98 results about "Polybutene" patented technology

The invention relates to a polyethylene and silica gel mixed material, a preparation method thereof and application of the polyethylene and silica gel mixed material in a composite optical cable silicon core tube. The composite material comprises the following components in parts by weight: high-density polyethylene, an ethylene-siloxane copolymer elastomer, a maleic anhydride grafted polyolefin elastomer, hydroxylated nano silicon dioxide, liquid paraffin, a crystallization nucleating agent, an ultraviolet light absorber, an auxiliary stabilizer, a processing aid and color master batch. The liquid paraffin is formed by blending dual-molecular-weight paraffin with different carbon chain lengths, and part of the liquid paraffin is grafted and modified by polybutylene so as to enhance the anchoring capacity of the lubricating phase; in addition, nano cellulose crystals grafted by a PEG-PCL (Polyethylene Glycol-Polycaprolactone) block copolymer are introduced, so that the dimensional stability and the interface structure integrity of the material are synergistically enhanced. The composite material has excellent low friction, thermal oxidation stability, creep resistance and ultraviolet aging resistance, and is suitable for preparation of a high-performance composite optical cable silicon core tube.

The present invention relates to a composition in the form of an oil-in-water bigel and comprising: (1) a (C1-C2 alkyl) acrylic acid / (C1-C2 alkyl) acrylic acid C10-C30 alkyl ester copolymer as an aqueous phase thickener; (2) an oil phase thickener preferably comprising one or more selected from the group consisting of olive oil sorbitol ester, dextrin palmitate and polybutylene; (3) a polyglycerol emulsifier having an HLB value from 0 to 8, preferably from 1 to 8, more preferably from 3 to 8; and (4) a solvent. By using the composition in the form of oil-in-water double gel containing the components, a cosmetic product which simultaneously has a high SPF value, good stability, water resistance and improved skin feeling can be prepared. The invention also relates to a preparation method of the composition and application of the composition for preparing cosmetics, especially sunscreen cosmetics.

A container closure, particularly a vacuum turnlock closure, comprises a sealing element containing or made of a polymer compound (excluding PVC). The polymer compound comprises at least one polybutene polymer, at least one polymer derived from at least partially 1,2-bonded isobutylene monomer, at least one (co)PP polymer, and optionally other components and additives. In a preferred embodiment, the polybutene polymer is a copolymer with ethylene in particular. In a preferred embodiment, the polybutene polymer has a Shore A hardness of less than 85.

A method for preparing a polybutene-1 composition with an elevated crystallization temperature, comprising blending as components A) 99.5-99.9% by weight, relative to the total weight of A)+B), of a butene-1 homopolymer, said butene-1 polymer being brought into or maintained in the molten state during the blending step, with B) 0.1-0.5% by weight, relative to the total weight of A)+B), of one or more alkanoyl hydrazines of specific formulas, the polybutene-1 composition thus obtained having a crystallization temperature T satisfying the following relationship: c C has. [0010] JPEG2024542582000029.jpg4092 Here, T c A is the crystallization temperature of butene-1 polymer A).

The application belongs to the technical field of polymer preparation, and discloses a preparation method of high isotactic polybutene-1. 10 The application discloses a preparation method of high isotactic polybutene-1, which comprises the following steps: carrying out a polymerization reaction on butene-1 and optional C2-C 10 α-olefin monomers under the action of a Ziegler-Natta catalyst system; the Ziegeller-Natta catalyst system contains a solid catalyst component, an organic aluminum compound and an external electron donor; the solid catalyst component contains a catalyst carrier, an internal electron donor and a reaction product of a halide containing titanium, and the internal electron donor contains a carboxylic acid ester compound and a polyhydric alcohol ester compound; the polymerization reaction conditions include that the polymerization temperature is 0-150 DEG C, and the polymerization pressure is higher than the saturated steam pressure of butene-1 at the corresponding polymerization temperature. The preparation method has high polymerization activity, and the obtained polymer has high isotacticity.

The invention discloses a method for regulating and controlling butylene polymer crystallization through temperature and blending components, and belongs to the technical field of polymer crystallization, the method comprises the following steps: heating a polybutylene / polypentene blend to eliminate thermal history, and carrying out primary cooling to crystallize polybutylene in the blend to obtain an initial crystal; and heating the initial crystal until the initial crystal is molten, and cooling again to obtain the butylene polymer crystal. The invention provides the method for regulating and controlling the crystallization of the butylene polymer through temperature and blending, the blank that the existing polybutylene blend product is less is filled, the polypentene component is added, and the mass fraction of the polypentene in the polybutylene / polypentene blend is regulated, so that the crystallization of the butylene polymer is regulated and controlled. A series of polybutylene / polypentene blends with high crystallization capacity are obtained, the crystallization capacity of polybutylene is improved by changing the melting temperature and the initial crystal form, the crystal form of the polybutylene is regulated and controlled, and a feasible method is provided for rapidly obtaining the stable crystal form of a polymer and improving the processing efficiency.

The invention discloses an ABS (Acrylonitrile Butadiene Styrene) composite material as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The invention provides an ABS (Acrylonitrile Butadiene Styrene) composite material. The ABS composite material comprises the following components in parts by weight: 60-90 parts of a styrene-butadiene-acrylonitrile copolymer, 15-35 parts of PETG (Polyethylene Terephthalate Glycol) resin, 3-10 parts of polybutylene resin and 0.5-2 parts of an auxiliary agent. According to the invention, the styrene-butadiene-acrylonitrile copolymer, the PETG resin and the polybutylene resin are selected as raw material components, and the cold-resistant and solvent erosion cracking-resistant ABS composite material is prepared.

Lubricant compositions comprising an oil of lubricating viscosity and a viscosity modifier that is a hydrocarbon polymer having a number average molecular weight (Mn) of less than 10,000 Daltons (Da). The viscosity modifier is present at greater than 2 wt %, based on a total weight of the lubricant composition. Exemplary hydrocarbon polymers include, but are not limited to, olefin polymers, such as polyisobutylene polybutene, ethylene α-olefin copolymers, or combinations thereof.

This invention provides a method for accelerating the crystal form transformation of isotactic polybutene-1 and the isotactic polybutene-1 resin prepared therefrom. The method includes blending isotactic polybutene-1, a hyperbranched polymer, and an optional antioxidant, followed by melt treatment, extrusion granulation, and storage. The hyperbranched polymer is selected from at least one of aliphatic and aromatic hyperbranched polymers. This invention is the first to propose a method for accelerating the crystal form transformation of isotactic polybutene-1 using a hyperbranched polymer. This method mainly utilizes the internal lubrication effect of the hyperbranched polymer to accelerate the rate of polymer chain conformation adjustment and chain rearrangement during the crystal form transformation of isotactic polybutene-1, thereby significantly improving the crystal form transformation rate. The method of this invention can shorten the time for isotactic polybutene-1 to transform from crystal form II to crystal form I from 7 days to within 2-4 days, showing good prospects for industrial application.

The application discloses a preparation method of a three-layer co-extrusion film for cigarette soft box packaging and belongs to the technical field of biaxially oriented polypropylene film. The application provides a film prepared by adopting a three-layer co-extrusion biaxial stretching process, which has a three-layer structure, i.e., an inner layer, a core layer and an outer layer, and the core layer is located between the inner layer and the outer layer. According to 100% of the mass percentage of each layer, the inner layer comprises heat-sealing material 50%-95%, stiffening agent 5%-50%, slip agent 1%-5%, anti-blocking agent 1%-5% and degradation agent 0%-10%; the core layer comprises propylene homopolymer 50%-90%, ethylene acrylic acid copolymer 10%-30%, stiffening agent 5%-35%, antistatic agent 1%-10% and degradation agent 0%-10%; and the outer layer comprises heat-sealing material 50%-95%, stiffening agent 5%-50%, slip agent 1%-5%, anti-blocking agent 1%-5% and degradation agent 0%-10%; the heat-sealing material is composed of ionic polymer, polybutylene resin and ethylene acrylic acid copolymer at a mass ratio of (4-6):(2-4):2. The cigarette soft packaging film provided by the application has high heat-sealing strength, high softness, good optical performance and degradable performance.

The invention belongs to the technical field of high polymer material processing, discloses a polybutylene pipe and a preparation method thereof, and solves the problems of insufficient weather resistance and filler dispersion of a traditional PB pipe through a rare earth sulfide composite light stabilizer, dopamine modified nano layered double hydroxide and a CO2-assisted forming process. The invention aims to provide the polybutylene pipe and the preparation method thereof, so as to solve the problems that the traditional polybutylene pipe is insufficient in weather resistance, is easy to photooxidize and degrade after long-term ultraviolet radiation, is reduced in mechanical property, is poor in nano filler dispersibility and is weak in interface bonding, and the conventional polybutylene pipe adopts multi-layer co-extrusion or a heavy metal stabilizer, so that the cost is low. And the composite material is suitable for harsh outdoor and high and low temperature environments, and is suitable for building water supply and drainage, floor heating systems and outdoor conveying pipelines.

The present application provides a perovskite solar cell, a preparation method therefor, and a photovoltaic module. The perovskite solar cell includes a perovskite light absorption layer. The perovskite light absorption layer includes a perovskite material and a complexing agent. The complexing agent includes one or more of a hydroxycarboxylic acid-based complexing agent, an organic phosphonic acid-based complexing agent, a polyacrylic acid-based complexing agent, and a polybutenoic acid-based complexing agent. The perovskite solar cell, the preparation method therefor, and the photovoltaic module according to the present application reduce ion migration in perovskite while passivating defects, to reduce the degradation of the perovskite light absorption layer and the failure of functional layers, thus improving the device efficiency and stability.

The invention relates to a film adhesive modified polybutylene polymer vibration-resistant material and a preparation method thereof, and belongs to the field of vibration-resistant materials, and the film adhesive modified polybutylene polymer vibration-resistant material comprises a film adhesive and a polybutylene polymer, the film adhesive comprises an ethylene copolymer, a tackifier, a dissolving agent, an emulsifier, a filler, a stabilizer and water; the polybutylene polymer comprises a polybutylene copolymer, a tackifier, a dissolving agent and a reinforcing agent. The raw materials used in the invention and the prepared vibration damping material are environment-friendly materials, are stable in performance in a room temperature environment, are not easy to deliquesce and mildew, do not generate substances harmful to a human body, prolong the storage life of the material, and do not influence the health of the human body. The prepared vibration damping material is good in flexibility, and the low-temperature mechanical property, the sound vibration absorption performance and the weakening performance are improved. According to the preparation method, the solvent can be thoroughly removed, the solvent recovery rate is high, the environment is not polluted, and operators are not hurt. The anti-vibration material prepared by the invention has a good anti-vibration effect.

The invention relates to the technical field of polyurethane materials, and discloses a formula and a preparation method of hydrolysis-resistant polyurethane synthetic leather, the formula comprises: 85.0-90.0 parts of poly (1, 4-butylene adipate); 12.0 to 15.0 parts of dimer acid polyester polyol; 3.0 to 4.0 parts of epoxy linseed oil; 1.0 to 1.5 parts of castor oil; and 41.0 to 46.0 parts of diphenylmethane diisocyanate (diphenylmethane diisocyanate). 13.3 to 20.0 parts of a chain extender solution and the like. The preparation method comprises the following steps: premixing the hydrophobic components, adding the main soft segment, dehydrating, reacting with isocyanate to obtain a prepolymer, carrying out solution chain extension to obtain slurry, and finally carrying out wet solidification, washing and drying to obtain a finished product. By utilizing the hydrophobic shielding effect of the long carbon chain side group of the dimer acid and the steric hindrance effect of the special chain extender, the hydrolysis resistance of the resin layer is remarkably enhanced, and the service life of the synthetic leather is prolonged.

To provide a thermoplastic resin composition that can produce molded articles with excellent extrusion moldability, flexibility, flame retardancy, and dielectric breakdown properties. [Solution] A thermoplastic resin composition comprising (A) 100 parts by mass of polybutylene (terephthalate / dodecadioate) copolymer having a melt mass flow rate of 3.0 g / 10 min or less, measured at a temperature of 250°C and a load of 1000 g in accordance with ISO 1133, (B) 10 to 20 parts by mass of a flame retardant having a benzene ring in its side chain, and (C) 3 to 8 parts by mass of an antimony compound.

The present invention provides a non-metallocene catalyst, a preparation method therefor, and a use thereof. The molecular structure of the non-metallocene catalyst is as represented by formula 1. In formula 1, R1 and R2 each are independently one of H, methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, and tert-butyl. The non-metallocene catalyst provided by the present invention has an open spatial structure and a multi-metal active center and can highly actively catalyze a polymerization reaction of butene-1 to prepare a polybutene product having bimodal width distribution.

The present invention relates to the field of thin films, and particularly to a low-temperature resistant polypropylene matte film, a preparation method thereof, and a cold laminating composite film. The matte film comprises a matte layer, a core layer, and an adhering layer arranged in sequence. The matte layer comprises 45-55 wt% of random copolymer polypropylene and 45-55 wt% of high-density polyethylene. The core layer comprises homopolypropylene and 5-10 wt% of poly(1,4-butylene glycol-1-butene) random copolymer. The adhering layer comprises homopolypropylene and 2-5 wt% of n-alkyl maleate graft-modified ethylene-vinyl acetate copolymer. The matte film of the present invention has appropriate flexibility in a low-temperature environment, and there is still appropriate adhesion between the adhering layer and the adhesive layer. During manufacturing, the film can be smoothly unwound and rewound, and can be used as the base film of a low-temperature resistant cold laminating film.

The invention relates to the technical field of polybutylene-1, and discloses a preparation method of polybutylene-1 resin and a method for improving the polybutylene-1 content of a solution containing the polybutylene-1 resin. The preparation method of the polybutylene-1 resin comprises the following steps: (1) in the presence of a solvent, carrying out polymerization reaction on butylene-1 to obtain a solution containing a polymer; (2) heating and cooling the solution containing the polymer to obtain a polymer dilute phase and a polymer enriched phase; wherein the temperature of the polymer-containing solution after heating is 25 DEG C or more higher than the temperature of the polymerization reaction. According to the method disclosed by the invention, the concentration effect of the polymer solution can be realized within a short time, and two-phase separation of a polymer dilute phase and a polymer enriched phase is realized, so that the subsequent separation process of unreacted monomers and polymers is simplified and shortened.

The invention belongs to the field of cable insulating materials, and relates to a modified polybutylene in-kettle alloy, application and a cable. The modified polybutylene in-kettle alloy is a polybutylene in-kettle alloy grafted copolymer; based on the total weight of the modified polybutylene in-kettle alloy, the content of the grafting unit in the modified polybutylene in-kettle alloy is 0.5-14wt%; the content of an n-heptane soluble substance is 20-75wt%; the melt flow rate of the modified polybutylene in-kettle alloy under the conditions that the temperature is 230 DEG C and the load is 2.16 kg is 0.1-6 g / 10 min; moreover, the modified polybutylene in-kettle alloy has at least one of the following characteristics: the elongation at break is greater than or equal to 250%; the tensile strength is greater than 16MPa; and the bending modulus is 450 to 750 MPa. The modified polybutylene in-kettle alloy disclosed by the invention has good insulating property, mechanical property and processability, and is particularly suitable for being used in middle and high voltage cables.

The application discloses an interlayer easy-peeling film, which comprises at least three layers of connecting layer, functional layer and heat-sealing layer which are sequentially stacked; wherein the connecting layer is a metallocene-catalyzed polyolefin material, the functional layer is a mixture of polybutene or polypropylene and polyethylene, and the heat-sealing layer is a low-stretching-property low-temperature heat-sealing material; and the polybutene or polypropylene:polyethylene is 1:1, 1:2 or 2:1. The application can control the degree of combination between the heat-sealing layer and the functional layer by adjusting the formula of the materials of the functional layer and the heat-sealing layer, that is, the peeling strength between the two layers can be controlled, so that a good peeling hand feeling can be obtained. The heat-sealing layer adopts a low-temperature heat-sealing material, and a trace of color masterbatch is added to cause visible heat-sealing transfer, which is suitable for medical packaging. Since the interlayer peeling strength between the heat-sealing layer and the functional layer is 3-5 N / 15 mm, the heat-sealing layer can be easily peeled from the functional layer, so that a stable peeling effect can be obtained.

The application relates to the field of polybutene, and provides a long-chain branched 1-butene / alpha-olefin copolymer and a preparation method thereof. The 1-butene / alpha-olefin copolymer contains a structure of omega-olefin-based dihalosilane inserted into a main chain of the 1-butene / alpha-olefin copolymer, and the molar percentage content of Si atoms in the 1-butene / alpha-olefin copolymer is 0.0001 ‰-1 ‰. The H type long-chain branched 1-butene / alpha-olefin copolymer has high creep resistance and mechanical properties.

To solve the above problems, the present application provides a heat-sealable laminated body and a heat-sealable packaging container. The heat-sealable laminated body is a laminated body in which a base material (A), an adhesive layer (B) and a heat-sealable resin layer (C) are sequentially arranged, the adhesive layer (B) contains an acrylic copolymer (D), and the heat-sealable resin layer (C) contains a polyethylene resin and further contains at least either of a polypropylene resin and a polybutylene resin.

The application relates to the technical field of polymer composite packaging films, and specifically discloses an anti-fatigue liquid packaging film material and a preparation method thereof. The anti-fatigue liquid packaging film material is a three-layer co-extrusion structure, the outer layer comprises the following components: 100 parts of bimodal high-density polyethylene, 60-90 parts of linear low-density polyethylene, 0.5-2 parts of an anti-scratching agent, 0.3-1 part of micron-sized silicon dioxide and 0.6-2.5 parts of a processing aid A; the core layer comprises the following components: 100 parts of a polyolefin elastomer, 4-12 parts of polybutene-1, 2-5 parts of an ethylene-vinyl acetate copolymer and 0.7-2.1 parts of a processing aid B; and the inner layer comprises the following components: 100 parts of a polyester polymer, 4-6 parts of polyisobutylene, 3-4 parts of an ethylene-acrylic acid copolymer, 1-3 parts of a maleic anhydride grafted polyolefin elastomer and a processing aid C. The film material prepared by the application has excellent anti-fatigue performance.

The present invention relates to the field of materials technology, and discloses a polybutene composition and application thereof, a polybutene pipe and a preparation method thereof. The polybutene composition, calculated by weight, comprises the following components: 100 parts of polybutene, 0.1-1 parts of a nucleating agent, and 0.2-1.2 parts of a lubricant; wherein the nucleating agent contains phthalylglycine, N1,N4 dicyclohexyl terephthalamide, and 2,2'-methylene-bis(4,6-di-tert-butylphenyl phosphate) basic aluminum in a weight ratio of 1:(1-5):(1-5). In the present invention, by selecting phthalylglycine, N1,N4 dicyclohexyl terephthalamide, and 2,2'-methylene-bis(4,6-di-tert-butylphenyl phosphate) basic aluminum in a specific weight ratio as the nucleating agent, not only can the polybutene pipe quickly reach maximum ring stiffness, but also the maximum ring stiffness of the polybutene pipe can be improved.

Provided is a battery packaging material in which the sealing strength gradually decreases as the temperature increases, and which is slowly unsealed. The object of the present invention is a battery packaging material (1) comprising a base material layer (13) as an outer layer, a sealant layer (20A) as an inner layer, and a barrier layer (11) disposed between the two layers. The sealing layer (20A) is formed of one or more layers, and the first sealing layer (21) is disposed on the innermost side of the sealing layer (20A). The resin constituting the first sealing layer (21) contains a polybutylene copolymer (A) that contains at least one of a butylene-ethylene copolymer, a butylene-propylene copolymer, and a copolymer of a C5 or more alpha-olefin and 1-butylene.

The invention belongs to the field of insulating materials, and relates to a polar modified polybutylene composition, application and a cable with a thermoplastic insulating layer. The polar modified polybutylene composition is prepared from a homo-polypropylene-acrylate graft polymer and polybutylene-1; the content of the homo-polypropylene-acrylate graft is 20 to 55 weight percent, and the content of the polybutylene-1 is 45 to 80 weight percent; the homo-polypropylene-acrylate graft comprises homo-polypropylene serving as a matrix and an acrylate grafting unit grafted on the homo-polypropylene, wherein the acrylate grafting unit accounts for 1.5-25wt% of the total weight of the homo-polypropylene-acrylate graft; the melt flow rate of the polar modified polybutylene composition under the conditions that the temperature is 230 DEG C and the load is 2.16 kg is 0.1-6 g / 10 min, and the bending modulus of the polar modified polybutylene composition under the conditions that the temperature is 230 DEG C and the load is 2.16 kg is 500-750 MPa. The polar modified polybutylene composition disclosed by the invention has both mechanical properties and electrical properties at a relatively high working temperature, and is suitable for working conditions of high temperature and high operation field intensity.

The invention discloses a sealing adhesive for a zinc-manganese battery. The sealing adhesive is prepared from the following components in parts by weight: 60 to 80 parts of polybutylene, 10 to 30 parts of C5 petroleum resin, 10 to 30 parts of amorphous alpha-olefin copolymer, 0.1 to 1.0 part of antioxidant B225 and 0.05 to 0.5 part of red dye, the invention also discloses a preparation method of the zinc-manganese battery sealing compound. When in use, the zinc-manganese battery sealing glue needs to be heated to 130-140 DEG C for gluing; the zinc-manganese battery sealing compound has good adhesion, creep resistance and aging resistance, does not deform and flow at high temperature, has good low-temperature adhesion and does not crack, so that the storage stability of a battery is improved, and the service life of the battery is prolonged. The preparation method of the sealing compound is simple, short in technological process and convenient for industrialization.

A peelable sealing composition for a sealing layer on extrusion coated packaging is described. The peelable sealing composition combines 10 to about 40 wt. % of poly butene-1 with a at least one polyolefin, and can be extruded coated as a sealing layer directly onto a substrate, or co-extruded with intermediate polymer layers onto a substrate. The resulting sealing layer can be heat sealed to allow for a controlled open package.

This invention relates to a polypropylene alloy material with high toughness, high light transmittance, and high haze. The alloy material comprises 69 to 85 parts by weight of polypropylene, 15 to 30 parts by weight of polybutene-1 elastomer, and 0.5 to 1 part by weight of a light diffusing agent. The polypropylene has a melt index greater than or equal to 30 g / 10 min at 230°C and 2.16 kg; the polybutene-1 elastomer has a melt index of 0.1 g / 10 min to 4.0 g / 10 min at 190°C and 2.16 kg. The polypropylene alloy material provided by this invention, through a reasonable combination of high melt index polypropylene, low melt index polybutene-1 elastomer, and light diffusing agent, can obtain a polypropylene alloy material that simultaneously possesses high toughness, high light transmittance, and high haze. This invention also relates to a method for preparing the above-mentioned polypropylene alloy material and its application, as well as an automotive trim part.

The invention relates to a vehicle tire which contains at least in one tread a vulcanizate obtained by sulfur vulcanization of a rubber mixture which contains at least the following components: a) 50 to 100 phr of at least one styrene-butadiene rubber (SBR) and b) 2 to 30 phr of a prevulcanized rubber sealing material homogeneously distributed in the rubber mixture, comprising at least one polybutene with a chlorine content of less than or equal to 5 mg / kg.