209results about "Silicon oxides" patented technology

The invention provides a silicon-based material and a preparation method thereof, a negative pole piece and a solid-state battery. The silicon-based material comprises an inner core and a surface coating layer, the inner core comprises a silicon-based negative electrode material, the surface coating layer is a carbon fluoride layer, the carbon fluoride layer internally comprises Li-M, LiF and LiX, M represents a metal element and is selected from at least one of Ag, Mg, Zn and Al, and X represents a non-metal element and is selected from at least one of N, S and P. The silicon-based negative electrode material is used as a core, the surface of the silicon-based negative electrode material is coated with the carbon fluoride layer, and the Li-M alloy / LiF / LiX composite lithium compound is introduced into the carbon fluoride layer, so that triple effects of ion-electron double-conduction network construction, interface chemical stabilization and mechanical buffer enhancement are achieved; and the chemical stability of an interface between the silicon negative electrode and sulfide solid electrolyte is improved while the rate capability of the negative electrode is improved and the expansion and shrinkage of the silicon negative electrode are relieved, and the cycling stability is improved.

The invention provides a silicon-based material and a preparation method thereof, a lithium ion battery monomer, a battery device and a power utilization device, the silicon-based material comprises a porous carbon matrix and silicon nanoparticles located in pores of the porous carbon matrix, the surface of each silicon nanoparticle is provided with a silicon oxide passivation layer formed through a passivation reaction, the ratio of the ID / IG of the silicon-based material to the ID / IG of the porous carbon matrix before the passivation reaction is (0.95-1.05): 1; the mass multiple of the Si element and the C element in the silicon-based material is recorded as A, the mass multiple of the Si element and the C element before the passivation reaction is recorded as B, and the ratio of A to B is (0.95-1.05): 1. According to the invention, the thermal safety performance, the cycle performance and the rate capability of the lithium ion battery monomer can be improved.

The invention provides a negative electrode active material and a preparation method and application thereof, the negative electrode active material comprises a modified carbon-coated silicon negative electrode material and a modified carbon nanotube, and the modified carbon-coated silicon negative electrode material comprises a carbon-coated silicon negative electrode material and heteroatoms; the carbon-coated silicon negative electrode material comprises a silicon material and a carbon layer coated on the outer surface of the silicon material, heteroatoms are arranged inside or / and on the surface of the carbon layer, and the heteroatoms comprise at least one of O, N and F elements; the modified carbon nanotube is wound on the surface of the modified carbon-coated silicon negative electrode material, the modified carbon nanotube comprises a carbon nanotube and a first oxygen-containing functional group, the first oxygen-containing functional group is arranged on the end surface or / and the defect position of the carbon nanotube, and the first oxygen-containing functional group is connected with the carbon layer through a hydrogen bond. According to the negative electrode active material, the heteroatoms and the first oxygen-containing functional group are introduced, so that the conductivity of the negative electrode active material can be improved, and the expansion of the silicon material in the charging and discharging process is inhibited.

The invention provides a mesoporous silicate molecular sieve as well as a preparation method and application thereof, and belongs to the technical field of molecular sieves. The framework component of the mesoporous silicate molecular sieve provided by the invention is only silica, 14 kinds of topology independent atoms are contained in the framework, a 36-membered ring one-dimensional mesoporous channel system is contained in the crystal structure of the mesoporous silicate molecular sieve, and the material is good in thermal stability and can be applied as a catalyst or an adsorbent.

The invention relates to the technical field of lithium battery material production, in particular to a lithium ion battery silicon-oxygen negative electrode material preparation system and method.The lithium ion battery silicon-oxygen negative electrode material preparation system comprises a transversely-arranged furnace body, the furnace body is internally provided with a preheating area and a high-temperature area, and the lithium ion battery silicon-oxygen negative electrode material preparation system further comprises a two-way conveying part, a driving assembly and a gas guide assembly; the driving assembly is arranged on the furnace body and connected with the two-way conveying piece. Through the arrangement of the two-way conveying part, the driving assembly and the air guide assembly, carrier particles can be preheated before entering a high-temperature area, and the situation that tiny cracks are generated due to the fact that thermal stress on the surfaces of the carrier particles is too large due to sudden temperature difference when the carrier particles enter the high-temperature area is avoided; and meanwhile, the carrier particles can be continuously subjected to'climbing-sliding-re-climbing 'movement in the rotating process of the two-way conveying part, so that full contact between the carrier particles and the reaction gas is ensured, and dual guarantee on the endurance performance of the lithium battery is realized.

An electrode for a lithium metal battery according to an embodiment of the present invention comprises a lithium metal storage layer containing silicon oxide particles. The silicon oxide particles have a porous structure, and the molar ratio of oxygen to silicon contained in the silicon oxide particles is 1.5 or more and less than 2.0. A lithium metal battery according to an embodiment of the present invention includes an electrode for a lithium metal battery according to the above embodiment.

The present application relates to the technical field of copper clad laminates, and discloses a copper clad laminate, a resin composition for the copper clad laminate, and spherical silicon and a preparation method therefor. The spherical silicon of the present application is composed of spherical silicon dioxide and zinc molybdate particles dispersedly grown on the surface of the spherical silicon dioxide in situ and has a diameter of less than 10 microns and a D50 of 0.6-6 microns. The content of zinc molybdate per unit area on the surface of the spherical silicon dioxide is 0.03-1 g / m2, and the size of the zinc molybdate particles is less than or equal to 400 nm. The preparation method comprises: enabling spherical silicon dioxide to come into contact with / be mixed with a soluble molybdate and a zinc salt in an aqueous reaction system; and reacting the soluble molybdate with the zinc salt in situ on the surface of the spherical silicon dioxide, so as to form spherical silicon chemically coated with zinc molybdate particles. In the present application, by directly synthesizing the zinc molybdate in situ on the surface of the spherical silicon dioxide by means of a hydrothermal method, the structural morphology of the obtained spherical silicon and the size of the zinc molybdate particles can be effectively controlled, thereby ensuring that the wear of a drill bit during the drilling of the copper clad laminate is effectively mitigated.

A rhombohedral Zn2SiO4 / cubic ZnFe2O4 / hexagonal SiO2 / C nanocomposite material includes a rhombohedral zinc orthosilicate (Zn2SiO4) phase, a cubic zinc ferrite (ZnFe2O4) phase, and a hexagonal silicon dioxide (SiO2) phase. The rhombohedral Zn2SiO4 / cubic ZnFe2O4 / hexagonal SiO2 / C nanocomposite material exhibits a morphology including spherical microscale particles with an average diameter ranging from 0.8 micrometer (μm) to 1.8 μm and irregular nanoscale aggregates with an average diameter ranging from 50 nanometer (nm) to 110 nm. The rhombohedral Zn2SiO4 / cubic ZnFe2O4 / hexagonal SiO2 / C nanocomposite material has an adsorption capacity for basic fuchsin dye of greater than or equal to 140 milligrams per gram (mg / g). Furthermore, a method for producing the rhombohedral Zn2SiO4 / cubic ZnFe2O4 / hexagonal SiO2 / C nanocomposite material includes calcination of metal precursors.

The invention relates to preparation and application of a C-N doped lithium ion battery silicon-based negative electrode material, and belongs to the technical field of lithium ion battery preparation. The C-N doped lithium ion battery SiOx negative electrode material is granular in structure and rich in holes, volume expansion of a silicon-based negative electrode is relieved, the capacity retention ratio is high after 500 cycles, and the battery rate performance is excellent. According to the invention, a large amount of N element is introduced into the coating layer, so that a C / N co-doping effect is achieved, and the cycle stability of the negative electrode material is improved. In the invention, the production process is simple, the process conditions are easy to control, the cost is lower, and industrial mass production is facilitated.

A negative active material for a rechargeable lithium battery, the negative active material including a porous amorphous carbon matrix having a porosity of about 10 % to about 64 %, silicon oxide distributed in pores of the porous amorphous carbon matrix, and a coating layer on a surface of the porous amorphous carbon matrix, the coating layer including an amorphous carbon.

The present invention relates to a method for preparing silicon monoxide nanopowder, and belongs to the technical field of non-metallic powder material preparation. The present invention uses SiO2 aerogel powder with a three-dimensional continuous structure surface as raw material, adsorbs hydrogen molecules on the surface of the powdered SiO2 aerogel, and axially feeds an argon-excited inductively coupled plasma torch. The hydrogen molecules are excited by the argon plasma torch to form a highly active hydrogen-rich plasma, which undergoes a reduction reaction with the SiO2 aerogel powder having the characteristics of high specific surface area and high porosity. The generated silicon monoxide vapor is quenched by argon downstream of the reaction device to obtain highly dispersible silicon monoxide nanopowder. This method overcomes the defects of the traditional solid-solid reaction method for preparing silicon monoxide, which has a slow reaction rate and low raw material conversion rate, and at the same time solves the safety problems existing in the traditional method of producing silicon monoxide by hydrogen reduction, thereby greatly improving production efficiency and safety.

The present invention relates to a method of preparing a negative electrode active material for a lithium secondary battery, which includes a first step of forming a silicon dispersion by dispersing silicon-based particles in a solvent; a second step of adding an iron salt and tannic acid to the silicon dispersion and stirring to form a reaction layer of the iron salt and the tannic acid on surfaces of the silicon-based particles; a third step of heat treating the reaction layer of the iron salt and the tannic acid to form an amorphous carbon coating layer; and a fourth step of acid treating the amorphous carbon coating layer to form a porous amorphous carbon coating layer, and a negative electrode active material prepared thereby.

To provide: a negative electrode capable of significantly increasing capacity while maintaining battery characteristics; and a method for manufacturing such negative electrode.SOLUTION: A negative electrode includes: a negative electrode current collector having a roughened surface; and a negative electrode active material provided on the negative electrode current collector. The negative electrode active material comprises negative electrode active material particles including a compound of lithium, silicon, and oxygen. The negative electrode active material particles can be represented by SiOxLiy, and a value of x is 0.8 or more and 1.2 or less, and a value of y is 0.5 or more and 3.4 or less. The negative electrode active material has a multilayer structure composed of two or more layers. In Si2p bond energy obtained by X-ray photoelectron spectroscopy analysis of a layer interior in each layer of the negative electrode active material having the multilayer structure, intensity of a peak A acquired in the vicinity of 98 eV and intensity of a peak B acquired in the vicinity of 100.5 eV have a relation (intensity of peak A)≥(intensity of peak B).SELECTED DRAWING: Figure 1

The present invention relates to a negative electrode active material, a negative electrode including the same, a secondary battery including the same and a method for preparing the negative electrode active material.

The present invention relates to the field of negative electrode materials and provides a negative electrode material, a manufacturing method thereof, and a battery. The negative electrode material includes a silicon-based active material and a lithium silicate, and further includes Mg, Al, and P, wherein the mass content of Mg in the negative electrode material is a%, the mass content of Al in the negative electrode material is b%, and the mass content of P in the negative electrode material is c%, and a, b, and c in the negative electrode material satisfy the relationship 0.3≦(a+b) / c≦1.5 and 0.5≦a+b+c≦10. The introduction of Mg, Al, and P into the negative electrode material provided by the present invention is beneficial to the formation of lithium ion transmission channels and can improve the rate performance of the negative electrode material.

This invention provides a nano-silicon@SiO x This invention relates to the field of silicon cutting waste recycling technology, specifically the MXene composite anode material and its preparation method. The invention involves oxidizing silicon cutting waste to obtain nano-silicon@SiO₂. x Then, nano-silicon@SiO x When mixed with a pH buffer solution, negatively charged nano-silicon@SiO₂ is obtained. x The precursor was MAX etched to obtain MXene. MXene was mixed with a cationic surfactant solution to obtain positively charged MXene. Finally, negatively charged nano-silicon@SiO2 was added. x Positively charged MXene and pH buffer solution were mixed to obtain nano-silicon@SiO. x / MXene composite anode material. Nano-silicon@SiO2 prepared in this invention. x The MXene composite anode material overcomes the problems of volume expansion and poor conductivity of silicon materials during the charging and discharging process of lithium-ion batteries, and significantly improves the electrochemical performance of silicon-based anode materials.

Provided are a negative electrode active material which includes negative electrode active material particles which includes a silicon oxide (SiOx, 0<x≤2); and at least one lithium silicate selected from Li2SiO3, Li2Si2O5, and Li4SiO4 in at least a part of the silicon oxide. A signal generated in a region of 200 to 600 cm−1 according to a Raman spectrum is subjected to deconvolution into three peaks, which are set to peak A, peak B, and peak C from lowest to highest of an absolute value of a wavenumber. Also disclosed are a method of preparing the same, and a negative electrode and a lithium secondary battery including the negative electrode active material.

There is provided herein a liquid solution for the recovery of oil from carbonate reservoirs comprising a solid chemical composition comprising Polyhalite in a % weight range of 70 to 99.5; NaCl in a % weight range of 5 to 30; SiO2 in a % weight range of 0.1 to 5; and injected water selected from the group including sea water, diluted sea water, desalinated seawater, produced water, aquifer water, river water, surface water, fresh water, distilled water or a combination of thereof;wherein said solid chemical composition is dissolved in said injected water in an amount of 1-10 grams of said solid chemical composition per 1 liter of said injected water.

The present application relates to a negative electrode active material, a method for manufacturing a negative electrode active material, a negative electrode composition, a negative electrode for a lithium secondary battery including the same, and a lithium secondary battery including a negative electrode.

The present application relates to a negative electrode active material, a method for preparing the same, a negative electrode composition, a negative electrode for a lithium secondary battery comprising the negative electrode composition, and a lithium secondary battery comprising the negative electrode. According to the present invention, a crystalline surface is etched by surface-etching a pulverized silicon-based active material itself via an alkaline solution treatment, so that lithium ion mobility can be controlled, and specific surface areas of a 111 plane and a 220 plane in the silicon-based active material can be adjusted in response to a change in etching conditions, thus, the lithium intercalation / deintercalation reaction is uniform, and the stress on the silicon-based active material is reduced.

The present invention relates to a negative electrode material and a preparation method thereof, and to a lithium ion battery. [Solution] The anode material comprises a core and a first coating layer covering at least a portion of the surface of the core, the core comprising a silicon-based material, the first coating layer comprising a carbon material, a fibrous material distributed on at least a portion of the surface of the first coating layer, and the fibrous material and the anode material satisfy the mathematical formula (I). The presence of the fibrous material on the surface of the first coating layer of the present invention allows the anode material to accept electrons and lithium ions at a high speed, improving the conductivity of the anode material and thereby improving the rate performance of the anode material. TIFF2025538257000009.tif17170 (In formula (I), D wire is the minimum fiber diameter (nm) of the fiber material, and D 10 is the particle size (nm) corresponding to when the cumulative particle size distribution number of the negative electrode material reaches 10%, and ρ is the powder conductivity (S / cm) of the negative electrode material.

The invention discloses a grain size controllable negative electrode and a preparation method thereof, and belongs to the technical field of secondary battery materials. The preparation method comprises the following steps: weighing raw materials according to a molar ratio of a lithium source to SiOx of 0.1-0.7, adding 5-10wt% of a carbon source (naphthalene), and uniformly mixing; and heating the mixed material to 600-800 DEG C at the speed of 1-10 DEG C / min in an inert gas atmosphere, and keeping the temperature for 2-10 hours to obtain the negative electrode material. Through in-situ carbon coating, the growth of silicon and lithium metasilicate grains is inhibited by using the high-temperature heat absorption characteristic of naphthalene, and meanwhile, the conductivity can be improved by an amorphous carbon layer formed by naphthalene carbonization; in the prepared negative electrode material, the grain size of silicon is 8-13nm, the grain size of lithium metasilicate is 9-20nm, the proportion of lithium metasilicate in the total lithium silicate is greater than or equal to 94%, and the capacity retention rate can reach 77.1-90.4% after 100 cycles at 0.5 C multiplying power. The preparation method is simple in process and suitable for industrialization, and the cycle performance and the first coulombic efficiency of the silicon-oxygen negative electrode can be remarkably improved.

The present invention provides a formula for a traditional Chinese medicine-based feminine care solution and its preparation method. The care solution consists of, by weight, 10-15 parts rose hydrosol, 3-5 parts mint hydrosol, 30-45 parts traditional Chinese medicine extract, 3-5 parts dipterocarpus, 1-5 parts chelated platinum ion, and 6-12 parts bacteriostatic agent. The preparation method involves adding the rose hydrosol and mint hydrosol to the traditional Chinese medicine extract to obtain a concentrate. The concentrate is then diluted, and the dipterocarpus is added. The mixture is thoroughly stirred and filtered to obtain a filtrate. The chelated platinum ion and bacteriostatic agent are then added and stirred uniformly.

Provided herein are methods, systems, and kits for generating a self-assembled monolayer of beads adjacent to (e.g., on or across) a substrate. The methods, systems, and kits provided herein may comprise contacting a substrate with a plurality of beads, which may comprise nucleic acid molecules coupled thereto, and providing conditions sufficient for the plurality of beads to self-assemble adjacent to the substrate. Sequencing of the nucleic acid molecules may be performed

The present application relates to a negative electrode active material, a method for producing a negative electrode active material, a negative electrode composition, a negative electrode for a lithium secondary battery including the same, and a lithium secondary battery including the negative electrode.

This invention discloses a low-resistivity silicon suboxide lithium-ion battery anode material and its preparation method. Fluorinated silicon suboxide is mixed with a carbon precursor and a solvent, ground until dry, and the solvent is removed to obtain an intermediate material. The intermediate material is then calcined in a protective gas atmosphere using gradient heating and / or gradient pressurization to obtain the anode material. This invention constructs a fluorine gradient hole structure, which preferentially transforms into a stable LiF-rich solid electrolyte interphase (SEI) film during electrochemical cycling, significantly reducing the lithium-ion diffusion barrier and interfacial charge transfer impedance. The gradient heating and / or pressurization sintering process carbonizes the carbon precursor in situ on the surface of the fluorinated layer, forming a dense and robust coating layer. This coating layer forms a strong interfacial bond through vacancy bonding and mechanical interlocking, buffering volume expansion. The anode material obtained using this invention exhibits excellent electrochemical performance and significantly reduces impedance.

A preparation method and use of a novel pure inorganic solid silicon-based sulfonic acid and / or phosphoric acid catalytic material are disclosed. The surface hydroxyl-rich metasilicic acid is used as the raw material, and by using a sulfonating reagent and / or phosphoric acid, the sulfonic acid group and / or the phosphoric acid group are bonded to the inorganic silicon material by chemical bonding to obtain a pure inorganic solid silicon-based sulfonic acid and / or phosphoric acid catalytic material. The catalytic material can be widely used in many acid-catalyzed organic reactions such as isomerization, esterification, alkylation, hydroamination of olefins, condensation, nitration, etherification, multi-component reactions and oxidation reactions. The inorganic solid silicon-based sulfonic acid and / or phosphoric acid catalytic material of the present invention has the advantages of high acid amount, high activity, good hydrothermal stability, no swelling, simple preparation, low cost, no pollution, no corrosion, easy separation and reusability.

The present invention improves at least one of initial efficiency, battery capacity, and cycle characteristics of a non-aqueous electrolyte secondary battery. A negative electrode active material for a non-aqueous electrolyte secondary battery according to one embodiment of the present invention contains porous composite particles containing silicon and a silicon oxide (SiOx, 0 < x < = 2), in which some or all of pores of the porous composite particles are filled with carbon, and some or all of surfaces of the porous composite particles are coated with carbon.

The present invention relates to a carbon-silicon-silicon / carbon composite comprising: a carbon-silicon composite including silicon disposed inside pores of a porous carbon support; and a silicon / carbon composite matrix disposed on the surface of the carbon-silicon composite, and a manufacturing method therefor. According to the present invention, the overall silicon size can be suppressed to be small, and the formation of Crystal-LixSiy (for example, Li15Si4 or Li3.75Si), which is an intermediate phase affecting the deterioration of battery performance, is suppressed, thereby mitigating the deterioration of battery performance during repeated charge–discharge cycles.