The invention relates to an
epoxy resin adhesive composition and a preparation method thereof, and belongs to the technical field of high-performance
polymer material modification and
electronic packaging materials, and the
epoxy resin adhesive composition comprises the following components by weight: 100 parts of basic
epoxy resin; 5-30 parts of a hyperbranched
liquid crystal modifier; adding the curing agent according to a stoichiometric ratio; 100 to 600 parts of a heat-conducting filler; 0.1-5 parts of an
accelerant and an auxiliary agent; the hyperbranched
liquid crystal modifier has a core-shell structure and is prepared from a
hydrogen-containing hyperbranched polysiloxane core and an alkenyl-terminated
liquid crystal epoxy
monomer through a
hydrosilylation reaction under the action of a catalyst, the hyperbranched polysiloxane core is introduced, the friction resistance among high-concentration fillers is reduced by utilizing the torispherical structure of the hyperbranched polysiloxane core, and the hyperbranched liquid
crystal modifier has the advantages that the friction resistance is reduced; under the condition that 350 parts of heat-conducting filler is filled, the modifier is added, so that the high-filling
system still has excellent flowability and leveling property while keeping
high heat-conducting property, and is suitable for high-precision micro-encapsulation scenes; the heat
conductivity of the scheme is obviously superior to that of a
system which does not use the modifier or does not adopt a stepped heating process.