5165 results about "Emulsion" patented technology

The present invention discloses a water-based emulsion of PHA, PBAT and PVOH and its application in paper-based barrier coatings. This emulsion is prepared by first melt-blending PHA and PBAT at 150-170 °C and then dispersing them into an aqueous PVOH solution at 80-95 °C. Plasticizers, cross-linking agents and surfactants can be added to improve the performance. After coating on paper and drying at 80-150 °C, a barrier film with a Cobb value of 10-15 g / m² and a Kit ≥ 10 grade is formed. Compared with traditional PE film laminating or fluorine-containing coatings, this system is more environmentally friendly and recyclable; PVOH dissolves in pulping water, PHA and PBAT are easily separated, and fibers can be efficiently recovered; in composting, soil and marine environments, PHA and PBAT have extensive biodegradability and are superior to PLA which is difficult to recycle and requires industrial composting. It is applicable to food, industrial, special packaging and agricultural paper products.

The invention discloses a repulpable and degradable PHA heat-seal barrier coating and a composition thereof, and belongs to the field of water-based functional coatings and cellulose-based packaging materials. The coating composition is prepared from the following components in percentage by non-volatile solids: 30 to 85 weight percent of polyhydroxyalkanoate emulsion, 5 to 60 weight percent of flaky natural inorganic matters, a water-based cross-linking agent and an auxiliary agent, and 1 to 20 weight percent of ethylene-acrylic acid or ethylene-methyl acrylate dispersion can be selected. The pH value of the composition is 6.5-9.0, and organic fluorine is not artificially added. When the dry weight is 6-20 g / m, the coating meets at least one of the following four items: the water vapor transmission rate (38 DEG C, 90% RH) is less than or equal to 80 g / m.d, Cobb60 is less than or equal to 15 g / m, the oil resistance grade is greater than or equal to 11, and the laboratory repulping rate is greater than or equal to 98%; and the heat-sealing peel strength is greater than or equal to 2.5 N / 15mm under the conditions of 150 DEG C, 0.2 MPa and 0.5 s. And the coating and the stripping film thereof meet the industrial composting standard.

The invention discloses a polyhydroxyalkanoate water-based barrier coating composition and application, and belongs to the technical field of packaging materials. The composition takes water as a dispersion medium and comprises polyhydroxyalkanoate, a plasticizer, an emulsifier and an inorganic nano filler. The stable emulsion with the volume average particle size of 400-700nm is prepared under specific proportioning and process conditions. After the emulsion is applied to a paper substrate according to the dry film coating weight of 10-12 g / m, the obtained coating shows good comprehensive performance: the oxygen permeability is not higher than 580 cm / m.d, the water vapor permeability is not higher than 290 g / m.d, and the heat sealing strength at 130 DEG C is not lower than 5.0 N / 15 mm. The biodegradable paper-based packaging film does not contain fluorine compounds, can be completely biodegraded, and provides a technical path for sustainable paper-based packaging.

The invention discloses a cement-based aerogel heat preservation and heat insulation coating material for concrete and a spraying construction process of the cement-based aerogel heat preservation and heat insulation coating material, and belongs to the technical field of concrete materials. The coating material is prepared from powder, composite emulsion and water, and the powder is prepared by mixing superfine sand, cement, modified silicon dioxide-carbon nanotube composite aerogel powder, hollow glass beads, nanofibers, graphene nanosheets, an ultraviolet light absorber, a water reducing agent and a defoaming agent. The composite emulsion is composed of an acrylate copolymer emulsion, a polyvinyl acetate-ethylene emulsion, a temperature-sensitive polymer emulsion and a coalescing agent. Based on the multi-stage pore network and multi-component emulsion optimization design and multi-component synergistic effect, the material has good fluidity after being mixed, and has low heat conductivity coefficient, high strength and high toughness after being hardened; the construction technology of high-pressure water flushing and layered spraying is provided, and the method has the advantages of being efficient in construction, stable in quality and the like and can be applied to heat preservation and heat insulation of a concrete structure in a severe environment.

Provided are a water-resistant wood-plastic reinforced composite flooring and a manufacturing method therefor. Wood flour is boiled in boiling water for 3-4 hours, filtered and dried, to obtain dried wood flour; polypropylene, butyl acrylate, methyl methacrylate, maleic anhydride and dicumyl peroxide are mixed evenly, extruded and granulated, and dried to obtain a compatibilizer; the dried wood flour and polypropylene are mixed evenly, the compatibilizer is added and mixed evenly, then extrusion and granulation, and injection molded, are performed, to obtain a wood-plastic flooring blank; a composite resin emulsion and a photoinitiator are ultrasonically mixed evenly, and the wood-plastic flooring blank is immersed therein, then taken out and dried at room temperature, and then vacuum dried and UV cured, to obtain water-resistant wood-plastic reinforced composite flooring.

The invention discloses a preparation method of a flexible material with double functions of radiation refrigeration and photothermal conversion storage, and relates to the field of composite phase change materials. The preparation method comprises the following steps: 1) preparing the flexible phase change material matrix by utilizing n-octadecane, SEBS and POE through hot pressing; 2) preparing a BaSO4 solution by using absolute ethyl alcohol, deionized water, a water-based defoaming agent, a water-based dispersing agent and an acrylic resin emulsion; (3) preparing an MXene solution; and 4) spraying the BaSO4 solution on the surface of one side of the flexible composite phase change material matrix by using a spray gun, and spraying the MXene solution on the surface of the other side of the flexible composite phase change material matrix to obtain the flexible composite phase change material. The radiation refrigeration layer can strongly reflect visible light and near-infrared light, has high emissivity in an infrared light area, especially in an atmospheric window wave band, reduces absorbed atmospheric heat radiation, reduces urban heat island effect caused by dense building groups in cities, and can effectively solve the problems of large day and night temperature difference and heat supply and demand in summer and winter.

To provide a device and a method for treating at least one of hypertension, pulmonary arteries, diabetes, obesity, heart failure, end-stage renal disease, digestive disease, urological disease, cancers, tumors, pain, asthma or chronic obstructive pulmonary disease by delivering an effective amount of a formulation to a tissue.SOLUTION: In embodiments of the present invention, the formulation may include at least one of a gas, a vapor, a liquid, a solution, an emulsion or a suspension of one or more ingredients. In embodiments of the present invention, amounts of the formulation and / or energy are effective in injuring or damaging tissue, nerves and nerve endings in order to relieve disease symptoms.SELECTED DRAWING: Figure 3B

The invention provides a preparation method of a waterproof flame-retardant multifunctional fabric, and belongs to the technical field of functional textiles. The preparation method comprises the following steps: heating dihydric alcohol until the dihydric alcohol is completely melted, adding diisocyanate, a flame retardant and a catalyst, reacting to obtain a polyurethane prepolymer, adding a chain extender for chain extension, then adding an end-capping reagent for end capping, cooling, adding an emulsifier to obtain a waterproof flame retardant emulsion, adding water to form a finishing agent, soaking a polyacrylonitrile pre-oxidized fiber fabric in the finishing agent for treatment, and drying to obtain the waterproof flame retardant fabric. And pre-drying and baking to obtain the multifunctional fabric. Polyhydric alcohol with a long alkane chain is adopted to carry out chain extension on a polyurethane prepolymer, the obtained waterproof agent has good film-forming property, can be firmly fixed on the surface of a fiber without the help of a cross-linking agent or an adhesive during application, and endows a modified textile with excellent washing fastness.

The invention relates to the technical field of polyurethane coatings, in particular to a hydrophobic flame-retardant polyurethane coating and a preparation method thereof. The preparation method comprises the following steps: firstly, taking 9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and methallyl alcohol as raw materials, and reacting to obtain hydroxyl grafted phosphaphenanthrene; taking 1, 1, 3, 3-tetramethyldisiloxane and methallyl alcohol as raw materials, and reacting according to a molar ratio of 1: 2 to obtain dihydroxy siloxane; then cyanuric chloride, hydroxyl grafted phosphaphenanthrene and dihydroxyl siloxane react according to the molar ratio of 1: 1: (1.5-1.8), and the dihydroxyl-terminated silicon-containing flame retardant is obtained. The preparation method comprises the following steps: mixing a dihydroxyl-terminated silicon-containing flame retardant with polytetrahydrofuran ether glycol to serve as a soft segment, and reacting with isocyanate to obtain a hydrophobic flame-retardant polyurethane emulsion; mixing the hydrophobic flame-retardant polyurethane emulsion, an anti-aging agent, an ultraviolet light absorber, a defoaming agent, kaolin, nano silicon dioxide and talcum powder to obtain the hydrophobic flame-retardant polyurethane coating.

The invention relates to the technical field of thermal management material preparation, solves the technical problems of loose heat conduction network structure and non-uniform heat conduction direction of a flexible composite phase change material, and particularly relates to a magnetic polymer-based flexible composite phase change material and a preparation method thereof. Comprising the following steps: preparing a modified polydimethylsiloxane prepolymer from a carbon nanotube dispersion liquid and a polydimethylsiloxane prepolymer; adopting a Pickering emulsion method to mix 42 # paraffin, the modified polydimethylsiloxane prepolymer and nano cellulose to prepare a composite phase change material emulsion; silver mirror reaction is adopted to carry out surface silver plating on the magnetic neodymium iron boron particles; the magnetic polymer-based flexible composite phase change material is prepared from the composite phase change material emulsion and the surface-silvered magnetic neodymium iron boron particles. The high flexibility and magnetism of the prepared material in a normal temperature state endow the material with a more convenient installation mode and lower contact thermal resistance, the heat conduction network structure and component compatibility of the material are improved, and the application requirements of a phase change thermal management technology can be met.

The invention discloses a photovoltaic POSS (polyhedral oligomeric silsesquioxane)-containing antireflection film coating liquid and a preparation method thereof, the coating liquid comprises the following raw materials in parts by weight: 80-100 parts of modified emulsion, 10-15 parts of modified graphene, 3-5 parts of sodium dodecyl benzene sulfonate, 1-3 parts of triethylene tetramine and 40-60 parts of deionized water, a modified additive in the coating liquid contains a polyhedral oligomeric silsesquioxane structure, the polyhedral oligomeric silsesquioxane structure can form uniformly-distributed nanopores and is matched with a two-dimensional honeycomb lattice structure in the graphene oxide, the surface roughness can be increased, the microstructure can scatter incident light and reduce specular reflection, so that the surface light transmittance is improved, and meanwhile, the modified additive molecule contains a fluoroalkyl structure, so that the surface light transmittance is improved. The fluoroalkane has a high refractive index, so that light reflection can be reduced, and the light transmittance is further improved.

The invention relates to a kitchen waste oil recovery treatment method, which comprises: S1, carrying out multi-field synergistic pretreatment: sequentially carrying out ultrasonic wave and high-frequency pulse electric field treatment on waste oil to break an emulsion layer, adding magnetic nanoparticles to adsorb polar impurities, and carrying out magnetic field separation to obtain high-purity oil; s2, supercritical catalytic reaction: under the CO2 supercritical condition, using a core-shell structure composite catalyst to synchronously perform transesterification reaction and glycerol dehydration reaction; s3, dynamic membrane separation: separating biodiesel and glycerol in real time through an intelligent membrane assembly; s4, gradient utilization of energy: recovering reaction waste heat to drive membrane distillation to concentrate wastewater, and using tail gas CO2 for carbonation reaction to generate calcium carbonate. Through four core technologies of multi-field collaborative pretreatment, low-temperature supercritical catalysis, dynamic membrane separation and energy gradient utilization, triple limitations on efficiency, cost and environmental protection in the prior art are remarkably broken through.

The invention discloses a water-borne epoxy resin coating which comprises a component A and a component B, the component A is prepared from 60 to 80 parts of 50 percent modified water-borne epoxy resin emulsion, 5 to 15 parts of deionized water, 0.5 to 1 part of wetting dispersant, 0.2 to 0.8 part of defoaming agent, 5 to 10 parts of modified zinc phosphate, 3 to 5 parts of ion exchange antirust pigment, 4 to 6 parts of sericite powder, 3 to 5 parts of glass flake, 5 to 10 parts of precipitated barium sulphate, 1 to 5 parts of nano silicon dioxide and 0.5 to 1 part of rheological additive; 1 to 2 parts of modified organic bentonite slurry; 0.1 to 0.3 part of a pH conditioning agent; and 0.2 to 0.8 part of a flash rust inhibitor. The component B is prepared from 40 to 50 parts of waterborne epoxy-amine adduct, 20 to 30 parts of 50 percent modified polyamide curing agent, 5 to 15 parts of 60 percent Mannich base phenolic aldehyde amine curing agent, 0.5 to 1.5 parts of epoxy silane coupling agent, 1 to 2 parts of nonionic surfactant and 15 to 20 parts of deionized water. The emulsion stability of the waterborne epoxy resin coating is improved through a bisphenol A / F mixed epoxy emulsion and a grafted polyethylene glycol hydrophilic chain segment.

The invention relates to the technical field of cables, in particular to a high-toughness halogen-free flame-retardant crosslinked cable and a preparation method thereof.High-density polyethylene, ethylene-vinyl acetate copolymer, modified MXene and auxiliaries are mixed and co-extruded, and ultraviolet radiation crosslinking is adopted to prepare a reinforcing layer of the cable; the preparation method comprises the following steps: firstly, coating MXene with dopamine, treating with tert-butyldimethylsilyl chloride, then grafting DOPO (9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide), and then introducing double bonds on the composite MXene; a self-repairing polyurethane emulsion, modified MXene and a photoinitiator are blended to prepare a protective coating, the surface of the reinforcing layer is coated with the protective coating, light curing treatment is carried out, and the water-resistant and corrosion-resistant protective layer sleeve with the self-repairing surface is prepared; a chain extender containing boric acid ester bonds and disulfide bonds is added in the preparation of the self-repairing polyurethane emulsion, and pentaerythritol triacrylate is used as a photosensitizer.

The invention provides a salt-tolerant hydrophobic association polymer suspension emulsion and a preparation method and application thereof, and belongs to the technical field of oil and gas well fracturing, the suspension emulsion comprises the following components by weight: 40-50 parts of white oil, 4-6 parts of a suspending agent, 40-50 parts of hydrophobic association polymer powder, 5-10 parts of an emulsifier, 1-2 parts of a conditioning agent, and 0.1-0.2 part of a preservative. The preparation method comprises the following steps: adding the white oil into a reaction kettle, and starting stirring for 30 minutes; sequentially adding the suspending agent and the hydrophobic association polymer powder into the reaction kettle, and stirring for 30 minutes; after uniformly dispersing, adding an emulsifier, and stirring for 30 minutes; adding a conditioning agent, continuously and circularly stirring for 30 minutes, and then adding a preservative to obtain the hydrophobic association polymer suspension emulsion for fracturing. The suspension emulsion provided by the invention has the advantages of rapid dissolution and tackification and good salt tolerance, and meets the technical requirements of large-displacement hydraulic fracturing construction for continuous mixing by using flow-back fluid.

The invention relates to a composition of polyester particles and sodium hyaluronate, which is prepared by the following steps: preparing PCL (Polycaprolactone) microspheres with the particle size of 20-50 microns by an emulsion method; hA is selected, and a PBS buffer solution is used for preparing an HA solution; repeatedly freezing and thawing in a refrigerator at-80 DEG C for 3 times to form micro-crosslinked HA gel; and mixing the microspheres and the micro-crosslinked HA gel according to a mass ratio of 25: 75. The invention provides a technology of taking the physically micro-crosslinked HA as a suspension carrier, so that the polyester particles or microspheres can be stably suspended in an HA solution system without a chemical crosslinking agent, and an injection product has better biocompatibility and safety. HA which does not contain a chemical cross-linking agent and polyester particles / microspheres are mixed to serve as a medical beauty filling system, and the problem of stable suspension of the polyester particles / microspheres in the HA is solved by performing physical micro-crosslinking on the HA.

The invention relates to the technical field of liquid-liquid homogeneous microextraction, in particular to a method for microextraction analysis of perfluorooctanoic acid by using a switchable eutectic solvent. Comprising the following steps: step 1, mixing a hydrogen bond acceptor and a hydrogen bond donor according to a set proportion value, and stirring and mixing at a set temperature value to obtain a eutectic solvent; step 2, filtering the water sample through a water-based filter membrane, then adding a set amount of deep eutectic solvent, dropwise adding an alkaline solution, carrying out full vortex mixing through a mixer, and then adding an acidic solution to form an emulsion; according to the method, the high selectivity of the green solvent with a specific structure on perfluorooctanoic acid and the characteristic that the solvent is switched between hydrophilic and hydrophobic forms are utilized, so that the microextraction time is shortened, and the impurity removal and enrichment effects are enhanced. The method is simple and convenient to operate, green, environment-friendly, low in cost and good in effect, has the advantage of efficiently and rapidly pretreating the batch small-size complex matrix sample, and has a relatively good application prospect.

The invention discloses high-strength corrosion-resistant pervious concrete and a preparation method thereof, and belongs to the technical field of concrete. The concrete is prepared from the following raw materials in parts by weight: 200-300 parts of cement, 1000-1300 parts of coarse aggregate, 20-30 parts of a composite admixture, 10-20 parts of a reinforcing agent, 1-1.5 parts of a water reducing agent, 3-5 parts of an additive and 100-130 parts of water, the reinforcing agent is prepared from modified basalt fiber and styrene-acrylic emulsion according to the mass ratio of (8 to 10): 1; the additive is a SiO2 (at) PDA (at) zeolite composite material; the composite admixture is composed of fly ash and modified steel slag powder according to a mass ratio of 2: 1. According to the invention, by optimizing the proportion of a plurality of composite materials, the interface bonding property with a gel material matrix is improved, the mechanical property and durability are remarkably improved while the water permeability is maintained, and the corrosion resistance of the concrete matrix is enhanced.

The invention provides a water-based intumescent fireproof coating as well as a preparation method and application thereof, and relates to the technical field of coating materials. The water-based intumescent fireproof coating is prepared from the following components in parts by weight: 25 to 35 parts of water-based silicone acrylic emulsion, 40 to 60 parts of flame retardant, 15 to 25 parts of water, 5 to 10 parts of titanium dioxide and 1 to 5 parts of coalescing agent, wherein the flame retardant is ammonium polyphosphate modified by 1-cyclohexylpiperazine. According to the water-based intumescent fireproof coating disclosed by the invention, the silicone acrylic emulsion is used as a main film forming substance, the 1-cyclohexylpiperazine modified ammonium polyphosphate is used as a flame retardant, and the titanium dioxide is used as a filler to form a fireproof intumescent system, so that the water-based intumescent fireproof coating has the advantages of simple production process, excellent performance, environment friendliness and the like; and the prepared fireproof coating has good fireproof performance and durability.

The invention discloses a corrosion-resistant polysilsesquioxane modified polyurethane emulsion and a preparation method thereof, and belongs to the technical field of emulsions.The preparation method comprises the steps that gamma-aminopropyltriethoxysilane, namely APTES, is subjected to hydrolytic condensation under the catalysis of tetraethylammonium hydroxide, and POSS is prepared; the preparation method comprises the following steps: carrying out hydrolytic condensation reaction on APTES, synchronously adding phenyltrimethoxysilane in the hydrolytic condensation reaction, forming phenyl-amino difunctional POSS (Polyhedral Oligomeric Silsesquioxane) according to a molar ratio of phenyltrimethoxysilane to APTES of 1: 4, and grafting POSS and graphene oxide GO in dimethyl sulfoxide through amidation reaction to prepare a POSS / GO composite material; dispersing POSS / GO / Zn in the polyurethane prepolymer, adding a curing agent and a solvent, and stirring to form a homogeneous emulsion; through phenyl trapezoid polysilsesquioxane modification and dynamic reversible self-repairing network design, the wear resistance of the coating is improved, microcracks can be closed at the temperature of 60 DEG C, and the maintenance requirement is reduced; laser micro-nano structured base material treatment is combined, the adhesive force is increased to be larger than or equal to 20 MPa, and meanwhile a gamma-butyrolactone low-VOC solvent is adopted.

A linerless wash-off label (100) comprising a paper-based face (101, 201) and pressure sensitive adhesive (102) is provided. The paper-based face (101, 201) comprises a base paper (206) and a release layer (203), and the release layer (203) and the pressure sensitive adhesive (102) are arranged on opposite sides of the base paper (206). The pressure sensitive adhesive (102) comprises a water-based acrylic emulsion polymer composition, the pressure sensitive adhesive (102) is sensitive to washing conditions, and the base paper (206) comprises wet strength resin and has water absorptiveness of from 10 to 30 g / m2 when measured according to an ISO standard 535 (contact time 60 s). Further, a label product roll comprising the linerless wash-off labels (100) as well as a labelled item comprising an item and a linerless wash-off (100) label are provided. Still further, use of the linerless wash-off label (100) and method of manufacturing a linerless wash-off label web for providing the linerless label product roll are provided.

The invention discloses sewage treatment equipment and method for oil field thickened oil produced water. The equipment comprises pretreatment equipment, main body equipment, dissolved gas supply equipment and a water outlet pump. Main body equipment comprises barrel equipment, and a flotation cyclone used for achieving the functions of dissolved air flotation and cyclone separation at the same time, separating out large-particle suspended solids through centrifugal force difference and achieving floating of oil drops through microbubble adsorption surfaces is sequentially arranged on the inner portion of the barrel equipment from top to bottom. The coalescence filler layer is made of oleophylic and hydrophobic core-shell structure fibers, and emulsified oil is promoted to polymerize and break emulsion through surface energy difference; and the inclined plate sedimentation device adopts an inclined tube labyrinth surrounding structure, performs deep sedimentation by utilizing a laminar flow principle, and further removes oil drops formed after coalescence.

The invention relates to the technical field of asphalt material preparation, in particular to a cold-mixing and cold-spreading waterborne acrylic hybrid epoxy environment-friendly asphalt material preparation process which comprises the following steps: physically mixing waterborne acrylic emulsion and waterborne epoxy emulsion to obtain waterborne acrylic hybrid epoxy emulsion; adding the asphalt pavement milling material and an activating agent into vibration stirring equipment, and stirring to obtain an activated milling material; after the activated milling material is obtained, continuously adding the water-based acrylic hybrid epoxy emulsion, the curing agent and the cold-mixed asphalt modifier into the vibration stirring equipment, and stirring and coating at normal temperature; pure water is added into the vibration stirring equipment, and the torque of the vibration stirring equipment and the temperature of the asphalt mixture are collected within a preset time period after the pure water is added; determining a local coating non-uniform evaluation value and a viscosity evaluation coefficient of the asphalt mixture; the curing reaction in the vibration stirring equipment is regulated and controlled, and the prepared asphalt material is obtained. The mechanical property of the prepared asphalt material is improved.

An emulsion comprises a first discontinuous phase comprising first droplets, a second discontinuous phase comprising second droplets, and a continuous aqueous phase. The first droplets include at least one first surfactant and at least one first fluorocarbon, and have a first diameter of more than 100 nm. The second droplets include at least one surfactant, at least one drug, and at least one solvent, and have a second diameter of no more than 100 nm.

The invention relates to a coating, in particular to a radiation refrigeration heat insulation coating and a preparation method thereof, and the radiation refrigeration coating comprises a water-based emulsion, a reflective inorganic filler, a radiation inorganic filler water-based emulsion, a radiation inorganic filler, functional nanocellulose and a functional additive. The radiation refrigeration coating can reflect energy of a sunlight wave band (0.3-2.5 [mu] m) and perform radiation heat exchange with the universe by utilizing an atmospheric window (8-13 [mu] m), and the cooling effect lower than the environment temperature can be achieved. In high-temperature weather in summer, the surface temperature of a building can be effectively reduced, and the use frequency of an air conditioner is reduced, so that energy consumption is remarkably reduced. Meanwhile, by adding heat insulation type inorganic filler (such as hollow glass beads, silicon dioxide aerogel and the like), the heat conductivity of the coating is reduced, the loss of heat in a building is reduced, and the heating energy consumption in winter is reduced. Due to the dual functions, the coating can achieve an energy-saving effect throughout the year, and the environment-friendly concept of energy conservation and carbon reduction is met.

The invention provides a rubber emulsion blocking agent as well as a preparation method and application thereof. The rubber emulsion plugging agent is prepared from the following raw materials: rubber, white oil, a cross-linking agent, an emulsifying agent, a dispersing agent and water.

The invention discloses a mildewproof and anticorrosive waterborne epoxy floor paint and a preparation method thereof, and belongs to the technical field of waterborne paints.The mildewproof and anticorrosive waterborne epoxy floor paint is prepared from, by mass, 45.5%-52.0% of modified waterborne epoxy emulsion, 0.5%-1.5% of a curing agent, 0.5%-1.5% of a curing agent and the balance water. 18.5%-20.0% of a water-based epoxy curing agent; 7.5%-8.5% of a mildew-proof microcapsule; 3.5% to 5.0% of silica powder; 2.5%-3.0% of nano zinc oxide; 0.3%-0.5% of a dispersing agent; 0.1%-0.3% of a defoaming agent; and the balance of deionized water. Aiming at the three technical problems of poor mildew preventive compatibility, insufficient long-term effect and reduced coating mechanical property of the existing water-based epoxy floor paint, the invention provides the water-based epoxy floor paint with long-term mildew and corrosion resistance, high mechanical property and environmental friendliness through material design and process improvement.

The invention discloses a preparation method of a lignin-based aqueous polyurethane emulsion. The raw materials of the lignin-based aqueous polyurethane emulsion include lignin, oligomeric polyols, polyisocyanates, hydrophilic chain extenders, polyol compounds, organic solvents, etc. In order to solve the disadvantages of traditional aqueous polyurethanes such as poor mechanical properties, poor water resistance, and poor anti-aging ability, the invention compositely blends a certain amount of lignin with polyols, and controls the prepolymerization time through process optimization, so that lignin reacts with isocyanate to form a certain cross-linked structure, greatly improving the mechanical properties and water resistance of the aqueous polyurethane on the premise of ensuring the stability of the emulsion; the invention not only prepares a novel lignin-based aqueous polyurethane emulsion with functional characteristics such as stability, low cost, environmental friendliness, high mechanics, anti-ultraviolet, antibacterial, and hydrophobicity, but also realizes the high-value utilization of lignin as a renewable resource.

The invention relates to the technical field of wax emulsions for yarn weaving, in particular to a wax emulsion which has spinnability, hand feeling and stability and is free of layer difference and a preparation method and application of the wax emulsion. The wax emulsion comprises a component A and a component B, wherein the component A is selected from two or more of oxidized modified polyethylene wax, fatty alcohol-polyoxyethylene ether and paraffin; the component B is prepared from the following components in percentage by weight: 2.5 to 5 percent of a cationic surfactant, 2.5 to 5 percent of a nonionic surfactant, 0.1 to 0.5 percent of an antibacterial agent, 0.5 to 1 percent of a pH regulator and the balance of water. The wax emulsion provided by the invention has excellent lubricating effect, softening effect and permeation effect, has no middle-outer layer difference and excellent stability, and does not influence the color light and fastness of a dyed fabric.

The invention discloses water-based high-barrier ink and a preparation method thereof, and relates to the technical field of ink. The water-based high-barrier printing ink is prepared from the following components: polyvinyl alcohol emulsion, acrylic resin emulsion, a nano composite material, a bio-based plasticizer, a dispersing agent, a wetting agent, a defoaming agent, a flatting agent and water. The preparation method comprises the following steps: preparation of a polyvinyl alcohol emulsion: dissolving polyvinyl alcohol in water, and adjusting the pH value to 2-4; adding a cross-linking agent for complete reaction; adding an emulsifier, stirring and emulsifying to obtain a polyvinyl alcohol emulsion; the raw materials are mixed and react according to the component proportion of the water-based high-barrier ink to obtain the water-based high-barrier ink. The high-barrier-property environment-friendly packaging film has high barrier property and excellent printability, meanwhile, the environment-friendly property is achieved to the maximum extent, and the high-barrier-property environment-friendly packaging film has the additional advantages of being good in flexibility, stability and the like and meets the urgent requirements of the high-end and environment-friendly packaging market.