adding the peroxysilane coupling agent, and the use of a primer in the coating process is omitted; by adding the hydroxyl MQ silicon resin and the phosphate adhesion promoter, the bonding strength of the pressure-sensitive adhesive is improved, and the high-temperature-resistant and high-stripping organic silicon pressure-sensitive adhesive is prepared. According to the invention, the high-temperature-resistant and high-stripping organic silicon pressure-sensitive adhesive can be obtained.

The invention relates to the technical field of coating materials, and particularly discloses a metallurgical strengthening preparation process of a wear-resistant coating of a high-stress valve ball. Comprising the following steps that S1, a porous structure supporting layer is prepared, specifically, cobalt-based alloy powder and a pore forming agent are mixed according to the mass ratio of (85-92): (8-15), and a porous middle layer is formed on the surface of a sphere base body through sintering; s2, coating slurry is injected; s3, sintering is carried out; s4, carrying out laser micro-texture treatment; s5, embedding a solid lubricant; s6, performing hot isostatic pressing densification; and S7, vibration auxiliary polishing is conducted. The metallurgical strengthening preparation process for the wear-resistant coating of the high-stress valve ball can be used for surface strengthening treatment of high-parameter valve core ball parts in the fields of petrochemical engineering, electrical energy, aerospace and the like, and has the advantages of high bonding strength between the coating and a matrix, excellent high-temperature wear resistance and thermal shock resistance, stable friction coefficient, long service life, high wear resistance and the like. And the method has the advantages of high process adaptability and low bonding failure risk.

The utility model discloses a high-strength assembly type building wallboard, which relates to the technical field of building wallboards, and comprises wallboard main bodies, a splicing frame is arranged between the two wallboard main bodies, the left side and the right side of the splicing frame are respectively provided with an assembly sliding groove, and the left side and the right side of each wallboard main body are respectively and fixedly connected with an assembly sliding plate. According to the utility model, the assembling sliding plate slides downwards and is inserted along the assembling sliding groove, so that the two wallboard main bodies and the splicing frame are spliced together, then cement can be injected into the formed pouring cavity, then the cover plate covers the top of the splicing frame, and after the cement is dry and hard, the assembling is completed; cement pouring can be used for filling gaps at the connecting positions to form an integral structure, loads can be effectively dispersed, shearing force can be effectively resisted, the bonding strength of cement is high, firm connection between the two wallboard bodies and the splicing frame can be ensured, and therefore the strength and the sound insulation and heat preservation effect after the wallboard bodies are assembled are improved.

The invention belongs to the technical field of rubber auxiliaries and rubber tracks, and particularly relates to a coupling agent composition for inhibiting rubber appearance flooding and application of the coupling agent composition in the rubber tracks. The coupling agent composition comprises the following components in percentage by weight: 15%-30% of coupling agent, 1%-15% of metal chloride and 70%-85% of clay mineral. Different from a microcapsule technology only aiming at anti-aging agent migration, the coupling agent composition disclosed by the invention can effectively capture various types of color-flooding source substances including carbon black residues, anti-aging agents, antioxidants and the like by starting from common characteristics (containing unsaturated bonds, heteroatoms and aromatic structures) of color-flooding small molecules and through the synergistic effect of the coupling agent and metal ions, so that the color-flooding source substances can be effectively captured. And the method has wide applicability. In addition, a composite system composed of the clay, the coupling agent and the metal chloride can improve the bonding strength of the rubber and a track framework material, and is suitable for being applied to a heavy-load rubber track.

The invention discloses high-strength durable pervious concrete and a preparation method thereof, and belongs to the technical field of building materials. The concrete is prepared from the following raw materials in parts by weight: 160 to 220 parts of cement, 1200 to 1600 parts of coarse aggregate, 170 to 230 parts of fine sand, 160 to 200 parts of water, 3 to 4.5 parts of polycarboxylate superplasticizer, 5 to 15 parts of silica fume, 1 to 3 parts of polypropylene fiber, 8 to 12 parts of modified nano cellulose and 5 to 7 parts of flexibilizer, wherein the flexibilizer comprises modified graphene oxide, propylene glycol monomethyl ether and polyisoprene rubber. The interface compatibility is enhanced through the modified nanocellulose, microcracks are reduced, the bonding strength of aggregate and cement is improved, and the compressive strength is improved; the toughening agent component endows the concrete with toughness and durability, the toughening agent component and the toughening agent component have a synergistic effect, and the concrete prepared by mixing the various raw materials has excellent mechanical properties and durability on the basis of good water permeability, and has a wide market application prospect.

The invention relates to the technical field of adhesives, and particularly discloses a low-formaldehyde environment-friendly adhesive and a preparation method thereof. The invention relates to a low-formaldehyde environment-friendly adhesive which is prepared from the following raw materials in parts by mass: 30-50 parts of modified starch, 15-25 parts of vegetable protein, 5-10 parts of modified nano cellulose, 2-5 parts of a composite cross-linking agent and 80-150 parts of water, the composite cross-linking agent comprises amino silane and polyaspartic acid; the modified starch is prepared by performing graft copolymerization on starch subjected to enzymolysis by alpha-amylase and composite anhydride; the vegetable protein is subjected to alkalization and heat treatment before being used; the modified nano-crystalline cellulose is prepared by performing ring-opening etherification reaction on nano-crystalline cellulose, epoxypropane and ethylene oxide in sequence. The low-formaldehyde environment-friendly adhesive prepared by the invention has relatively good bonding strength and relatively low formaldehyde emission.

A frame terminal 8 is bent so that its cross-sectional shape is an S-shape, and such that separation distances L1, L2 and L3 in a horizontal direction between an uppermost portion and a lowermost portion, in the vertical direction, of an end portion side face 21a of a resistance element 8 built into a mold divider 1, and a part substantially midway between an uppermost point and a lowermost point thereof, and the parts of the surface of the frame terminal 6 that correspond to these parts in the horizontal direction satisfy the relation L1>L2≥L3. As a result, in the mold divider 1, a space which is to be filled with a joining material and which has a non-uniform separation distance is formed between the frame terminal 6 and the end portion side face 21a, thereby making it possible to ensure the bonding strength between the resistance element 8 and the frame terminal 6.

The invention relates to a preparation, regulation and control method of a thermoplastic elastomer encapsulating material in the technical field of new materials, which comprises the following steps: realizing an in-situ reaction process by controlling the concentration and reaction temperature of reactive functional groups in the encapsulating material according to an interface reaction rate constant and active group distribution density; if the reaction conversion rate reaches a preset value, a chemically bonded interface bonding layer is formed; monitoring the stress distribution state in the rubber coating layer by adopting a stress analysis algorithm, and when detecting that local stress concentration exceeds the yield strength of the material, dispersing a stress concentration area by adjusting the length of a flexible chain segment and the density of a rigid cross-linking point in a cross-linking network; and deformation data and a bonding strength change trend of the interface bonding layer in the temperature cycling process are obtained, if the bonding strength attenuation rate exceeds a preset threshold value, a dynamic cross-linking mechanism is activated, and the dynamic equilibrium state of interface bonding is maintained through fracture and recombination of a reversible covalent bond.

The invention discloses a method and a device for detecting the bonding strength of a coating, and belongs to the technical field of coating detection. The method for detecting the bonding strength of the coating comprises the following steps: respectively bombarding test areas of a plurality of samples to be detected by adopting first laser according to different control parameters; the method comprises the following steps: detecting the falling degree of a coating in a test area of each to-be-tested sample from a substrate, and judging whether the falling degree reaches a set degree or not; taking the control parameter of the first laser corresponding to the to-be-detected sample with the falling degree reaching the set degree as a critical control parameter; and controlling the first laser to bombard a coating area of a to-be-tested product with the same model as the to-be-tested sample according to the critical control parameter, and evaluating the coating bonding strength of the to-be-tested product according to the surface appearance of the to-be-tested product. The coating bonding strength can be measured without contact with the coating, matrix damage is avoided, detection precision and detection efficiency can be improved, manual intervention is reduced, cost is reduced, and environmental pollution is avoided.

The invention discloses a stainless steel surface treatment method and a stainless steel material. The stainless steel surface treatment method comprises the following steps: S1, carrying out roughening pretreatment on a stainless steel substrate; s2, NiCr-Cr3C2 gas atomization powder is adopted as a raw material; and S3, the raw materials are sprayed on the surface of the stainless steel base body in a cold spraying mode, and the corrosion-resistant coating is formed on the surface of the stainless steel base body. The NiCr-Cr3C2 powder is used as the raw material, the corrosion-resistant coating is formed on the surface of the stainless steel in a cold spraying mode, high bonding strength, low porosity and excellent corrosion resistance are achieved, and the comprehensive service performance of the stainless steel material in nuclear power, chemical engineering, ocean and other extreme environments can be remarkably improved.

The invention belongs to the technical field of hard alloy surface engineering, and particularly relates to an MT-TiCN gradient coating of a hard alloy cutter and a preparation method of the MT-TiCN gradient coating. The coating sequentially comprises a TiN bottom layer, an MT-TiCN gradient layer, a transition layer and an Al2O3 layer from inside to outside, wherein the C / N atomic proportion of the MT-TiCN gradient layer is in gradient distribution from rich N to rich C in the thickness direction. The coating is prepared through a medium-temperature chemical vapor deposition process, the internal stress of the coating is effectively relieved, and the bonding strength, toughness and wear resistance of the coating and a matrix are remarkably improved.

The invention discloses an anti-oxidation coating and a manufacturing method thereof, and belongs to the field of coatings. The anti-oxidation coating is arranged on the surface of a zirconium alloy matrix, the anti-oxidation coating is a pure Cr coating, the hardness of the anti-oxidation coating is in gradient distribution in the thickness direction, the hardness of a surface layer is larger than that of a bottom layer, and the hardness gt of the bottom layer of the anti-oxidation coating is larger than that of gt; the hardness gt at the 1 / 2 thickness is 4GPa; the hardness of the surface layer is gt; and 6 GPa. Good bonding strength is achieved between the anti-oxidation coating and the zirconium alloy matrix, cracks are not prone to being generated on a bonding interface when the anti-oxidation coating serves in a long-term high-temperature and high-pressure corrosion environment, the service life of the zirconium alloy matrix can be effectively prolonged, and the reliability of the zirconium alloy matrix can be effectively improved.

The invention provides an epoxy adhesive solution composition, a preparation method of an epoxy adhesive solution and a modified cellular board. The epoxy adhesive liquid composition comprises the following components in parts by weight: 53-58 parts of epoxy resin, 2-10 parts of a silane coupling agent, 1-10 parts of a curing agent, 1-5 parts of blocked isocyanate and 60-70 parts of water, wherein a blocking group of the blocked isocyanate is selected from hydroxyl, oximido, acylamino, amino, imidazolyl, pyrazolyl or piperazinyl. By introducing the blocked isocyanate with the specific structure, the epoxy adhesive liquid can be subjected to pre-crosslinking reaction in the early drying treatment process, the modulus and high temperature resistance of a formed dry film are improved, and the phenomenon of glue overflow in the subsequent curing stage is inhibited; therefore, the structural integrity and the bonding strength of the adhesive layer in the modified cellular board under the high-temperature condition are improved.

The invention relates to the technical field of synthetic leather, in particular to super-soft waterborne polyurethane leather and a preparation method thereof. The leather sequentially comprises a surface layer, a middle layer and a bottom layer from top to bottom, wherein the surface layer is composed of a PCL-PEG-PCL flexible film; the bottom layer is composed of base cloth and a PCL-PEG-PCL flexible film coated on the surface of the base cloth; and the middle layer is composed of modified waterborne polyurethane prepared from PCL-PEG-PCL flexible dihydric alcohol and aliphatic linear chain diisocyanate. The preparation method comprises the following steps: synthesizing PCL-PEG-PCL dihydric alcohol, preparing each layer, and performing condensation reaction on the middle layer and the surface / bottom layer to realize chemical curing. The leather is normally super-soft, the stress strength is remarkably improved, a full-water-based system is environment-friendly, the low-temperature stability and interlayer binding strength are excellent, and the leather is suitable for the field of high-end flexible materials such as furniture veneers, automobile interiors and shoe materials.