829 results about "Propenyl" patented technology

A process for producing 2-acrylamide-2-methyl propane sulfonic acid (ATBS) which comprises reacting acrylonitrile, fuming sulfuric acid, and isobutylene. During the reaction, the concentration of 2-methyl-2-propenyl-1-sulfonic acid (IBSA) and / or that of 2-methylidene-1,3-propylenedisulfonic acid (IBDSA) in the reaction system are determined. When the IBSA concentration exceeds 12,000 mass ppm and / or the IBDSA concentration exceeds 6,000 mass ppm, then the concentration of sulfur trioxide in the reaction system is reduced. Thus, ATBS having an IBSA content of 100 mass ppm or lower and an IBDSA content of 100 mass ppm or lower is produced.

The invention relates to a water-soluble drag reducer as well as a preparation method and application thereof. The preparation method is characterized by adding an emulsifier and solvent oil to a reactor to form an oil phase, adding a lipophilic propenyl monomer to the oil phase, dissolving a hydrophilic propenyl monomer in water, regulating the pH value to 8-9 to form an aqueous phase, slowly dropping the aqueous phase into the oil phase, carrying out emulsification while stirring, adding an initiator by times under the condition of introducing nitrogen, reacting at 30 DEG C for 48 hours, cooling, adding a polymerization inhibitor so as to obtain an inverse microemulsion system, and mixing the prepared inverse microemulsion system with a surfactant so as to obtain the water-soluble drag reducer. The water-soluble drag reducer is used in quick water fracturing fluid to reduce the friction drag of pipelines, reduces the pump power, improves the sand-carrying capacity of the construction fluid, is suitable for oil and gas exploitation of unconventional low permeability reservoirs, has good dissolving property and obvious drag reduction effect which can reach 50-70% compared with that of the clear water, and is convenient to use.

This invention relates to a functionalized co-oligomer having an Mn of 300 to 30,000 g / mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(−0.94(mole % ethylene incorporated)+100), when 10 to 60 mole % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mole % ethylene is present in the co-oligomer, and 3) X=(1.83*(mole % ethylene incorporated)−83), when 70 to 90 mole % ethylene is present in the co-oligomer. This invention also relates to a functionalized homo-oligomer, comprising propylene, wherein the oligomer has: at least 93% allyl chain ends, an Mn of about 500 to about 20,000 g / mol, an isobutyl chain end to allylic vinyl group ratio of 0.8:1 to 1.2:1.0, and less than 100 ppm aluminum. This invention also relates to a process of making functionalized homo- or co-oligomer, comprising propylene, wherein the productivity is greater than 4500 g / mmol Hf (or Zr) / hour.

In a process for producing a propylene-based olefin homopolymer or copolymer, a monomer composition comprising propylene is contacted with a polymerization catalyst system under homogeneous polymerization conditions (such as solution, supersolution or supercritical conditions), wherein the polymerization catalyst system includes an activator and a bridged bis-indenyl transition metal (group 4) compound substituted with a carbazole (unsubstituted or substituted) at the 4 position.

The invention discloses a method for preparing a dissaving vinyl or propenyl amide polymer, which can be used for preparing the dissaving vinyl or propenyl amide polymer with high conversion in a polar solvent system through reversible addition-fragmentation transfer polymerization by adopting a semi-continuous operating technique and using a diene monomer and a chain transfer agent with low proportion for RAFT polymerization. The polymerization process can be controlled easily and the molecular weight and distribution of the final product can be regulated and controlled.

The invention relates to a method for preparing high-hydroscopicity resin in uniform-phase aqueous medium by using straw as a raw material. The method comprises the following steps: adopting a double-phase saline aqueous solution system of inorganic acid and polyethylene glycol to sequentially process the straw to obtain cellulose; then, adding the cellulose to a pre-prepared sodium hydroxide-urea aqueous solution or a lithium hydroxide-urea aqueous solution; putting the solution in a refrigerator to be cooled, taking out the solution for mechanically stirring to obtain a uniform cellulose solution; afterwards, adding propenyl monomer to the obtained cellulose aqueous solution and carrying out homogeneous glycerol polymerization to obtain the high-hydroscopicity resin. The hydroscopicity resin has the advantages of low cost, high hydroscopicity and potential biodegradable characteristic and has wide application space in the fields, such as agriculture, forestry, sanitary health products, building materials, perfume emission, and the like.

The invention discloses an electroplating solution for acid copper-plating for a circuit board as well as a preparation method and an application method for the same. The electroplating solution disclosed by the invention is characterized in that a home-made synthesised levelling agent is added, and the levelling agent is matched with water-soluble copper salt, sulphuric acid, a brightening agent, chloride ions, a gloss agent and a surfactant to form the electroplating solution. The home-made levelling agent is one or more of the copolymer of N-vinyl imidazole onium salt and propenyl esters, and the polymer of N-vinyl imidazole and epoxides. The electroplating solution containing the home-made synthesised levelling agent is great in covering power and the dispersing power, capable of improving the uniform distribution of copper layers in the through holes of the printed circuit board, and capable of effectively reducing the ratio of the thickness of the surface copper layers to the thickness of the copper layers in the centres of the holes.

In a process for producing a propylene-based olefin homopolymer or copolymer, a monomer composition comprising propylene is contacted with a polymerization catalyst system under homogeneous polymerization conditions (such as solution, supersolution or supercritical conditions), wherein the polymerization catalyst system includes an activator and a bridged bis-indenyl transition metal (group 4) compound substituted with a carbazole (unsubstituted or substituted) at the 4 position.

The invention provides a slump loss resistant type gather carboxylate water-reducing agent, which is a polymer of prenyl polyoxyethylene ether or prenyl polyoxyethylene propenyl ether or methyl allyl polyoxyethylene ether or methallyl polyoxyethylene propenyl ether (a macro-monomer A) and unsaturated carboxylic acid (a micro-monomer B) and an unsaturated carboxylic acid derivative (a micro-monomer C), belonging to the field of concrete admixtures. A synthetic method is as follows: the water-reducing agent is prepared by initiating the macro-monomer A, the micro-monomer B and the micro-monomer C through an oxidative-reductive initiating system by taking water as a solvent at lower temperature, and carrying out copolymerization under the action of a chain transfer agent. The water-reducing agent overcomes the disadvantages of being poor in slump loss resistance, long in setting time and the like of the water-reducing agent synthesized by allyl polyoxyethylene ether and has the advantages of being high in slump loss resistance, good for being suitable to different cements and low in influence on concrete setting time.

The invention provides a preparation method for a molecular imprinting material and the molecular imprinting material prepared through the preparation method. The preparation method comprises the steps that silicon oxide is coated on the surfaces of magnetic ferroferric oxide nanometer particles, the magnetic ferroferric oxide nanometer particles are modified with gamma-(methacryloyl chloride) amino propyl trimethoxy silane to obtain magnetic ferroferric oxide nanometer particles with propenyl on the surfaces, the magnetic ferroferric oxide nanometer particles with the propenyl on the surfaces serve as carriers, estrogen receptors are simulated, functional monomers are optimized, a surface imprinting technology is adopted, and then the molecular imprinting material which can simultaneously identify seven kinds of environmental endocrine disrupting chemicals is prepared. According to the preparation method, the easy separation of a magnetic nanometer material, the good water solubility of a silicon oxide nanometer material, the specific recognition ability of molecular imprinting polymers and the surface imprinting technology are mutually combined, the preparation technology is simple, the conditions are mild, the prepared molecular imprinting material is large in adsorption capacity, fast to respond, high in magnetism, good in chemical stability and high in repeating utilization rate, and the problems that at present, multiple trace, steroid and phenol environmental endocrine disrupting chemicals are difficult to simultaneously identify, separate and enrich are solved.

The concrete water reducing agent of polycarboxylic acid is prepared through esterification between polyglycol and acrylic acid in the presence of catalyst to obtain esterified product PEA, and the copolymerization of the esterified product PEA with methyl propenyl sodium sulfonate and other sulfonate and acrylic acid. The concrete water reducing agent contains carboxy radical, sulfo radical and polyoxyethylene side chain. The concrete water reducing agent has low alkali content and high water reducing rate, and may be added into concrete in the amount of 0.6-1.2 wt% of gelatinous material to result in concrete with easy operation, high flowability, excellent placeability, no loss of slump and raised early strength. The concrete water reducing agent may be used as the important component of high performance concrete.

The invention discloses a preparation method of cefprozil, which comprises: 7-amin cethalosporanic acid (7-ACA) reacts with triphenyl phosphine to get 7- trimethylsilyl amino-3-triphenyl phosphate methylene-4-cethalosporanic acid trimethylsilyl ester through silanization protection and iodination reagent replacing under the condition of catalyst existing; WITTIG reaction is made for the product and acetaldehyde to get 7-trimethylsilyl amino -3-(propenyl-1-alkenyl)-4-cethalosporanic acidtrimethylsilyl ester; then the compound reacts with D-para hydroxybenzene glycine dane potassium salt to geta compound (6R, 7R)-7-[(2R)-2- ethoxycarbonyl-1-methyl - ethylene amino (4-trimethylsilyl oxyphenyl) acetamido group(amide)]-8-oxo-3- (1- propenyl)-5-thio-1- heterobicycle [4.2.0] octylene-2-ene-2-carboxylic acid trimethylsilyl ester; hydrolytic treatment is then used to get the cefprozil. The invent adopts the method of one pot and can participate in next reaction without separating intermediateproducts. The preparation method of cefprozil has the advantages of low cost, convenient operation and high overall yield, adapting to demands of industrial production.

A method of improving the yield and vigor of agronomic plants, in particular leguminous plants such as soybeans, involves treating such plants and / or the propagation material of plants with a composition that includes an active agent, such as a fungicide, that has no significant activity against fungal plant pathogens of the treated plant. When the plant is not wheat, a preferred agent of this type is 4,5-dimethyl-N-(2-propenyl)-2-(trimethylsilyl)-3-thiophenecarboxamide (silthiofam). Plants and plant propagation material, such as seeds, that have been treated by the novel method are also described.

The present invention discloses silicon-containing (methyl) acrylate monomer and its copolymer and their preparation process. The silicon-containing (methyl) acrylate monomer as silane or silane oligomer with methyl propenyl acyloxy radical or propenyl acyloxy radical is prepared through the catalytic reaction of silane coupler with (methyl) propenyl acyloxy radical, and hexamethyl disilane or hexamethyl disilane and active organosilicon under the action of catalyst. The present invention also discloses one kind of silicon-containing (methyl) acrylate copolymer and its solution copolymerization, water emulsion copolymerization and ultraviolet curing process. The copolymer has excellent adhering performance, waterproof and antifouling performance and weather resistance.

The invention relates to a salt-tolerant resistance-reducing agent applied for a shale gas reservoir. The resistance-reducing agent is a biopolymer comprising an acrylamide unit and a propenyl quaternary ammonium salt unit. The weight percent of the acrylamide in the biopolymer is 10%-80%. The propenyl quaternary ammonium salt is one of a propenyl trialkyl ammonium chloride, an alkyl acrylamido propyl trialkyl ammonium chloride or a dialkyl diallyl ammonium chloride. The weight percent of the propenyl quaternary ammonium salt in the biopolymer is 20%-90%, and the molecular weight of the propenyl quaternary ammonium salt is 1*10<6> to 2*10<6>. The resistance-reducing agent provided by the invention can be used as resistance-reducing agents for fracturing flow-back fluid, cavern water and underground produced water, wherein the fracturing flow-back fluid, the cavern water and the underground produced water contain divalent metal ions, and the weight percent resistance-reducing agent provided by the invention for using is 0.05%-0.1%. The resistance-reducing agent provided by the invention has good salt tolerance and resistance-reducing properties, and overcomes problems, of other polypropanamide resistance-reducing agents at present, comprising salt tolerance deficiency in using processes and incapability of being applied for hypersalinity water that comprises Ca<2+> and Mg<2+> at the same time.

The invention relates to photo-crosslinking sericin protein hydrogel and a preparation method and application thereof. The preparation method comprises the steps that methyl propenyl modified sericin protein is prepared into a solution to be mixed with a photoinitiator (Irgacure 2959) solution, and the sericin protein hydrogel is obtained through ultraviolet irradiation. The obtained sericin protein hydrogel has the good biodegradability, autofluorescence characteristic and injectable property, and wounds caused by implanting or taking out biomaterials can be effectively reduced. Most importantly, the sericin protein hydrogel has good biocompatibility both in vivo and in vitro, and adhesion of carried cells can be effectively promoted. Serving as 2D and 3D cytoskeleton, the sericin protein hydrogel can effectively promote proliferation of the carried cells and promote the carried cells to form functional tissue under the condition of being free of serum support; serving as wound accessories, the sericin protein hydrogel can repair skin wounds and can serve as tissue engineering and regenerative medicine biological materials.

The use of certain synthetic phospholipids to preserve pharmaceutical compositions from microbial contamination is described. The synthetic phospholipids have unique molecular arrangements wherein a phosphate group is linked to a quaternary ammonium functionality via a substituted-propenyl group, and the quaternary ammonium functionality is further linked to at least one long hydrocarbon chain. Such molecular arrangements are what make the phospholipids of formula (I) highly water soluble, e.g., the length of the hydrocarbon chain assists to maintain solubility and efficacy of the molecules for the uses described herein. The synthetic phospholipids described herein have been found to be particularly useful as antimicrobial preservatives for ophthalmic, otic and nasal pharmaceutical compositions, especially ophthalmic compositions. These compounds may also be utilized to disinfect contact lenses. The invention is based in-part upon a finding that the antimicrobial activity of the synthetic phospholipids is affected by the ionic strength of the compositions in which the compounds are contained. The provision of compounds having limited ionic strengths is therefore preferred.

The invention relates to a corrosion inhibitor used in carbon steel corrosion in an ammonia-method desulphurization ammonium sulfate preparation system. The corrosion inhibitor is composed of, by weight, 20-80% of a thiourea derivative, 10-50% of organic amine, and 5-40% of imidazoline quaternary ammonium salt. The thiourea derivative is one selected from phenyl thiourea, diphenyl thiourea, thiosemicarbazide and propenyl thiourea. The organic amine is one selected from polyacrylamide, dodecylamine, hexadecylamine and octadecylamine. The chemical structural formula of the imidazoline quaternary ammonium salt is represented as the following, wherein R is phenyl, C2-C11 straight-chain alkyl, CH3(CH2)7CH=CH(CH2)7 or CH3(CH2)9CH=CH(CH2)7, and n is 2, 3, or 4. The corrosion inhibitor has good corrosion inhibiting performance. When the corrosion inhibitor is applied in inhibiting the corrosion in the ammonia-method desulphurization ammonium sulfate preparation system, the dose is low, and application is simple and convenient.

The invention provides propenyl phenoxy compounds with a three-branch aromatic structure and a preparation method thereof, and a bismaleimide resin modified by the propenyl phenoxy compounds, relating to the field of thermosetting resins and adhesives for high-temperature-resistant composite materials. The invention aims to solve the problems of higher curing temperature and higher after-treatment temperature in the existing bismaleimide resin and the problem of poor long-time thermal aging resistance of the cured resin at high temperature. The structural general formula is disclosed in the specification. The preparation method comprises the following steps: adding trifunctional fluoro ketone, allyl phenol and a catalyst into a solvent, heating to react under reflux, filtering, cooling, precipitating, washing with water and baking. The bismaleimide resin modified by the propenyl phenoxy compounds is prepared from bismaleimide, propenyl phenoxy compounds with three-branch aromatic structure, and diallylphenyl compounds. The invention mainly discloses a propenyl phenoxy compounds with three-branch aromatic structure and a preparation method thereof, and a bismaleimide resin modified by the propenyl phenoxy compounds.

The invention provides a preparation method of a molecularly imprinted material and a molecularly imprinted material prepared by the same. The preparation method comprises the following steps: depositing Fe3O4 on a graphite-like-phase carbon nitride surface by a coprecipitation process to obtain a Fe3O4-g-C3N4 nano material, thereby obtaining a propenyl-surface-modified magnetic silicon dioxide graphite-like-phase carbon nitride nano material; and by using the propenyl-surface-modified magnetic silicon dioxide graphite-like-phase carbon nitride nano material as a carrier, optimizing a functional monomer, and carrying out a surface imprinting technique to obtain the molecularly imprinted material capable of quickly indentifying seven environmental endocrine disrupting chemicals at the same time. The molecularly imprinted material has the advantages of high adsorption capacity, favorable selectivity, high response speed, high chemical stability and high utilization ratio, is convenient for operation, can simultaneously implement identification and separate enrichment of multiple trace steroid / phenol environmental endocrine disrupting chemicals, and widens the application range of the existing magnetic nano material, graphite-like-phase carbon nitride material and molecularly imprinted material.

The invention relates to a method of silence enhancing magnesium alloy cathode electrophoresis corrosion resistant coating layer. It takes silence enhancing process to the surface of magnesium alloy after cleaning. The silence solution adopts aqueous solution of 2-3 ethoxy, silicone base propyl tetrasulfide, propenyl-3-ethoxy silicane, gama- glycidol ether oxygen propyl-3-methoxyl silence or 2, 3 ethoxy silicone base ethane, and pH value is acidity. The method need not special device to heat, and combining with cathode electrophoresis, the binding power of cathode electrophoresis lacquer and magnesium alloy basal body would be enhanced.

The invention provides a polymer microgel and preparation method thereof. The polymer microgel comprises segmented copolymer containing poly (L-glutamic acid) repeat unit; the preparation method of the microgel includes that: aminated poly (ethylene glycol methyl ether) or aminated polyethylene glycol is taken as initiator, ring-opening reaction of gamma-phenmethyl-L-glutamate-N-inner carboxylic acid anhydride is carried out and phenmethyl protection is removed, thus synthsizing poly (ethylene glycol methyl ether)-b-poly (L-glutamic acid) or poly (L-glutamic acid)-b-polyethylene glycol-b-poly (L-glutamic acid), then condensation reaction is carried out to prepara 3-phenyl-2-propenyl or 2-methacryloxyethyltrimethyl functionalized poly (ethylene glycol methyl ether)-poly (L-glutamic acid) segmented copolymer or polyethylene-poly (L-glutamic acid) segmented copolymer, and finally UV-irradiation crosslinking is utilized to prepare polymer into gel. The polymer microgel has pH and ionic strength sensibility.

The invention discloses a new making method of cepham propone parent nucleus 7-amino-3-propenyl cepham alkyl acid (7-APCA), which comprises the following steps: reacting 7-ACA(2) protected by silicane and substituted by iodine with triphenylphosphor in the solvent during -10-120 deg. c; obtaining the compound (3); reserving the compound (3) in the alkaline metal salt; reacting the compound (3) and acetaldehyde to obtain the compound (4); crystallizing the compound (4) through removing the protector; obtaining the product to synthesize the cepham propone.

The invention relates to an ultrahigh-mobility propenyl elastomer grafting copolymer and a preparation method thereof. The copolymer comprises the following components in percentage by weight (wt%): 50-100wt% of propenyl elastomer resin, 0-50wt% of polyolefin resin, 0.5-5wt% of grafted monomer, 0.01-2wt% of initiator, 0.1-1wt% of crosslinking inhibitor, 0.1-1wt% of antioxygen and 0.1-2wt% of liquid accessory ingredient, wherein other components except the initiator are mixed in a high-speed mixer at a certain ratio and are added into a double-screw extruder by main feeding; the initiator is added into the extruder by side feeding; and a product is obtained by fusing, plastifying, kneading, mixing, extruding from a handpiece, bracing, cooling, pelletizing and drying. Compared with the prior art, the ultrahigh-mobility propenyl elastomer grafting copolymer disclosed by the invention has the advantages of higher product grafting ratio, lower gel content, excellent comprehensive performance and excellent impact performance by the side feeding technology, and is especially suitable for thin-wall products and large producing pieces in the fields, such as interior / exterior trim parts ofautomobiles, bumpers, railway equipment and the like.

The invention relates to application of N-{5-(1,2,4-triazole-1-yl) thiazole-2-yl} fatty acid amide in preparing an influenza virus neuraminidase inhibitor. The N-{5-(1,2,4-triazole-1-yl) thiazole-2-yl} fatty acid amide has the chemical structural formula shown as I, wherein in the formula I, R is selected from C1 to C2 alkyls, C3 to C4 straight chains or branched alkyls; R1 is selected from C1 to C2 alkyls, C3 to C11 straight chains or branched alkyls, C12 to C17 straight chains or branched alkyls, vinyls, allyls or C4 to C17 alkyls containing dual keys or three keys.

The invention provides a thickener and a preparation method and application thereof. The preparation method of the thickener includes the following steps that 1, 25-35 parts by weight of hydrophilic propenyl monomers are dissolved in 65-75 parts by weight of water, then the pH value is regulated, and a solution with the pH of 6.5-7.5 is obtained; 2, 1-5 parts by weight of hydrophobic monomers and 0.5-2 parts by weight of emulsifier are added into the solution, stirring is carried out, and 0.05-0.3 part by total weight of initiator is added in batches under a protective atmosphere for a polymerization reaction, wherein the hydrophilic propenyl monomers include acrylamide, acrylic acid and 2-acrylamido-2-methylpropane sulfonic acid in the weight ratio of (15-20):(4-5):(5-15). By adding the thickener in the process of preparing fracturing fluid from highly mineralized water, the fracturing fluid with a high thickening capacity can be formed, and fracturing construction requirements can be effectively met.

The collecting agent for floatation of copper sulfide ore is prepared by using thionocarbamate, diethylthionitrogen ester, 730A, dialkyl phosphorodithioate and propenyl butyl sulfonate according to the ratio of 0.6-0:0-0.06:0.2-0.1:0.1: 0.1-0.2, and its preparation method includes the following steps: respectively filtering thionocarbamate and 730A; under the condition of normal temp. and normal pressure slowly adding diethylthionitrogen ester while stirring, uniformly stirring them, then adding it and propenyl butyl sulfonate into dialkyl phosphorodithioate, stirring for 1 hr. then standing still for 2 hr. and removing precipitate so as to obtain the invented collecting agent with good selectivity and strong collecting power, and it can effectively separate copper-sulfur, copper-in and copper-arsenic, etc.

The invention relates to an amino-containing crosslinkable polyether sulfone and a preparation method thereof and applications of a gas separation membrane, belonging to the field of a polymer nanocomposite material. Aiming at solving the problems of compatibility of gas permeability and separating property of the existing gas separation membrane, a membrane formed mixing and casting crosslinkable polyether sulfone with molecular side chain containing phenylamino and allyl, together with pyrrolidone, or a thermal-crosslinked membrane is formed by adding benzoyl peroxide in mixing with N-methyl pyrrolidone and casting can be utilized, in addition, a mixed matrix membrane or mixed matrix thermal-crosslinked membrane can formed by adding a multiwalled carbon nanotube. The amino containing can have hydrogen bond interaction with carboxyl of the carbon nanotube, the carbon nanotube can be more evenly dispersed in polymer, and the two interfaces have good binding power, so that the gas permeability and selectivity of the mixed matrix membrane can be enhanced. The amino-containing crosslinkable polyether sulfone is used for preparing the gas separation membrane and gas separation.

This invention relates to resin glasses, which comprise: diethylene glycol propenyl dicarbonate (Brite-55) 50-95 wt.%, diethylene glycol propenyl carbonate (RAV 7AT) 0-48 wt.%, 2-(2'-hydroxyl-5-tert-octyl)-benzotriazol (UV-5411) 0.1-0.2 wt.%, inorganic paint B 0.3-0.4 wt.%, inorganic paint A 0.1-0.2 wt.%, diisopropyl peroxydicarbonate (IPP) 1-3.5 wt.%, distyryl dibenzotriazol (UV-0) 0.01-0.5 wt.%. The resin glasses are produced by: preparing the raw materials, filling, curing, treating the substrate glass, returning to the furnace, and treating the glasses. The obtained resin glasses can block total UV (below 400 nm) and blue-violet light (between 400-420 nm), thus can protect eyes from UV and blue-violet damage, and can satisfy the requirements of people in welding locus, banks, UV sterilization rooms, highland, torrid zones, and subtorrid zones.