81 results about "Triketone" patented technology

This application relates to the field of biosynthesis technology, and specifically discloses a pyridone compound, its biosynthesis method and application. Based on synthetic biology-related technologies, this application modifies non-ribosomal peptide synthetase, heterologously expresses non-ribosomal peptide synthetase mutants in a variety of hosts, and for the first time discovers and obtains a pyridone compound, and determines its chemical formula as C5H4N2O3, named 5-amino-pyridine-2,3,6-trione or 5-hydroxy-3-imino-pyridine-2,6-dione. This novel pyridone compound can be used as a raw material or intermediate in the development and preparation of novel antibiotics, drugs and dyes.

The present disclosure relates to herbicidal combinations, compositions and methods for controlling weeds comprising the carbamate herbicide asulam and an additional herbicide selected from the group comprising cyclohexanedione oxime herbicides, pyrimidinylsulfonyhirea herbicides, triazolopyrimidine herbicides, imidazolinone herbicides, alkylazine herbicides, triketone herbicides, N-phenylimide herbicides or chloroacetamide herbicides. Specifically, the additional herbicide may be one of clethodim, chlorimuron, diclosulam, imazamox, imazethapyr, indaziflam, mesotrione, saflufenacil, tiafenacil or S-metolachlor.

A transgenic cotton event, Gh_CSM63718, is provided. Transgenic plant cells, plant parts, plants, seeds, progeny plants, and agricultural and commodity products containing event Gh_CSM63718 are also provided. Recombinant DNA molecules unique to the event Gh_CSM63718, and methods of using and detecting Gh_CSM63718 are also provided. Cotton plants containing the event Gh_CSM63718 exhibit tolerance to glufosinate, B-triketone HPPD inhibitors, dicamba, glyphosate, PPO inhibitors, and combinations of any thereof.

The invention provides a cyanuric acid-containing halamine / quaternary ammonium salt copolymerization modified antibacterial material and application, and relates to the technical field of antibacterial materials. 1-allyl-s-triazine-2. 4.6-triketone potassium salt is synthesized from the cyanuric acid-containing halamine / quaternary ammonium salt copolymerization modified antibacterial material through nucleophilic substitution; the preparation method comprises the following steps: grafting a chlorinated halamine / quaternary ammonium salt copolymer to 3-chloropropyltrimethoxysilane pretreated natural fiber, copolymerizing the modified fiber and dimethyl ethyl methacrylate through continuous steps, reacting in ethanol with alkyl bromide, and substituting in a disinfectant to obtain the chlorinated halamine / quaternary ammonium salt copolymer modified material. The cyanuric acid-containing halamine / quaternary ammonium salt copolymerization modified antibacterial material prepared by the invention can quickly and efficiently kill escherichia coli and staphylococcus aureus, and has good recovery and regeneration capacity, ultraviolet radiation resistance and self-cleaning capacity.

A geopolymer precursor includes an alkaline reactive solid material containing aluminum, silicon, and oxygen, and a fluid loss control material having an ionic stability property that has a first value in water and a second value in a 3M solution of NaOH, wherein a ratio of the second value to the first value is in a range of 0.5 to 2.0. The fluid loss control material may be, or may include a crosslinked polymer, which may include a reaction product of one or more of acrylamide, 2-acrylamido-2-methyl propane sulfonic acid, N,N‑dimethylacrylamide, N,N‑diethylacrylamide, vinyl acetate, or another monomer, and a crosslinker including one or more of methylene bisacrylamide, triallyl amine, pentaerythritol allyl ether, triallyl-triazine-trione, or another material. The geopolymer precursor may include an activator, an alkaline solution having pH of at least about 9, or both.

A formulation delivery system for use with an outdoor cleaning device is provided. The formulation delivery system has a composition containing chlorine, wherein the composition is in the form of a solid chemical component, and the outdoor cleaning device is a spray bar that houses the composition. The chlorine is selected from the group consisting of calcium hypochlorite, 1,3,5-triazine-2,4,6(1H,3H,5H)-trione, 1,3-dichloro-sodium salt, dihydrate (dichloroisocyanuric acid), 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione (trichloroisocyanuric acid), chloramine-T hydrate, and combinations thereof. A spray bar is also provided that has a refill cartridge for housing the composition in solid form.

The present application relates to the technical field of materials, in particular to a multi-stage solidification shape memory polymer for 4D printing and a preparation method thereof. In view of the problem that it is difficult to build gradient mechanical functions by precisely regulating the structure modulus in a single structure of 4D printing, the present application obtains a single-component multi-stage solidification shape memory polymer by regulating the ratio of toluene-2, 4-diisocyanate-hydroxypropyl acrylate, shape memory polymer, polyethylene glycol 400 and 1, 3, 5-tris (6-isocyanate hexyl) -1, 3, 5-triazine-2, 4, 6-trione under the test feedback of the printing structure modulus, and solves the problem that it is difficult to build gradient mechanical properties in a single structure of 4D printing.

The present disclosure relates to a herbicidal combination comprising a carbamate herbicide and a triketone herbicide.

The invention provides a synthesis method and application of a tetra-substituted pyran compound. The tetra-substituted pyran compound is directly constructed through a one-pot cascade reaction under an organic base catalysis system by taking triketone olefin and allyl ammonium salt as key reaction raw materials. The method has the advantages that the operation is simple and convenient, no water or oxygen is needed, the reaction is efficient, the steps are simple, the method is environment-friendly, the reaction is easy to amplify, and the method has practical value. Activity tests prove that the compounds have certain inhibitory activity on alpha-glucosidase, or can be used for treating diabetes mellitus.

The invention provides a preparation method of 17 alpha-hydroxypregna-4-ene-3, 11, 20-triketone and an intermediate compound prepared by the preparation method, and relates to the technical field of medicine synthesis. The target product disclosed by the invention is prepared by taking 11 alpha-hydroxy-4-androstenedione as a starting material and carrying out six-step reaction, namely oxidation, ethynylation, ketalation, sulfonylation, etherification and hydrolysis. The starting material 11 alpha-hydroxy-4-androstenedione of the process is prepared from 4-androstenedione through enzyme transfer, and compared with 11 alpha, 17 alpha-dihydroxyprogesterone prepared from 17 alpha-hydroxyprogesterone through enzyme transfer, the enzyme transfer technology of the former is more mature, the conversion rate and the yield are higher, and the cost is lower. Meanwhile, the preparation method disclosed by the invention is easy to operate and implement in production and high in reaction conversion rate, avoids the use of a highly toxic reagent acetone cyanohydrin, and is more beneficial to large-scale industrial production.

An object of the present invention is to provide a resin composition that has excellent impregnability into fibers, enables favorable continuous production of a prepreg, and enables production of a prepreg that enables favorable production of a molded article.SOLUTION: A three dimensional crosslinked structure in which a compound (A) having two or more acetoacetic acid ester groups, aldehyde groups, or triketone structures alone or in combination in a molecule and an amine compound (B) having two or more primary amino groups in a molecule are bonded to each other, and a ketimine compound (D) in which at least one primary amino group of the amine compound (B) and a ketone group of the ketone compound (C) are condensation-bonded, wherein among the primary amino groups of the amine compound (B) constituting the ketimine compound (D), a proportion of the primary amino groups bonded to the ketone compound (C) is 1kPa% or more, the ketone compound (C) having a steam pressure at 20 °C of 0. 50mol or more.SELECTED DRAWING: None

This invention belongs to the field of flame retardant materials technology, and particularly relates to a P-N flame retardant, its preparation method, and its application. The preparation method of the P-N flame retardant includes the following steps: (1) diluting aminotrimethylenephosphonic acid with a solvent; (2) adding 1,3,5-tris(2-hydroxyethyl)1,3,5-triazine-2,4,6-trione to the solution obtained in step (1), reacting in a constant temperature oil bath for 2-5 hours to obtain a P-N flame retardant precursor solution; (3) preparing an aqueous solution of an amino compound; (4) adding the P-N flame retardant precursor solution dropwise to the aqueous solution of the amino compound, reacting in a constant temperature oil bath for 5-10 minutes to produce a white precipitate, continuing the reaction for 0.5-1 h after the precipitate is produced, washing and filtering the precipitate, and drying to obtain the P-N flame retardant. The P-N flame retardant of this invention is a white solid that is almost insoluble in water at room temperature and has good flame retardant effect on bio-based materials.

The application provides a pyridinone compound and a preparation method and application thereof, and belongs to the technical field of compound synthesis.The pyridinone compound is (E)-5-[(hydroxyl methylene)amino]-1,2,3,6-tetrahydropyridine-2,3,6-trione, and the molecular formula is C6H4N2O4.The pyridinone compound of the application simultaneously contains a hydroxyl group, an imino group and multiple carbonyl functional groups in the structure, forms a unique conjugated system and hydrogen bond network, and has the potential to be used as a bioactive precursor or a functional material.The pyridinone compound with a purity greater than 95% and a yield greater than 94% can be obtained by using the preparation method of the application, the compound shows good performance in dyeing applications, not only expands the application range of the pyridinone compound, but also provides a new way for realizing high-value utilization of fermentation broth resources, and has the advantages of environmental protection and economic benefits.

The invention relates to the technical field of organic synthesis of steroid compounds, in particular to a preparation method of androstane-4-ene-3, 6, 17-triketone. Dehydroepiandrosterone acetate is used as an initial raw material to prepare androstane-4-ene-3, 6, 17-triketone through four steps of reactions including chlorohydrination, hydrolysis, oxidation and elimination, the yield and purity of androstane-4-ene-3, 6, 17-triketone are improved, 4-AD impurities are not generated, the total yield of a route reaches 80%, and the purity is larger than or equal to 98.0%; and the preparation process does not involve the use of dangerous chemicals and environment-polluting chromium oxidants, and is suitable for industrial production.

The invention discloses a preparation method of 1, 3-diallyl-5-ethylene oxide methyl-[1, 3, 5] triazine-2, 4, 6-triketone, sodium isocyanurate, chloropropene and epoxy bromopropane are used as raw materials, and a product is synthesized through two-step reaction: S1, preparation of intermediates: the sodium isocyanurate and the chloropropene are subjected to a reaction in a polar aprotic organic solvent, the reaction is carried out for 2-4 hours, and the product is obtained; carrying out a first-step reaction under the action of a catalyst and a cocatalyst, filtering, evaporating the solvent to dryness, and purifying to obtain an intermediate diallyl isocyanurate; s2, preparation of a target product: in a polar aprotic organic solvent, carrying out a second-step reaction on the intermediate and epoxy bromopropane under the action of an acid capturing agent, carrying out rotary evaporation to remove the solvent, washing and drying, and purifying to obtain the target product, a plurality of aspects such as a catalyst and a reaction system are researched, the reaction temperature is reduced, and a product with the purity conforming to the application in the field of electronic chemistry is obtained.

The invention relates to control of resistant pests. In particular, the present invention relates to a method of controlling an insecticide-resistant pest comprising exposing the insecticide-resistant pest to a pest control amount of a triketone compound.

The invention discloses ionic conductive polyurethane with high adhesion and self-repairability and a preparation method thereof, and belongs to the technical field of high-performance conductive binding materials, the method comprises the following steps: mixing 1-ethylimidazole and 3-chloro-1, 2-propylene glycol, condensing and refluxing, sequentially extracting in trichloromethane and acetone solutions, and drying in vacuum to obtain the ionic conductive polyurethane with high adhesion and self-repairability. The dihydroxy imidazolyl ionic liquid is prepared; the preparation method comprises the following steps: adding a dihydroxy imidazolyl ionic liquid solution into a polyurethane prepolymer, stirring for reaction, adding a polyhydroxy MXene-OH dispersion liquid subjected to etching treatment and a 1, 3, 5-tri (6-isocyanatohexyl)-1, 3, 5-triazine-2, 4, 6-trione cross-linking agent, carrying out chain extension cross-linking reaction, adding 1-ethyl-3-methylimidazoline bis (trifluoromethylsulfonyl) imine, and carrying out reaction, so as to obtain a polyurethane prepolymer; and carrying out mold pouring and drying treatment to obtain the ionic conductive polyurethane with high adhesion and self-repairing property. The covalent cross-linked network endows the material with good toughness, and the bi-cross-linked structure can also effectively block permeation of water molecules, so that the problem of poor water resistance of the traditional polyurethane material is solved.

The application discloses a new use of androsta-4,6,8(9),13(14)-tetraen-3,11,16-trione, namely, application of the androsta-4,6,8(9),13(14)-tetraen-3,11,16-trione in preparation of a medicine for treating lymphoma. 50 The IC value of the androsta-4,6,8(9),13(14)-tetraen-3,11,16-trione in the SR cell line is detected by a CCK-8 method, and the cytotoxicity of the androsta-4,6,8(9),13(14)-tetraen-3,11,16-trione on human umbilical vein endothelial cells Huvce and human immortalized keratinocytes Hacat is detected, in the body, the androsta-4,6,8(9),13(14)-tetraen-3,11,16-trione significantly inhibits tumor growth and shows good biological safety and no systemic toxicity; TUNEL staining, gamma-H2AX staining and neutral comet experiment prove that the compound of the application inhibits the growth of SR by causing serious damage to DNA, the application not only adds the diversity of the biological activity of the androsta-4,6,8(9),13(14)-tetraen-3,11,16-trione, but also provides a new direction for developing a new medicine for treating lymphoma.

The invention provides a fireproof flame-retardant fiber reinforced composite material, a preparation method thereof and a photovoltaic module, and belongs to the technical field of photovoltaic modules, the fireproof flame-retardant fiber reinforced composite material comprises the following preparation raw materials by weight: 60-70 parts of a fiber reinforced fabric; 27 to 32 parts of a resin matrix; 3-8 parts of a flame retardant; the flame retardant comprises a triazine triketone compound. The fireproof and flame-retardant fiber-reinforced composite material provided by the invention comprises the fiber-reinforced fabric, the resin matrix and the flame retardant, all the components are matched with one another, and particularly, the flame retardant of a specific type is introduced, so that the fiber-reinforced composite material has better fireproof and flame-retardant properties, and the fireproof and flame-retardant fiber-reinforced composite material is used for a photovoltaic module and has a good application prospect. And the photovoltaic module also has relatively good fireproof and flame-retardant properties.

The application discloses a kind of heat-insulating fireproof materials and preparation method thereof, from top to bottom sequentially include first encapsulation layer, first fireproof support layer, first viscose layer, heat-insulating layer, second viscose layer, second fireproof support layer and second encapsulation layer;The first viscose layer, second viscose layer are independently made of the following raw materials respectively: amino-terminated hyperbranched polyimide, acrylic modified poly (ether ether ketone), 1,3-bis (oxymethylene methyl) -5- (2-propenyl) -1,3,5-triazine-2,4,6 (1H,3H,5H) -trione, 1,1,3,3-tetramethyl-1,3-divinyl disilazane, 3- (1,1-difluoro-2-propylene-1-yl) -2 (1H) -quinoxaline ketone, 2- (1-propylene-2-yl) benzo [d] oxazole, terpene resin, initiator, solvent.The material heat-insulating fireproof effect is remarkable, and mechanical mechanical property and high temperature resistance are sufficient.

The present invention belongs to the technical field of composite materials, and specifically relates to a glass fiber reinforced flame-retardant vinyl ester resin composite material and a preparation method thereof. The preparation method of the glass fiber reinforced flame-retardant vinyl ester resin composite material of the present invention comprises the following steps: S1. 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) reacts with hydrogen peroxide to obtain DOPO-OH. S2. DOPO-OH reacts with piperazine (PIP) to obtain DOPO-OH-PIP. S3. Phosphoric acid reacts with 1,3,5-tris(2-hydroxyethyl)-1,3,5-triazine-2,4,6-trione to obtain the product PTTA. S4. Flame retardant DPPTTA is obtained by reacting PTTA with DOPO-OH-PIP. S5. The obtained DPPTTA flame retardant, methyl ethyl ketone peroxide, N,N-dimethylformamide, cobalt naphthenate, and vinyl ester resin are thoroughly mixed, and then gradually added to a mold containing glass fiber for curing to obtain the glass fiber reinforced flame-retardant vinyl ester resin composite material.

The present invention relates to aqueous dispersions comprising an ALS inhibitor, typically a sulfonylurea herbicide, specifically from the class of triazolinones herbicides, a HPPD inhibitor, specifically a triketone as from the class of 2-benzoyl-1,3-cyclohexanedione herbicides, optionally a safener from the class of the sulfonamides, a water-soluble herbicide present as a salt, specifically glyphosate and to dispersions resulting from dispersing the concentrate suspension in water, to a method of making the aqueous suspension and to a method of controlling unwanted plants using these dispersions.

The invention belongs to the technical field of organic synthesis, and particularly discloses a terpyridine derivative synthesis method, which comprises: carrying out a hydrolysis / carboxylation reaction on a 2-cyanopyridine derivative under the catalysis of an acidifying agent, the method comprises the following steps: adding a catalyst into a pyridine-2-carboxylic acid derivative in an aprotic polar solvent, and carrying out intermolecular condensation cyclization on the pyridine-2-carboxylic acid derivative; the preparation method comprises the following steps: in the presence of an ammonium salt, constructing a terpyridine skeleton through a dehydration ring-closing reaction of a 1, 5-di (2-pyridyl) pentane-1, 3, 5-triketone derivative; a chlorination reagent is adopted to carry out selective chlorination reaction on a terpyridyl skeleton. According to the synthesis method of the terpyridyl derivative, the economical efficiency, the safety, the environmental protection property and the industrial feasibility are considered, a new path is provided for efficient, green and low-cost preparation of terpyridyl compounds, and the synthesis method has important practical application value and market prospects.

Disclosed are compounds that are parathyroid hormone receptor 1 agonists, and methods useful for preventing or treating osteoporosis, fracture, osteomalacia, arthritis, thrombocytopenia, hypoparathyroidism, hyperphosphatemia or tumoral calcinosis. Also disclosed are agonists of GLP-1R, GCGR, and / or GIPR, and methods of treating various therapeutic indications by administering an effective amount of an agonist of GLP-1R, GCGR, and / or GIPR.

The disclosed technology provides a thermoplastic copolymer comprising: a plurality of difunctional triketone species; (b) a plurality of a first diamine species, wherein the first diamine species contains one or more primary amine groups and / or one or more secondary amine groups, and wherein the first diamine species does not contain a tertiary amine group; a plurality of a second diamine species, wherein the second diamine species contains one or more primary amine groups and / or one or more secondary amine groups, wherein the second diamine species does not contain a tertiary amine group, and wherein the second diamine species is different than the first diamine species; and optionally, a plurality of monofunctional amine-reactive groups. Some embodiments provide segmented thermoplastic copolymers. Methods of making and using the thermoplastic copolymer are also described, including depolymerizing the thermoplastic copolymer to form recycled monomers. The recycled monomers may then be repolymerized in a closed-loop system.

A method of controlling pests includes exposing the pests to a pest controlling amount of a triketone compound in combination with at least one second pesticide. Formulations and kits can include the combination.

The present invention relates to a liquid herbicidal composition. In particular, the present invention relates to a liquid herbicidal composition comprising triazolone herbicide and at least one co-herbicide selected from triketone herbicide and chloroacetamide herbicide; a process for preparing said composition; and a method for controlling weeds using the same.

The present disclosure relates to recombinant DNA molecules and engineered proteins useful for conferring tolerance to β-triketone herbicides such as mesotrione. The present disclosure also provides herbicide tolerant transgenic plants, plant parts, cells and seeds comprising the recombinant DNA molecules, and methods of using the same.

A transgenic cotton event, Gh_CSM63718, is provided. Transgenic plant cells, plant parts, plants, seeds, progeny plants, and agricultural and commodity products containing event Gh_CSM63718 are also provided. Recombinant DNA molecules unique to the event Gh_CSM63718, and methods of using and detecting Gh_CSM63718 are also provided. Cotton plants containing the event Gh_CSM63718 exhibit tolerance to glufosinate, ß-triketone HPPD inhibitors, dicamba, glyphosate, PPO inhibitors, and combinations of any thereof.

The present invention is relative to an agrochemical composition comprising as herbicidal substance a combination of a phenylpyridazine derivative and a triketone, a defined solvent, and a surfactant system comprising a non ionic and an anionic surfactant. The invention also concerns a process for the preparation of said agrochemical composition, an agrochemical emulsion or suspoemulsion obtainable by diluting said agrochemical composition and a method of controlling undesired vegetation using said agrochemical composition.