The invention relates to a low-temperature-resistant
epoxy resin adhesive and a preparation method thereof, and belongs to the technical field of
high polymer materials. The modified
epoxy resin adhesive comprises the following components in parts by weight: 90-120 parts of
epoxy resin, 8-24 parts of a curing agent, 1-3 parts of a
diluent, 0.5-5 parts of a curing accelerator, 4-18 parts of
graphite, 1-4 parts of a hyperbranched
polymerization flexibilizer and 10-30 parts of conductive filler,
polyimide in the hyperbranched
polymerization flexibilizer is difficult to crystallize, has no interchain winding, and cooperates with a flexible Si-O-Si
chain segment with high
bond energy and large bond angle to enhance low-temperature tensile strength and
toughness, and
chloroprene rubber effectively improves
impact resistance and bending resistance; according to the low-temperature-resistant epoxy
resin adhesive disclosed by the invention, a conductive network is constructed by
indium tin oxide, good
conductivity and
chemical corrosion resistance are given to a matrix, a
polyaniline layer is used for modifying a structural body and enhancing interface adhesion, and the prepared low-temperature-resistant epoxy resin
adhesive not only has good low-temperature-resistant
toughening and conductive effects, but also has excellent
corrosion-resistant and
flame-retardant effects.