18014 results about "Acrylic acid" patented technology

There are disclosed a water-absorbent resin composition and its production process, wherein the water-absorbent resin composition causes little gel-blocking and is excellent in the liquid permeability and liquid diffusibility and is high also in the absorption performances and further is strong also against the physical damage; and there are further disclosed a water-absorbent resin composition and its production process, wherein the water-absorbent resin composition has the following further advantages, in addition to the above, of involving little segregation of the metal compound and further having a dust prevention effect. One of water-absorbent resin compositions according to the present invention is a water-absorbent resin composition comprising water-absorbent resin particles obtained by polymerizing a monomer including acrylic acid and/or its salt, with the composition having a mass-average particle diameter of 100 to 600 μm and comprising water-soluble polyvalent metal salt particles and the water-absorbent resin particles that have been surface-crosslinked.

There is disclosed a water-absorbing agent which combines both performances of the capillary suction force and the liquid permeability. This water-absorbing agent is a particulate water-absorbing agent comprising water-absorbent resin particles (α) and a liquid-permeability-enhancing agent (β), wherein the water-absorbent resin particles (α) are surface-crosslink-treated particles of a crosslinked polymer of a monomer including acrylic acid and/or its salt; with the water-absorbing agent being characterized in that the particulate water-absorbing agent has: a mass-average particle diameter (D50) in the range of 234 to 394 gm, a logarithmic standard deviation (σξY) of a particle diameter distribution in the range of 0.25 to 0.45, an absorption capacity without load (CRC) of not less than 15 g/g, and a water-extractable component content of not higher than 15 mass %; and further a liquid-permeability-enhancing agent (β) content in the range of 0.01 to 5 mass parts per 100 mass parts of the water-absorbent resin particles (α).

Blends of oligomeric urethane multi(meth)acrylate; optionally at least one other monomer selected from the group consisting of acrylic monomers, styrenic monomers and ethylenically unsaturated nitrogen heterocycles, preferably a polyol multi(meth)acrylate; and nanoparticles of an ethylenically unsaturated, preferably (meth)acrylic-functionalized, titanium or zirconium compound can be cured by ultraviolet radiation in contact with a photoinitiator to produce optical resinous articles having high refractive indices, haze ratings of at most 5% and other properties which may be tailored according to the desired use.

An object of the present invention is to provide: a water-absorbent resin which can sufficiently overcome the problem of the gel blocking, can manifest sufficient absorption capacity without load and sufficient absorption capacity under load and, at the same time, can also exert excellent liquid permeability under load; and a process for producing the same. As a means of achieving this object, a first production process among the processes according to the present invention for producing a water-absorbent resin having a treated surface is a process comprising: a step of mixing a water-absorbent resin having an internal crosslinked structure obtained by polymerizing a monomer containing acrylic acid and/or a salt thereof as a main component, a complex containing a polyvalent metal atom as a central atom and an organic secondary crosslinking agent in the presence of an aqueous liquid; and a step of crosslinking a surface of the water-absorbent resin with the organic secondary crosslinking agent. And a second production process is a process comprising a step of mixing a water-absorbent resin having an internal crosslinked structure and a crosslinked surface obtained by polymerizing a monomer containing acrylic acid and/or a salt thereof as a main component, and a complex containing a polyvalent metal atom as a central atom in the presence of an aqueous liquid.

The invention relates to a composite comprising a weight fraction of single-wall carbon nanotubes and at least one polar polymer wherein the composite has an electrical and/or thermal conductivity enhanced over that of the polymer alone. The invention also comprises a method for making this polymer composition. The present application provides composite compositions that, over a wide range of single-wall carbon nanotube loading, have electrical conductivities exceeding those known in the art by more than one order of magnitude. The electrical conductivity enhancement depends on the weight fraction (F) of the single-wall carbon nanotubes in the composite. The electrical conductivity of the composite of this invention is at least 5 Siemens per centimeter (S/cm) at (F) of 0.5 (i.e. where single-wall carbon nanotube loading weight represents half of the total composite weight), at least 1 S/cm at a F of 0.1, at least 1×10^{−4 S/cm at (F) of 0.004, at least 6×10−9} S/cm at (F) of 0.001 and at least 3×10⁻¹⁶ S/cm (F) plus the intrinsic conductivity of the polymer matrix material at of 0.0001. The thermal conductivity enhancement is in excess of 1 Watt/m-° K. The polar polymer can be polycarbonate, poly(acrylic acid), poly(acrylic acid), poly(methacrylic acid), polyoxide, polysulfide, polysulfone, polyamides, polyester, polyurethane, polyimide, poly(vinyl acetate), poly(vinyl alcohol), poly(vinyl chloride), poly(vinyl pyridine), poly(vinyl pyrrolidone), copolymers thereof and combinations thereof. The composite can further comprise a nonpolar polymer, such as, a polyolefin polymer, polyethylene, polypropylene, polybutene, polyisobutene, polyisoprene, polystyrene, copolymers thereof and combinations thereof.

An ink jet ink composition comprising an aqueous media and a pigment dispersion comprising a pigment and a polymeric dispersant wherein said polymeric dispersant is a copolymer comprising at least a hydrophobic methacrylate or acrylate monomer containing an aliphatic chain having greater than or equal to 12 carbons; and a hydrophilic methacrylic or acrylic acid monomer; wherein said copolymer comprises at least 10% by weight of the methacrylate or acrylate monomer and at least 5% by weight of the methacrylic or acrylic acid monomer; and wherein the copolymer comprises, in total, 20 to 95 weight % of hydrophobic monomer.

A golf ball has a cover member and a core member. The cover member contains: 3 to 30 parts by weight of a thermoplastic elastomer containing polyamide; 5 to 50 parts by weight of a terpolymer ionomer containing ethylene, (meth)acrylic acid, and (meth)acrylic ester; 30 to 80 parts by weight of a copolymer ionomer containing ethylene and (meth)acrylic acid; and 1 to 20 parts by weight of an epoxidized-diene-based block copolymer. The core member is formed by vulcanizing a rubber composition containing: 100 parts by weight of a base rubber, A parts by weight of an alpha, beta-unsaturated carboxylic acid or a metal salt thereof, B parts by weight of an organic peroxide, and C parts by weight of a sulfide where A, B, and C satisfies the relationship:andA lies in the range from 25 to 45.

Object of the present invention is an extrudable blend comprising (i) a copolymer of ethylene and acrylic acid or methacrylic acid (ii) a modified EVA copolymer and (iii) a polybutylene. Included are the films comprising said blend in the sealant layer or in a layer directly adhered to the sealant layer, and the easy-to-open packages obtained therefrom.

A hydrogel polymer obtained by polymerizing a monomer component including acrylic acid (salt) is post-neutralized so that each of polymer particles derived from a polymer produced by neutralizing the hydrogel polymer has an allowable neutralization ratio. The polymer as obtained by neutralizing the hydrogel polymer is reacted with a crosslinking agent reactive to a functional group of the polymer. The allowable neutralization ratio, for example, is a neutralization ratio which is not lower, by not less than 20 mole percent, or more than, at least 55 mole percent, than an average neutralization ratio of a mass of the polymer particles, and the post-neutralization is carried out so that a number of polymer particles having a non-allowable neutralization ratio outside the allowable neutralization range is not more than 10 in 200 polymer particles, thus obtaining a water-absorbent agent having high absorbency under no applied pressure and high pressure wherein the amount of water soluble component is lower compared with the conventional water-absorbent agent and a change in pH of a swollen gel is small.

The invention discloses an acrylic emulsion as well as a preparation method and an application thereof. The preparation method of the acrylic emulsion comprises the following steps: (1) mixing all monomers, 1/4-1/3 of deionized water and 2/3-3/4 of anionic emulsifier in raw materials, and emulsifying the mixture for 10-30 minutes to obtain a pre-emulsion; adding the left deionized water, the leftanionic emulsifier and 1/20-1/5 of pre-emulsion to a reactor, heating the reactor to 75-85 DEG C, adding an initiator, and making the mixture react for 0.5-1 hour; and (2) dropwise adding the left pre-emulsion for 2-4 hours, preserving heat for 2 hours at 75-85 DEG C, decreasing the temperature to 60 DEG C, adding a non-ionic emulsifier, stirring for 20 minutes, cooling the mixture to 20-30 DEG C, adjusting the pH value of the mixture to 7-8, adding a cross-linking agent, stirring and discharging. The acrylic emulsion has good rebound elasticity and good batch stability, can well disperse inorganic powder and overcomes a series of defects of the existing acrylic emulsion, and the preparation process of the acrylic emulsion is simple and is easy to realize industrial production.

The invention relates to an optionally foamed sealing composition for preformed seals which can swell when treated with water. The invention also relates to a method for the production thereof out of natural rubber and/or elastomers with a matrix comprised of natural rubber/elastomer components and particle-shaped water absorbing material stored therein. The water absorbing material is a combination of (A) polysaccharide(s) selected from cellulose, starch, starch derivatives removed from grafted starch, amylose, amylopectin, dextran, pectin, inulin, chitin, xanthan, alginic acid, alginates, carrageenan, pustulan, callose, laminarin, guluronic acid, pullulan, lichenin or mixtures of the same with (B) a highly water absorbent synthetic polymer selected from polymers based on (meth)acrylate, poly(meth)acrylic acid and the salts thereof, polyacrylamide, polyalcohols or copolymers of said synthetic polymers. The invention also relates to additional cross-linking and processing auxiliary agents and to property improving agents. It is possible to securely seal superstructures, substructures, tunnels and canals with the assistance of the inventive sealing compositions.

The invention relates to a preparation method for the hydroxyl acrylic aqueous dispersion of high performance and two-component waterborne polyurethane, which comprises four steps: synthesizing hydroxyl acrylic resin, removing a solvent, a neutralization salt forming reaction and deionization and aqueous dispersion. The hydroxyl acrylic aqueous dispersion prepared by the invention has proper molecular weight and the molecular weight is distributed much narrower, thus being beneficial for forming a uniform coating, reducing the plasticizing effect of small molecule substance to the coating, and increasing the comprehensive performance of the coating. The dispersion can be combined with an isocyanate curing agent to be used as wood coatings, corrosion protective coatings, industrial maintenance coatings, floor coatings and the like, and also can be used for preparing a two-component waterborne polyurethane adhesive, etc.

A wet-skin adhesive includes a pressure-sensitive adhesive component that includes at least one monoethylenically unsaturated (meth)acrylic acid ester comprising an alkyl group having at least 4 carbons on average and at least one monoethylenically unsaturated reinforcing monomer; and a film-forming component that includes at least one monoethylenically unsaturated (meth)acrylic acid ester comprising an alkyl group having less than 4 carbons on average and at least one hydrophilic acidic monomer, wherein the wet-stick pressure-sensitive adhesive has an initial wet skin adhesion of at least about 0.8 N/dm. Advantageously, the wet-stick adhesive has an initial wet skin adhesion that is at least about 65% of an initial dry skin adhesion.

The invention discloses a molecular sieve based catalyst, a preparation method and an application thereof in crylic acid preparation by lactic acid dehydration. The method comprises the following steps: processing the ZSM-5 molecular sieve in aqueous alkali, or adopting an impregnation method to support phosphate, drying, roasting and finally obtaining the modified molecular sieve based catalyst. The catalyst realizes the reaction of crylic acid preparation by lactic acid dehydration in low temperature and has the advantages of high lactic acid conversion rate and crylic acid selectivity, and long-life of catalyst, the conversion rate of lactic acid dehydration reaction is 100%, and crylic acid selectivity can reach as high as 83.9%, thus having good industrial application prospect.

The invention relates to a process for producing mouldings by injection moulding, the steps in the process being A) Melting a mixture made from a) a (meth)acrylate copolymer composed of from 40 to 100% by weight of free-radical-polymerized C1-C4-alkyl esters of acrylic or methacrylic acid and from 0 to 60% by weight of (meth)acrylate monomers having an anionic group in the alkyl radical, where the copolymer comprises b) from 0.1 to 3% by weight of a release agent, and, where appropriate, the mixture may comprise c) from 0 to 50% by weight of a drier, d) from 0 to 30% by weight of a plasticizer, e) from 0 to 100% by weight of additives or auxiliaries, f) from 0 to 100% by weight of an active pharmaceutical ingredient, g) from 0 to 20% by weight of another polymer or copolymer, where the amounts given for components b) to g) are based on the (meth)acrylate copolymer a) and the mixture prior to melting has a content of more than 0.5% by weight of low-boiling constituents with vapour pressure of at least 1.9 bar at 120° C., B) Devolatilizing the mixture in the thermoplastic state at temperatures of at least 120° C., thereby lowering to not more than 0.5% by weight the content of the low-boiling constituents with vapour pressure of at least 1.9 bar at 120° C., C) Injecting the molten and devolatilized mixture into the mould cavity of an injection mould, the temperature of the mould cavity being below the glass transition temperature of the (meth)acrylate copolymer by at least 10° C., cooling the molten mixture, and removing the resultant moulding from the mould.

An dispersant for plaster comprising a copolymer prepared by copolymerizing (a) a polyalkylene glycol monoester monomer having 2 to 300 mols of an oxyalkylene group(s) each having 2 to 3 carbon atoms, with (b) at least one monomer selected from among acrylic monomers, unsaturated dicarboxylic monomers and allylsulfonic monomers. When the dispersant of the present invention is used in preparing a plaster board, the foam stability is maintained so that the quality of the plaster board composition can be easily controlled.

Disclosed is an electrochemical device, which comprises: (A) a binder comprising polymer particles obtained from the polymerization of: (a) 20-70 parts by weight of a (meth)acrylic acid ester monomer; (b) 20-60 parts by weight of a vinyl monomer; and (c) 0.01-30 parts by weight of an unsaturated carboxylic acid monomer, based on 100 parts by weight of a binder polymer; and (B) electrochemical cells stacked multiply by using the binder, wherein the binder allows electrode active material particles in an electrode to be fixed and interconnected among themselves and between the electrode active material and a collector, and the electrode and a separator that is in contact with the electrode are bonded to each other by way of hot fusion. The binder is also disclosed. The binder has excellent adhesion and thermal bonding characteristics, and thus is useful for an electrochemical device comprising multiply stacked electrochemical cells, and can improve the overall quality of a battery.

An aqueous ink composition comprising: a pigment, having a particle diameter as determined by the light scattering method of no less than 20 nm and no more than 200 nm; and a water dispersible polymer, having a styrene-equivalent number average molecular weight of as determined by gel permeation chromatography no less than 5000 and no more than 200000, having a surface tension of no less than 20 mN/m and no more than 40 mN/m, and wherein the abovementioned pigment is a polymer-coated pigment that is coated with the abovementioned water dispersible polymer, is provided. The water-dispersible polymer may be a copolymer of monomers, mainly comprising acrylic acid and/or methacrylic acid and an acrylate and/or methacrylate. With this ink composition, the printing quality can be improved.

Organisms are provided which express enzymes such as glycerol dehydratase, diol dehydratase, acyl-CoA transferase, acyl-CoA synthetase β-ketothiolase, acetoacetyl-CoA reductase, PHA synthase, glycerol-3-phosphate dehydrogenase and glycerol-3-phosphatase, which are useful for the production of PHAs. In some cases one or more of these genes are native to the host organism and the remainder are provided from transgenes. These organisms produce poly (3-hydroxyalkanoate) homopolymers or co-polymers incorporating 3-hydroxypropionate or 3-hydroxyvalerate monomers wherein the 3-hydroxypropionate and 3-hydroxyvalreate units are derived from the enzyme catalysed conversion of diols. Suitable diols that can be used include 1,2-propanediol, 1,3 propanediol and glycerol. Biochemical pathways for obtaining the glycerol from normal cellular metabolites are also described. The PHA polymers are readily recovered and industrially useful as polymers or as starting materials for a range of chemical intermediates including 1,3-propanediol, 3-hydroxypropionaldehyde, acrylics, malonic acid, esters and amines.

A method of preparing fiber reinforced acrylic thickened compositions which can be molded under low pressures and temperatures to provide thermoset articles, wherein liquid reactive components are slowly absorbed in high molecular weight solid acrylic resin in the form of large particles. The acrylic resin functions as a thickener which delays the viscosity build allowing fiber reinforcement to be incorporated before molding. The molding composition is well suited for use in dentistry and other fields where small amounts or molding composition are used occasionally.

A production method of the present invention is a polyacrylic water-absorbent resin powder production method including the steps of: producing an acrylic monomer solution in which gas is dissolved and/or dispersed; polymerizing the acrylic monomer solution in the absence of a surface active agent or in the presence of not more than 300 ppm of a surface active agent; during or after the step of polymerizing, fragmenting a hydrated gel crosslinked polymer obtained by polymerizing the acrylic monomer solution; and drying by heat the hydrated gel crosslinked polymer thus fragmented, the gas being dissolved and/or dispersed in the acrylic monomer solution by at least one of the methods (a) to (c): (a) applying pressure to the acrylic monomer solution and the gas; (b) creating swirling flows of the acrylic monomer solution and the gas; and (c) introducing the gas with the acrylic monomer solution via fine holes. Accordingly, the production method of the present invention makes it possible to efficiently produce a water-absorbent resin having an excellent water-absorption rate without deteriorating a liquid-absorbent property of a sanitary product or the like.

The invention discloses a preparation method of super-strong high temperature-resistant chlorinated polyvinyl chloride tubes, which is characterized in that the tubes are made by the following steps: 75 to 100 portions of chlorinated polyvinyl chloride resin, 0 to 25 portions of vinyl chloride resin, 3 to 10 portions of ABS, 1 to 8 portions of acrylic acid resin, 3 to 8 portions of bismaleimides, 1 to 5 portions of plasticizing accelerator, 1 to 5 portions of compatibilizer, 10 to 25 portions of engineering plastics, 1 to 3 portions of lubricant, 1 to 5 portions of nanometer materials, 4 to 8 portions of stabilizing agent, 2 to 15 portions of filler, 0 to 1 portion of cross-linking agent, 1 to 5 portions of processing modifier and 3 to 10 portions of impact modifier are mixed and blended according to weight proportion, and then extruded by a mould. Compared with the prior art, the super-strong high temperature-resistant chlorinated polyvinyl chloride tubes has the advantages of being high in vicat softening point, being capable of meeting the high-temperature requirement of more than 120 DEG C, and having good anti-aging performance, antiflaming and insulation performance, and compression resistance, and long service life.

The invention relates to a preparation method for a muscle relaxing antagonistic agent sugammadex sodium. The preparation method comprises the following steps: preparing sulfydryl gamma-cyclodextrin by taking halogenated gamma-cyclodextrin and thiourea as reactants; then, initiating sulfydryl-alkene click reaction by illuminating or using an initiator on sulfydryl gamma-cyclodextrin with acrylic acid or acrylic esters or sodium acrylate so as to prepare high-purity sugammadex sodium in a water phase. According to the preparation method for the sugammadex sodium, the the operation environment is gentle, the yield is increased, and the purifying process for the final product sugammadex sodium is simpler.

Disclosed herein is an elastomeric article having a hydrogel donning coating. The hydrogel donning coating is made of a copolymer of hydroxy ethyl acrylate (HEA), hydroxy ethyl methacrylate (HEMA), and acrylic acid. The hydrogel donning coating is applied to the elastomeric article using an aqueous hydrogel dipping solution containing the hydrogel donning coating copolymer. The aqueous hydrogel dipping solution demonstrates thixotropic characteristics which allows for better manufacturing process control.

The present invention provides flexible packaging webs comprising a non-oriented metallized sealant film characterized by a secant modulus of less than 120,000 psi and an elongation at break of greater than 150%, wherein the non-oriented metallized sealant film comprises (1) a thermoplastic base layer of a material selected from the group consisting of ethylene/vinyl alcohol copolymer, ethylene/acrylic acid copolymer, ethylene/norbornene copolymer, polyamide and blends thereof; (2) a metal coating deposited on the base layer and having an optical density of 1.0 to 3.0; and (3) a heat sealing layer. The packaging webs of the present invention each exhibit an oxygen gas transmission rate of between 0 to 10.0 cm³/100 in²/24 hours at 73° F. (0 to 155 cm³/m²/24 hours at 23° C.) and 0% relative humidity and a water vapor transmission rate of between 0 to 0.1 g/100 in²/24 hours at 100° F. (0 to 1.55 g/m²/24 hours at 38° C.) and 90% relative humidity. The sealant films are formed by a blown coextrusion method.

A coating composition which comprises (A) a resin having a glass transition temperature of 50 to 120 DEG C., a number average molecular weight of 2,000 to 100,000, a hydroxyl value of 50 to 150 mgKOH/g and an acid value of 1 to 25 mgKOH/g, which is produced by copolymerizing 10 to 90 percent by weight of (a) a (meth)acrylic acid ester of a C1 to C12 alkyl alcohol, 10 to 50 weight % of (b) a first polymerizable double bond-containing and hydroxyl group-containing monomer, 0.1 to 10 weight % of (c) a polymerizable double bond-containing and carboxyl group-containing monomer, 0 to 20 weight % of (d) styrene, 0 to 20 weight % of (e) acrylonitrile and 0 to 10 weight of (f) a second polymerizable double bond-containing monomer, (B) at least one compound selected from the group consisting of a polyisocyanate compound having two or more unblocked isocyanate groups and/or blocked isocyanate groups in the molecule and an aminoplast resin, (C) a dispersing component of at least one inorganic oxide sol selected from the group consisting of an aluminum oxide sol, a silica sol, a zirconium oxide sol and an antimony oxide sol, wherein an amount of a nonvolatile matter of component (C) is 5 to 60 percent by weight based on a total amount of nonvolatile matter of resin (A), compound (B) and component (C). The coating composition provides cured films having excellent weathering resistance, light resistance, stain resistance, stain-removing property, chemical resistance, moisture resistance and appearance and is environmentally friendly and safe.

The invention discloses a specific nanometer paint of energy-saving environment-protective typed aluminium alloy section bar (door and window), which comprises the following parts: 90-100% filming agent, 0.1-10% hardener, 0.5-8% levelling agent, 0.5-10% nanometer material, 20-50% fill and 10% hollow microball, wherein the filming agent is one or more of epoxy resin, polyester resin, acrylic acid resin, amino resin, phenol resin or alkide resin; the hardener is one or more of dicyandiamide, imidazole, dihydrazide, polybasic carboxylic acid, beta-hydroxyalkyl amide or triglycidol isocyanuric ester hardener; the levelling agent is one or more of polyacrylic resin, siliceous acryl resin, polyvinyl butyral, benzoin, hydrocastor oil, cellulose acetate butyrate or epoxy soy oil; the nanometer material is nanometer zinc oxide; the hollow micro-ball is hollow ceramic microball.

A wood-plastics composition is prepared from used or waste plastics, wooden fibres for modifying plastics, and resin compatibilizer through fusing and proportionally mixing. Said resin compatibilizer is prepared from EVA, acrylic acid or acrylate and polyvinyl chloride through mixing. Its advantages are high strength toughness, and improved machinability.

An image receptor medium including an image reception layer having two major opposing surfaces. The image reception layer comprises a terpolymer of ethylene vinyl acetate carbon monoxide, optionally blended with at least one other polymer that can be wherein the image reception layer further comprises at least one other polymer blended with the terpolymer, wherein the other polymer is selected from the group consisting of ethylene vinyl acetate resins, ethylene (meth)acrylic acid copolymer resins, polyethylene resins, polypropylene resins, ionomers, acid-modified or acid/acrylate modified ethylene vinyl acetates and a polymer comprising at least two monoethylenically unsaturated monomeric units, wherein one monomeric unit comprises a substituted alkene where each branch comprises from 1 to about 8 carbon atoms and wherein one other monomeric unit comprises a (meth)acrylic acid ester of a nontertiary alkyl alcohol in which the alkyl group contains from 1 to about 12 carbon atoms and can include heteroatoms in the alkyl chain and in which the alcohol can be linear, branched, or cyclic in nature, and combinations of such other polymers thereof. Alternatively, the image receptor medium includes a substrate layer comprising a polymer substrate layer having two major opposing surfaces and an image reception layer on a first major surface of the substrate layer. The image reception layer has an outer surface for receiving images, and comprises a terpolymer identified above. Either embodiment of the image receptor medium may further include an optional prime layer, an optional adhesive layer, and an optional inkjet layer.

A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a separator interposed between the positive and negative electrodes, and a non-aqueous electrolyte. The positive and negative electrodes are wound together with the separator. The negative electrode includes composite particles and a binder. Each of the composite particles includes: a negative electrode active material including an element capable of being alloyed with lithium; carbon nanofibers that are grown from a surface of the negative electrode active material; and a catalyst element for promoting the growth of the carbon nanofibers. The binder comprises a polymer having at least one selected from the group consisting of an acrylic acid unit, an acrylic acid salt unit, an acrylic acid ester unit, a mathacrylic acid unit, a methacrylic acid salt unit, and a mathacrylic acid ester unit.