133 results about "Isobutylene" patented technology

This invention discloses a catalyst for the alkylation of tert-butanol with styrene to prepare tert-butylethylbenzene and ethylbenzene, its preparation method, and its application. The catalyst consists of a support and active components loaded on the support. The active components are oxides of rare earth metals and high-valence oxides of transition metals. The support is H-β zeolite. The mass contents of the oxides of rare earth metals and high-valence oxides of transition metals on the support are 3-5% and 2-4%, respectively. This invention makes a breakthrough in the reaction mechanism by loading rare earth metals and transition metals onto a β-molecular sieve and using tert-butanol and styrene as raw materials for alkylation. This avoids the polymerization of styrene (raw material) and the dimerization of isobutylene (intermediate product), reduces the generation of by-products, and makes the catalytic process controllable.

The application belongs to the technical field of lubricating oil additives, and particularly relates to a polyisobutylene succinimide dispersant as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing polyisobutylene maleic anhydride, base oil and aromatic hydrocarbon solvent, then adding aminobenzene boronic acid, and performing reaction by increasing temperature to reflux temperature, and obtaining the polyisobutylene succinimide dispersant after filtration. The polyisobutylene succinimide dispersant is prepared by using polyisobutylene maleic anhydride and aminobenzene boronic acid, the molecular structure of the polyisobutylene succinimide dispersant contains not only an aromatic ring but also an oxygen-containing benzene boronic acid group, the aromatic ring and the benzene boronic acid group both have a good adsorption effect on soot particles, and the ability of the polyisobutylene succinimide dispersant to disperse soot is improved. The performance test results show that the oil product prepared by using the polyisobutylene succinimide dispersant of the application not only improves the soot dispersion performance of the oil product, but also improves the high-temperature detergency of the oil product, and the preparation process is simple and easy to implement.

The application provides a hybrid vehicle engine lubricating oil composition and a preparation method thereof.The hybrid vehicle engine lubricating oil composition comprises the following components: (A) a benzotriazole derivative; (B) a composite antioxidant comprising an alkylated diphenylamine antioxidant and a sulfide phenolic antioxidant; (C) a polyisobutylene succinimide ashless dispersant; (D) a sulfonate and / or a sulfated alkyl phenate; (E) a zinc dialkyldithiophosphate; (F) a composite friction modifier comprising an oil-soluble organic molybdenum friction modifier and an ashless friction modifier; (G) a phosphite type extreme pressure antiwear agent; and (H) a major amount of a lubricating oil base oil; wherein the structure of the benzotriazole derivative is shown in formula (I): wherein the definitions of the groups are shown in the specification.The hybrid vehicle engine lubricating oil composition has excellent antioxidant performance, corrosion resistance and rust resistance, and good emulsion retention performance and wear resistance.

This invention relates to a matting agent for water-based paints and its preparation method, belonging to the technical field of matting agents. In the preparation of the matting agent, N-methyl-3-aminopropyltrimethoxysilane and N-(2-aminoethyl)-3-aminopropyltrimethoxysilane are added simultaneously to synthesize an organically modified silica matting agent, introducing an amino structure and improving the water wettability of silica. Simultaneously, N-(2-aminoethyl)-3-aminopropyltrimethoxysilane also assists ammonium phosphate in acting as a pore-forming and compatibilizing agent, thereby enhancing the matting effect of the matting agent. Furthermore, the addition of methyl 2-hydroxypropyl isobutylene ensures a greater surface roughness of the matting agent, and also ensures that the coating surface has a lower gloss when used in paint.

This application discloses a method for preparing n-butene from isobutene, comprising the following steps: contacting a raw material containing isobutene with a catalyst and reacting to obtain a product containing n-butene; the catalyst is composed of MgAl2O4 and a hierarchical porous molecular sieve; and obtaining the catalyst through the following steps: 1) subjecting the molecular sieve to alkali treatment and acid treatment in sequence to obtain the porous molecular sieve; 2) wet mixing of magnesium source and aluminum source and calcining to obtain the MgAl2O4; 3) mixing the porous molecular sieve with the MgAl2O4 and calcining to obtain the catalyst.

The application discloses a device and method for preparing tert-butylamine by directly ammoniating isobutene, which comprises sequentially connected raw material preparation unit, reaction separation unit, rectification separation unit and circulating recovery unit; the raw material preparation unit is used for storing, mixing and heating raw materials; the reaction separation unit is used for pressurizing reaction of the raw materials in the raw material preparation unit and gas-liquid separation of products; the rectification separation unit is used for rectification separation of liquid-phase products separated by the reaction separation unit and recovery of part of unreacted raw materials; and the circulating recovery unit is used for rectification recovery of part of raw materials of gas-phase products separated by the reaction separation unit. The application has the characteristics of low overall equipment investment, high energy utilization rate, simple product separation and purification, perfect overall device design and small environmental pollution.

This invention relates to low-odor extreme pressure agents, gear oil additive compositions, gear oil compositions, and methods for their preparation. The extreme pressure agents comprise components having the structure shown in Formula I, where n is a positive integer from 1 to 5; R1 and R2 may be the same or different; R1 and R2 are independently selected from C... 1～12 Alkyl, substituted or unsubstituted C 3～10 cycloalkyl, substituted or unsubstituted C 6～14 aryl or the structure shown in Formula II; in Formula II, R3 is selected from C 1‑4 Alkylene; the substituted C 3～10 Substituents of cycloalkyl groups, substituted C 6～14 The substituents of the aryl group are each independently selected from hydrogen, halogen, and C. 1～5 One or more alkyl groups. The extreme pressure agent and gear oil additive composition of the present invention has a low odor, mainly solving the problem of unbearable odor caused by the addition of sulfurized isobutylene in existing products.

The application belongs to the technical field of pipeline connecting structure, and discloses an antistatic flexible connecting structure and a pipe network connecting assembly, which comprises a flexible connecting bellows used for connecting two pipeline bodies, and the composition of the flexible connecting bellows is as follows in terms of weight percentage: polyolefin elastomer 40%-60%, carbon black 15%-25%, vinyl elastomer 5%-15%, antistatic additive 1%-5%, heat stabilizer 0.5%-2%, ethylene-vinyl alcohol copolymer 5%-10%, lubricant 0.5%-2%, and the balance is polyisobutylene. In the application, the components synergistically act to make the flexible connecting bellows have good flexibility, mechanical property, elasticity, fatigue resistance and sealing property, have antistatic characteristics, have good processing and molding effects, can prevent thermal aging degradation, and guarantee core performance.

This invention discloses a firming and wrinkle-reducing eye cream, comprising a moisturizer, a whitening agent, a skin repair additive composition, a thickener, a preservative, a film-forming agent, a skin moisturizer, and a surfactant. The weight ratio of the moisturizer, whitening agent, anti-aging additive composition, thickener, preservative, film-forming agent, skin moisturizer, and surfactant is 20:1:2:3:0.3:0.5:1:0.2. The moisturizer includes butylene glycol, glycerin, polydimethylsiloxane, and hydrogenated polyisobutylene. The skin-repairing additive composition includes hydroxypropyl tetrahydropyranotriol, adenosine, cell growth factors, ceramides, and salicylic acid, comprising olefins, betaine, trehalose, 1,2-hexanediol, hydrogenated lecithin, allantoin, and Euglena galactosides. The film-forming agents include polyacrylamide, cyclohexylsiloxane, and polydimethylsiloxane alcohol. The emollients include C13-14 isoparaffins, polydimethylsiloxane / vinyl dimethylsiloxane crosspolymers, and cyclopentamethoxysiloxane. This invention can repair cells and provide long-lasting anti-wrinkle and whitening protection for the corners of the eyes.

The application relates to the field of lubricating oil, in particular to a high-temperature-resistant high-lubricating stainless steel cutting oil and a preparation method thereof. The cutting oil is composed of base oil, extrusion agent, additive, anti-emulsifier and diluent in specific proportions, wherein the additive comprises polyisobutylene succinic anhydride, amine and propylene oxide polymer, boron-containing compound, basic alkyl salt, imidazoline oleate, antioxidant compound and ethylene-propylene copolymer. By optimizing the proportions of various components and selecting suitable materials, the application can significantly improve the oxidation resistance and cleanliness of the cutting oil, effectively prolong the temperature of the cutting oil in the recycling and reuse process, reduce equipment wear and contamination, and improve the production efficiency of stainless steel.

This invention belongs to the field of coolant technology, specifically relating to a coolant and its application in an immersion liquid-cooled energy storage system. The coolant, by weight, comprises 80-95 parts base oil, 1-5 parts thermally conductive nanoparticles, 0.5-2 parts composite dispersant, 0.3-1 part composite corrosion inhibitor, 0.1-0.5 parts antioxidant, 0.2-0.5 parts pour point depressant, and 0.01-0.05 parts defoamer. The base oil is a mixture of polyalphaolefin and synthetic ester, and the composite dispersant is a compound of polyisobutylene succinimide and Mannich base dispersant. Aging tests show that this coolant exhibits high thermal conductivity retention, low acid value increase, and low corrosion rate. The coolant of this invention can effectively maintain the dispersion stability of nanoparticles in the environment of precipitates from sealing materials, extending the fluid change cycle.

This invention relates to the field of metal protection and lubrication materials, and discloses a silent, vibration-damping, film-forming, long-lasting rust-preventive oil for bearings and its preparation method. The rust-preventive oil comprises a base oil, a dynamic borate ester-organosilicon-tungsten bridging synergistic modifier, itaconic acid hydrazine, a dimer ester, calcium petroleum sulfonate, polyisobutylene, a phosphate extreme pressure agent, and an antioxidant. The dynamic borate ester-organosilicon-tungsten bridging synergistic modifier forms a reversible dynamic covalent network of borate esters with phenylboronic acid through a diol-based compound, and then undergoes a confined sol-gel polymerization reaction with vinyltriethoxysilane to form silicon-oxygen segments. These segments are then coordinated and bridged by tungstate and diol groups to construct a three-dimensional coupled structure. The rust-preventive oil of this invention has advantages such as high film density, strong adhesion, good vibration damping and noise reduction effect, and strong rust prevention durability, making it suitable for the storage and operational protection of high-end bearings.

This invention proposes a lubricating oil composition for a four-stroke engine specifically designed for unmanned aerial vehicles (UAVs) and its preparation method. The lubricating oil composition for a four-stroke engine of this invention comprises the following components: (A) a nitrogen-containing organoboron compound; (B) an alkyl diphenylamine; (C) polyisobutylene succinimide; (D) sulfonates and / or sulfurized alkylphenol salts; (E) zinc dialkyl dithiophosphate; (F) dialkyl dithiocarbamate; (G) polymethyl methacrylate; and (H) a base oil in a major amount. The structure of the nitrogen-containing organoboron compound is shown in formula (I) and / or formula (II), with the definitions of each group provided in the specification. The lubricating oil composition for a four-stroke UAV engine of this invention exhibits excellent extreme pressure anti-wear, anti-oxidation, and detergency properties, effectively suppressing the increased wear caused by the high power-to-weight ratio and harsh lubrication conditions of four-stroke UAV engines.

This invention belongs to the field of lithium-ion secondary battery technology, specifically relating to a method for transferring a solid electrolyte membrane, an electrode with a solid electrolyte membrane on its surface, and a solid-state battery. This invention obtains an adhesive with both moderate adhesion and high elasticity by compounding polyisobutylene with a styrene-ethylene-butene-styrene block copolymer (SEBS). This adhesive utilizes the synergistic effect of polyisobutylene providing interfacial adhesion and SEBS providing stress buffering, achieving temperature-sensitive transfer control with low-temperature pickup and high-temperature release within a specific temperature range. By adjusting the ratio of polyisobutylene to SEBS, a rigid-tough layer formulation for the positive electrode and a flexible layer formulation for the negative electrode are obtained, further constructing a bilayer solid electrolyte membrane. This invention achieves high-fidelity transfer of the solid electrolyte membrane to the electrode, significantly reducing interfacial defects and short-circuit risks, improving the cycle stability and thermal safety of the battery, and is suitable for the large-scale manufacturing of high-energy-density all-solid-state batteries.

The application belongs to the field of high polymer materials, and discloses a volatile-preventing and string-preventing high-barrier butyl rubber septum material and a preparation method thereof. The material comprises, by weight, butyl rubber 90-110 parts, modified sheet layer filler 5-12 parts, silane coupling agent containing dynamic bond 2-5 parts, polyisobutylene core-fluorine-containing hydrophobic shell core-shell microsphere 1-3 parts, vulcanizing agent 1.5-3 parts, vulcanization accelerator 0.8-2 parts, and activator 3-5 parts. By constructing a triple synergistic structure of "sheet layer directional barrier-dynamic interface plugging-matrix hydrophobic network interception", the penetration and stringing of volatile organic components in the sealing system are effectively inhibited. The preparation method comprises the steps of sheet layer filler modification, rubber matrix mixing, dynamic vulcanization and post-molding vulcanization, and has high controllability. The prepared material has excellent gas barrier property, puncture resistance and low-temperature elasticity, and is suitable for chromatographic sample bottle sealing systems.

The application relates to the technical field of light-adjusting films, and particularly discloses a low-voltage-driven intelligent dynamic light-adjusting film and a preparation method thereof. The low-voltage-driven intelligent dynamic light-adjusting film comprises a transparent substrate, a transparent electrode and an electrophoretic medium layer, the transparent electrode is plated on one side of the transparent substrate, the transparent electrode is bonded with the electrophoretic medium layer through an adhesive, and the components of the electrophoretic medium layer include electrophoretic particle microcapsules and a binder. The electrophoretic particle microcapsules are used for storing an internal phase, the components of the internal phase include electrophoretic particles, a charge control agent, a stabilizer and a dispersed mobile phase, and the components of the stabilizer include polyisobutylene succinimide. The polyisobutylene succinimide is used for increasing the steric hindrance of the inner surface of the capsule wall, hindering the agglomeration of the electrophoretic particles on the inner surface of the capsule wall, and increasing the light transmittance adjustment range of the light-adjusting film under low-voltage driving.

This application relates to the field of lubricating greases, and more particularly to a high and low temperature resistant, fretting-wear-resistant harmonic reducer grease. To improve the lubrication effect of the grease in harmonic reducers at high and low temperatures, this application employs a composite molybdenum complex system of molybdenum dialkyldithiocarbamate and molybdenum amine complex. Simultaneously, polyisobutylene is used to improve stability and film-forming properties at high temperatures, and polyurea micropowder is used to improve viscosity at low temperatures, thus forming a uniform lubrication system that exhibits excellent lubrication performance at both high and low temperatures.

A working medium for a heat cycle includes trifluoroethylene, a low boiling point compound having a lower boiling point than the boiling point of the trifluoroethylene, and high boiling point compounds having higher boiling points than the boiling point of the trifluoroethylene. In the working medium, the low boiling point compound is at least one selected from the group consisting of carbon dioxide, R116, and R41, and the high boiling point compounds are at least two selected from the group consisting of HFC-32, HFO-1234yf, HFO-1234ze (E), HFO-1243zf, PFC-14, HFC-134, HFC-143a, HFC-227ea, cyclopropane, isobutene, isobutane, dimethyl ether, and ammonia. An application of the working medium is provided.

The present disclosure provides devices, systems incorporating the devices, methods for manufacturing the devices, and methods of using the devices for carrying out assays, such as chemical and / or biological assays. The systems include a wearable device including a biosensor having a plurality of electrodes. A functionalized coating is coupled to an electrode of the biosensor. A controller may sense an electrochemical response of the biosensor, and determine whether a health-related biomarker is present based on the electrochemical response. The functionalized coating may include a sulfonated block copolymer such as sulfonated styrene-isobutylene-styrene (SIBS). The health-related biomarker may include cardiac troponin I (cTnI).

The present application relates to the technical field of adhesive, especially to the field of IPC C09J7, more particularly to a hot melt pressure sensitive adhesive for adhesive plaster and a preparation method thereof. The hot melt pressure sensitive adhesive component comprises 15-40 parts of main polymer, 45-60 parts of petroleum resin, 20-40 parts of filling oil, 5-20 parts of liquid rubber and 0.1-5 parts of auxiliary agent. The weight ratio of the main polymer and the liquid rubber is 3: (1-2), which can effectively improve the peeling strength (24N / in) and the bonding performance (22N / in) of the pressure sensitive adhesive 2 ); polyisobutylene comprises PB950 (Daling) and PB1300 (Daling), and the weight ratio of the PB950 (Daling) and the PB1300 (Daling) is 1: (2-4), which can balance the initial adhesion and the peeling strength, and can also reduce the residual glue rate between the skin, and is suitable for the adhesive plaster glue layer.

The application belongs to the technical field of adhesives and sealants, and specifically provides a sealing wax as well as a preparation method and application thereof. The sealing wax comprises the following components in parts by mass: microcrystalline wax 40-60 parts, polyethylene wax 1-5 parts, ethylene-vinyl acetate copolymer 3-8 parts, low-molecular-weight polyisobutylene 2-5 parts, medium-molecular-weight polyisobutylene 2-5 parts, tackifying resin 15-20 parts, and flame retardant 3-5 parts. The number-average molecular weight of the low-molecular-weight polyisobutylene is less than 5000, and the viscosity-average molecular weight of the medium-molecular-weight polyisobutylene is 10000-40000. Through the design and mutual compounding of the components, the sealing wax has a high melting point, a low water absorption rate, a high volume resistivity, good high-temperature and low-temperature resistance, and strong waterproof and moisture-proof performance, high mechanical strength and toughness, high insulation, high transparency, and strong sealing effect, and has good flow leveling property and good flame retardant performance, and can meet the strict use requirements of high-end electronic equipment.

This invention discloses a novel method for preparing a clean fuel additive, relating to the field of clean fuel additive technology. Its components include: a main cleaning agent: Mannich base; a dispersant: polyetheramine; a surfactant: highly active polyisobutylene; an antioxidant: N,N-di-sec-butyl-p-phenylenediamine; an octane booster: dimethyl carbonate; a solvent: 120# solvent oil; a combustion improver: C9-C11 mixed olefins; a stabilizer: trimethylolpropane; an ignition promoter: nitrobenzene; and auxiliary additives: n-dodecane, sodium polystyrene sulfonate, and eugenol methyl ether. This invention achieves a significant synergistic effect among the core components such as Mannich base, polyetheramine, polyisobutylene, amine antioxidants, and dimethyl carbonate. This synergistic effect allows the additive to comprehensively optimize the cleanliness, anti-knock properties, stability, and combustion efficiency of fuel at a relatively low total addition amount.

The application discloses a method for normalizing mixed C4 olefins containing isobutene. The method comprises the following steps: 1) adding 1-20wt% of tert-butyl alcohol into mixed C4 hydrocarbon; 2) feeding the obtained mixed raw material into a normalizing unit to generate normal butene under the conditions of 280-400 DEG C and normal pressure. The normalizing catalyst comprises the following components: a) 10-20wt% of a binder; and b) 80-90wt% of ZSM-35 molecular sieve. In the method, the tert-butyl alcohol can be hydrolyzed into isobutene and water in the reaction process, the isobutene can be used as the C4 raw material, the water can react with the C4 olefins to generate the intermediate product C4 alcohol, the C4 alcohol can be dehydrated to generate normal butene, and in addition, the water can play a role in inhibiting the hydrogenation of the raw material or the intermediate in the reaction system, thereby reducing the generation probability of alkanes and improving the selectivity of normal butene. The method can efficiently and stably convert the C4 olefins in the raw material into normal butene-rich product, and provides an effective way for synthesizing normal butene.

This invention discloses an ultra-thin, tensile-reinforced packaging film, relating to the field of agricultural packaging film technology. The film has a seven-layer co-extruded structure with a total thickness of 15–22 micrometers. It comprises an outer surface unwinding weather-resistant layer, an inner surface adhesive layer, a core layer with pinhole self-sealing in the middle, and tensile-reinforced crack-blocking layers on both sides. The core layer contains a polyisobutylene sealing phase, a dynamic ionic framework composed of a blend of sodium and zinc ionomers and unneutralized ethylene-acid copolymer, and a compatibilizer containing epoxy-based ethylene copolymers. The molar ratio of epoxy to free acid groups is 0.05–0.25, resulting in polyisobutylene forming a sealing microdomain with a median particle size of 0.3–1.2 micrometers and 90% of the particles having a diameter no greater than 2.5 micrometers. The blocking layer contains a microfibrillated reinforcing phase. Under pre-tension, the film can quickly seal pinholes and reduce oxygen intrusion, while simultaneously inhibiting the migration of the sealing phase, reducing in-roll adhesion and downtime for repairs.

This invention discloses a high-resilience EPDM rubber sealing gasket and its preparation method, belonging to patent classification number C08K13 / 02, and relating to the field of EPDM rubber technology. The method first introduces flexible segments composed of liquid polyisobutylene and hydroxyl-terminated polybutadiene into an EPDM matrix to construct a low-energy-consumption subelastic network; then, a core-shell structure filler with silica as a rigid core and acrylate copolymer as an elastic shell is prepared to eliminate the rigid constraints of traditional filler interfaces; simultaneously, hyperbranched polyesteramide and nano-boron nitride are introduced as a synergistic system to bridge the polarity difference between the flexible segments and the core-shell filler through molecular bridging, and to reduce energy loss by utilizing the low friction and thermal conductivity of nano-boron nitride. The resulting sealing gasket exhibits high resilience, low compression set, and excellent mechanical strength.

The present application relates to the technical field of fluorinated chemical industry, and particularly relates to a method for removing perfluoroisobutene in mixed gas, comprising the following steps: passing the mixed gas containing perfluoroisobutene through a perfluoroisobutene absorption membrane to remove perfluoroisobutene therein; wherein the perfluoroisobutene absorption membrane comprises a perfluoroisobutene absorbent, the perfluoroisobutene absorbent comprises solid alcohol and solid acid, and the mass ratio of the solid alcohol to the solid acid is (70-95):(5-30). The method can completely absorb perfluoroisobutene in the mixed gas, the crude cracking gas generated in the process of producing hexafluoropropylene by thermal cracking is treated by the method, the perfluoroisobutene removal effect is good, the cracking gas is not polluted, no additional purification operation is needed, the utilization rate of the absorbent is more than 90%, and the method has good popularization and application value.

The application discloses a method for recycling and utilizing isobutylene amination waste liquid, and steps of the method comprise the following: the isobutylene amination waste liquid and heated ammonia gas are introduced into a reaction rectifying tower, the tower is filled with an ammonolysis catalyst bed layer, the isobutylene amination waste liquid and the ammonia gas are reversely contacted in the catalyst bed layer, an ammonolysis reaction is carried out, and a tert-butylamine product is obtained. The method is extremely simple in process, low in equipment investment and operation cost, can recycle and utilize the isobutylene amination waste liquid, reduces product unit consumption and device operation cost, greatly reduces three-waste emissions, and is more green and environment-friendly.

This invention provides a method and system for preparing ethylene glycol mono-tert-butyl ether, relating to the field of chemical synthesis technology. The method for preparing ethylene glycol mono-tert-butyl ether includes: in a plug flow reactor, ethylene glycol and isobutylene undergo an etherification reaction in the presence of a liquid acid catalyst to obtain a mixture one; the mixture one is subjected to azeotropic separation to obtain a mixture two containing ethylene glycol mono-tert-butyl ether and ethylene glycol di-tert-butyl ether; the mixture two is purified and separated to obtain ethylene glycol mono-tert-butyl ether and ethylene glycol di-tert-butyl ether respectively; the separated ethylene glycol di-tert-butyl ether is returned to the plug flow reactor so that the subsequent etherification reaction can be carried out in the presence of ethylene glycol di-tert-butyl ether. This invention utilizes a plug flow reactor reaction and reactive distillation technology, and employs a liquid acid catalyst to provide a high concentration of protons, reducing the activation energy of the reaction, thereby efficiently activating the reactant molecules and achieving the goal of efficiently producing ethylene glycol mono-tert-butyl ether.