1271 results about "Silica particle" patented technology

The invention discloses a composite solid electrolyte diaphragm which comprises a bacterial cellulose membrane, fluorinated metal modified PEO electrolyte particles and functional group modified particles, and the fluorinated metal modified PEO electrolyte particles and the functional group modified particles are loaded in a three-dimensional network structure of the bacterial cellulose membrane. The functional group modified particles are functional group modified silicon dioxide particles and functional group modified LATP particles, the functional group modified silicon dioxide particles uniformly wrap the functional group modified LATP particles, and fluorinated metal of the fluorinated metal modified PEO electrolyte particles is combined with functional groups of the functional group modified particles through coordinate bonds. The invention also discloses a preparation method of the electrolyte diaphragm and a battery with the electrolyte diaphragm. The ionic conductivity of the electrolyte diaphragm is improved.

The invention discloses a method for preparing synthetic quartz sand by a sol-gel method, which comprises the following steps: mixing silicon alkoxide and an alcohol solvent, and stirring to form a homogeneous solution marked as L1; mixing an acidic catalyst, an alcohol solvent and ultrapure water to form a mixed solution, and recording the mixed solution as L2; dropwise adding the L1 solution into the L2 solution, and continuously stirring and hydrolyzing to obtain sol; dropwise adding ammonia water into the sol until the pH value is 5-10, and standing in a vacuum drying oven to obtain wet gel; and drying and sintering the wet gel to obtain the high-purity synthetic quartz sand. The gelation time is accurately controlled through acid-base two-step catalysis, the production period is shortened, and the production efficiency is improved; meanwhile, the size and uniformity of silicon dioxide particles are controlled by controlling the dripping speed of a silicon source, so that the sintering temperature of the synthesized quartz sand is greatly reduced, and the solvent is recycled through distillation when wet gel is dried, so that the production cost is reduced, and the pollution to the environment is reduced.

The invention provides an asymmetric modified silicon dioxide particle doped sulfonated polyether ether ketone membrane and a preparation method and application thereof, the preparation method comprises the following steps: (1) under a heating condition, mixing surface hydroxylated silicon dioxide particles and paraffin, adding a first solvent, stirring, and cooling to obtain paraffin emulsion droplets; (2) mixing the paraffin emulsion droplets obtained in the step (1) with a sulfydryl-containing silane coupling agent, and reacting to obtain a mixture; and mixing the mixture with a hydrogen peroxide solution, and carrying out oxidation reaction to obtain the asymmetrically modified silicon dioxide particles, and (3) mixing the asymmetrically modified silicon dioxide particles and sulfonated polyetheretherketone, and drying to obtain the asymmetrically modified silicon dioxide particle doped sulfonated polyetheretherketone membrane. The asymmetric modified silicon dioxide particle doped sulfonated polyether ether ketone membrane provided by the invention is low in swelling property, relatively high in proton conductivity and relatively good in ion selectivity, and the performance of a flow battery can be improved when the membrane is used for the flow battery.

The invention relates to the technical field of super-hydrophobic anti-icing coatings, in particular to a low-temperature thermochromic super-hydrophobic anti-icing coating and a preparation method thereof. According to the specific technical scheme, low-temperature thermochromic phase change microcapsules and nanoscale hydrophobic silicon dioxide particles are dispersed in an organic solvent, an adhesive and a curing agent are added, and the super-hydrophobic surface with the micro-nano hierarchical structure, the latent heat regulation function and the temperature visual feedback function is constructed through a spraying method. The obtained coating has excellent super-hydrophobicity, and water drop adhesion can be effectively reduced; the phase change microcapsules contained in the coating release latent heat during low-temperature solidification, and surface temperature reduction and icing are remarkably delayed; and meanwhile, the color of the coating is obviously and reversibly changed along with the reduction of the temperature, so that the visual early warning of the low-temperature icing risk is realized. The problems that a traditional super-hydrophobic coating is insufficient in low-temperature anti-icing long-term effect and lacks an early warning function are solved, the super-hydrophobic coating is suitable for low-temperature anti-icing occasions, and the sensing-regulation-protection integrated function is achieved.

The invention discloses a preparation method of a metal organic framework modified fluorine-free super-amphiphobic coating, and belongs to the technical field of super-amphiphobic coatings. According to the technical scheme, the method comprises the steps of preparation and modification of a metal organic framework and formation of a fluoride-free super-amphiphobic coating. Adding a metal oxide and nano silicon dioxide particles into a polyacrylic acid solution to form spherical particles; enabling the spherical particles to react with imidazole ligands to obtain metal organic framework particles with porous spherical structures, and wrapping nano silicon dioxide particles in the metal organic framework particles; modifying the metal organic framework particles by using a silane coupling agent; the preparation method comprises the following steps: firstly, attaching modified metal organic framework particles to the surface of a metal matrix, then attaching fluorine-free alkyl silane to the surface of the metal matrix, and heating and curing to obtain the fluorine-free super-amphiphobic coating. The fluorine-free super-amphiphobic coating is applied to the aspect of a metal surface super-amphiphobic coating, and the problems that an existing fluorine-free super-amphiphobic coating is poor in oleophobic and hydrophobic performance and poor in durability are solved.

The invention provides a preparation method of a bio-based membrane with efficient waterproof and moisture permeable performance, which comprises the following steps: a) mixing polyurethane, a polymer and a mixed solvent to obtain a mixed solution; the polymer is selected from one or more of PVA (Polyvinyl Alcohol), PVA-co-PE (Polyvinyl Alcohol-co-Polyethylene) and chitosan; b) stirring the mixed solution, standing and defoaming; c) performing electrostatic spinning on the obtained spinning solution; d) grafting silicon dioxide particles on the surface of the obtained PU nanofiber membrane by adopting a hydrothermal assisted sol-gel process, carrying out heat treatment, soaking, taking out, and continuously carrying out heat treatment; e) soaking the obtained PU nanofiber membrane grafted with the SiO2 particles on the surface in an ethanol solution containing tetraethoxysilane, taking out and carrying out heat treatment; and f) drying and cooling the obtained waterproof permeable membrane with the multi-layer pore structure to obtain the bio-based membrane with efficient waterproof and moisture-permeable properties. The bio-based membrane prepared by the method has efficient waterproof and moisture permeable properties.

The invention belongs to the technical field of quartz sand, and discloses a roasting method for controlling the pore defect of quartz sand and increasing the stacking density, which comprises the following steps: 1) drying silicon dioxide gel prepared by a sol-gel method to obtain silicon dioxide powder; (2) the silicon dioxide particles are placed in a roasting furnace, the furnace temperature is preheated to 400-700 DEG C after vacuumizing is conducted, then the furnace is maintained in a vacuum environment for a period of time, then oxygen-containing atmosphere is filled into the furnace and maintained for a period of time, the vacuum environment and the oxygen-containing atmosphere environment are alternately conducted, and sufficient decarburization is achieved; and (3) vacuumizing again, raising the furnace temperature to 1100-1300 DEG C, maintaining for a period of time in a vacuum environment, filling inert gas into the furnace, maintaining for a period of time, alternately vacuumizing and filling the inert gas, and sintering the quartz sand. According to the method, preheating is performed for sufficient decarburization, then high-temperature sintering is performed, the finally obtained quartz sand does not have obvious air holes, and the bulk density is larger than or equal to 1.3 g / cm < 3 >.

The invention provides a nano-modified composite gel foam inhibitor for inhibiting spontaneous combustion of coal and a preparation method of the nano-modified composite gel foam inhibitor, and relates to the technical field of preparation of composite inhibitors. The nanometer modified composite gel foam stopping agent is prepared from six components including sodium polyacrylate serving as a gelling agent, konjac glucomannan serving as a cross-linking agent, lauryl sodium sulfate serving as a foaming agent, xanthan gum serving as a foam stabilizer, nanometer silicon dioxide particles and modified antioxidant powder, the optimal proportion of the gelling agent is 2.5 wt%, the optimal proportion of the cross-linking agent is 0.3 wt%, the optimal proportion of the foaming agent is 0.3 wt%, and the optimal proportion of the modified antioxidant powder is 0.3 wt%. The optimal proportion of the foam stabilizer is 0.4 wt%, the optimal proportion of the nano SiO2 particles is 4 wt%, and the optimal proportion of the modified antioxidant is 2 wt%. Different components endow the nano SiO2 modified composite gel foam with different physical and chemical structural characteristics and coal spontaneous combustion prevention performance characteristics, and by adding the nano SiO2 particles and the bentonite modified tert-butylhydroquinone antioxidant, the overall stability and inhibition efficiency of the gel foam are improved.

Even when used for polishing a semiconductor wafer provided with a silicon nitride film, there is provided sulfonic acid-modified colloidal silica capable of forming a highly flat polished surface at high speed. Sulfonic acid-modified colloidal silica, wherein the sulfur content of the silica particles is 700 mass ppm or more and less than 3000 mass ppm per 1 g of the silica particles, the sulfur content in the solvent is 250 mass ppm or less per 1 g of the solvent, and the content of coarse particles having a particle size of 0.2 μm or more contained in the silica particles is 10,000,000 particles / mL or less when the silica particle concentration is 1 mass%.

The invention discloses a transparent super-hydrophobic cultural relic protection material and a preparation method thereof.The method comprises the steps that firstly, a hydrolyzed silane coupling agent is grafted to the surface of silicon dioxide, then amino of the hydrolyzed silane coupling agent reacts with carboxyl of chain fatty acid, chain alkyl is grafted to the surfaces of silicon dioxide particles, and the transparent super-hydrophobic cultural relic protection material is obtained. The prepared material has excellent super-hydrophobicity, the contact angle of water drops on the surface of a coating is large, the rolling angle of the water drops on the surface of the coating is small, the water drops are difficult to stay on the surface of the coating, and therefore water permeation is effectively prevented. Meanwhile, due to the transparency of the silicon dioxide particles and the chain fatty acid, the coating can keep high transparency, and the original color and pattern of the cultural relic cannot be shielded or changed. The silane coupling agent serves as a bridge for connecting the silicon dioxide particles and the chain fatty acid, the chemical bonding effect in the coating can be enhanced, the coating is not prone to aging and cracking, the material has the advantages of being good in high temperature resistance and ultraviolet light resistance, and therefore the preservation life of the cultural relics is prolonged.

The present invention discloses a silicon active material for ultra-high capacity secondary batteries, which uses nano-sized silicon dioxide particles as a matrix, and the surface of the silicon dioxide particles is directionally coated with a mixed solution, and silicon nanoparticles with a three-dimensional structure are formed after a high-temperature reduction reaction in a hydrogen environment. The obtained nanoparticles are coated with a surface conductive layer to obtain a silicon active material with a mechanically and electrochemically stable three-dimensional structure. The present invention also provides a preparation method and use of the above-mentioned silicon active material for ultra-high capacity secondary batteries. The silicon active material of the present invention has the characteristics of ultra-high specific capacity, stable cycle performance, and low cost, high flexibility in raw material selection, low price, and simple preparation process.

Cerium oxide (CeO2) coated silica (SiO2) particles, optionally comprising the inorganic group-SO2X, and methods of making such particles. The addition of the cerium oxide (CeO2) coated silica (SiO2) particles to fluorinated polymers containing sulfonic acid functional groups increases their stability to free radical degradation when used in fuel cell applications or electrolytic applications.

A toner includes toner particles. A cohesion cluster containing fine silica particles and a binder component is present on surfaces of the toner particles. The toner includes fatty acid metal salt particles. An arithmetic mean value of a Feret diameter of the cohesion cluster is 1,000 to 8,000 nm. A number percentage CI of toner particles having the cohesion cluster is 1 to 15 number %. Number percentages of toner particles having the cohesion cluster in the toner after treatment under ultrasonic wave conditions A and B are represented by Ca and Cb, respectively. CI, Ca, and Cb satisfy formulae (1) and (2): ultrasonic wave condition A: output frequency 30 kHz, output capacity 0.75 W, irradiation time 300 s, ultrasonic wave condition B: output frequency 30 kHz, output capacity 25 W, irradiation time 300 s0.9≤Ca / CI≤1.Formula⁢ (1)0.1≤Cb / CI≤0⁢.40.Formula⁢ (2)

To provide a laminate excellent in mechanical characteristics, damping characteristics, transparency and shock resistance.SOLUTION: A laminate obtained by laminating a resin composition containing a polyacrylate resin and silica particles at least on one surface of a transparent substrate is such that: the polyacrylate resin contains as a monomer unit, an acrylate monomer (A) represented by the following formula (1) [in the formula (1), R0 represents a hydrogen atom, a methyl group or an ethyl group; R1 represents a hydrogen atom or a methyl group; and n represents an integral number of 1-9]; a content of the silica particles is 15-50 vol.% based on the entire resin composition; and an average particle diameter of the silica particles is less than 150 nm.SELECTED DRAWING: Figure 1

The invention provides a preparation method of a nano super-hydrophobic material. The preparation method comprises the following steps: firstly, selecting nano silicon dioxide particles with the particle size of 20-50 nanometers, and matching the nano silicon dioxide particles with heptadecafluorodecyl trimethoxysilane and other raw materials; the nano silicon dioxide particles are subjected to surface modification for 3-5 hours at 40-60 DEG C by controlling the volume ratio of absolute ethyl alcohol to deionized water to be (3-5): 1 and the mass ratio of the long-chain alkyl silane coupling agent to the nano silicon dioxide particles to be (0.5-1.5): 1. Adding 0.1-0.5% hydrochloric acid or sulfuric acid for catalysis, and stirring at room temperature for 2-4 hours to form a sol-gel system; ultrasonically cleaning the substrate, activating with a sodium hydroxide solution, coating by a spraying, dip-coating or spin-coating method, and drying and curing at 60-80 DEG C for 2-3 hours to obtain a finished product. The water contact angle of the prepared material is not lower than 150 degrees, the rolling angle is not higher than 5 degrees, the performance is stable in the environment with the temperature ranging from-20 DEG C to 80 DEG C and the humidity ranging from 20% to 90%, and the water contact angle is still not lower than 140 degrees after more than 500 times of abrasive paper friction tests.

The optical sheet has a first surface and a second surface facing the first surface. The substrate and the functional layer are provided in this order from the second surface toward the first surface. The functional layer contains a binder resin, hollow silica particles, and metal oxide particles other than silica particles. The arithmetic average roughness Sa of the first surface is 5.2 nm or less.

The invention belongs to the technical field of silicon dioxide preparation, and particularly relates to a preparation method of a spherical silicon dioxide anti-blocking agent for a plastic film, and the method comprises the following steps: 1) preparing spherical silicon dioxide particles by a flame method; and 2) carrying out surface modification on silicon dioxide. According to the prepared silicon dioxide anti-blocking agent, the content of SiO2 is 90%-99.9%, the content of iron is smaller than or equal to 0.01 ppm, the content of sodium ions is smaller than or equal to 0.6 ppm, and the silicon dioxide anti-blocking agent has the advantages of being narrow in particle size distribution (D50: 150-1000 nm), excellent in dispersity, low in oil absorption value (15-30 mL / 100 g) and the like. The modified silicon dioxide is compounded with a plastic matrix to prepare a film, and compared with a plastic film without the silicon dioxide anti-blocking agent, the silicon dioxide anti-blocking agent can remarkably improve the anti-blocking performance and mechanical properties of the plastic film, for example, the tensile strength is improved by 10-30%, the elongation at break is improved by 10-30%, and the light transmittance is larger than 92%. Meanwhile, the thermal oxidation yellowing phenomenon caused by metal ions can be effectively inhibited.

To provide an organosilica sol in which hollow silica particles containing aluminum atoms are dispersed in a polymer, especially an organosilica sol formed by dispersing the hollow silica particles in a polymer having a rotaxane structure.SOLUTION: There are provided a hollow silica organosol containing components (A), (B), and (C), wherein the organosol contains component (C) in an amount of 0.001 mass% or more and 90 mass% or less based on the total amount of the organosol (100 mass%), and a method for producing the same. (A) Component: a hollow silica particle containing aluminum atoms, wherein the amount of aluminum atoms present throughout the hollow silica particle is 120 to 50,000 ppm / SiO2 per gram of the hollow silica particle, calculated as Al2O3. (B) Component: a polymer with a molecular weight of 1000 or more, containing ester, ether, or hydroxy group, and additionally possessing an acrylic structure. (C) Component: Organic solvent.SELECTED DRAWING: None

To provide a coated fertilizer having a hydrophilic surface.SOLUTION: A coated fertilizer comprises: a granular fertilizer core; a first coated layer that is formed on a surface of the granular fertilizer core and is composed of a first coating composition including an acrylic polymer; and a second coated layer that is formed on the first coated layer and is composed of a second coating composition including an acrylic polymer, fine silicon powder, polymer sponge powder, and a hydrophilic substance. A silica particle layer is provided on a surface of the fine silicon powder.SELECTED DRAWING: Figure 1

The invention discloses a flue gas water-based three-phase foam system and a profile control method, the flue gas water-based three-phase foam system comprises dispersed-phase gas, suspended-phase solid particles and continuous-phase liquid, the liquid comprises the following components in percentage by weight: 0.5-2.0 wt% of a foaming agent, 0.05-0.5 wt% of a stabilizer, 0.05-0.2 wt% of a thickening agent, 0.1-0.8 wt% of a suspending agent, 0.3-1.0 wt% of inorganic salt and the balance of liquid preparation water; the gas comprises flue gas or mixed gas of one or at least two of nitrogen, natural gas, carbon dioxide, air and flue gas and the flue gas; the solid particles comprise one or a mixture of at least two of silicon dioxide particles, montmorillonite particles, bentonite particles, kaolin particles and fly ash particles, and the particle sizes of the solid particles are from nanometer to micrometer. According to the method, the flue gas discharged by the steam-injection boiler is captured and treated and then is injected into the stratum together with the water-based three-phase foam system and the steam segmented plug according to a certain proportion to assist in steam recovery of the thickened oil, so that the recovery rate of the thickened oil can be increased, the emission of greenhouse gases can be reduced, the capture, storage and utilization of CO2 can be realized, and the environmental protection situation requirements of carbon peak reaching and green development are met.

The present invention discloses a transparent super-hydrophobic cultural relic protection material and a preparation method thereof. The method first grafts a hydrolyzed silane coupling agent onto the surface of silica, and then utilizes the amino group of the hydrolyzed silane coupling agent to react with the carboxyl group of a chain fatty acid to graft a chain alkyl group onto the surface of silica particles. The prepared material has excellent super-hydrophobicity, a large contact angle of water droplets on the coating surface, and a small rolling angle, making it difficult for water droplets to stay on the coating surface, thereby effectively preventing moisture penetration. At the same time, due to the transparency of the silica particles and the chain fatty acid, the coating can maintain a high transparency and will not block or change the original color and pattern of the cultural relic. The silane coupling agent acts as a bridge connecting the silica particles and the chain fatty acid, which can enhance the chemical bonding inside the coating, making the coating less prone to aging and cracking, and giving the material good high-temperature resistance and the advantage of resisting ultraviolet light, thereby extending the preservation life of the cultural relic.

The present application provides a heat exchanger and a manufacturing method of a heat exchanger. The heat exchanger includes a metal substrate, the metal substrate has a fluid channel for circulating a heat exchange medium; and the heat exchanger further includes a coating, the coating includes resin, silica and titanium dioxide, and the coating is arranged to cover at least part of a surface of the metal substrate. Silica particles and titanium dioxide particles are conducive to the formation of a complex micro-nano structure, and leveling and stability of hydrophilic resin contribute to long-term maintenance of the micro-nano structure. The coating of the heat exchanger according to the present application has excellent hydrophilic durability.

A method for producing spherical silica particles according to the present disclosure includes: a raw material silica particle preparation step of preparing a liquid dispersion of raw material silica particles from a raw material solution obtained by dissolving silicic acid in a mixed solvent of water and an organic solvent in the presence of a basic substance; and a heating step of heating the liquid dispersion or the raw material silica particles so as to remove an organic substance contained in the liquid dispersion, thereby preparing spherical silica particles. The mixed solvent has a relative permittivity of 21 or higher and 40 or lower, and a quaternary ammonium derived from the basic substance is blended in a blending ratio of 0.3 or higher and 0.8 or lower in terms of molar ratio with respect to a silicon element derived from the silicic acid.

An electrophotographic belt is provided, which includes a base layer and a surface layer in direct contact with the base layer, wherein the surface layer includes heteroaggregates of a first particle and a second particle, the first particle is at least one selected from the group consisting of a hollow silica particle and a solid silica particle, and has a number-average particle diameter of primary particles, which is greater than 30 nm and less than 100 nm, the second particle contains a conductive metal oxide, and has a number-average particle diameter of primary particles, which is 5 nm to 40 nm, the surface layer has protruded portions derived from the heteroaggregates on an outer surface opposite to the surface facing the base layer, an arithmetic mean height (Sa) of the outer surface is 0.1 μm to 0.7 μm, and the base layer includes specific cation and anion.

The invention belongs to the technical field of aluminum electrolysis waste treatment, and particularly relates to a method for green recovery of aluminum electrolysis waste. The method comprises the following steps: mixing and roasting aluminum electrolysis waste, aluminum-containing waste and sulfuric acid to prepare modified waste; the modified waste is smashed and stirred, and filter residues A and filtrate A are filtered and separated out; removing impurities from the filtrate A to obtain filter residues B and filtrate B; reacting the filtrate B with water-soluble carbonate or phosphate to prepare a lithium product; mixing and roasting the filter residue A, the filter residue B and a silicon-containing substance to generate aluminum oxide and silicon tetrafluoride gas; dissolving the aluminum oxide through hydrochloric acid, and reacting the silicon tetrafluoride gas with an aluminum chloride solution to form silicon tetrachloride gas and aluminum fluoride; the silicon tetrachloride gas is combusted to generate hydrogen chloride gas and silicon dioxide particles, and the hydrogen chloride gas is converted into a hydrochloric acid solution through water absorption. According to the method, recycling of aluminum and lithium resources in the aluminum electrolysis waste is effectively achieved, by-products are converted into valuable chemical substances, and resource recycling is promoted.

Provided is a polishing composition that can offer a high-grade surface. The polishing composition contains silica particles (A), a basic compound (B), a first water-soluble polymer (C1), a second water-soluble polymer (C2), and water (D), wherein the first water-soluble polymer (C1) is a polyvinyl alcohol-based polymer. A product (ER × ζ) of an etching rate ER [µm / h] of the polishing composition and zeta potential ζ [mV] of the polishing composition is -900 nmV / h or more and -90 nmV / h or less.

The invention discloses a high-strength, light-weight and multifunctional composite shell for a warhead, and relates to the field of ship protection, the composite shell comprises a front protection layer, a rear protection layer and a composite sandwich panel arranged between the front protection layer and the rear protection layer, the composite sandwich panel is of a honeycomb structure, and the composite sandwich panel is of a honeycomb structure. The honeycomb structure is filled with energy-absorbing substances. The energy absorption substance is shear thickening glue doped with silicon dioxide particles. By manufacturing the light multifunctional composite shell and integrating the energy absorption layer, the impact resistance and fragment penetration resistance of the shell are improved. Material distribution is optimized, light weight and structural strength are balanced, a shear thickening material (STG) is added, and multi-dimensional energy dissipation is achieved.

The invention belongs to the technical field of temporary plugging agents, and relates to a medium-temperature drilling fluid nano temporary plugging agent and a preparation method thereof. The temporary plugging agent is prepared from the following raw materials in parts by mass: 10 to 15 parts of small-particle-size coated silicon dioxide, 15 to 20 parts of medium-particle-size coated silicon dioxide, 30 to 50 parts of large-particle-size coated silicon dioxide, 15 to 20 parts of fiber, 5 to 8 parts of polyether diglycidyl ether, 5 to 8 parts of hyperbranched polyethyleneimine, 1 to 1.5 parts of water-soluble cellulose and 0.5 to 1 part of cationic quaternary ammonium salt. The coated silicon dioxide takes chitosan and glutaraldehyde as wall raw materials and silicon dioxide as a core material, and the particle size of the small-particle-size core material is 0.3-1 mu m; the particle size of the medium-particle-size particle core material is 150-250 microns; the particle size of the large-particle-size particle core material is 250-350 microns, the coated silicon dioxide particles are bonded together through a microscopic interpenetrating network formed by the reaction of hyperbranched polyethyleneimine and polyether diglycidyl ether, and the particles are matched with fibers to improve the bearing strength.

The invention relates to the technical field of composite fibers, in particular to a light-absorbing and heat-generating composite fiber and a preparation method thereof.The preparation process comprises the following steps that 1, core-shell structure light-absorbing and heat-generating particles are prepared; (2) carrying out surface modification on ferroferric oxide coated silicon dioxide particles; (3) in-situ polymerization; and (4) melt spinning. According to the scheme, nano ferroferric oxide is selected as a core light absorption material, and due to a unique Fe < 2 + > / Fe < 3 + > mixed valence electronic structure, while wide-spectrum light absorption is realized, oxidative photo-generated holes are hardly generated, so that the photocatalytic degradation risk similar to titanium dioxide is avoided from the source, and the long-term stability of a polymer matrix is guaranteed; in combination with in-situ polymerization, axial gradient magnetic field spinning processes and the like, the washing resistance, aging resistance and strength of the light-absorbing and heating composite fiber are synchronously improved.

The invention relates to the technical field of fire extinguishing agents, and particularly discloses a lithium battery fire extinguishing agent and a preparation method thereof. The degradable surfactant is selected from at least one of alkyl glycoside and fatty acid methyl ester sulfonate; the particle size of the nanoscale silicon dioxide particles is 10 to 100 nm; the composite flame retardant is formed by compounding an organic phosphorus compound and graphene oxide according to a mass ratio of 1: (0.5-2); the antifreeze agent is selected from at least one of ethylene glycol and propylene glycol; the thickening agent is selected from at least one of xanthan gum and sodium carboxymethyl cellulose; the preservative is selected from at least one of sodium benzoate and potassium sorbate; through the synergistic effect of the composite flame retardant, the fire extinguishing efficiency is remarkably improved, reburning is inhibited, in addition, nano silicon dioxide is uniformly dispersed after being subjected to surface modification to form a compact heat insulation layer, the degradable surfactant and the environment-friendly preservative are combined, and the agent is free of toxic residues.