1422 results about "Modified cellulose" patented technology

The present invention relates to a method of producing a cellulose based paper, the paper itself and the use thereof where the paper exhibits enhanced mechanical properties. The method involves providing a suspension of well dispersed modified cellulose at a low concentration. The properties and the chemical structure of the paper make it suitable for in vivo applications such as implant material.

The invention provides a water-based drilling fluid composition containing an amine compound, which comprises the following components: a 0.5 to 5 weight percent of water-based amine compound as shown in formula I: RHN-Y-[OY']X-NHR', wherein Y, Y',x, R and R' are as defined in a manual; 0.1 to 1.0 weight percent of water-based tackifier which is selected from one or more types of xanthan gum, acrylamide-acrylic copolymer and hydroxyl ethyl cellulose; 0.5 to 5 weight percent of water-based fluid loss agent which is selected from one or more types of modified lignite, acrylic polymer, modified starch and modified cellulose; 2 to 12 weight percent of water-based inhibitor which is selected from one or more types of potassium chloride, potassium sulfate, formic acid, formic acid sodium, potassium chloride and epoxypropyltrimethylammonium chloride; and the composition can also further comprises coating agent, weighting agent, lubricant, borehole stabilizer and the like. The water-based drilling fluid composition has good inhibiting performance to clay shale drilling cuttings.

A low cost process of making modified cellulosic materials by melt blending with at least 30% recycled and commingled plastic waste stream at higher temperature and pressure where at least 70% of plastics melts and encapsulate the filler. The plastic encapsulated filler can be used as a feed stock for continuous or discontinuous process of compression, extrusion, coextrusion and injection molded structural (e.g. profiles, stake, panel) and non-structural (e.g. sheet, thin-board) articles by mixing with a thermoplastic (e.g. polyethylene, polypropylene, polyvinyl chloride, polystyrene) or a hybrid mixture of said thermoplastics, bonding agents, plastic processing additives, impact modifiers, colorant and with / without a lightner.

The invention discloses a preparation method of modified cellulose adsorbents. The preparation method comprises the following steps: (1) activating cellulose in alkaline aqueous solution to obtain activated cellulose; (2) reacting the activated cellulose with epoxy chloropropane to obtain epoxy cellulose; (3) reacting the epoxy cellulose with an oxidizing agent to obtain epoxy dialdehyde oxidized cellulose; (4) reacting cyclodextrin with epoxy dialdehyde oxidized cellulose to obtain cyclodextrin grafted modified cellulose; and (5) reacting the cyclodextrin grafted modified cellulose with amino-terminated hyperbranched polymer to obtain the modified cellulose adsorbents. The raw material source is wide, the price is low, and the environment-friendly effect is achieved; the preparation method is simple, the reaction condition is mild, the equipment requirement is low and scale production is facilitated; and the prepared adsorbent has stable performance and broad-spectrum adsorption capacity for heavy metal ions, dyes and other organic matters and is environment-friendly, the cellulose additional value is remarkably promoted, and good economic and social benefits are achieved.

The present invention provides a method for producing modified nanofibrillated cellulose characterized by bringing cellulosic material into a fiber suspension, adsorbing a cellulose derivative or polysaccharide or polysaccharide derivative onto fibers in said fiber suspension under special conditions and subjecting the obtained fiber suspension derivative to mechanical disintegration. A modified nanofibrillated cellulose obtainable by a method of the present invention is provided. Furthermore, the invention relates to the use of said modified nanotibrillated cellulose.

The present invention provides an aqueous composition useful for CMP of a semiconductor wafer containing a metal comprising oxidizer, inhibitor for a nonferrous metal, complexing agent for the nonferrous metal, modified cellulose, 0.001 to 10% by weight copolymer blends of a first copolymer and a second copolymer and balance water.

Methods to improve dewatering in industrial and municipal sludges are described. One method involves admixing sludge from a papermaking process and modified cellulose to provide modified sludge with the modified cellulose present in an effective amount to improve dewatering in the treated sludge, such as in allowing use of reduced amounts of coagulant and / or reducing dewatering times, increased dewatered volumes, and reduced sludge product moisture contents, and the like. The dewatered sludge may be formed into a dried particulate, and may be used as filler or other component of concrete, rubber, asphalt, plastics, resin-wood composite products, and other composite products.

The invention discloses a dust inhibitor, which comprises the following raw material in percentage by weight: 0.6 to 0.8 percent of plant seed colloid, 0.1 to 0.3 percent of modified cellulose, 0.05 to 0.09 percent of dispersant and the balance of water. The dust inhibitor can be prepared at normal temperature in a common mixing equipment from mixed aqueous solution of plant seed colloid, modified cellulose, crosslinking agent, dispersant and reinforcing agent; and after being prepared, the dust inhibitor can be sprayed onto the surface of coal in carriages to allow the coal to form a layer of cured film on the surface, the viscosity of the film is high, the wind corrosion rate of the film is low, so that the dust pollution along railways in railway transportation of the coal and the dust loss of the coal are avoided. Besides, dust inhibition in railway coal transportation, the dust inhibitor can be used for dust inhibition on roads in mining areas, urban roads, constructions sites, stations, ports and the like so that the dust inhibitor can be used almost without being limited by fields, and the dust inhibitor can be widely used.

The invention discloses a method for preparing a waterproof moisture-permeable coated fabric. The moisture permeability of a polyurethane coated fabric is improved by adding modified cellulose powder which accounts for 5 to 50 percent of the weight of polyurethane and is modified by a silane coupling agent into a polyurethane coating agent, and the waterproof property of the polyurethane is improved by adding inorganic powder which accounts for 0.5 to 5 percent of the weight of the polyurethane and is modified by the silane coupling agent, wherein the silane coupling agent accounts for 0.5 to 1 percent of the weight of the modified cellulose powder; and the silane coupling agent accounts for 0.5 to 1 percent of the weight of the inorganic powder. The modified polyurethane which accounts for 15 to 50 percent of the weight of a base fabric is coated on the base fabric of a knitted fabric, a woven fabric or a non-woven fabric to prepare the waterproof moisture-permeable coated fabric with good performance. The method is simple and easy, and can perform mass production; and the prepared fabric has excellent waterproof and moisture-permeable abilities, solves the contradiction between the waterproof capacity and the moisture-permeable capacity of the fabrics, and can be applied to coated fabrics for functional clothing, shoes, tents and buildings in a large quantity.

Viscosity-modified carbohydrate binder compositions are described. The binder compositions may include a carbohydrate, a nitrogen-containing compound, and a thickening agent. The binder compositions may have a Brookfield viscosity of 7 to 50 centipoise at 20° C. The thickening agents may include modified celluloses such as hydroxyethyl cellulose (HEC) and carboxymethyl cellulose (CMC), and polysaccharides such as xanthan gum, guar gum, and starches.

The invention is directed to an improved dental composition useful in the repair of cavities, apex repairs, root perforations and root canals. Disclosed is a dental composition and dental composition additive which have improved handling characteristics, for example improved viscosity and setting time. The addition of effective amounts of a modified cellulose and calcium chloride to available dental repair compounds, such as mineral trioxide compound, results in the improved dental composition without affecting the other characteristics of the dental repair compound.

The invention discloses a method for preparing a bifunctional modified cellulose adsorbing agent from peanut shells and application of the method. The method comprises the following preparation steps of: washing, drying and crushing waste peanut shells, which are taken as raw materials, and removing flavochrome, hemicellulose and xylogen from the crushed peanut shells so as to obtain peanut shell cellulose; and performing surface functional modification on the materials through substitution and amidation further so as to finally obtain the amino and carboxy bifunctional modified peanut shell cellulose adsorbing material. The product is powdery and light brownish yellow, and the particle size of the product is 1.5-2.5 microns. The bifunctional modified peanut shell cellulose adsorbing material has a good adsorption effect for excessive heavy metals such as copper, chrome and mercury, phosphate, methylthionine chloride dye, and the like in water. The adsorbing agent is simple in preparation method, low in cost, cheap, easily available, good in biological compatibility and environment-friendly, contains a great deal of functional chelation groups, can realize simultaneous adsorption and removal of negative ions and positive ions, and has the advantages of being recyclable and the like.

The invention relates to a method for preparing a durable cellulose fiber fabric with a super-hydrophobic surface. The method comprises the following three steps: preparing modified SiO2 composite sol, preparing a modified fabric and performing super-hydrophobic finishing on the fabric. The active groups are introduced into nanometer SiO2 and fiber surface, the fabric is finished by adopting a simple one-step method, the binding force between the fabric and the inorganic nanometer SiO2 is enhanced by virtue of the active groups on the fiber surface and the cross-linking effect on the modified SiO2 surface, the covalent bonding firmness between the modified sol and the surface of the modified cellulose fiber fabric is improved, and the super-hydrophobic interface of a fluoride-free cellulose fiber fabric with certain washing fastness is finally obtained. Compared with the prior art, the preparation method disclosed by the invention is economical and environmentally friendly, and the industrial production is promoted.

Several hemostatic bandages that are commercially available function by tightly sealing a wound so that hemostasis can occur before excessive blood loss takes place. Hemostatic bandages which seal a wound but which do not actually speed the coagulation mechanism include chitosan and chitin-based bandages. Hemostatic gauzes based on chemically modified cellulose are also commercially available. These bandages and gauzes, used in combination with various inorganic materials such as zeolite, silica, and / or diatomaceous earth powder show a synergistic effect. It has been found that the inorganic material activates the contact coagulation mechanism while the biopolymer component binds the wound and prevents excessive blood loss.

The invention discloses a coal railway transportation dust depressor, which is invented for solving the problems of high cost, poor depression effect and so on in the prior art. The raw materials by weight percent for preparing effective compositions in the coal railway transportation dust depressor are: 2 to 7 percent of synthesized water-soluble polymer, 0.1 to 5 percent of modified cellulose water-soluble polymer, 85 to 95 percent of water and 0 to 2 percent of bluestone, wherein the synthesized water-soluble polymer is prepared by complexing at least two water-soluble polymers. The coal railway transportation dust depressor consists of more than two synthesized water-soluble polymers and a small amount of auxiliary agent, and has the advantages of high viscosity and low cost. When used, the coal railway transportation dust depressor is uniformly sprayed on particles on the surface of a coal bed to form a curing layer with certain strength, thereby the coal-dust particles of various grain sizes are bonded together and have certain toughness, and the aim of preventing flying dust on the surface of the coal bed is achieved.

The invention discloses a preparation method of a multifunctional cellulose elastic aerogel, belonging to the field of aerogel materials. The preparation method comprises the following steps: dispersing cellulose in water, carrying out pretreatment by adding sodium chlorite or / and in a solvothermal way, and cleaning with deionized water to obtain a purified cellulose dispersion solution; adding a modifier to perform chemical modification, thereby obtaining a modified cellulose suspension; dispersing the modified cellulose suspension in an organic solvent, forming, drying to form a modified cellulose gel, and finally, carrying out heat treatment on the modified cellulose gel to obtain the multifunctional cellulose elastic aerogel. The cellulose is subjected to pretreatment and chemical modification, thereby lowering the density of the aerogel, greatly enhancing the elasticity and mechanical strength of the aerogel, endowing the aerogel with excellent magnetism, electric conductivity, superhydrophobicity, superoleophobicity and many other functions, and widening the application range of the traditional cellulose aerogel.

The invention provides a cigarette core material for heating incombustible cigarettes. The cigarette core material is prepared from the following components in percentage by weight: 10-50% of tobaccofiber and tobacco powder, 5-30% of wood pulp fibers, 5-30% of one or more of hemp fibers, bamboo fibers, soybean fibers, cocoon fibers, cotton fibers, polylactic acid fibers and modified cellulose fibers, 10-50% of tobacco essence, 10-30% of smoke producing agent, 1-10% of heat conduction material, 1-10% of phase change absorption material and 1-20% of paper coating component which is selected from one or more of a hydrophobic material, a microcapsule suspension and an essence suspension containing the tobacco powder. According to the cigarette core material, the heat conduction material is added, so that the heat can be uniformly conducted; the cigarette core paper is uniformly heated in the heating process; in addition, the phase change absorption material is used and is capable of achieving phase change and absorbing heat under the heated condition so as to prevent the cigarette core material paper from being locally overheated in the heating process.

A conditioning composition is used in functional systems (personal care and household care compositions) that has a nonionic hydrophobically modified cellulose ether (HMCE) having a weight average molecular weight (Mw) with a lower limit of 400,000 and an upper limit of 2,000,000 and a hydrophobic substitution lower limit of 0.6 wt % and an upper limit amount which renders said cellulose ether insoluble in a 5 wt % solution of surfactant and less than 0.05% by weight soluble in water and wherein the cellulose ether provides conditioning benefit to the functional system substrate. This composition has at least one active functional system ingredient.

The invention discloses a preparation method of an efficient polyethyleneimine modified cellulose-based heavy metal adsorbent shown by a formula (I), belonging to the technical field of high-molecular function modification and synthesis of a natural material. By adopting cellulose as a framework, benzoyl peroxide (BPO) as an initiator, a mixture of water and acetone as a solvent and glycidyl methacrylate (GMA) shown by a formula (III) as a monomer, the method comprises the following steps of: performing a free radical-initiated graft copolymerization reaction on the surface of microcrystalline cellulose shown by a formula (II); performing amination on a graft product shown by a formula (IV) by use of graft polyethyleneimine (PEI) shown by a formula (V); and washing and drying the product to obtain a powdery solid product, wherein the reaction is easy to operate, and the conditions are mild. The heavy metal adsorbent prepared by the preparation method has the advantages of excellent adsorption property, large adsorption capacity and fast adsorption, can be regenerated and recycled, and has broad application prospects in the water treatment fields such as control of heavy metal industrial pollutants and the like.

The invention relates to a method for producing glassine paper, which is characterized by comprising the following steps: a. respectively carrying out pulping on bleached sulfate needle wood chemical pulp and bleached sulfate broadleaf wood chemical pulpboard, respectively adding an beater auxiliary agent modified cellulase in the pulp for beating; b. preparing the pulp according to weight ratio, adding a sizing agent for mixing, forming by net part dehydration, carrying out shoe pressing and drying; c. passing the paper through at least 3 pressing areas when superpressing. The method of the present invention saves beating energy consumption by 10-15% and steam consumption by 5%.

The invention discloses amino-terminated modified cellulose, and a preparation method and application thereof. The method comprises the following steps: firstly, soaking a bagasse material which is cleaned and dried into constant weight in concentrated alkaline for over 10 hours; washing, carrying out suction filtering and drying to obtain alkaline bagasse fibers; then carrying out an oxidation reaction on the alkaline bagasse fibers and a strong oxidant in a dark condition, so as to obtain dialdehyde bagasse cellulose; with methyl methacrylate and ethanediamine as raw materials, stirring in an organic solvent under dark and oxygen-isolated conditions to carry out a polymerization reaction, so as to obtain an amino-terminated hyperbranched polymer; and finally carrying out a reflux reaction after dissolving the dialdehyde bagasse cellulose and the amino-terminated hyperbranched polymer into the organic solvent, so as to obtain the amino-terminated hyperbranched grafted dialdehyde cellulose. The modified cellulose not only has good adsorptive property on heavy metal ions in a wastewater solution, but also is easy to separate after adsorption. Thus, the amino-terminated modified cellulose has the water purification effects of simple method and low cost.

A method for the manufacturing of nanocellulose. The method includes a first modification of the cellulose material, where the cellulose fibres are treated with an aqueous electrolyte-containing solution of an amphoteric cellulose derivative. The modification is followed by a mechanical treatment. By using this method for manufacturing nanocellulose, clogging of the mechanical apparatus is avoided. Also the nanocellulose is manufactured in accordance with the method and uses of the cellulose.

The invention relates to a polymer gel particle for profile control and water plugging of deep parts as well as a preparation method thereof. The particle mainly solves the problems of rapid expansion in the early stage and slow expansion in the later stage, low plugging strength in large channels and the like of profile control and water plugging agents in the prior art. The polymer gel particle for profile control and water plugging of deep parts is used, and is prepared by polymerization of a mixture shown in the following in parts by mass: (1) 100 parts of acrylamide; (2) 0-60 parts of a comonomer; (3) 0.1-15 parts of modified cellulose; (4) 0.001-0.5 parts of a cross-linking agent; (5) 200-2000 parts of water. The technical scheme can better solve the problem, and can be applied to traditional profile control and water plugging technology in the prior art.

The invention relates to a preparation method of a protein modified cellulose fiber, comprising the steps that: (1) a protein and a cellulose are dissolved in ion solution to prepare homogeneous mixing spinning solution; (2) the spinning solution is deaerated, filtered, measured, and extruded out through spinning jet to form spinning rills, and the spinning rills pass through a wet air layer and enter into a solidification bath to be solidified and molded; (3) the yarn is extended, cleaned by water, dried and heat molded, and formed into fiber to prepare the protein modified cellulose fiber. The method has the advantages of environmental protective, low cost, fast spinning speed and high production efficiency, and the prepared fiber has the advantages of comfort and health care, etc.

Dry solids of anionically modified cellulose nanofibers with good redispersion are provided by incorporating 5 to 300% by mass of a water-soluble polymer relative to the anionically modified cellulose nanofibers during the preparation of the dry solids of anionically modified cellulose nanofibers.

The invention discloses an esterification modification method for wood fiber biomasses, comprising the following steps of: firstly, pretreating wood fiber biomasses, i.e. drying and smashing; carrying out pre-ball milling; adding esterification reagent, and continuously carrying out ball milling to carry out an esterification modification reaction; and washing and drying products after the reaction to obtain the esterified modified products of the wood fiber biomasses. According to the method, various wood fiber biomasses are taken as raw materials, wide in source, low in cost, and high in resource utilization rate, and the conventional mode of the single modified cellulose can be changed; and the wood fiber biomasses are esterified in the process of ball milling, the esterification reaction can be carried out within a dissolved homogeneous system or a heterogeneous system in which the solvent is dispersion medium, and the esterification modification method is simple in modifying technology, environment-friendly, and free from the generation of 'the three wastes', and does not need recover the solvent. The infrared and weighing method result shows that the product is good in esterification effect, very good in practical applicability, and better in economic prospect.

The present invention provides an aqueous composition useful for polishing copper on a semiconductor wafer comprising by weight percent 1 to 15 oxidizer, 0.1 to 1 inhibitor for a nonferrous metal, 0.05 to 3 complexing agent for the nonferrous metal, 0.01 to 5 carboxylic acid polymer, 0.01 to 5 modified cellulose, 0.0001 to 2 salt having a cationic and an anionic component, and balance water, the salt reducing noise level from vibration between the wafer and a polishing pad.

The present invention relates to water-soluble ionic cellulose ethers from the group of the hydroxyalkylcelluloses which are substituted by on average from 0.001 to 1.0 alkyl group per anhydroglucose unit and which carry from 0.01 to 0.1 sulfoalkyl group per anhydroglucose unit, to processes for preparing them and to the use of water-soluble ionic cellulose ethers from the group of the hydroxyalkylcelluloses which are substituted by on average from 0.001 to 1.0 alkyl group per anhydroglucose unit and which carry from 0.01 to 0.4 sulfoalkyl group per anhydroglucose unit as protective colloids in polymerizations.