The invention discloses a poly 1-
butene / 1-butylene-propylene
copolymer in-reactor
alloy material and a preparation method thereof, belongs to the field of
polyolefin material, and relates to poly 1-
butene in-reactor
alloy, and a preparation method and applications thereof. According to the poly 1-
butene / 1-butylene-propylene
copolymer in-reactor
alloy material, a poly 1-butene homopolymer is taken as a main ingredient, and the poly 1-butene / 1-butylene-propylene
copolymer in-reactor alloy material comprises a small amount of a 1-butylene / propylene copolymer, wherein
molar content of propylene
monomer unit ranges from 2 to 25%,
molar content of 1-butene
monomer unit range from 75 to 98%,
mass content of poly 1-butene ranges from 65 to 89%, and
mass content of the 1-butylene / propylene copolymer ranges from 35 to 11%. The poly 1-butene / 1-butylene-propylene copolymer in-reactor alloy material is prepared by adopting a high-efficient loaded Ti catalytic
system and via two-stage bulk in-suit
polymerization. The
polybutene alloy material possesses excellent
shock resistance and
thermal creep resistance, and low shrinking rate of the poly 1-butene homopolymer; is capable of increasing
crystal transfer rate of poly 1-butene, and shortening shaping and
curing time at the same time; and can be used for replacing a part of
polyethylene and
polypropylene for preparation of tubular products or for
toughening modification of
polypropylene.