709results about How to "Good temperature and salt resistance" patented technology

The invention provides a hydrophobic associated polymer, comprising repeating units shown in formula (I) and formula (II), wherein x: y = 1: (0.001 to 0.06); A is a monomeric unit of a hydrophobic monomer; the viscosity average molecular weight of the hydrophobic associated polymer is 5 to 35 million. Compared with the prior art, the hydrophobic associated polymer comprises two monomeric units, and a hydrophilic unit is a monomeric unit of acrylamide, can provide a hydrophilic group for a hydrophobic associated polymer, and ensures that the polymer has good water solubility; a hydrophobic unit is a monomeric unit of the hydrophobic monomer, can provide a hydrophobic side group for the hydrophobic associated polymer, and ensures that a polymer chain has a certain hydrophobic character, and hydrophobic groups gather in water due to a hydrophobic interaction to form a spatial network structure, thereby providing necessary viscoelasticity for a solution; under the combined action of the two units, the temperature resistance and salt tolerance and shear resistance of the hydrophobic associated polymer are improved.

The invention discloses a comb-type structural reactive polymer with the molecular weight ranging between 1x10<5> and 5x10<6>, wherein the main chain of the reactive polymer is obtained through the copolymerization of acrylamide monomer and functional monomers such as 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid sodium salt, etc., which endues polymer aqueous solution with higher apparent viscosity and better temperature resistance and salt resistance; and the branched chain of the reactive polymer consists of unsaturated macromonomer molecule, which endues the polymer aqueous solution with higher surface activity. The invention also discloses a preparation method for the polymer, comprising the following steps: firstly, through process operation including esterification, prepolymerization and sulfonation, polyurethanes active macromonomer with a novel structure is prepared; then, under the action of oxidation reduction initiator, the copolymerization reaction of the active macromonomer and other functional micromolecule monomers is initiated quickly at low temperature. The comb-type structural reactive polymer can be used as oil displacement agent and has the advantages of high molecular weight and low surface tension, etc.

The invention relates to a synthesis method of drilling fluid filtrate reducer. The method comprises: a, nonionic compound emulsifying agent is dissolved in oil and oil phase is made up; a first monomer chosen from fumaric acid, maleic acid, itaconic acid or crylic acid, a second monomer chosen from N, N- dimethylacrylamide, N, N-diethylacrylamide or acrylamide and a third monomer chosen from 4-vinylbenzenesulfonic acid sodium salt, sodium allylsulfonate, 3-allyloxy-2-dydroxy-1-sodium allylsulfonate, 2- methacryloxypropyl-2-methyl propanesulfonic acid, 2-acrylamido-2-methyl propanesulfonic acid or SMAS are dissolved in water with the molar ratio of 1:1 to 5:1 to 5, the pH value of the solution is adjusted to be between 8 and 11, evocating agent is added and water phase solution is made up; and b, the water solution is added to the oil phase solution and the temperature rises to 40 to 70 DEG C for polymerization. The method of the invention has the advantages of fast polymerization speed, high outcome molecular weight and high outcome stability, good filtrate reducing performance, high temperature resistance and high salt resistant performance.

The invention relates to a polymer mobility control agent suitable for an ultrahigh-salinity oil deposit and a preparation method thereof, and the polymer mobility control agent is mainly used for solving the problem that a polymer can not meet the requirement for tertiary oil recovery due to poor temperature resistant property, salt resistant property and shearing resistant property in the prior art. In order to better solve the problem, the technical scheme adopted by the invention is as follows: the control agent for an amphoteric hydrophobic associated polymer comprises the following components in parts by weight of the amphoteric hydrophobic associated polymer: 5-99.9 parts of nonionic water-soluble monomers, 0-50 parts of anionic monomers or/and cationic monomers, 0.1-10 parts of hydrophobic monomers with surface activity, 0.1-5 parts of inorganic substances and 1-20 parts of surface active agents. The preparation method disclosed by the invention can be used for the industrial production of the polymer mobility control agent suitable for the ultrahigh-salinity oil deposit.

The invention discloses an amphoteric heat-resistant and salt-resistant filtrate reducer for drilling fluid and a preparation method. The amphoteric heat-resistant and salt-resistant filtrate reducer is prepared from, by weight parts, acrylamide, alkenyl sulfoacid or alkenyl sulphonate, acrylic acid, cationic monomers, rigid monomers, sodium hydroxide, potassium hydroxide, dispersant, deionized water, a molecular weight modifier and an initiator. The preparation method includes the steps that acrylamide, acrylic acid, alkenyl sulfoacid or alkenyl sulphonate, the cationic monomers, the rigid monomers and the deionized water are added into a reactor, after the materials are dissolved, the pH value of the solution is adjusted, the dispersant is added, the materials are mixed, then the mixture is transferred into a reaction still, nitrogen is introduced for deoxygenization, the initiator is added for triggering polymerization, and jelly is taken out after the reaction is completed, dried, smashed and sieved. The molecular weight of the filtrate reducer for the drilling fluid is controllable; the filtrate reducer can adapt to complex drilling conditions, and can be used in horizontal wells, high-temperature deep wells and evaporite beds; fewer residual monomers of the filtrate reducer for the drilling fluid are generated; the filtrate reducer and other oil field chemicals are good in compatibility; the preparation method is simple; the cost is low, and popularization is promoted.

The invention relates to an amphoteric ionic polymer clay stabilizer and a preparation method thereof. The polymer has water solubility, is low in use level and shows excellent temperature resistance and shear resistance. According to the technical scheme, the amphoteric ionic polymer clay stabilizer is prepared from the following raw materials and monomers in percentage by mass: 53.5-59.9 percent of acrylamide AM; 40-45 percent of sodium acrylate NaAA (obtained from neutralization of crylic acid and sodium hydroxide), 0.1-1.5 percent of N-allyl oleamide NAO and 0.1-1.5 percent of dimethyl diallyl ammonium chloride DMDAAC. The preparation method comprises the following steps: firstly adding NAO in a reactor, then adding an emulsifier and water; after complete emulsification, adding AM, NaAA, DMDAAC to prepare a solution with the total mass percentage concentration of monomer being 10-25 percent, adjusting pH to be 6-8, and introducing N2 for 20 min; then adding an initiator, continuing to introduce N2 for 20 min, and reacting for 8-12 h at 30-70 DEG C; washing with absolute ethyl alcohol, grinding and drying to obtain AM/NaAA/DMDAAC/NAO quadripolymer. The result of an anti-swelling test of 0.2wt% solution shows that the anti-swelling rate can reach 86 percent.

The invention discloses a polymer nano-silica temperature-resistant, salt-tolerant and fluid loss reducing agent and a preparation method thereof. According to the preparation method, in the presence of nano-silica, a polymer-base nanometer composite material with amphiphilic block hydrophobic associating polymer wrapping inorganic nano-silica is successfully synthesized by virtue of a micellar emulsion polymerization method and combines the rigidity and the heat stability of the inorganic nano-silica and the characteristics of the amphiphilic block hydrophobic associating polymer together, and the temperature resistance, the salt tolerance and the thickening property of the polymer are obviously improved by virtue of the polymer-base nanometer composite material on the basis of the existing good performances of the amphiphilic block hydrophobic associating polymer. As a temperature-resistant, salt-tolerant and fluid loss reducing agent for a drilling fluid in the drilling engineering, the polymer nano-silica temperature-resistant, salt-tolerant and fluid loss reducing agent has a remarkable fluid loss reducing effect under high temperature and high salinity.

The invention relates to a profile controlling and flooding composition for high-temperature oil reservoirs with high salinity and an application of the composition in tertiary oil recovery of the high-temperature oil reservoirs with high salinity, and mainly aims at solving the problems of poor heat resistance and salt tolerance and low oil displacement efficiency of an oil displacement agent under the conditions of high temperature and high salinity in the prior art. The problems are well solved by virtue of the following technical scheme: the profile controlling and flooding composition for high-temperature oil reservoirs with high salinity is prepared from the following components in percentage by weight: (1) 0.01-3.0% of heat-resistant and salt-tolerant polyacrylamide microspheres, (2) 0.01-5.0% of anionic-nonionic surfactant and (3) 92.0-99.98% of injected water; and the profile controlling and flooding composition can be applied to field applications for increasing the recovery rate such as depth profile controlling, water plugging and oil displacement for tertiary oil recovery of the high-temperature oil reservoirs with high salinity.

The invention provides a tackifier for a drilling fluid, and a preparation method and application thereof. The tackifier is a quadripolymer formed by polymerization of four alkene monomers, wherein the four alkene monomers are selected from a temperature-resistant salt-tolerant monomer, a hydrated monomer and an adsorptive monomer; the temperature-resistant salt-tolerant monomer is selected from an alkenyl sulfonic acid monomer; the hydrated monomer is selected from alkenyl carboxylic acid, alkenyl alkane ketone and double-bond-containing quaternary ammonium salt compounds; and the adsorptive monomer is selected from an alkenyl amide monomer. The tackifier provided by the invention can resist a high temperature of no less than 180 DEG C, is resistant to saturated salt, has remarkable tackifying effect, is low in toxicity and environmentally friendly, and can obviously improve the dehydration and wall building capability of the drilling fluid, thereby effectively reducing the dehydration. The invention solves the downhole complexity possibly caused by the fact that the drilling fluid system can not carry and suspend rock debris and thus can not clear boreholes in time due to reduced viscosity shearing force as a result of poor temperature resistance and salt tolerance of the tackifier in deep well, ultradeep well, horizontal well and extended reach well operations.

The invention relates to a preparation method of partially hydrolyzed polyacrylamide with improved temperature and salt resisting performances by using a template polymerization mode. The polymerization initial temperature of the partially hydrolyzed polyacrylamide is controlled to be 0-15DEG C at which template materials are more remarkably acted with functional monomers of polymerization monomers to facilitate the forming of a polyacrylamide product with a block structure; by adopting the template polymerization at the polymerization phase, polymer colloid particles have superhigh molecular weight and maintain favorable dissolving performance at the same time; and by using the temperature of the polymer colloid particles during generation, NaOH is added for hydrolysis during discharge. The number average molecular weight of the partially hydrolyzed polyacrylamide disclosed by the invention can reach 25-32 millions; meanwhile, compared with a random copolymerization product, the high polymer structure has more ordered block sequence structure, so that the partially hydrolyzed polyacrylamide has favorable dissolving performance; in addition, higher viscosity can be maintained in saline water with high temperature and high salinity.

The invention relates to a polymer mobility control agent suitable for a high-temperature and high-salinity harsh reservoir and a preparation method of the polymer mobility control agent, and the polymer mobility control agent is mainly used for solving the problems that the polymer in the prior art is poor in heat and salt resistance and long-term stability, and cannot meet the requirements of tertiary oil recovery. In order to better solve the problems, the technical scheme adopted by the invention is as follows: an amphoteric hydrophobic association polymer is prepared from the following raw materials in parts by weight: 5-99.9 parts of a non-ionic water-soluble monomer, 0-50 parts of an anionic monomer or/and cationic monomer, 0.1-10 parts of a hydrophobic monomer with surface activity, 0-20 parts of a viscosity stabilizer and 0-20 parts of a surfactant. The preparation method can be applied to industrial production and application of the polymer mobility control agent for the high-temperature and high-salinity harsh reservoir.

The invention relates to an oil-displacing agent and an oil-displacing method for enhancing the recovery ratio of high-temperature, high-salinity and high-hardness reservoir crude oil. The oil-displacing agent is composed of the following components in percentage by mass: A, 0.05-0.07% of an amine oxide type amphoteric surfactant; B, 0.15-0.20% of alkylphenol ethoxylate carboxylate; and C, the balance of water. The oil-displacing method disclosed by the invention is implemented through injecting the oil-displacing agent into a natural core subjected to oil-displacing under the conditions that the oil reservoir temperature is 100-120 DEG C, the total salinity of formation water is (10-15)*10<4> mg/L, and the amount of calcium-magnesium divalent metal ions is 7000-10000 mg/L, so that residual oil is in contact with the oil-displacing agent, and then the residual oil is fully displaced. The oil-displacing agent provided by the invention reaches the magnitude order of 10<-3> mN/m under the condition of high-temperature, high-salinity and high-hardness salt reservoirs, and the interfacial tension still can be maintained in an ultra-low interfacial tension state after the oil-displacing agent is aged for a long time under the condition of oil reservoirs, therefore, the oil-displacing agent is applied to the tertiary oil recovery production of oil fields.

The invention relates to a temperature-resistant anionic-nonionic amphoteric hydrophobically associating copolymer and a preparation method thereof. The temperature-resistant anionic-nonionic amphoteric hydrophobically associating copolymer is prepared by copolymerizing a monomer A, a monomer B and a monomer C, wherein the weight ratio of the monomer A to the monomer B to a monomer C is 10: (0.5-1.5): (0.05-0.15); the monomer A is acrylamide; the monomer B is 2-acrylamido-2-methyl propane sulfonate (AMPS), alpha-alkenyl sulphonate or vinyl sulfonate; the monomer C is poly(ethylene glycol) octadecyl methacrylate (OEMA). With a sulfonic acid group, the copolymer has excellent water solubility and temperature resistance; meanwhile, with a non-ionic hydrophobic unit, the copolymer has unique shear resistance and viscosifying ability; the copolymer has excellent performance, has a wide application prospect in the oil and gas resource exploitation under high temperature, high salt, low permeability, and can be used in an oil field displacement agent and a fracturing fluid thickener.

The invention discloses an in-situ polymerization intercalation-type composite gel material and a preparation method and application thereof. The preparation method comprises the following steps: (1) interlayer dressing agent and clay are dissolved in water and are stirred 40 minutes to 60 minutes at a stirring speed of 10,000 to 15,000 r/min till the mixture is mixed evenly, thereby obtaining the mixing solution of the clay; (2) water-soluble monomer and initiator are added in the solution and are stirred 20 to 40 minutes at a stirring speed of 500 to 1,000 r/min till the mixture is mixed evenly; and (3) the reaction of the mixture is carried out under 80 to 140 DEG C for 6 hours to 12 hours. Moreover, the water-soluble monomer is one of or the random combination of acrylamide monomer, acrylic acid monomer, acrylonitrile monomer, acrylic ester monomer, allyl alcohol monomer, allyl urea monomer, allyl ether monomer, allyl ester monomer, allyl ether ester monomer and allyl azide monomer. Because the interlayer dimension of the composite gel material is between 4.5 nm and 6.0 nm, the composite gel material has excellent mechanical strength, injection performance, temperature resistance, salt resistance and plugging performance, thereby having a broad application prospect in the preparation of material for profile control and water shutoff.

The invention discloses a method for preparing a high-stability heat-resistance and salt-tolerance air foam oil displacing agent. According to the method, a nanometer and nanometer modification technology is adopted, and nanometer hectorite is used as a foam stabilizer and a high-temperature stabilizer to prepare the high-stability heat-resistance and salt-tolerance air foam oil displacing agent. The technology includes the following steps that the hectorite is added into deionized water at the temperature of 50-90 DEG C, stirred and dispersed evenly, cooled to the room temperature and stewed and aged for a period of time to obtain hectorite aqueous dispersion, quantitative cationic surface active agents are added, evenly stirred, stewed and aged, finally, foaming agents are added, high-speed stirring is conducted on a high-speed emulsification machine, and the high-stability heat-resistance and salt-tolerance air foam oil displacing agent is obtained. The foam half-life period reaches up to 768 hours, the high foam stability is achieved, the foam half-life period reaches up to 70 hours under the condition that the degree of mineralization is 30000 mg/L, the good salt tolerance is achieved, the apparent viscosity reaches up to 2000 mPa.s, the heat resistance performance reaches 90 DEG C, the high foam strength and the heat resistance are achieved, the shearing rate is 170 per second, the foam apparent viscosity reaches 800 mPa.s after shearing is conducted for 60 minutes, the good shearing performance is achieved, and the method is suitable for exploration and development of conventional and unconventional oil fields.

The invention relates to an initiator composition used for synthesizing polyacrylamide capable of displacing oil, which mainly solves the problems of low polyacrylamide molecular weight, poor heat resistance and salt resistance performances and difficult satisfaction for technical requirement of tertiary oil extraction. The initiator composition used for synthesizing polyacrylamide capable of displacing oil comprises the following ingredients by weight percentage: (a) 0.5-20% of persulfate; (b) 0.1-40% of sulfite or acid sulfite; (c) 0.5-20% of NR1R2R3-represented trialkylamine compounds or N<+>R4R5R6R7-represented quaternary ammonium compounds or NH2R8-represented aliphatic amine compounds, wherein R1-R7 in the formula are selected from C1-C14 straight chain or branched chain alkyl or alkyl derivatives, R8 is selected from straight chain or branched chain alkyl or alkyl derivatives; (d) 10-80% of urea, thiourea or ammonia liquor; (e) 5-60% of ethylenediaminetetraacetic acid. The technical scheme of the invention better solves the problems and can be used in industrial production of oil displacement.

The invention relates to an oil displacing system for increasing oil recovery in high temperature high salt mid-low permeability oil reservoir, and a preparation method thereof, and aims to solve the problems that in the prior art, hydrophobic associated polymer can easily obstruct the holes of sandstone formation, the injection performance of oil displacing agent is bad in the immediate vicinity of wellbore, the oil displacing agent can only applied to mid-high permeability oil reservoirs, and the hydrophobic associated polymer can easily react with oil displacing surfactant to generate chromatographic separation. The oil displacing agent comprises the following components in parts by weight: 0.01 to 1 part of adsorption resisting agent, 0.05 to 3 parts of hydrophobic associated polymer, 0.2 to 5 parts of oil displacing surfactant, and 91 to 99.8 parts of water; wherein the adsorption resisting agent is one or more of nonionic surfactant and anionic surfactant. The provided oil displacing agent well solves the problems mentioned above, and can be applied to the onsite oil displacing in a mid-low permeability oil reservoir.