This invention discloses a method for improving the adhesion of fluororubber surfaces, aiming to solve the defects of existing fluororubber
surface modification technologies, such as low
adhesion strength, poor stability, narrow applicability, and environmentally unfriendly processes. The method is achieved through the following steps: 1. Pre-treatment of the fluororubber surface, removing oil and impurities and
drying; 2. Preparation of a composite
silane treatment agent, dispersing four
silane coupling agents containing olefins, cyano groups, amino groups, and peroxy groups in an alcoholic
solvent according to a specific mixing order, sealing and storing for later use; 3. Construction of a composite molecular layer,
coating the treatment agent onto the fluororubber surface and pre-curing; 4. Bonding and
vulcanization curing, allowing the fluororubber coated with the composite molecular layer to be bonded to the substrate and simultaneously vulcanized. This invention overcomes the
bottleneck of low reactivity of fluororubber surfaces by synergistically constructing a three-in-one composite molecular layer of "reactive layer - polar bonding layer - flexible entanglement layer" using multiple
silanes, achieving stable adhesion between fluororubber with different
vulcanization systems and various
metal / resin substrates. Its initial peel strength is ≥850N / m, and its strength
retention rate after immersion in
aviation hydraulic oil at 200℃ is ≥91.9%. The process is simple and
environmentally friendly, and it is suitable for harsh working conditions such as
aerospace and automotive power systems, and has important industrial application value.