568 results about "Aqueous dispersion" patented technology

The invention discloses a PHA-acrylic acid structural unit water-based dispersion based on interface engineering regulation and control, a preparation method thereof and application of a paper-based barrier coating, and belongs to the technical field of high polymer materials, interface engineering and water-based coatings. The stable interface layer is constructed in situ between the crystalline PHA and the acrylic resin through the amphiphilic polymer, so that the problems of poor compatibility and film forming defects of a bio-based material are effectively solved. The dispersion can realize excellent waterproof, oil-proof and gas barrier effects by only needing a relatively low coating weight, and the material consumption is remarkably reduced. The unique gradient structure of the coating has excellent mechanical adhesive force and efficient re-pulping and recycling characteristics, and the technical defect that a traditional barrier coating is difficult to recycle is overcome. And an ideal solution with high performance and high safety is provided for green packaging.

The invention discloses a cellulose paper-based diaphragm for a zinc-iodine battery as well as a preparation method and application of the cellulose paper-based diaphragm. The diaphragm is of a three-layer composite structure and comprises a matrix layer formed by paper pulp fibers such as softwood pulp, hardwood pulp, bamboo pulp or straw pulp through a wet papermaking technology, and compact functional layers which cover the two sides of the matrix layer and are formed by oxidized nanocellulose (TOCN). The preparation method mainly comprises the following steps: preparing the paper-based diaphragm matrix through wet papermaking, coating the two sides of the paper-based diaphragm matrix with TOCN aqueous dispersion, and finally carrying out hot-pressing drying treatment to enable the three layers to be tightly combined. According to the invention, the nano aperture and the surface negative electricity functional group of the TOCN layer are utilized, so that physical blocking and electrostatic repulsion of polyiodide ions can be realized at the same time, and the shuttle effect is effectively inhibited; and the uniform pore channels can guide zinc ions to uniformly deposit and inhibit dendritic crystal growth. The diaphragm is green in raw material, simple in process and low in cost, and the cycle life and coulombic efficiency of the battery can be remarkably improved when the diaphragm is applied to the zinc-iodine battery.

The invention relates to the technical field of memristors, and provides a chitosan-based memristor which comprises a substrate, a buffer layer, a composite dielectric layer and a top electrode which are sequentially stacked from bottom to top, the buffer layer is formed by spin-coating a PEDOT: PSS aqueous solution on the substrate and then carrying out heat treatment; the composite dielectric layer is formed by spin-coating the buffer layer with an ultrasonic composite solution formed by a graphene oxide aqueous dispersion and a chitosan acetic acid solution and then carrying out heat treatment. By adopting a collaborative architecture of the chitosan-graphene oxide composite dielectric layer and the PEDOT: PSS buffer layer, the prepared bio-based memristor has the effects of relatively high switching ratio, relatively low operating voltage and good performance stability. Meanwhile, based on stable high and low resistance states of the device, all seven basic logic operations including a NOT gate, an AND gate, an OR gate, a NAND gate, a NOR gate, an XOR gate and an XNOR gate are completely realized on a single bio-based platform, the function accuracy can reach 100%, and an unexpected effect is achieved.

The invention discloses a paper-based molded coffee capsule capable of being naturally composted, a PHA aqueous dispersion in-situ film forming barrier heat-sealing composite layer, a preparation method and application thereof, and belongs to the field of degradable packaging and single-cup extraction capsules. The capsule body is formed by molding paper pulp and is provided with a side wall, a bottom wall and a mouth flange; the biodegradable polyester-based film sealing component is connected to the flange in a sealing manner; and the polyhydroxyalkanoate barrier heat-sealing composite layer covers the inner surface of the body and the sealing surface of the flange. The composite layer is obtained by in-situ film forming of a particle size gradient double-layer aqueous dispersion and comprises a permeation anchoring layer located in paper pulp pores and a continuous compact layer located on the outer side in the thickness direction. The flange is a hot-pressing densified area, and a local thickening heat sealing ring is formed on the sealing face of the flange. Through physical anchoring of the small-particle-size components and surface film forming of the large-particle-size components, the moisture and oxygen blocking and interface bonding performance is achieved, and the brewing sealing performance is guaranteed.

A method for preparing a heavy-duty tire with a natural rubber (NR) modified by graphene / carbon blacks varying in particle size synergized with a vulcanization system is provided. Carbon blacks varying in particle size are subjected to surface modification to obtain an graphene oxide / carbon blacks varying in particle size aqueous dispersion. Subsequently, a graphene oxide / carbon blacks varying in particle size modified NR masterbatch is prepared using an aqueous-phase synergistic aggregating precipitating process. Finally, a natural rubber heavy-duty tire is prepared from graphene / carbon blacks varying in particle size synergistically vulcanized modified natural rubber through a molding process. Compounding of graphene with the carbon blacks varying in particle size is utilized to improve dispersion of reinforcing fillers within the rubber matrix. Adjustment of a ratio of a vulcanizing agent to an accelerator is utilized to regulate a cross-linked network structure of the rubber.

The application discloses a paper-based moulded coffee capsule capable of natural composting, a PHA aqueous dispersion in-situ film-forming barrier heat-sealing composite layer and a preparation method and application thereof, and belongs to the field of degradable packaging and single-cup extraction capsules. The capsule comprises a capsule body formed by moulded paper pulp, a side wall, a bottom wall and a mouth flange, a biodegradable polyester-based film sealing member sealed to the flange, and a polyhydroxyalkanoate barrier heat-sealing composite layer coated on the inner surface of the body and the sealing surface of the flange. The composite layer is obtained by in-situ film-forming of a particle size gradient double-layer aqueous dispersion, and comprises an infiltration anchoring layer located in the pores of the paper pulp and a continuous dense layer on the outside along the thickness direction. The flange is a heat-pressed densification area, and a locally thickened heat-sealing ring is formed on the sealing surface of the flange. The application realizes the moisture and oxygen barrier and interface bonding performance through physical anchoring of small particle size components and surface film-forming of large particle size components, and guarantees the brewing sealing performance.

The invention provides a polyhydroxyalkanoate aqueous composite dispersion and a preparation method and application thereof, the polyhydroxyalkanoate aqueous composite dispersion comprises a polyhydroxyalkanoate aqueous dispersion, an acrylic emulsion and a stabilizer, and the stabilizer is a surfactant with an HLB value of 12-14 or a combination thereof. By adding the surfactant with a specific HLB value, the polarity difference between particles is reduced, and the stability of a PHA aqueous dispersion and acrylic emulsion composite system is improved. The preparation method is simple in production process and has a wide application prospect.

To provide a method for producing a conductive polymer dispersion liquid in which a conductive composite exhibiting excellent conductivity is dispersed, and a method for producing a conductive laminate using the dispersion liquid.SOLUTION: A method for producing a conductive polymer dispersion liquid comprises a step of adding an oxidizing agent that polymerizes a monomer forming a π-conjugated conductive polymer to a reaction liquid containing a polyanion, the monomer forming the π-conjugated conductive polymer, and an aqueous dispersion medium to cause a polymerization reaction and to form a conductive composite containing the π-conjugated conductive polymer and the polyanion, wherein a ratio represented by absorbance A at 600 nm of the reaction liquid immediately before addition of the oxidizing agent divided by a concentration C on a mass basis of the monomer contained in the reaction liquid (absorbance A / concentration C) is 90 or more and 650 or less.SELECTED DRAWING: None

The present invention relates to a method of preparing a superabsorbent polymer. More particularly, the preparation method performs a polymerization reaction of a monomer in the presence of an aqueous dispersion of hydrophobic particles, thus enabling the preparation of a superabsorbent polymer having a high surface tension and an improved absorption rate without deterioration in absorption properties.

The invention relates to a modified aramid nanofiber aqueous dispersion, cellophane and a preparation method of the modified aramid nanofiber aqueous dispersion. The preparation method comprises the following steps: dispersing para-aramid fiber in a DMSO / KOH system to obtain DMSO dispersion liquid of aramid fiber; adding acid anhydride for esterification modification, putting the modified dispersion liquid into a dialysis bag, dialyzing in deionized water, taking out, and carrying out mechanical treatment, so as to obtain the modified aramid nanofiber aqueous dispersion liquid. Carboxylate ions are introduced to the surface of the aramid fiber by adopting an esterification modification method for the first time, so that the aramid fiber is stably dispersed in water for a long time under the action of electrostatic repulsion, the preparation method is simple, the cost is low, and the diameter of the aramid nanofiber can be controlled by regulating and controlling the charge ratio of anhydride. The modified aramid nanofiber cellophane prepared from the aqueous dispersion through vacuum filtration and hot pressing has high strength and high transparency, the tensile strength can reach 257 MPa, the maximum visible light transmittance can reach 83%, and the modified aramid nanofiber cellophane has good application prospects in the field of high-performance transparent materials.

The invention belongs to the technical field of nano-crystalline cellulose materials, and discloses a method for enhancing dissolved nano-crystalline cellulose papermaking. The method comprises the following steps: 1) dissolving a cellulose raw material with a solvent to obtain a cellulose solution; 2) mixing the cellulose solution with an anti-solvent, and performing nanoscale dispersion to obtain a dissolved nano cellulose dispersion; (3) washing the dissolved nano-cellulose dispersion to obtain a dissolved nano-cellulose aqueous dispersion; 4) adding the dissolved nano cellulose aqueous dispersion into the paper pulp, stirring, dispersing and homogenizing to obtain mixed pulp; and 5) performing papermaking forming on the mixed pulp to obtain enhanced paper. The method is simple, and compared with other nanocellulose, the water filtering time is effectively shortened. According to the method, the strength of the paper is remarkably improved, the problems that traditional paper is low in strength and water filtering time is long after the nano cellulose is added are effectively solved, application of the paper in the high-performance field and the industrial field is facilitated, and the application range of the paper is widened.

The application relates to the field of graphene oxide, and discloses modified graphene oxide, which comprises graphene oxide and grafted polyoxyethylene chains, the chemical formula of the polyoxyethylene chains being -CH2CH(OH)CH2O(CH2CH2O) n CH2CH2OH, wherein n is any integer of 3-20; the grafting rate of the polyoxyethylene chains in the modified graphene oxide is 30-50%. The modified graphene oxide has good salt resistance, can resist acid / alkali aqueous solutions, and effectively inhibits the accumulation and agglomeration of graphene oxide.

A one-component waterborne coating composition comprising: a) an aqueous dispersion of polymer particles, which polymer particles comprise an anionic-stabilized copolymer having a Mw of at least 100,000 g / mol and self cross- linking functionality, wherein the copolymer is an acrylic copolymer, an acrylic-vinyl copolymer, or a polyurethane vinyl-acrylic copolymer; and b) an organosilane; wherein: the organosilane is unreactive towards carboxylic acid functionality; and the organosilane is present in an amount of at least 5 wt.% of the total solids of the coating composition; and a coated substrate comprising a substrate and a coating, which coating is obtained by applying said coating composition to the substrate and allowing the coating composition to dry.

Provided is a magnesium oxide.　This magnesium oxide, when being made into an aqueous dispersion containing the magnesium oxide at a proportion of 16 g per 100 g of water, exhibits a relaxation time satisfying 1000 milliseconds or less in TD-NMR at 40°C.

Disclosed is a modified polymer obtained by enclosing and / or grafting a non-thermosensitive polymer particle with a thermosensitive polymer, the modified polymer has a viscosity exhibiting a significant change at 40 to 90℃. Also disclosed is a polymer having a core-shell structure, wherein the core particle consists essentially of a non-thermosensitive polymer, and the shell is located on the outer surface of the core particle and consists essentially of a segment derived from a thermosensitive polymer, the polymer has a viscosity exhibiting a significant change at 40 to 90℃. Further disclosed is a method for preparing an aqueous dispersion of polymer. Still further disclosed is a coating composition comprising the above modified polymer, the above polymer, or the above aqueous dispersion of polymer, a substrate coated with the coating composition, as well as use of the modified polymer, the polymer, or the aqueous dispersion of polymer.

There is provided a composition for a semiconductor process, the composition comprising silica particles, and the composition having a value of 6.30% to 9.60% according to Formula 1. Further, a composition for a semiconductor process is provided, the composition comprising silica particles, and having a value of greater than 5.80% and less than 8.80% according to Formula 2. Further, provided is a method for preparing a composition for a semiconductor process, the method comprising: a step (a) of stirring an aqueous dispersion solution of silica having a hydrogen ion concentration (pH) in the range of 4.0 to 5.5; a step (b) of introducing a silica surface modifier containing an aminosilane component when the temperature of the aqueous silica dispersion solution is 25 DEG C or more and less than 40 DEG C; (c) introducing a hydrogen ion concentration (pH) regulator into the aqueous silica dispersion solution into which the silica surface modifier has been introduced; and (d) stirring the aqueous silica dispersion solution into which the hydrogen ion concentration (pH) regulator has been introduced so that the final reaction temperature is within the range of 50 DEG C to 65 DEG C. Further, a method of manufacturing a semiconductor device using the composition for a semiconductor process is provided.

This invention discloses an aqueous dispersion of a polyhydroxyalkanoate-grafted ethylene-acrylic acid copolymer with a self-emulsifying core-shell structure, its preparation method, and its recyclable paper packaging, belonging to the field of reactive modification of polymer materials and green packaging technology. This invention employs in-situ reactive extrusion technology to construct stable microparticles with a hydrophobic polyhydroxyalkanoate core and a hydrophilic ethylene-acrylic acid copolymer salt as the shell, overcoming the industry challenge of poor compatibility of bio-based materials. The aqueous dispersion requires no external emulsifier, achieving the same excellent barrier and heat-sealing effects with a lower coating weight, significantly reducing usage costs. Its unique alkali-induced swelling mechanism endows the coating with intelligent peeling properties, achieving efficient separation of the coating and fiber during resizing, greatly improving the purity of recycled fibers.

To improve the adhesion of the coating film to the resin and the resistance of the coating films to blocking each other. [Solution] The polyurethane aqueous dispersion according to the embodiment comprises a polyurethane resin (A) containing a polyester polyol as a constituent component dispersed in an aqueous dispersion medium, and includes a carbodiimide group-containing compound (B) and a salt (C) of an acid and an alkali metal. The polyurethane resin (A) has carboxyl groups, and the salt (C) is at least one selected from the group consisting of bicarbonates, carbonates, monocarboxylates, dicarboxylates, tricarboxylates, and phosphates, and the salt (C) exists in an ionized state in the aqueous dispersion medium.

The present invention provides an aqueous polyamide resin dispersion that does not require the removal of organic solvents and exhibits excellent storage stability, adhesion to PET and OPP substrates, ejection stability when used as an inkjet ink, and abrasion resistance of printed materials. [Solution] A polyamide resin aqueous dispersion containing a polyamide resin (A) and a surfactant (B), wherein the total amine value of the polyamide resin (A) is less than the acid value of the polyamide resin (A), the total amine value of the polyamide resin (A) is 0.5 to 10 mg KOH / g, the surfactant (B) contains a polyoxyalkylene alkyl ether, and the content of the surfactant (B) is 9 to 35% by weight based on the total weight of (A) and (B).

The present invention relates to a method of manufacturing a heat-seal packaging material (1) comprising: providing a support layer (2b) comprising paper (2a), applying a first barrier coating composition (7) in the form of an aqueous dispersion, thereby forming a first barrier coating (4) comprising at least 45% by weight of a binder based on the total dry weight of the first barrier coating (4), and applying a second barrier coating composition (7) in the form of an aqueous dispersion, thereby forming a second barrier coating (4) comprising at least 45% by weight of a binder based on the total dry weight of the first barrier coating (4). Applying a second barrier coating composition (8) to form a second barrier coating layer (5) wherein the second barrier coating composition (8) comprises a dispersed heat-sealing polymer which comprises at least 45% by weight of the total dry weight of the second barrier coating layer (5). The invention also relates to a heat-sealing packaging material, to a package comprising the heat-sealing packaging material, and to the use of the heat-sealing packaging material (1) in a package.

This invention belongs to the technical field of carbon dioxide capture methods, specifically relating to a carbon dioxide capture material and method based on porous liquid physical absorption. The carbon dioxide capture material consists of a hydrophobic solid porous material and an aqueous dispersion medium containing polyvinylpyrrolidone (PVP). The aqueous dispersion medium accounts for 90-95 wt% of the total system mass, and the solid porous material accounts for 5-10 wt%. The preparation method includes the following steps: Step 1, placing the weighed PPVP-containing aqueous dispersion medium in an open container, forming a gentle vortex through stirring, and then slowly adding the solid porous material; Step 2, dispersing in an ultrasonic water bath; Step 3, oscillating in a constant-temperature shaker; Step 4, repeating the above ultrasonic and oscillation steps. Compared with a pure water system, the third type of porous liquid system based on hydrophobic porous particles obtained by this invention can achieve better continuous carbon dioxide capture through the synergistic effect of the solid porous material and the solid-liquid interface interaction region.

The invention relates to the technical field of oil field reservoir damage inhibition, in particular to a carbon quantum dot biological composite material and a preparation method and application thereof. The preparation method of the carbon quantum dot biological composite material provided by the invention comprises the following steps: mixing a scenedesmus extracting solution with an aqueous dispersion of carbon quantum dots, then adjusting the pH value to 8-10, and carrying out a grafting reaction to obtain the carbon quantum dot biological composite material, the scenedesmus extracting solution is a mixed solution of intracellular substances released after scenedesmus cells are broken and water. The carbon quantum dot biological composite material prepared by the method can be used as an asphaltene deposition inhibitor, has the characteristics of greenness, high efficiency and low cost, and can effectively inhibit asphaltene deposition, so that the fluidity of crude oil is improved, reservoir damage is reduced, and the production cost is reduced.

A composition comprising a first perfluoro polymer having a glass transition temperature of 10°C or less, and a second fluoro polymer different from the first perfluoro polymer and containing a structural unit based on tetrafluoroethylene and a structural unit based on hexafluoropropylene, wherein the content of a structural unit based on perfluoro (alkyl vinyl ether) with respect to the total content of all structural units of the first perfluoro polymer and the second fluoro polymer is 0.1-5.0 mol %.

An abrasive article comprises abrasive particles secured to a substrate by at least one binder material. The at least one binder material comprises a cured reaction product of components comprising: a) at least one phenolic resin; and b) an aqueous dispersion of at least one polyurethane, wherein, based on the total solids weight of components a) and b), the components comprise 56 to 91 percent by weight of component a) and 44 to 9 percent by weight of component b). Methods of making and using the abrasive articles are also disclosed.

A composition comprises an aqueous dispersion of polymer particles, polymeric organic crosslinked microspheres, and colloidal silica particles. The composition is useful in coating compositions for exterior applications to achieve a balance of excellent dirt pickup resistance and durability performance under accelerated testing conditions.

Inorganic particles comprised in an aqueous dispersion according to the present invention consist of agglomerates of crystalline and amorphous microparticles, and exhibit spherical and smooth surfaces. The spherical appearance, low crystallinity, and narrow particle size distribution of the inorganic particles are further advantageous in reducing scratch defects in a CMP process. In addition, since the microparticles on the inorganic particle surfaces provide more active sites and thus the removal rate is high, the inorganic particles may be advantageous as next-generation CMP polishing materials. In addition, the aqueous dispersion according to the present invention further comprises an amino acid, and the amino acid may be adsorbed on a surface of a silicon oxide wafer to strengthen electrostatic attraction between the silicon oxide wafer and the inorganic particles, resulting in an effect of further improving the removal rate.

A method for producing a laminate having a substrate layer and a resin layer formed on at least one side of the substrate layer, the resin layer containing a poly(3-hydroxybutyrate)-based resin and having a weight per unit area (dry weight) of 15 to 50 g / m 2 On the surface of the substrate layer, an aqueous dispersion (HB-A) containing a poly(3-hydroxybutyrate)-based resin (a1) and a dispersant (a2) containing a water-soluble high molecule is applied to form a coating film (a), and heating is performed to form a coating layer (A) having a weight per unit area (dry weight) of 0.5 to 10 g / m 2 On the surface of the coating layer (A), an aqueous dispersion (HB-B) containing a poly(3-hydroxybutyrate)-based resin (b1) and a dispersant (b2) containing a water-soluble high molecule is applied to form a coating film (b), and heating is performed to form a coating layer (B). The content of the dispersant (b2) containing a water-soluble high molecule is 0 to 0.5 parts by weight per 100 parts by weight of (b1).

Provided is a coating composition which has excellent coating properties and which forms a coating film that has good water vapor resistance and corrosion resistance. A coating composition comprising an aqueous dispersion containing a water-soluble polyamideimide resin (P), a polyethersulfone resin (Q), and a fluorine-containing polymer (R) containing a non-melt-processable fluorine-containing polymer (S) and a melt-processable perfluoropolymer (T) having a melting point of 200-350 DEG C, the mass ratio of the water-soluble polyamideimide resin (P) to the polyethersulfone resin (Q) is 10 / 90 to 40 / 60.

A crystalline polyester resin aqueous dispersion containing a crystalline polyester resin has excellent solvent solubility and therefore needs only a small amount of an organic solvent to form an aqueous dispersion, and is capable of forming a coating film that has excellent processability and retort resistance. The crystalline polyester resin aqueous dispersion contains a crystalline polyester resin satisfying requirements (1) to (3) described below. (1) The crystalline polyester resin has a melting point of 120° C. to 160° C. (2) The crystalline polyester resin has a crystallinity of 60% to 90%, the crystallinity being determined from a heat quantity of fusion (J / g) of an endothermic peak obtained when the crystalline polyester resin is heated from −50° C. to 200° C. at 20° C. / min by differential scanning calorimetry (DSC) after subjected to an aging treatment at 100° C. for 10 minutes. (3) The crystalline polyester resin has an acid value of 180 eq / ton or more.

An alkyl pendant polymer-type non-silicone, non-fluorine release agent resin is applied to the surface of a substrate film without using organic solvents, forming a coating and release layer without the coating liquid being repelled from the surface of the substrate film. [Solution] A method for manufacturing a release film comprises, in this order, the steps of obtaining a release film precursor by applying an aqueous dispersion of a non-silicone, non-fluorine release agent resin to the first surface 11a of a base film 11 having a first surface 11a and a second surface 11b, the first surface 11a of the base film 11 having a polyester resin on the first surface 11a, and drying the release film precursor, wherein the aqueous dispersion comprises water, a release agent resin which is a non-silicone, non-fluorine release agent resin and is an alkyl pendant polymer, and a surfactant, the surfactant comprising an acetylene glycol-based nonionic surfactant having an HLB value of 11 or more.