1667 results about "Fly ash" patented technology

The invention discloses a fiber foamed concrete and a preparation method thereof. The fiber foamed concrete comprises the following raw materials in parts by weight: 5290 parts of cement, 4965 parts of water, 1.361 part of foaming solution, 1.2964 part of fly ash and 10 parts of fiber. The preparation method comprises the following steps: proportionally weighing the components; sequentially adding the cement and fly ash into a stirrer, proportionally weighing the water, uniformly stirring the mixture by the stirrer, and adding the fiber; preparing and adding the foaming solution; gradually adding the foam into the mixture, and continuously stirring until all the components are uniformly mixed; pouring the mixture into a mold on which lubricating oil is brushed, and curing in a curing chamber; after 24 hours, removing the mold; and respectively curing for 3 days, 7 days and 28 days for experimental detection. The fiber foamed concrete has the advantages of favorable thermal insulation property, favorable compression resistance and favorable bending resistance, and is applicable to a railway bed strengthening layer.

The invention discloses a cementing material for a solid waste-based road of a coal-fired power plant and a preparation method of the cementing material. The cementing material mainly comprises a cementing component, an alkali-activated component and a reinforcing component, the gelling component is a mixture of coal-fired power plant fly ash and furnace slag; the alkali-activated component is a mixture of alkali residues, red mud, blast furnace slag and coal-fired power plant desulfurized gypsum; the reinforcing component is rice hull ash or peanut hull ash. The mass ratio of the gelling component to the alkali-activated component is (4 / 1)-(10 / 1); and the addition amount of the reinforcing component is 1-3% of that of the main body material. The coal-fired power plant solid waste fly ash, the furnace slag and the desulfurized gypsum are used as main bodies, a small amount of other industrial solid waste is added, and the cementing material belongs to a full-solid-waste low-carbon cementing material and can be applied to a road base, a subbase or a base layer. The invention has the characteristics of low carbon emission, high solid waste consumption, simple production process and strong pavement performance, and in addition, the invention has a good stabilization effect on the problem that part of solid waste heavy metals and sulfate ions in a coal-fired power plant exceed the standard.

The invention discloses a high-content steel slag-based functionalized nano-composite cementing material and a preparation method thereof, and belongs to the technical field of solid waste resource comprehensive utilization. The nano composite cementing material is prepared from the following raw materials in parts by mass: 50 to 65 parts of steel slag, 10 to 20 parts of fly ash, 10 to 25 parts of carbide slag, 8 to 15 parts of desulfurized gypsum, 0.3 to 1.0 part of nano silicon dioxide and 0.003 to 0.03 part of silane coupling agent. On the basis of a solid waste synergism theory and an internal alkali excitation effect, quaternary solid wastes such as steel slag and fly ash are optimized and compounded by adopting methods of mechanical-thermal activation, addition of modified nano silicon dioxide, synergistic gelling between solid wastes and the like; the paint is prepared through gradient grinding and a medium-temperature wet curing process. The preparation method is simple, high-temperature calcination is not needed, cement clinker and exogenous excitant do not need to be added, the obtained cementing material can replace part of cement to be applied to the fields of road bases, mine filling, low-carbon building material products and the like, resource utilization and high-value utilization of regional bulk industrial solid waste can be achieved, and carbon emission and production cost are effectively reduced.

The invention provides a fly ash composite material goaf filling body interface quality intelligent evaluation method, and belongs to the technical field of mining engineering and artificial intelligence detection crossing. The method comprises the steps that firstly, filling body interface quality characteristic data are collected and comprise interface sound wave signals, stress strain, coal ash composite material physical parameters and environment working condition data; secondly, constructing a multi-physical field data completion model, performing unsupervised learning on the acquired sound wave, stress, temperature and moisture content data, and generating completion data of global spatial distribution; secondly, constructing a multi-field fusion interface quality index prediction model, and inputting multi-source data into the model to obtain an interface quality index; and finally, combining the quality index to realize interface defect mode classification and grade evaluation, and generating a targeted maintenance strategy. The invention provides an intelligent evaluation method which fuses multi-source data and gives consideration to real-time performance and comprehensiveness, so as to solve the industrial pain points of interface quality evaluation lag, low precision, large destructiveness and the like.

The invention discloses a preparation method of a green high-performance industrial solid waste-based grouting material, and belongs to the field of industrial solid waste treatment and grouting reinforcement, and the preparation method comprises the following steps: performing dry mixing on red mud, slag, fly ash and cement which are dried and ground to specified fineness according to a preset proportion to obtain a uniform dry material; preparing a composite alkali activator from water glass and sodium hydroxide according to a molar ratio of 3: 1, premixing the composite alkali activator with water, and adding the dry material in batches to form wet slurry; and carrying out high-speed shearing and stirring on the wet slurry, and standing and curing to obtain the solid waste-based slurry which can be directly used for grouting. The method obviously improves the solid waste utilization rate, relieves the environmental pressure, and is suitable for related projects such as stratum settlement control, gushing water blocking, mine roadway broken rock mass supporting and underground cavity concrete lining crack repairing in tunnel and subway projects.

The invention provides a coal ash composite material goaf closed filling parameter intelligent matching method, and belongs to the technical field of deep learning and mining engineering crossing. According to the method, dynamic optimization and accurate matching of the filling parameters are realized through combination of data driving and an intelligent algorithm. The method comprises four core links: multi-source data perception and fusion, a material performance prediction model, key parameter identification and boundary constraint, and intelligent matching and optimization decision. According to the method, the modeling capability of the model for the complex coupling relationship is improved through the attention mechanism and the feature cross network; the performance evolution trend of the material under different proportions and process conditions is accurately predicted, key regulation and control parameters are automatically identified, and efficient search and optimal matching of a parameter space are achieved through a strategy gradient method. According to the method, multi-source data can be fused, key parameters can be dynamically identified, and the intelligent matching and optimizing capability is achieved.

The invention discloses a high-content fly ash unfired water permeable brick and a preparation method thereof, and relates to the technical field of building materials, the unfired water permeable brick comprises the following raw materials by weight: 55-75 parts of fly ash, 20-35 parts of aggregate, 8-15 parts of a composite cementing material, 0.5-2 parts of toughening fiber, 1-3 parts of a pore regulator, 0.1-0.5 part of a surfactant, and 10-18 parts of water. Wherein the aggregate is 1-3mm waste ceramic particles and 2-5mm building recycled aggregate (1: 1-1: 2); and the rest components have specific proportions, specifications and modification requirements. According to the invention, 55-75 parts of F-type II-grade or higher high-content fly ash is matched with the waste ceramic particles and the pretreated building recycled aggregate to serve as the composite aggregate, solid waste is digested, natural resource dependence is reduced, and the method conforms to the direction of green building materials; by means of a modified composite fiber and composite gel system, the pressure resistance is larger than or equal to 25 MPa, the fracture resistance is larger than or equal to 3.5 MPa, the water permeability is larger than or equal to 1.5 * 10 cm / s, the freeze-thaw loss is smaller than or equal to 3.5%, and the grinding pit is smaller than or equal to 30 mm; through graded mixing, bidirectional pressurization and segmented maintenance, the porosity is kept to be 15%-25%, the percent of pass is increased, and the cost is reduced.

The invention discloses a red-mud-based multi-element solid waste cementing material as well as a preparation method and application thereof, and belongs to the technical field of building materials. The red-mud-based multi-element solid waste cementing material comprises the following components in parts by mass: 30-40 parts of red mud, 5-15 parts of fly ash, 10-20 parts of superfine slag powder, 30 parts of Portland cement, 4 parts of dihydrate gypsum and 2-25 parts of an alkali activator, alkaline components of the red mud are utilized to excite potential activity of the superfine slag powder and the fly ash, the additional alkaline activator excites potential activity in the red mud, and meanwhile, several industrial solid wastes and the Portland cement generate gel substances such as hydrated aluminosilicate under the synergistic effect, so that the mechanical property of the cement is improved; the building material meeting the strength requirement is provided while a large amount of red mud is consumed.

The invention discloses a fly ash dioxin separation method, fly ash dioxin separation equipment, a fly ash treatment method and a fly ash treatment system, and solves the technical problems of high energy consumption, high cost and lack of efficient and low-energy-consumption dioxin dissociation and enrichment separation means in a fly ash treatment process in the prior art. Comprising the following steps: mixing fly ash with water to prepare fly ash slurry; the method comprises the following steps: adding an oxidizing agent into fly ash slurry to carry out oxidation reaction so as to carry out oxidation treatment on reducing substances on the surface of the fly ash, adding acid into the fly ash slurry subjected to oxidation treatment to carry out modification reaction so as to etch the fly ash by using the acid to dissociate dioxin particles from the surface of the fly ash and show hydrophobicity; or adding acid into the fly ash slurry to carry out modification reaction, and controlling the pH value of the fly ash slurry after the modification reaction to be 6-12.5; bubbles are generated or introduced into the fly ash slurry after the modification reaction, the dioxin particles are captured by the bubbles and float upwards to form scum, so that the scum is separated from mother liquor, and detoxified slurry is obtained.

The invention relates to the technical field of solid waste treatment, in particular to a cementing material as well as a preparation method and application thereof. The invention provides a preparation method of a cementing material, which comprises the following steps: S1, adding water into waste incineration fly ash, electrolytic manganese residue and carbide slag, and carrying out mechanical activation to obtain mixed slurry; s2, after the mixed slurry is subjected to pouring forming, curing is conducted, and a cementing material is obtained; the doping amount of the carbide slag accounts for 5-10 wt% of the total mass of the waste incineration fly ash, the electrolytic manganese slag and the carbide slag solid. According to the method, the waste incineration fly ash, the electrolytic manganese residues and the carbide slag are subjected to mechanical activation and synergistic treatment, self-cementation solidification is achieved in an alkaline environment provided by the carbide slag by utilizing the complementary effect of potential gelation activity of aluminosilicate in the electrolytic manganese residues and calcium-rich substances in the waste incineration fly ash, traditional excitants such as cement and lime do not need to be additionally added, and the cost is reduced. The dependence on additional raw materials is obviously reduced, and an effective solution is provided for recycling of a large amount of solid wastes.

The invention discloses a treatment system and method for waste incineration fly ash washing liquid cooperating with flue gas purification, and the system comprises a semi-dry desulfurization tower, a dust remover, an ash silo, a washing tank, a buffer tank, a water supply preheater and a wet washing tower which are connected with a main flue of an incineration plant, the method comprises the following steps: transferring waste incineration fly ash collected in the system into the water washing tank, and adding water for washing to obtain water washing liquid and desalted fly ash; the method comprises the following steps: spraying fly ash water washing liquid by using a wet washing tower, recovering tail flue gas waste heat, deeply removing residual acid gas in flue gas, concentrating and reducing the water washing liquid, and controlling the spraying amount to adjust the concentration ratio so as to realize the separation and solid-liquid separation of chlorine salt; introducing the concentrated water washing liquid into a semi-dry desulfurization tower, atomizing the water washing liquid into fine liquid drops by using a rotary atomizer, contacting the fine liquid drops with hot flue gas, evaporating the fine liquid drops to dryness, and absorbing acid gas in the flue gas at the same time, thereby realizing zero emission of the water washing liquid and cooperating with flue gas purification. According to the invention, the problem of high energy consumption of fly ash washing liquid treatment is solved, and the resource utilization rate of the washing liquid is improved.

Ultrafast flash evaporation joule heating synthesis methods and systems, more particularly, ultrafast synthesis methods for recovering metals from ores, fly ash, and bauxite residue (red mud).

The invention discloses an efficient lithium slag solidification and stabilization agent and a preparation method thereof. The efficient lithium slag solidification and stabilization agent comprises the following raw materials in parts by weight: 20-50 parts of lithium slag, 5-10 parts of carbide slag, 8-12 parts of nano silicate, 6-12 parts of slag powder, 3-6 parts of hydroxyapatite, 2-5 parts of bentonite, 4-8 parts of fly ash and 1-3 parts of aluminum sulfate. The method disclosed by the invention has the advantage of environmental protection, and solves the problems that when the existing lithium slag is recycled, the lithium slag is inconvenient to solidify and stabilize, the lithium slag often contains heavy metals, and if the lithium slag is not fixed in a lattice structure through solidification and stabilization technologies, the heavy metals can be leached along with rainwater to enter soil and water, and long-term ecological pollution is caused.

The invention discloses an inorganic normal-temperature rapid-hardening coal-rock mass reinforcing and filling material, and relates to the technical field of mine reinforcement. The material comprises a liquid A and a liquid B, the liquid A is prepared from cement, fly ash, magnetic nano silicon dioxide, citric acid and a layered bimetal oxide-sodium hexametaphosphate compound; and the liquid B comprises water glass, superfine limestone and water. During use, the liquid A and the liquid B are mixed according to the volume ratio of 1: 1 and injected into a target area, and a 1.5 Tesla magnetic field is applied at the initial stage of grouting until the grout is initially set. Through the synergistic effect of the compound protection dispersing agent, the magnetic particles and an external magnetic field, the technical problems that an existing material is unstable in performance due to temperature change, nanoparticles are prone to agglomeration, and magnetic response is attenuated in an alkaline environment are effectively solved; the technical effects of rapid solidification, high strength and excellent durability in high-temperature, low-temperature and complex mine environments are achieved.

The invention discloses a preparation method and application of a wind cap of a circulating fluidized bed gasifier, the wind cap is arranged at the bottom of a gasifier body, the wind cap mainly comprises a wind cap gas inlet, a wind cap gas outlet and a wind cap gas flow channel, and the wind cap gas flow channel is composed of a Tesla valve fluid channel. The air cap is prepared from modified fly ash through a combined method of freezing ball-milling nano modification, 3D printing coupling microwave-assisted sintering and salt bath chromizing strengthening. According to the method, a large amount of solid waste of fly ash can be consumed to realize carbon emission reduction, the efficiency of the circulating fluidized bed can be improved through structural optimization, meanwhile, the preparation cost of the hood can be reduced, and the method has relatively high application and popularization values.

The invention discloses a fracturing proppant using coal gangue and fly ash and a preparation process thereof, and relates to the field of fracturing proppants, the fracturing proppant comprises coal gangue, fly ash, silica fume, nanometer alumina, a composite pore-forming agent and a fluxing agent, and the preparation process comprises raw material pretreatment, mixing granulation, microwave-gradient sintering and post-treatment. The raw material pretreatment comprises the following steps: removing iron and impurities through carbon thermal reduction-magnetic separation; the composite pore-forming agent is enriched on the surface of the green body during mixed granulation; the microwave-gradient sintering is used for cooperatively regulating and controlling growth of mullite crystals through microwave preheating and resistance heating to form an internal acicular mullite interlaced structure and a surface micro-convex structure; a finished product is obtained through post-treatment grading and surface cleaning. Resource utilization of industrial solid waste is achieved, the strength and flow conductivity of the proppant are improved through raw material synergy, crystal structure regulation and control and surface microstructure design, preparation energy consumption is reduced, and the proppant is suitable for oil and gas field fracturing engineering.

The invention discloses an intelligent dynamic regulation and control method for compaction quality of a high-liquid-limit fly ash roadbed, which comprises the following steps of: establishing a mapping relation among high-spectral characteristics of high-liquid-limit fly ash, a specific surface area index, a total hydroxyl content and a water content through a first neural network model, and establishing an optimal water content prediction model through a second neural network model; the third to fifth neural network models construct the correlation of the compactness, the dielectric constant, the rigidity and the water content; two-stage water content regulation and control of a storage yard and a paving layer are realized through hyperspectral imaging of an optical fiber probe and an unmanned aerial vehicle, and pre-humidification and secondary precise regulation and control are performed in combination with an intelligent spraying system; in the compaction stage, data are collected in real time through a multi-frequency ground penetrating radar and a vibration sensor, compaction degree distribution is inverted, layered evaluation is conducted, and rolling parameters are dynamically adjusted. According to the invention, a hyperspectral technology, multi-source sensing and deep learning are fused, intelligent management of compaction quality is realized, and construction uniformity and quality stability of the fly ash roadbed are significantly improved.

The invention discloses a composite mineral admixture prepared from heat-stewed steel slag and a preparation method of the composite mineral admixture, and the mineral admixture is prepared from the following raw materials in parts by weight: 40-50 parts of heat-stewed steel slag powder, 20-30 parts of granulated blast furnace slag powder, 20-40 parts of fly ash, 0.01-0.1 part of a grinding aid and 0.5-4.0 parts of an exciting agent, wherein the grinding aid comprises glycerol and diethanol isopropanolamine, and the exciting agent comprises diphenyl phosphate, sodium sulfate and ammonium bicarbonate. The preparation method comprises the following steps: mixing calcium bicarbonate and water, spraying the mixture on high-temperature steel slag at 600-800 DEG C, carrying out hot braising under the condition of steam pressure of 0.2-0.5 MPa for 8-12 hours to pulverize the steel slag until the particle size is less than 5-10 mm, and carrying out vertical milling on the pulverized steel slag and a grinding aid for 20-40 minutes to obtain hot-braised steel slag powder; uniformly mixing the heat-stewed steel slag powder, granulated blast-furnace slag powder, fly ash, a grinding aid and an exciting agent in proportion to obtain mixed powder; and finally, grinding the mixed powder for 30-50 minutes by adopting a high-energy planetary ball mill to obtain the cement concrete composite mineral admixture with the specific surface area being greater than or equal to 600m < 2 > / kg. According to the invention, the potential hazard of poor stability of a cement concrete material caused by high f-MgO content in the steel slag is broken through, the steel slag is efficiently utilized to prepare a low-carbon green building material, a composite mineral admixture is developed, and the performance meets the II type requirement in JG / T 486-2015 Composite Admixture for Concrete.

The invention relates to a waste incineration fly ash artificial aggregate and a preparation method thereof. The method comprises the following steps: uniformly mixing the waste incineration fly ash, cement and fly ash, then adding water, and uniformly stirring to obtain an aggregate mixture; placing the aggregate mixture in a mold for compression molding to obtain a molded product; the compression molding comprises the following steps: pre-pressing for 10-20 seconds at 6-10 MPa, then pressing for 20-40 seconds at a medium pressure of 12-18 MPa, then uniformly increasing the pressure to a high pressure of 22-28 MPa, and maintaining the pressure for 4-6 seconds at the high pressure of 22-28 MPa; and performing standard curing on the molded product, demolding to obtain a demolded sample, and sequentially performing crushing treatment and steam curing to obtain the waste incineration fly ash artificial aggregate. The prepared waste incineration fly ash artificial aggregate is low in crushing value, low in water absorption rate, high in strength and high in heavy metal curing capacity, a feasible path is provided for resource utilization of waste incineration fly ash, and the waste incineration fly ash artificial aggregate has important environmental protection value and economic value.

The invention discloses industrial solid waste treatment and resource utilization, and particularly relates to a washing-free sintering resource treatment method for household garbage incineration fly ash. Fly ash which is not washed with water, a silicon-aluminum hardening and tempering agent and solid fuel are mixed according to a specific proportion, granulated and sintered, and dioxin control and heavy metal directional migration are achieved through the temperature gradient of a material layer. According to the invention, low-temperature (1t, 150 DEG C) and low-pollution flue gas is shunted for common purification according to the temperature and component difference of flue gas at each sintering section, and dust (product dust) is returned for utilization; high-temperature (more than or equal to 150 DEG C) and high-pollution flue gas is divided for quenching and activated carbon deep purification, and dust (heavy metal concentrated ash) of the flue gas is sold for metallurgy. According to the invention, the fly ash washing link is thoroughly omitted, and the consumption of the adsorbent and the operation cost are greatly reduced while ultra-low emission is ensured through a flue gas quality-dividing and flow-dividing technology, so that low-cost, thorough harmlessness and high-value recycling of the fly ash are realized.

The utility model discloses a high-quality fly ash efficient winnowing device which comprises a winnowing box, an air inlet is formed in one end of the winnowing box, two sets of angle-adjustable baffles are arranged in an inner cavity of the winnowing box in the air inlet direction, each set of baffles is movably connected with a set of first collecting pieces, and the heights of the two sets of baffles are gradually increased. The angle-adjustable baffle can be flexibly matched with pulverized coal with different sources and different particle distributions, particles with different particle sizes can be effectively separated by adjusting the angle of the baffle when the particle size distribution of the pulverized coal particles changes, the winnowing efficiency is greatly improved, and the winnowing efficiency is improved. By accurately controlling the angle of the baffle, the winnowing process can be more stable, it is guaranteed that the quality of collected fly ash is uniform, the production requirement of high-quality fly ash is met, and meanwhile the adaptability of the winnowing device to different wind forces is enhanced.

The invention relates to the cross technical field of industrial solid waste resource utilization and environmental pollution abatement, and discloses a modified fly ash environmental remediation material as well as a preparation method and application thereof. According to the material, industrial solid waste fly ash is used as a raw material, a glass body structure is destroyed through physical or chemical modification treatment, the specific surface area is increased, active functional groups such as surface hydroxyl groups are enriched, and the adsorption and fixation capacity on heavy metal lead (Pb < 2 + >) and cadmium (Cd < 2 + >) is remarkably improved. The chemical modification adopts an acid solution or an alkali solution, and the preparation method comprises the steps of raw material pretreatment, modification reaction, solid-liquid separation and washing, and drying and screening. When the material is applied to heavy metal contaminated soil remediation, heavy metal in an ion exchange state is promoted to be converted into a stable residue state, the bioavailability and the leaching risk of the heavy metal are remarkably reduced, meanwhile, high-added-value resource utilization of the fly ash is achieved, and the material has environmental, economic and social benefits and is suitable for large-scale remediation of Pb and Cd single or combined contaminated soil.

The invention discloses an efficient consolidation agent for tailings in an underground mine filling mining method and a preparation method thereof, and relates to the technical field of consolidation agents, the consolidation agent is prepared from a gelling base material, a nano reinforcing agent, a chemical exciting agent and an organic fiber reinforcing agent according to a specific mass ratio; aiming at the problems of unstable volume, insufficient strength and the like of a traditional consolidation agent, through high-temperature calcination of the steel slag to eliminate harmful components, dealkalization treatment of the red mud, acid activation of the phosphogypsum and volcanic ash reaction of the fly ash, the volume stability and the gelling activity of a filling body are remarkably improved, and the consolidation agent is suitable for complex underground environment requirements; aiming at the pain points of low early strength, weak interface bonding and the like of the consolidation agent, the cohesion is improved by strong bonding of the surface-modified nano SiO2 and a gelling base material, a chemical exciting agent is added to cooperate with CO2 carbonization to generate nano crystal nucleuses, hydration sites are provided, a pore structure is optimized, bleeding is inhibited, the fluidity and stability of slurry can be effectively improved, and the consolidation effect is good. And the requirements of underground filling homogeneity and pumpability are met.

The invention discloses a coal-fired boiler combustion optimization method, system and equipment based on machine learning and a medium, and belongs to the technical field of boiler operation optimizing.The method comprises the steps that operation parameter data and generated fly ash carbon content data are collected; constructing a machine learning model, and performing primary training on the machine learning model; the number of operation parameter data is reduced, secondary training is performed on the machine learning model, and the optimal parameter number is determined according to the fitting effect; screening the operation parameter data, and reserving the operation parameter data of which the quantity accords with the optimal parameter quantity; the method comprises the following steps: constructing a fly ash carbon content prediction model, optimizing an extreme value of the fly ash carbon content prediction model through an optimization algorithm, and determining an optimal boiler combustion operation parameter, and solves the problems that the actual measurement workload is large and the lowest fly ash carbon content cannot be obtained by only depending on a thermal-state multi-working-condition test and easily deviating from the optimal working condition; the existing prediction method has the problems that a local optimal solution is easy to generate and the generalization ability of a model is low.

The application discloses a nodular cast iron pipe with a composite coating and belongs to the technical field of metal corrosion prevention, comprising a nodular cast iron pipe base body, a composite outer coating coated on the outer surface of the nodular cast iron pipe base body and an inner coating closely attached to the inner surface of the nodular cast iron pipe base body, characterized in that the composite outer coating comprises an alkali-activated gel layer and a zinc-based coating, the zinc-based coating is arranged between the outer surface of the nodular cast iron pipe base body and the alkali-activated gel layer, the alkali-activated gel layer is an alkali-activated slag fly ash corrosion-resistant gel material, and the zinc-based coating is one or more of a pure zinc coating, a zinc-aluminum alloy coating or a zinc-rich coating layer. The alkali-activated gel layer provided by the application is coated on the inner or outer surface of the pipe and provides further corrosion protection for the nodular cast iron pipe, so that the pipe can be used in extremely harsh construction environments, and has extremely strong weather resistance in acidic soil and overhead fields.

The invention discloses an efficient pollution-free treatment method for municipal waste incineration fly ash, and relates to the technical field of waste resource utilization and environmental protection. Comprising the following steps: S1, adding the garbage fly ash into a hydrochloric acid solution, carrying out wet grinding, and carrying out centrifugal separation to obtain heavy metal filtrate and heavy metal-removed fly ash; washing the heavy metal-removed fly ash with clear water to obtain a washing solution; mixing the washing liquid with the heavy metal filtrate to obtain a heavy metal solution; s2, adding a complexing agent into the heavy metal solution, stirring and mixing, standing overnight, performing centrifugal separation to obtain a heavy metal removal solution and a heavy metal complex, and adjusting the pH value of the heavy metal removal solution to be neutral to complete heavy metal removal treatment; s3, uniformly mixing the washed heavy metal-removed fly ash and a catalyst, performing low-temperature pyrolysis treatment, sieving and separating to obtain dioxin-removed fly ash, and completing dioxin removal treatment; and S4, the heavy metal removal solution and the heavy metal complex are treated, and garbage fly ash treatment is completed.

The invention belongs to the technical field of refractory materials, and particularly relates to a mullite refractory material with high mechanical property and a preparation method thereof. The mullite refractory material is prepared by taking coal gangue, bauxite and fly ash as raw materials, and the three industrial solid wastes are converted into the refractory material with high additional value, so that the concept of circular economy is met. According to the invention, coal gangue, bauxite and fly ash are used as raw materials, CaF2, V2O5 and lanthanide rare earth oxide are used as sintering aids, the problems of insufficient mechanical properties and overhigh sintering temperature of the mullite refractory material prepared by purely using coal gangue, bauxite and fly ash as raw materials are solved, and the performance of the mullite refractory material can be greatly improved. CaF2 and V2O5 promote substance transport and grain growth, and rare earth oxide inhibits excessive growth of grains. The balance of'promotion 'and'inhibition' is favorable for forming a compact, fine, uniform and interlaced mullite crystal network, and meanwhile, the mullite crystal network has high strength and good toughness.

This invention relates to a detoxification method for simultaneously removing dioxins and heavy metals from waste incineration fly ash. The method includes fly ash pretreatment and simultaneous removal of dioxins and heavy metals. First, sodium and potassium salts are removed from the fly ash by immersion washing to avoid reducing the ability of the sintered products formed during high-temperature sintering to solidify heavy metals. Then, the pretreated fly ash is separated to obtain a solid phase, which is mixed with magnesium and / or calcium salts and subjected to high-temperature roasting. This allows the chlorine from the decomposition of dioxins in the fly ash to react with the heavy metals to form gaseous heavy metal chlorides, thus removing the heavy metals from the fly ash. During the high-temperature roasting process, the magnesium and / or calcium salts react with the ash in the fly ash to form calcium silicate and / or magnesium silicate, enhancing the solidification ability of the internal lattice of the fly ash sintered products. After detoxification treatment of waste incineration fly ash using this method, no heavy metals Hg, Pb, Cd, Cu, and Ni were detected in the fly ash leachate, significantly reducing the leaching risk of residual heavy metals in the fly ash.

The invention belongs to the technical field of boiler waste heat, gas and pressure utilization, and particularly relates to a lifting type intelligent soot blowing system and method for low-temperature area deposited soot, and the soot blowing system comprises a primary air pressurization soot blowing system, a vertical guide rail advancing soot blower and an intelligent control module. And the intelligent control module uses a blockage prediction intelligent algorithm and a dynamic soot blowing strategy. The primary air pressurization soot blowing system leads out part of dust-free primary air from an outlet of a boiler air pre-heater to serve as soot blowing primary air, and the dust-free primary air is conveyed to a lifting soot blower driven by a vertical guide rail after being pressurized to 0.5-0.8 MPa. The primary air pressurization soot blowing system is deeply coupled with the low-temperature economizer warm flue gas system, primary air is used as a soot blowing medium, the temperature of the soot blowing medium is about 320-350 DEG C, ammonium bisulfate condensate can be effectively dried and removed, and fly ash adhesion is reduced; and the soot blowing coverage rate reaches 100%, soot blowing according to needs is achieved, and the operation stability and economical efficiency of the unit are remarkably improved.

The invention belongs to the technical field of rock core cutting, and particularly relates to a solid mineral exploration rock core automatic cutting device which comprises a box body, and a fixing frame is fixed to the upper portion of the box body; the fixing assembly is used for fixing a rock core, the fixing assembly comprises a mounting plate arranged in the box body, a pair of U-shaped frames are arranged on the mounting plate, a supporting rod is arranged in the middle of each U-shaped frame, the two ends of each supporting rod are fixedly connected with the side wall of the corresponding U-shaped frame through connecting rods, and pressing rods are slidably arranged on the connecting rods on the two sides respectively; the hydraulic cylinder is arranged below the mounting plate and used for controlling the mounting plate to ascend or descend; the hydraulic cylinder is arranged to sink a rock core into water before cutting and after cutting, on one hand, floating dust on the surface of the rock core can be removed before cutting, and fly ash generated in the cutting process is reduced; on the other hand, mud attached to the fixing assembly and the rock core in the cutting process can be effectively removed, and the cleaning effect is improved.