872 results about "Isobutylene" patented technology

The invention discloses a single-ion conductor polymer, a ternary composite binder solution, high-solid-content sulfide electrolyte slurry and a wet film forming method and application thereof, and belongs to the technical field of all-solid-state lithium batteries. The key technical problems in the wet membrane preparation of the sulfide electrolyte are solved through an innovative solvent-binder synergistic system, and the method specifically comprises the steps that 1, through the synergistic effect of a non-polar solvent and a weak-polar solvent, low-viscosity coating of high-solid-content slurry is achieved while the chemical stability of the sulfide electrolyte is guaranteed; 2, a poly (lithium styrenesulfonate-butyl acrylate), styrene butadiene rubber and polyisobutene ternary composite binder is designed, a lithium ion transmission channel is provided through a lithium sulfonate group, a benzene ring structure in the styrene butadiene rubber enhances the mechanical strength, long-chain alkane in the polyisobutene improves the interface adhesive force, and the mechanical strength is improved; the three components cooperate to realize balance of mechanical and electrochemical properties of the electrolyte membrane, so that the prepared electrolyte membrane has low porosity, high ionic conductivity and mechanical strength.

The invention discloses high-performance anti-wear engine lubricating oil as well as a preparation method and application thereof. The high-performance anti-wear engine lubricating oil is prepared from the following raw materials: self-developed lubricating oil base oil, poly-alpha-olefin, zinc dialkyl dithiophosphate, calcium sulfonate, polyisobutylene succinimide, an antioxidant, polymethacrylate, an organic molybdenum complex, a de-foaming agent and a pour point depressant. The preparation method comprises the following steps: 1) synthesizing 9, 10-bis (2-tert-butyl-4-methylphenoxy) trimethylolethane stearate as base oil of the lubricating oil; and 2) mixing the base oil with other assistants to obtain the high-performance anti-wear engine lubricating oil. According to the preparation method, novel-like synthetic ester oil is firstly prepared, a phenol group and a large steric hindrance substituent group are introduced into a polymer, the anti-oxidation function is directly built in base oil molecules, meanwhile, super-strong heat resistance is achieved, and finally the high-performance anti-wear engine lubricating oil is obtained and can be applied to high-end application scenes such as aero-engines or gas turbines.

The invention discloses a catalyst for an n-butene isomerization reaction and a preparation method thereof, and belongs to the technical field of catalysts. The preparation method comprises the following steps: mixing a silicon source, an aluminum source, tetrapropylammonium hydroxide and water, adding boric acid, and crystallizing to obtain a seed crystal; the method comprises the following steps: mixing a silicon source, an aluminum source, pyridine and water, adding a seed crystal and ammonium fluoride, and crystallizing to obtain a core-shell type molecular sieve; adding the core-shell type molecular sieve into the bimetallic complex solution for dipping to obtain a metal-loaded type molecular sieve; adding the metal-loaded molecular sieve into a triethyl phosphine ethanol solution for treatment to obtain a phosphorus-modified molecular sieve; uniformly mixing the phosphorus-modified molecular sieve, pseudo-boehmite, sesbania powder and water, kneading, performing extrusion molding, drying and calcining to obtain the catalyst. The catalyst prepared by the invention is used for n-butene isomerization reaction, and has excellent catalytic activity and isobutene selectivity.

The invention belongs to the field of functional composite materials, and particularly relates to low-viscosity and high-dispersity aluminum oxide slurry and a preparation method thereof.The low-viscosity and high-dispersity aluminum oxide slurry is prepared from a newly-designed phosphono-carboxyl block copolymer and biquaternary ammonium salt polyether silane as composite modifiers; and efficient anchoring and stable dispersion of the surfaces of alumina particles are realized through the synergistic effect of molecular structures. The phosphono-carboxyl block copolymer is prepared through controllable polymerization and deprotection reaction, and strong chemical bonding is formed between a phosphono group and the surface of aluminum oxide; the biquaternary ammonium salt polyether silane is subjected to click chemical synthesis, and electrostatic adsorption of quaternary ammonium salt and the steric hindrance effect of a polyether chain are combined. When the slurry is prepared, the two modifiers are sequentially added into water, the aluminum oxide powder is added after the pH value is adjusted, finally, the isobutylene maleic anhydride copolymer and the defoaming agent are introduced, and the slurry is obtained through vacuum defoaming and filtering. The slurry prepared by the method has the characteristics of high solid content, low viscosity and good dispersion stability.

A high-thermal-conductivity phase change sheet and a preparation method therefor. The high-thermal-conductivity phase change sheet is prepared from the following raw materials in parts by mass: 3-5 parts of a resin, 80-100 parts of a thermally conductive filler, 0.1-1 part of a treating agent, 0.1-1 part of an antioxidant, and 1-2 parts of a phase change material, wherein the resin is low-molecular-weight polyisobutylene, the thermally conductive filler comprises aluminum powder of 10 μm, aluminum powder of 2 μm and zinc oxide of 0.2 μm, and heat treatment and vacuumizing operation are involved in the preparation process.

The invention discloses a super-retarding type polycarboxylic acid water reducing agent and a preparation method and application thereof, and belongs to the field of concrete water reducing agents. The preparation method comprises the following steps: taking acrylic acid AA, isobutenol polyoxyethylene ether HPEG and hydroxyethyl acrylate HEA as monomers, taking mercaptopropionic acid MPA as a chain transfer agent, taking hydrogen peroxide H2O2 and L-ascorbic acid Vc, and mixing in proportion to serve as an initiator; preparing a first and second monomer mixed solution; adding bottom water into the reaction kettle, and carrying out stepwise polymerization reaction; and cooling the reaction liquid, adjusting the pH value, filtering, and discharging to obtain the product. According to the invention, an ester functional monomer hydroxyethyl acrylate HEA is introduced, and a step-by-step polymerization technology is adopted to control the dispersion process of water reducing agent molecules on cement particles, so that the water reducing agent molecules continuously disperse the cement particles within a certain period of time; the problem that the slump loss is too fast due to long-time and long-distance transportation of concrete or transportation in high-temperature weather is effectively relieved.

The invention discloses a polypropylene composite material as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. The invention provides a polypropylene composite material. The polypropylene composite material comprises the following components in parts by weight: 40-80 parts of copolymerized PP (polypropylene), 5-25 parts of POE (polyolefin elastomer), 5-25 parts of polyisobutene and 10-30 parts of filler, the number-average molecular weight of the polyisobutene is greater than 600. The POE elastomer, the polyisobutene and the filler are introduced into the copolymerized PP, so that the polypropylene composite material with low sink mark characteristic and good mechanical property can be obtained.

The invention relates to the technical field of waterproof coiled materials, and particularly discloses a self-adhesive modified rubber asphalt waterproof coiled material and a preparation method thereof. The self-adhesive modified rubber asphalt waterproof coiled material comprises a surface isolating membrane, an asphalt layer, a reinforcing layer and a bottom surface isolating membrane from bottom to top, and the asphalt layer comprises the following raw materials: regenerated rubber modified asphalt, SEBS, terpene resin, polyisobutene amine, an antioxidant and an ultraviolet light absorber; the surface isolating membrane and the bottom isolating membrane are selected from sand surface isolating membranes, and the thickness of the surface isolating membrane and the bottom isolating membrane is 0.8-1.2 mm; and the reinforcing layer is a long-fiber polyester base reinforcing layer. The tensile strength of the self-adhesive modified rubber asphalt waterproof coiled material is 4.5-5.6 N / mm < 2 >, the self-adhesive modified rubber asphalt waterproof coiled material does not flow or drip at 70 DEG C and does not crack at-30 DEG C, the self-adhesive modified rubber asphalt waterproof coiled material has high use performance, the joint peel strength of the waterproof coiled material is 3.2-4.2 N / mm, the holding power is greater than 15 min, and the self-adhesive property of the waterproof coiled material is improved.

The invention relates to the field of sealing materials, in particular to a butyl rubber sealing material and a preparation method thereof. Comprising the following components in parts by weight: 50-70 parts of butyl rubber, 30-50 parts of a brominated isobutylene-p-methylstyrene copolymer, 30-50 parts of carbon black, 8-12 parts of an alkyl phenolic resin vulcanizing agent, 3-5 parts of zinc oxide, 1-3 parts of stearic acid, 1-3 parts of an anti-aging agent and 5-10 parts of a plasticizer. The butyl rubber provides ideal air tightness and heat aging resistance, bromine atoms are introduced into the brominated isobutylene-p-methylstyrene copolymer, co-vulcanization with the butyl rubber is achieved, it is ensured that a uniform and stable co-crosslinking network can be formed between the two rubber molecules, and the service life of the rubber is prolonged. The alkyl phenolic resin vulcanizing agent can form a C-C bond with high bond energy with two rubber molecules, so that the thermal aging resistance of the butyl rubber sealing material is effectively improved, the compression set is reduced, and the butyl rubber sealing material with excellent performance is prepared.

The present invention relates to a composition in the form of a water-in-oil emulsion, including, (a) one or more esters formed from at least one fatty acid having more than 13 carbon atoms; (b) a polymer component including one or more polymerized (iso)butenes; (c) at least about 3% by weight of one or more carbohydrate fatty acid ester emulsifiers; (d) one or more fillers comprising hydrophobic silica; and (e) one or more pigments. The composition is substantially free of silicones & alkanes.

The invention discloses a hydrogenation device scale inhibitor for heavy high-sulfur raw oil and a preparation method of the hydrogenation device scale inhibitor, and relates to the technical field of scale inhibitors. The scale inhibitor is prepared from a polyisobutylene succinimide dispersing agent, a high-temperature-resistant scale inhibition dispersing agent, an anti-rust agent, an imidazoline corrosion inhibitor, an antioxidant, a sulfide chelating agent, a clearing agent, cup carbazole alkylbenzene sulfonate and a solvent in specific parts by weight. The preparation method comprises the following steps: heating the solvent to 80-100 DEG C, sequentially adding the other components, and stirring for 30-40 minutes. Aiming at the characteristics of heavy high-sulfur raw oil, the scale inhibitor realizes high scale inhibition rate, excellent high-temperature stability and strong sulfur corrosion resistance through a multi-component synergistic effect, effectively solves the problems of scaling and corrosion of a hydrogenation device, prolongs the operation cycle of the device, and is suitable for a hydrogenation process of high-sulfur and high-asphaltene raw oil.

A composite oil phase and composite emulsion matrix for site-mixed emulsion explosive and preparation methods therefor. The composite oil phase is divided into material A and material B, wherein in the material A, a high-viscosity polyisobutylene maleic anhydride amine esterification derivative is used as a primary emulsifier to increase the strength and thickness of an emulsification film of an emulsion matrix, thereby improving the stability of the emulsion matrix; in the material B, a low-viscosity polyisobutylene maleic anhydride amine esterification derivative and SP-80 are used as primary emulsifiers to regulate the ammonium nitrate dissolution rate of the emulsion matrix, thereby improving the sensitization characteristic of the emulsion matrix; and the emulsion matrix prepared from two composite oil phases can effectively improve the water resistance of the emulsion matrix while the problems of high-temperature over-sensitization and low-temperature insensitivity are solved, so that the explosion quality is guaranteed.

An electroconductive pressure-sensitive adhesive tape includes at least an electroconductive pressure-sensitive adhesive layer containing at least a rubber component and electroconductive particles. The rubber component contains a polyisobutylene (A) having a viscosity average molecular weight of 400,000 or more and 800,000 or less and a polyisobutylene (B) having a viscosity average molecular weight of 100,000 or less. The electroconductive pressure-sensitive adhesive tape achieves both a superior adhesive property and a high swelling resistance to an electrolyte layer, especially, a high swelling resistance to an electrolyte layer containing dimethyl carbonate.

A composite board, including a core, and a capstock positioned to at least partially cover the core, where the capstock includes 10 wt. % to 70 wt. % of polyvinyl chloride (PVC), based on a total weight of the capstock, 1 wt. % to 60 wt. % of acrylonitrile-styrene-acrylate (ASA), based on the total weight of the capstock, 1 wt. % to 60 wt. % of styrene-acrylonitrile (SAN), based on the total weight of the capstock, and 1 wt. % to 60 wt. % of a thermoplastic elastomer, where the thermoplastic elastomer includes styrene-isobutylene-styrene (SIBS), a thermoplastic copolyester elastomer, a polymeric plasticizer, and combinations thereof, wherein the capstock does not include thermoplastic polyurethane.

The invention provides a preparation method of hexafluoroisobutene, which comprises the following steps: firstly, reacting hexafluoroisopropanol with p-toluenesulfonyl chloride to generate an organic phase, then reacting with a cyano source to obtain 3, 3, 3-trifluoro-2-(trifluoromethyl) propionitrile, then reacting with an acid solution and a reducing agent in sequence to obtain hexafluoroisobutanol, and finally reacting with an acid solution and a reducing agent to obtain the hexafluoroisobutanol. And finally, carrying out alkali dehydration to generate hexafluoroisobutene. The preparation method provided by the invention is simple in process route and mild in reaction condition, the solvent used in the preparation process can be recycled, the pollution in the preparation process is reduced, and the preparation method is less in three wastes, environment-friendly and suitable for large-scale production.

The invention provides a special fiber material and a preparation method thereof, and belongs to the technical field of polymer composites.The preparation method comprises the following steps that cellulose and an ethanol solution are mixed, polyvinyl alcohol and a 3-glycidoxypropyltrimethoxysilane solution are added, the pH is adjusted to be acidic, heating, suction filtration and drying are conducted, and modified cellulose is obtained; mixing expanded graphite, deionized water, ammonium persulfate and dilute sulphuric acid, heating, cooling, dropwise adding amino polyethylene glycol silane, heating, washing and drying to obtain modified expanded graphite; the preparation method comprises the following steps: mixing modified cellulose, modified expanded graphite, phosphate montmorillonite, 3-(methacryloyloxy) propyltrimethoxysilane, bisphenol A diglycidyl ether and 2-methylimidazole, stirring, heating, defoaming, and carrying out two-stage constant-temperature treatment to obtain the special fiber material. The special fiber material disclosed by the invention has good flame retardance, mechanical strength, water resistance and filtering performance, and can be applied to various organic composite boards, filter membranes and the like with high quality requirements.

The invention belongs to the technical field of ceramic connection, and discloses a silicon carbide pipe sealing connecting piece for laser-assisted high-entropy glass connection and a preparation method and application thereof. According to the method, silicon oxide, aluminum oxide, titanium oxide, iron oxide and rare earth oxide which are equal in mole are subjected to planetary ball milling, rotary evaporation, drying and sieving to prepare solder powder. And slurry obtained by mixing an isobutylene maleic anhydride polymer 104 aqueous solution and solder powder is added from the other end assembled by the silicon carbide cladding tube and the end plug, and a to-be-connected piece is obtained. And placing the to-be-connected piece in laser equipment, heating the connection part through laser in different atmospheres until the connection part is molten, and rapidly cooling to obtain the high-entropy glass connected silicon carbide pipe sealing connection piece. The connecting layer of the connecting piece is compact, the connecting piece is tightly combined with the silicon carbide cladding pipe and the end plug of the silicon carbide cladding pipe, the connecting piece has good corrosion resistance and sealing performance, high mechanical strength is kept at 800 DEG C, and the connecting piece can be applied to the field of silicon carbide ceramic cladding end plug sealing.

Provided is a photocurable resin composition comprising components (A) to (D), wherein the content of each of the components is within a specific range.　Component (A) is a polymer which has a number-average molecular weight of 1,000-100,000 and which has a polyisobutylene skeleton and two or more (meth)acryloyl groups. Component (B) is a monofunctional (meth)acrylate compound which has a C4-18 linear or branched hydrocarbon group and which has one (meth)acryloyl group per molecule. Component (C) is inorganic particles which have an average particle size of 0.1-200 μm and the surfaces of which are modified by an organic group. Component (D) is a photoradical polymerization initiator.

The present application relates to specifically defined copolymers, a method for their preparation, a complex containing this copolymer, the use of the copolymer for solubilizing and stabilizing membrane proteins as well as a kit for this use containing the polymers according to the present invention.

The invention relates to the technical field of agricultural fertilizers, in particular to a slow / controlled-release fertilizer for saline-alkali soil and a preparation method of the slow / controlled-release fertilizer. The slow / controlled-release fertilizer sequentially comprises a core layer, an inner coating, a shell layer and an outer coating from inside to outside, the core layer comprises a functional aid, diammonium hydrogen phosphate, urea, isobutylidene diurea, potassium nitrate and biochar; a shell layer contains bagasse, a compound strain and fulvic acid; the coating material is an adhesive containing montmorillonite powder; the functional additive is loaded with an organic acid and polymethacrylamide network through modified diatomite, so that the synergistic effect of sodium ion adsorption, acid-base regulation and nutrient slow release is realized; through the multi-layer structure design and the component synergistic effect, it is guaranteed that the slow and controlled release fertilizer can improve the saline-alkali soil structure in a long-acting mode, accurately regulate nutrient release and improve the stress resistance of crops, and the slow and controlled release fertilizer is suitable for efficient utilization of saline-alkali soil.

A container closure, particularly a vacuum turnlock closure, comprises a sealing element containing or made of a polymer compound (excluding PVC). The polymer compound comprises at least one polybutene polymer, at least one polymer derived from at least partially 1,2-bonded isobutylene monomer, at least one (co)PP polymer, and optionally other components and additives. In a preferred embodiment, the polybutene polymer is a copolymer with ethylene in particular. In a preferred embodiment, the polybutene polymer has a Shore A hardness of less than 85.

The invention relates to a polyisobutylene polyether alcohol amine compounds and compositions thereof. The invention also is directed to a new process for making the polyisobutylene polyether alcohol amine compound(s) by reacting a polyisobutylene epoxide with a specific polyetheramine, a protic solvent, a diluent, and optionally a catalyst. In addition, the invention further relates to the many uses of the polyisobutylene polyether alcohol amine compound(s) and composition(s) including but not limited to its use in lubricants, surfactants, emulsifiers, adhesives, resins, and the like.

The invention provides low-ash low-sulfur vehicle lubricating oil and a preparation method thereof, and belongs to the technical field of lubricating oil. According to the invention, an amphiphilic molecular structure is generated through modified polyisobutylene succinic anhydride and polyamidoamine, a supramolecular ordered film is formed through self-assembly, combustion products and carbon deposition particles are captured, and ash content and sediment generation are reduced, so that the performance requirements of low-ash-content and low-sulfur lubricating oil are met; the reversible reaction of N-(2-aminoethyl) maleimide and 2, 5-bis (aminomethyl) furan is adopted to endow molecular broken bond-recombination self-repairing capability, and micro cracks of a lubricating system are repaired; for the anti-wear agent, UV / O3 is adopted to activate MXene, and multi-step modification of tributyl borate and fluoroalkyl silane is combined, so that the lubricating oil is endowed with low friction coefficient, high thermal stability and excellent dispersing performance, lasting lubrication and effective protection are provided under high-temperature and high-pressure conditions, and lasting lubrication protection under extreme working conditions is realized.

The invention discloses a durable corrosion-resistant water-stop belt and a preparation method thereof, and relates to the technical field of compositions containing polyisobutene high-molecular compounds. The durable corrosion-resistant water-stop belt is prepared from the following raw materials in parts by mass: 30 to 60 parts of ethylene propylene diene monomer, 20 to 40 parts of polyisobutene, 20 to 50 parts of filler, 0.5 to 3 parts of antioxidant, 0.5 to 3 parts of anti-aging agent, 1 to 5 parts of peroxide cross-linking agent and 1 to 10 parts of processing aid. Through the synergistic effect of the specific anti-aging agent and the antioxidant, photo-oxidative aging and thermo-oxidative aging of the material are effectively inhibited. The anti-aging agent absorbs ultraviolet rays and converts the ultraviolet rays into heat energy to prevent the ultraviolet rays from damaging polymer chains; and the antioxidant delays oxidative degradation. The two layers form double protective barriers, so that the service life of the waterstop is greatly prolonged, and the performance attenuation trend is slowed down. Through material innovation (anti-aging agent + PBS + EPDM) and process optimization (segmented mixing / cooling), three core advantages of prolonging the service life, strengthening corrosion resistance and improving construction convenience are synchronously realized.

The invention relates to a new and improved process for making an epoxidized olefin, specifically, polyisobutylene epoxide. The inventive process generally comprises (a) combining a polyisobutylene and a solvent to form a first mixture, (b) combining a peroxide, a carboxylic acid and an acid catalyst to form a second mixture, (c) reacting the first and second mixtures forming a non-aqueous phase comprising a polyisobutylene epoxide and an aqueous phase; (d) separating the non-aqueous phase from the aqueous phase; (d) washing and neutralizing the non-aqueous phase, and (e) recovering in a high yield and high purity polyisobutylene epoxide. It was discovered that specific mole ratios and amounts of reactants provide for recovering in high yield and purity polyisobutylene epoxide with reduced detrimental by-products.

A composite board, including a core, and a capstock positioned to at least partially cover the core, where the capstock includes 10 wt. % to 70 wt. % of polyvinyl chloride (PVC), based on a total weight of the capstock, 1 wt. % to 60 wt. % of acrylonitrile-styrene-acrylate (ASA), based on the total weight of the capstock, 1 wt. % to 60 wt. % of styrene-acrylonitrile (SAN), based on the total weight of the capstock, and 1 wt. % to 60 wt. % of a thermoplastic elastomer, where the thermoplastic elastomer includes styrene-isobutylene-styrene (SIBS), a thermoplastic copolyester elastomer, a polymeric plasticizer, and combinations thereof, wherein the capstock does not include thermoplastic polyurethane.

The invention belongs to the technical field of production processes of chemical products, and relates to a device and a method for continuously preparing 2-acrylamido-2-methylpropanesulfonic acid. The annular pipeline reaction system comprises a crystallization reactor, a tubular reactor group and a mother liquor internal circulation pipeline which form an annular passage; the solid-liquid separation refining system comprises a solid-liquid separation device, a reduced pressure distillation device, a product refining device, a drying device and a heat exchanger; the external circulation and feeding system comprises a mother liquor external circulation pipeline, an isobutene feeding pipeline, a sulfuric acid feeding pipeline, an acrylonitrile feeding pipeline and an acrylonitrile reflux pipeline; the acrylonitrile feeding pipeline is divided into three branches, one branch is connected with the crystallization reactor, one branch is converged with the isobutene feeding pipeline, the mother liquor external circulation pipeline and the acrylonitrile backflow pipeline to be connected with an isobutene feeding port, and the other branch is converged with the sulfuric acid feeding pipeline, the mother liquor external circulation pipeline and the acrylonitrile backflow pipeline to be connected with a sulfuric acid feeding port. According to the invention, the production efficiency is improved, and the yield and purity of the product are higher.

The invention provides a gas engine lubricating oil composition and a preparation method thereof. The gas engine lubricating oil composition of the present invention comprises: (A) an alkyl phosphate compound; (B) alkylated diphenylamine; (C) a polyisobutylene succinic acid pentaerythritol ester dispersing agent; (D) a salicylate and / or sulfonate; (E) zinc dialkyl dithiophosphate; (F) an oil-soluble organic molybdenum friction modifier; (G) a metal corrosion inhibitor; (H) a pour point depressant; (I) a major amount of a lubricating base oil. The gas engine lubricating oil composition disclosed by the invention has excellent high-temperature oxidation resistance, cleaning performance, extreme pressure anti-wear performance and anti-corrosion performance.

The invention relates to a device and a method for preparing isobutene and methanol by cracking methyl tert-butyl ether. The device comprises a methyl tert-butyl ether vaporization refining tower, a reactor, a cooling tower, an absorption tower, a methanol extraction tower, an isobutene light component removal tower and an isobutene heavy component removal tower which are sequentially connected along a material conveying direction, a top discharge hole of the cooling tower is connected with a lower gas-phase material inlet of the absorption tower; an absorbent outlet at the bottom of the absorption tower is circularly connected with a cooling absorption liquid inlet at the top of the cooling tower; the bottom extract liquor outlet of the methanol extraction tower is circularly connected with the top absorbent inlet of the absorption tower; an isobutylene discharge hole is formed in the top of the isobutylene heavy component removal tower; the device further comprises a methanol recovery tower and a methanol refining tower which are connected in sequence along the material conveying direction; a bottom cooling absorption liquid outlet of the cooling tower is connected with the methanol recovery tower; a methanol discharge hole is formed in the bottom of the methanol refining tower. The device provided by the invention not only can relax the limitation of the purity of methyl tert-butyl ether in raw materials, but also can prepare high-purity isobutene and high-purity methanol at the same time.

The invention relates to the technical field of tire rubber manufacturing, and discloses a low-odor low-VOC sidewall rubber composition, a mixing method thereof and a tire, a brominated copolymer (BIMS) of isobutene and p-methylstyrene is adopted, and the use of an amine anti-aging agent is canceled; according to the invention, tetrabenzylthiuram disulfide (TBzTD) is adopted as a main accelerant, and a traditional sulfenamide accelerant is replaced; the softening and reinforcing resin is adopted to replace an oil softener, so that small molecular substances in aromatic hydrocarbon oil or naphthenic oil are prevented from being separated out, and phenol possibly generated by using phenolic resin is avoided; carbon black is matched with a small amount of white carbon black, so that odor molecules are effectively adsorbed; and the steps of lifting an upper top peg and opening a charging door for exhausting are added in the plastifying and mixing sections. The synergistic effect of the optimized formula raw materials effectively avoids the generation of odor molecules, the escape of a large number of VOC molecules is improved, and the exhaust step further reduces the residual quantity of the VOC molecules in the final mixed rubber, so that the odor grade of the tire is improved.