1859results about "Aldehyde/ketone condensation polymer adhesives" patented technology

Building panels with a thin and embossed surface layer and a sub layer between a surface layer and a core.

An organic electroluminescence device which includes a power line formed on the same layer as source and drain electrodes of a thin film transistor (TFT) and formed on a substrate on which the TFT is formed, a first insulating layer formed on the TFT, a lower electrode that electrically connected to one of the source and drain electrodes of the TFT and disposed on the first insulating layer, a first auxiliary power line and a second auxiliary power line formed on the same layer as the lower electrode in the second insulating layer, a second insulating layer formed on an edge portion of the lower electrode and not formed on the second auxiliary power line, wherein an opening that exposes a portion of the lower electrode is formed, an organic film formed on a substrate; and an upper electrode formed on the substrate.

This invention is directed to a method of preparing a natural resin by liquefying wood, bark, forest residues, wood industry residues, or other biomass using rapid destructive distillation (fast pyrolysis). Fast pyrolysis produces both vapors and char from biomass, and following removal of the char from the product vapors, a liquid pitch product is recovered and processed by distillation, evaporation, or a combination thereof, in order to obtain a natural resin which may be in either liquid or solid form. The natural resin comprises a total phenolic content from about 30% to about 80% (w/w), and is a highly-reactive ligninic compound that has been found to be suitable for use within resin formulations without requiring any further extraction or fractionation procedures. Resins comprising up to 60% natural resin have been prepared and tested in board production and found to exhibit similar properties associated with commercially available resins. The natural resin may substitute for phenol, or for both phenol and formaldehyde within phenol-containing resins. Similarly, the natural resin can replace a substantial part of the components within urea-containing resins.

The invention relates to adhesive for collecting formaldehyde and paint for collecting the formaldehyde, both of which use formaldehyde collecting agent as a composition of active components. The adhesive is used for adhesion of the outmost layer in a man-made board or adhesion and edge sealing at a kerf of the man-made board, can effectively absorb formaldehyde released by the man-made board, does not cause influence on the adhesive strength of the board, and is comparatively cheap. The paint is used for painting indoor walls, absorbs the formaldehyde in the indoor air, can also be used for painting the surface of the man-made board, seals and absorbs formaldehyde gas, and reduces the release amount of the formaldehyde. Compared with the prior art, the adhesive and the paint for collecting the formaldehyde have the advantages that the adhesive and the paint are cheap, can efficiently adsorb the formaldehyde and generate stable compounds, and do not re-decompose and release the formaldehyde, so the adhesive and the paint cannot generate other secondary pollutants.

A moisture-curable adhesive composition that may be formulated to be free of volatile organic compounds, or substantially free of volatile organic compounds which is safe for chronic exposure, resistant to combustion, and provides a high peel strength useful for securing a rubber membrane material to a rigid roof deck includes a polymer having silicon-containing hydrolyzable terminal groups, a phenolic resin, and a non-polymeric silicon-containing hydrolyzable compound, wherein the ratio of the amount of polymer having silicon-containing hydrolyzable terminal groups by weight to the amount of phenolic resin by weight is greater than 2:1.

A method for attaching a substrate such as a semiconductor wafer in which cracking or chipping can be prevented when the substrate is thinned involves applying adhesive liquid onto a circuit (element)-formed surface of a semiconductor wafer. The adhesive liquid undergoes preliminary drying, so that its flowability is reduced and it can keep its shape as an adhesive layer. For the preliminary drying, heating is conducted for 5 minutes at a temperature of 80° C. by using an oven. The thickness of the adhesive layer is determined based on the irregularities of the circuit which has been formed on the surface of the semiconductor wafer. Next, a supporting plate is attached to the semiconductor wafer on which the adhesive layer of a desired thickness has been formed.

The invention provides a production method for a melamine modified urea-formaldehyde resin with low residual quantity of formaldehyde. Main raw materials used in the invention comprise formaldehyde, melamine and urea, wherein formaldehyde is fed in one step, and urea is fed in three steps. Production of the urea-formaldehyde resin comprises the three stages of prepolymerization, polymerization and later polymerization; the addition amounts of urea and reaction temperatures in each stage are different; the phenomenon of gelatinization is avoided in the process of polymerization by using the production method; the obtained urea-formaldehyde resin has narrow molecular weight distribution and low residual quantity of formaldehyde, is used for production of artificial boards and can reduce formaldehyde emission of the artificial boards.

The invention discloses a method for producing a flame-retardant veneer plywood, which comprises the following steps: placing wood veneers into a flame retardant aqueous solution to perform dipping treatment, applying the mixed adhesive to the upper surfaces and the lower surfaces of the veneers after the veneers are dried, assembling the veneers into a plate blank according to the principle that odd layers are crossed and symmetrical with even layers, and then performing the processes of cold pressing, hot pressing, cutting edge, sanding, surface treating and the like to obtain the flame-retardant veneer plywood product the thickness of which is between 2.7 and 20 millimeters. The flame retardant in the method is a mixture of low ammonium polyphosphate, ammonium phosphate, ammonium pyrophosphate, urea phosphate, boric acid and pentaerythritol, and the mixed adhesive is a uniform mixture of wood adhesive, filler, and a curing agent. The flame-retardant decorative veneer plywood prepared by the method has the advantages of excellent flame-retardant and fireproof performance, environmental prevention performance, and good mechanical properties.

The invention discloses a flexible substrate used for optoelectronic devices and comprises a flexible substrate; the invention is characterized in that a bonding layer and a conductive thin film are arranged on the surface of the flexible substrate; the conductive thin film is deposited on the surface of the bonding layer; and the material of the bonding layer is an adhesive with a double-curing system comprising UV curing-thermal curing or UV curing-microwave curing or UV curing-anaerobic curing or UV curing-electron beam curing. The substrate solves the problem of poor adhesion between the deposited conductive thin film and the substrate due to low surface energy of the flexible substrate and improves the barrier properties of the substrate on water and oxygen, and also achieves good smoothing effect on the surface of the substrate; besides, the preparation method is simple and effective, which can significantly reduce the substrate production cost and process difficulty and increase the substrate yield rate in the etching process.

A method for preparing alkali lignin modified phenol-formaldehyde resin comprises the following steps: phenol, a first batch of formaldehyde solution, alkali lignin, metal oxide and dilution water are added into a reactor; a second batch of formaldehyde solution is added into the reactor; and a third batch of formaldehyde solution and a first batch of alkaline solution are added, formaldehyde trapping agent and a second batch of alkaline solution are added, and then material is discharged after cooling. The invention adopts the copolymerization technique to prepare an alkali lignin phenol formaldehyde adhesive, lignin and the phenol are added simultaneously, obtained hydroxymethylated lignin is reacted with hydroxymethyl phenol, a small part of the obtained hydroxymethylated lignin participates in the polycondensation of the hydroxymethyl phenol to form a main chain, and a large part of the obtained hydroxymethylated lignin forms branch chains through graft copolymerization, therefore, the lignin is introduced into a molecular chain and the aim of modifying phenol-formaldehyde resin is achieved. The invention can replace the use of 30-50 percent of the phenol, realizes stable and easy reaction control and easy industrial production; the bonding strength satisfies the requirements of national I-level plates; formaldehyde release reaches E0 level; therefore, the invention provides a new approach to the development of environment-friendly biomass-based wood adhesive and resource utilization of waste materials.

The invention provides a preparation method for phenolic adhesive based on lignin phenolization liquid and application thereof. Under the condition of normal pressure heating or thermalcatalysis, phenol is taken as liquefaction reagent, lignin is added, the temperature is raised to 90 to 150 DEG C, the thermal insulation liquefaction reaction is made to cool to obtain a lignin liquefaction product; basic catalyst and formaldehyde are directly added into the liquefaction liquid, the temperature is raised to 70 to 97 DEG C under normal pressure to react for 1 to 3 hours, the reaction is terminated when the viscosity is measured to meet the preset requirement, and low-free formaldehyde environmental protection type phenolic adhesive based on lignin phenolization liquid is obtained. The adhesive obtained by the invention has lower cost and lower content of free formaldehyde than the prior phenolic resin adhesive. The plywood pressed by using the adhesive obtained by the invention has good bonding performance.

The invention relates to a silver coated nickel powder conductive adhesive. The silver coated nickel powder conductive adhesive comprises, by mass, 40-90% of a conductive filler, 5-45% of a resin, 0.5-20% of a curing agent, 0-50% of a solvent and 0.1-20.0% of an assistant, and the conductive filler comprises at least one of micro-silver coated nickel powder and nano-silver coated nickel powder. The silver coated nickel powder conductive adhesive has the advantages of excellent conductivity, low cost, no lead, no halogens and the like. The invention also discloses a preparation method of the silver coated nickel powder conductive adhesive. The method is characterized in that the curing agent is added in a dispersion process after grinding, so the conductivity, the cementability, the viscosity and the like can be effectively regulated, and the untoward influences of the interaction of all components of the conductive adhesive in the dispersion and grinding processes to the storage, application and stability of the conductive adhesive are avoided.

A transfer film configured for transferring optical beads to a substrate is disclosed. The transfer film typically contains optical beads, a temporary bead carrier layer retaining the optical beads, and an optional adhesive layer configured to permanently adhere the optical beads to a substrate. The temporary bead carrier layer contains a carrier backing and a heat-resistant carrier coating that temporarily holds the beads during application at elevated temperatures to a substrate. The carrier coating is formed such that it initially softens to retain the beads, but is then hardened or thermoset (such as by crosslinking) to prevent the carrier coating from softening during transfer of the beads to a substrate.

The invention provides a preparation method of plywood of E0 grade. The urea formaldehyde resin adhesive has an advantage of simple preparation technology, good reproducibility, lower cost and long store time. By using the urea formaldehyde resin adhesive, the plywood/three-ply board/overlaying panel/multilayer board accord with the requirements of plywood of E0 in terms of the bonding strength and the formaldehyde emission. The method in the invention has the advantages that: the preparation of the urea formaldehyde resin adopts the alkali-acid-alkali traditional craft; the urea and the melamine are added in three times; the urea is added in three times which adjusts the quality of the resin molecule; especially, the urea, which is added in the second time, not only degrades and resets the large molecules but also decreases the content of the ether linkage and reduces the release of the formaldehyde; during the composite process, the pH value in the condensation polymerization is rigidly controlled; by the two-step condensation polymerization, the condensation polymerization can rapidly proceed in good order.

The invention discloses a method for making a clutch facing by using phenolic resin as adhesive. The method comprises the following steps that: (1) the latex modified water soluble phenolic resin is used as the adhesive to make the clutch facing, and water is used as solvent, and the adhesive and the solvent are mixed by stirring and prepared into pulp; (2) fibers are impregnated in the pulp; (3) fibers containing the pulp are dried; (4) the dried fibers containing the pulp are wound to become blanks; (5) blanks are heat moulded; (6) the clutch facing is obtained after subsequent treatments. The method of the invention has the advantages of saving a large amount of organic solvent, avoiding the environmental pollution caused by the consumption and the volatilization of the solvent, greatly saving the energy used for the preparation of the pulp and saving equipment cost on aspects of safety, fire fighting and environmental protection and management cost; moreover, the clutch facing made by the method of the invention is excellent in performance.

An adhesive binder composition containing a urea-formaldehyde resin modified with a protein, preferably with a source of soy protein and the use of the binder for preparing wood composites, especially particleboard.

An adhesive binder comprising a phenol-formaldehyde resin, polyvinyl ester resin, and a protein is disclosed. The adhesive binder is useful for preparing wood composites.

The invention provides a composite modification method for a phenolic resin adhesive. A mixture of organic silicon and (or) a polyhydric compound serves as a modifier in a synthetic process of phenolic resin. The composite modification method is technically characterized in that: the modifier is added in a prepolymerization reaction process or after the prepolymerization reaction; formaldehyde is added at one time under an alkaline condition; dehydration is not performed in the later period of the reaction; the whole process flow is simple and is easy to operate; the product has stable performance and does not pollute environment; and the content of free formaldehyde is low.

The invention relates to a production method of an environmental-friendly type low-cost middle and high density fiber board. Self-made modified urea-formaldehyde glue, a composite curing agent and a formaldehyde trapping agent are used in a glue blending procedure, wherein the modified urea-formaldehyde glue is prepared by heating formaldehyde, melamine and urea in a reaction kettle through a chemical reaction; the composite curing agent is prepared by mixing ammonium chloride, boric acid, oxalic acid and water; and the formaldehyde trapping agent is prepared from phosphoric acid, urea, a catalyst and water under a certain temperature condition. When the middle and high density fiber is produced, the application amount of the formaldehyde trapping agent is 3 percent or 4 percent of the weight of modified urea-formaldehyde glue solid, the application amount of the modified urea-formaldehyde glue solution is 12.5 percent of the weight of absolute dried fiber, and the application amount of the composite curing agent is 3 percent or 2 percent of the weight of the modified urea-formaldehyde glue solution. The middle and high density fiber board produced using the three ingredients can completely meet Eo level environmental-friendly requirements, has good compatibility and high bonding strength and greatly reduces production cost of the fiber board.

The invention discloses a binder and making method of modified urea-formaldehyde resin, which comprises the following steps: adopting urea-formaldehyde resin, fill, reinforcer, deoxidation agent, formaldehyde catching agent, anti-aging agent, anti-shrinking agent, hardener and auxiliary reinforcer; adopting modified copolymer of acrylic acid, sodium acrylate, N, N-dimethylamino propyl methyl acrylamide as anti-shrinking agent; making polyacrylamide solution reacted by acrylamide and ammonium persulphate as formaldehyde catching agent; allocating each component according to proportion; blending evenly; casting; extracting into vacuum; stripping; stewing; drying naturally; coating a layer of polymethacrylate paint on the surface of product; proceeding colorful paint; obtaining the product.

The invention discloses a modified lignin and a urea-formaldehyde resin synthesized from same and preparation methods of the modified lignin and the urea-formaldehyde resin, belonging to the field of bonding agents used in wood processing. A technological synthetic route with weak base-weak acid-weak base is adopted, the molar ratio of formaldehyde to urea is controlled during an addition stage to generate a reasonable structure, the modified lignin as well as residual hydroxymethyl and free formaldehyde are added at the later stage of reaction in order to accomplish reaction, thus the content of methylene ether link (-CH2-O-CH2-) and the content of hydroxymethyl in the resin are reduced to a certain extent, the formaldehyde emission of the resin is lowered, and simultaneously, higher bonding strength and water resistance are ensured. The urea-formaldehyde resin in the invention is simple and brief in process and low in cost, the formaldehyde emission of the plate prepared by adoptingthe bonding agent reaches the E0-level standard and the plate can maintain high bonding strength after being cooked in hot water. The modified lignin is simple in synthesis method and low in cost andis especially suitable for the modification of the urea-formaldehyde resin with low molar ratio.

Branched, amorphous, polyester-based macropolyols having a narrow molecular weight distribution and a process for making the macropolyol.

The invention discloses a low release aldehyde adhesive agent which comprises in the proportion of urea formaldehyde condensate of 100 shears, filler of 18-25 shears, curing agent of 1.0-2.0 shears, reinforcing agent P of 1.0-2.0 shears and curing accelerating agent Pa of 0.06-0.12 shear, wherein the reinforcing agent P is a water-soluble polyisocyanates and process art of low release aldehyde adhesive agent comprises the following steps: A, the preparation of thiourea resin, B, adding the said thiourea resin in a container, running the agitator and adding the filler slowly, intimate mixing and adding the curing agent, intimate mixing adding the accelerating agent dissolved using water, stirring, meter adding addition agent P slowly and stirring to get the low release aldehyde adhesive agent. The said low release aldehyde adhesive agent can be used in binding between wood and wood. In the invention, the content of methyl aldehyde is decreased in the preparation process.

This invention provides a high performance electric conduction paste preparation. The mixed powder of argentine nanometer lines and argentine nanometer particles is produced in bulk with the method of ethylene glycoldeoxidizing argent nitrate. A neotype isotrope electric conduction paste is made with such mixed powder of argentine nanometer lines and argentine nanometer particles which is used as electric conduction bulking agent and filling epoxy resin and phenol formaldehyde resin. Compared with traditional electric conduction paste, this paste not only has outstanding electricity performance, but also has outstanding mechanics performance just because the reduction of bulking agent.

The powder molding additive belongs to a compound additive mainly composed of inorganic substances. It is composed of dimensioning agent 1-99% (weight), forming agent (1-99% (weight) and reinforcing agent, tackifier, toughening agent, and combustion agent. The present invention can be used for carbon-containing powder .Using carbon-containing substances to reduce substances, or mixing powders of the two, can also be used in fertilizers, chemicals, daily chemicals and other industries. It has no smoke caused by starch and has certain water resistance. No matter at low temperature or high temperature, the produced The products have the required strength and their cost is low.

The invention relates to a melamine-urea-formaldehyde copolycondensation resin (MUF) wood adhesive and a preparation method thereof, and belongs to the technical field of wood processing and production. The adhesive is formed through the copolycondensation of melamine (M), urea (U), formaldehyde (F) and amino-terminated hyperbranched polymer PAMAM, and is mainly characterized in that the formaldehyde and melamine are added at one step, urea is added at different times, PAMAM is added at the initial synthesis stage of the MUF resin. The MUF resin related to the invention belongs to resin with high content of melamine, the melamine accounts for 45% above the total amount of urea and melamine, wherein the formaldehyde and urea added for the first time are added at the initial reaction stage at one step, and then the PAMAM is added; after the urea added for the first time is added, the molar ratio of formaldehyde to urea is controlled above 3.0; the melamine is added at the middle and later alkaline stage; urea added for the second time is added at the later reaction stage. The melamine-urea-formaldehyde copolycondensation resin wood adhesive provided by the invention has the remarkable characteristics that the stability and performance are good, more importantly, and the storage period is long (lasting for longer than 5 months), and the adhesive can be applied to production of artificial boards, especially high hydrolytic-resistance artificial boards and laminated wood, and the like.

The invention relates to a process for preparing a liquid melamine urea formaldehyde resin that has long term stability. The invention also relates to a liquid MUF resin with a high formaldehyde and melamine content. The invention further relates to a liquid suspension hardener including a catalyst, a thickener, a filler, and water. The invention also relates to a adhesive composition for use in wood bonding that is made by adding a hardener to the resin.

The present invention relates to urea-formaldehyde resin, and is especially low toxicity urea-formaldehyde resin for E0 level veneer and its preparation process and application. The low toxicity urea-formaldehyde resin is prepared with formaldehyde 100 weight portions, PVA 1-1.5 weight portions, reinforcer 3.75-6 weight portions, alkaline catalyst 2000-2500 ml and acid catalyst 600-800 ml, and through reaction while controlling the molar ratio of the material, pH value and reaction temperature. It is applied as adhesive for veneer. The low toxicity urea-formaldehyde resin has the advantages of low free formaldehyde content, low cost, long storage life, high pre-pressing performance and high adhering strength; and the preparation process is simple and low in cost.

The invention relates to a new binder composition which is particularly suitable for the manufacture of composite materials utilizing such new binder composition in the required nonwoven materials. Composite materials using such new binder composition in their nonwoven part are suitable, in particular, for composites materials for interior construction, for linings, floor coverings, and for the manufacture of furniture and similar products.

The invention discloses an environmental-friendly urea-formaldehyde resin adhesive and a production method thereof. The production method comprises the following steps: lowering the traditional mol ratio (F/U) of the formaldehyde to urea into 0.94-1.0 from not less than 1.0; keeping the mol ratio basically unchanged after feeding the urea for the first time and the second time in the traditional process, increasing the urea amount for the third time, and adding a compound adjuvant which accounts for 0.1%-0.3% of the weight of the urea-formaldehyde resin adhesive for producing synergistic effect; in the acidic polycondensation stage, observing until a white vaporous shape appears in water at 40-45 DEG C by a muddy point method; and adjusting the pH value of a reactant into 6.5 from a traditional value of 7.5 so that the added urea for the second time can continuously participate in reaction, then observing until a white vaporous shape appears in water at 60-65 DEG C by the muddy point method for the second time, and finally ending reaction. The production method can obviously lower formaldehyde release of an artificial board and product cost of the adhesive, and ensure product quality of the urea-formaldehyde resin adhesive and physical and mechanical properties of the artificial board.