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1835 results about "Alkane" patented technology

In organic chemistry, an alkane, or paraffin (a historical name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in which all the carbon–carbon bonds are single. Alkanes have the general chemical formula CₙH₂ₙ₊₂. The alkanes range in complexity from the simplest case of methane (CH₄), where n = 1 (sometimes called the parent molecule), to arbitrarily large and complex molecules, like pentacontane (C₅₀H₁₀₂) or 6-ethyl-2-methyl-5-(1-methylethyl) octane, an isomer of tetradecane (C₁₄H₃₀).

Single-ion conductor polymer, ternary composite binder solution, high-solid-content sulfide electrolyte slurry and wet film forming method and application of high-solid-content sulfide electrolyte slurry

The invention discloses a single-ion conductor polymer, a ternary composite binder solution, high-solid-content sulfide electrolyte slurry and a wet film forming method and application thereof, and belongs to the technical field of all-solid-state lithium batteries. The key technical problems in the wet membrane preparation of the sulfide electrolyte are solved through an innovative solvent-binder synergistic system, and the method specifically comprises the steps that 1, through the synergistic effect of a non-polar solvent and a weak-polar solvent, low-viscosity coating of high-solid-content slurry is achieved while the chemical stability of the sulfide electrolyte is guaranteed; 2, a poly (lithium styrenesulfonate-butyl acrylate), styrene butadiene rubber and polyisobutene ternary composite binder is designed, a lithium ion transmission channel is provided through a lithium sulfonate group, a benzene ring structure in the styrene butadiene rubber enhances the mechanical strength, long-chain alkane in the polyisobutene improves the interface adhesive force, and the mechanical strength is improved; the three components cooperate to realize balance of mechanical and electrochemical properties of the electrolyte membrane, so that the prepared electrolyte membrane has low porosity, high ionic conductivity and mechanical strength.
Owner:SHANGHAI FIRM LITHIUM NEW ENERGY TECH CO LTD

Pyrolysis method and system for recycled waste

A pyrolysis method and system are provided that enhances the production of alkanes and minimizes the production of aromatics in the resulting pyrolysis oil. More particularly, the disclosed pyrolysis method and system may be configured to enhance the production of alkanes due to the use of certain pyrolysis catalysts and more intense pyrolysis conditions.
Owner:EXXONMOBIL PRODUCT SOLUTIONS CO

Pt-Sn bimetallic catalyst and preparation method and application thereof

The invention provides a Pt-Sn bimetallic catalyst and a preparation method and application thereof.The preparation method comprises the steps that 1, a Y molecular sieve is placed in a mixed solution of KOH and methyl alcohol, centrifugation and washing are conducted till the Y molecular sieve is neutral after stirring, drying and roasting are conducted, and a non-acid KY molecular sieve is obtained; the silica-alumina ratio of the Y molecular sieve is 3-100; 2) taking the non-acidic KY molecular sieve as a carrier, and loading Sn by adopting an atomic layer deposition technology to obtain a Sn-modified non-acidic KY molecular sieve; and 3) loading Pt by using the Sn-modified non-acidic KY molecular sieve as a carrier and adopting an atomic layer deposition technology to obtain the Pt-Sn bimetallic catalyst. According to the preparation method provided by the invention, spatial distribution of Pt and Sn is accurately regulated and controlled by combining an atomic layer deposition technology, so that the electronic state of Pt species is adjusted, alkane is promoted to be dehydrogenated into an olefin intermediate, and the aromatization catalytic activity and the aromatic hydrocarbon selectivity of alkane are improved.
Owner:SHANDONG ENERGY GROUP COAL GASIFICATION & NEW MATERIALS TECHNOLOGY CO LTD

Method and system for photocatalytic oxidation of gaseous alkane

The invention belongs to the technical field of photocatalytic oxidation of gaseous alkanes, and particularly relates to a method and system for photocatalytic oxidation of gaseous alkanes, and the method comprises the following steps: under illumination, enabling a photocatalyst, bubbles containing gaseous alkanes and chlorine-containing active substances to react at an interface of a two-phase system containing an organic phase and a water phase to generate an oxidation product, the oxidation product comprises one or more of acid, alcohol and aldehyde, and the organic phase can dissolve the chlorine-containing active substance. The method provided by the invention is beneficial to improving the generation rate of oxidation products and the apparent light quantum efficiency of photocatalytic reaction.
Owner:BEIJING NORMAL UNIV AT ZHUHAI

Compositions for separating plasma and methods of use thereof

The invention relates to the field of plasma separation and detection, in particular to a composition for separating plasma and a using method thereof. The composition comprises: a phase change component, which is selected from n-alkanes, which are selected from at least one of n-tetradecane, n-pentadecane, n-hexadecane, n-heptadecane, n-octadecane, n-nonadecane, n-eicosane, n-heneicosane or n-docosane; a liquid phase carrier component, wherein the liquid phase carrier component is selected from silicone oil; the structural framework and rheology regulation and control component comprises fumed silica, and the structural framework and rheology regulation and control component comprises fumed silica; the dispersion and stabilization auxiliary agent component is selected from at least one of TiO2 and BaSO4, the density adjusting filler component is selected from at least one of TiO2 and BaSO4, and the dispersion and stabilization auxiliary agent component comprises a silane coupling agent. According to the device, plasma and blood cells can be reliably, rapidly and effectively separated only through one-time low-temperature centrifugation, and remixing caused by transportation jolting can be avoided.
Owner:SHANGHAI WEIHE MEDICAL LAB CO LTD

Novel hindered amine light stabilizer, preparation method and application

The invention provides a novel hindered amine light stabilizer as well as a preparation method and application thereof, and relates to the field of light stabilizers. According to the preparation method of the novel hindered amine light stabilizer, specific dibasic acid dimethyl ester and 2, 2, 6, 6-tetramethylpiperidinol are used as raw materials, an alkane solvent or a benzene solvent is used as a solvent, and a catalytic reaction solution is obtained through a heating reaction under the condition of a catalyst; and neutralizing and washing the catalytic reaction liquid to obtain the novel hindered amine light stabilizer. According to the preparation method, ideal preparation effects (such as purity, yield and the like) can be achieved, meanwhile, the chroma of the product is effectively reduced, the problem that the product is prone to yellowing due to the fact that the hindered amine light stabilizer absorbs visible light is solved, and the compatibility and stability of the hindered amine light stabilizer and a high polymer material are further improved.
Owner:WEIFANG YUANLI NEW MATERIAL CO LTD

Dechlorination regeneration method of chlorine poisoning noble metal catalyst and application of regenerated noble metal catalyst in polyolefin hydrogenolysis

The invention discloses a dechlorination regeneration method of a chlorine poisoning noble metal catalyst and an application of the regenerated noble metal catalyst in polyolefin hydrogenolysis, and the dechlorination regeneration method comprises the following steps: dispersing the chlorine poisoning noble metal catalyst in water, adding a strong nucleophilic reagent for treatment, and carrying out centrifugal separation, washing and drying treatment to obtain the chlorine poisoning noble metal catalyst. The regenerated noble metal catalyst is obtained. A strong nucleophilic reagent dechlorination regeneration strategy under a room temperature mild condition is provided, chemically inert metal-chlorine bonds are broken through a nucleophilic substitution effect, noble metal particles are prevented from being agglomerated and sintered while deep dechlorination is realized, polyolefin hydrogenolysis activity of the catalyst can be completely recovered, activity improvement can be realized, and the catalyst has a good application prospect. Meanwhile, the regeneration cost is greatly reduced, and the regenerated noble metal catalyst can be used for efficiently hydrogenolyzing, upgrading and recycling waste polyolefin to obtain liquid alkane fuel with high additional value.
Owner:SUZHOU UNIV

High-grinding-efficiency color paste, preparation method thereof and dispersed ink

The invention provides high-grinding-efficiency color paste, a preparation method thereof and dispersed ink, and belongs to the technical field of dispersed ink, and the high-grinding-efficiency color paste comprises the following components in percentage by weight: 15%-30% of disperse dye toner, 15%-25% of a dispersing agent, 5%-15% of resin ammonium salt, 10%-20% of a dissolution promoting mixture, 0.5%-2% of a wetting agent and the balance of water; the dispersing agent comprises a hyperbranched polymer and a sodium naphthalene sulfonate improved polymer; the hyperbranched polymer takes a benzene ring as a center, hydrophobic groups and hydrophilic groups on a branched chain are randomly distributed, the hydrophilic groups of the branched chain comprise carboxylate and sulfonate, and the hydrophobic groups of the branched chain comprise alkane, ester and aryl. According to the invention, the hyperbranched polymer and the sodium naphthalene sulfonate improved polymer are mixed with the dispersing agent, so that the problem of abrupt change of ink viscosity can be avoided when the content of ink toner is relatively high, thereby obtaining the color paste with strong dispersion and high stability, and further obtaining the dispersed ink with good stability.
Owner:SERUDAN (HUBEI) IMAGE PIGMENT CO LTD

Flame-retardant cooling liquid and preparation method thereof, immersed energy storage device, data center and electric equipment

The invention relates to the technical field of energy storage safety, and particularly discloses flame-retardant cooling liquid, a preparation method of the flame-retardant cooling liquid, an immersed energy storage device, a data center and electric equipment. According to the present invention, the base oil is at least one of the liquid halogenated alkane containing 2-6 carbon atoms, the liquid halogenated olefin, the liquid halogenated ketone and the liquid halogenated cycloalkane containing 3-6 carbon atoms, such that the high biodegradability of the base oil is maintained, the system viscosity is effectively reduced, the heat dissipation performance is improved, the insulating property of the base oil is significantly improved, and the service life of the base oil is prolonged. Meanwhile, the flame retardance is further enhanced. Therefore, the heat management efficiency of the cooling liquid is remarkably improved while environmental protection and safety are considered, and the cooling liquid has a good application prospect.
Owner:TSINGHUA UNIVERSITY +2

Synthesis method of allyl phosphonic acid diester

The invention discloses a synthesis method of allyl phosphonic acid diester. According to the method, phosphorous acid diester and an allyl chloride compound are used as raw materials and react in the presence of a specific transition metal catalyst and alkali under the conditions of normal pressure and 45-60 DEG C to obtain the allyl phosphonic acid diester. The method has the advantages of mild reaction conditions, simple operation, high product yield (90-99%), no by-product, no generation of halogenated alkane gas and easy industrial production, and is suitable for the fields of polymer flame retardants, electronic materials, pesticide and medicine intermediates and the like.
Owner:SUZHOU LEAD BIOTECH CO LTD

Method for preparing alkane olefin by catalyzing microalgae pyrolysis through alkali modified molecular sieve

The invention provides a method for preparing alkane olefin by catalyzing microalgae pyrolysis through an alkali modified molecular sieve, and belongs to the field of biomass energy utilization. According to the method, the ZSM-5 molecular sieve raw powder is modified by adopting the alkaline solution, so that the pore structure of the ZSM-5 molecular sieve can be improved, the distribution of acidic sites can be optimized, the regulation and control of a microalgae pyrolytic reaction path can be realized under relatively mild conditions, the deoxidation reaction can be promoted, the content of oxygen-containing products can be reduced, and the generation of alkane olefin substances can be promoted; the aromatization reaction strength is reduced, and the selectivity of light hydrocarbons is improved, so that the content of alkanes and olefins in the pyrolysis bio-oil reaches 70% or above, and the quality of the pyrolysis bio-oil is remarkably improved. Results of the embodiment show that the pyrolysis bio-oil provided by the invention is subjected to gas chromatography-mass spectrometry detection, and the alkane-olefin peak area content is greater than 70%.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Micro-molecular alkane VOCs catalytic oxidation device and method capable of regenerating and desorbing

The invention discloses a micromolecular alkane VOCs catalytic oxidation device and method capable of regenerating and desorbing, and belongs to the technical field of VOCs control. The device adopts a U-shaped flue, and is sequentially provided with a high-temperature flue gas heat exchange module, an integral catalyst and a noble metal catalysis plate module along a flue gas flow. The method comprises the following steps: preheating inlet VOCs through high-temperature flue gas heat exchange, carrying out primary catalytic oxidation by using an integral catalyst, carrying out heat exchange and temperature regulation, and then entering a noble metal catalytic plate module for deep catalytic oxidation; and in-situ regeneration and catalytic activity recovery of the noble metal catalytic plate are realized in a microwave-assisted air regeneration manner. According to the invention, high-efficiency, stable and energy-saving removal of micromolecular alkane VOCs can be realized, and the problem of deactivation of a noble metal catalyst caused by carbon deposition and sintering is effectively solved.
Owner:ZHEJIANG UNIV

Catalytic method for converting alpha-olefin into internal olefin in alkane-olefin mixture and application

The invention discloses a catalytic method for converting alpha-olefin in an alkane-olefin mixture into internal olefin and application, raw materials and a solid acid catalyst are carried out in a fixed bed or a reaction kettle, the reaction temperature is 50-150 DEG C, the reaction pressure is 15-400 psi, and the reaction environment is an inert gas atmosphere; when the reaction is carried out on the fixed bed, the mass space velocity of the solid acid catalyst is 1h <-1 >-20h <-1 >; when the reaction is carried out in the reaction kettle, the conversion frequency of the raw materials is 5000 mol substrate mol acid site density <-1 > h <-1 > to 50000 mol substrate mol acid site density <-1 > h <-1 >; wherein the raw material is an alkane-alkene mixture; the solid acid catalyst comprises an active component and a carrier, wherein the carrier contains at least one inorganic oxide; the active component has a structure as shown in a formula (1) and / or a formula (2), in the formula (1) and the formula (2), R is alkyl or phenyl, and n is greater than or equal to 1. According to the catalysis method provided by the invention, the conversion rate of alpha-olefin can be increased, and the proportion of skeleton isomerization products and oligomers in internal olefin products can be reduced.
Owner:内蒙古伊泰煤炭股份有限公司

Full-bio-based multifunctional antibacterial nylon material as well as preparation method and application thereof

PendingCN120944103AAlkaneCarboxylic acid
The invention discloses a full-bio-based multifunctional antibacterial nylon material as well as a preparation method and application thereof, relates to the technical field of high-molecular polymers, and solves the problems that the preparation process of a nylon material in the prior art depends on petroleum resources, the function is single and the application scene is limited. The method comprises the following steps: reacting an aminocaprolactam solution with corresponding aldehyde / carboxylic acid / halogenated alkane, and purifying to obtain a cyclic lysine derivative monomer M; the preparation method comprises the following steps: mixing and heating a cyclic lysine derivative monomer M, an initiator and a catalyst, reacting, and purifying to obtain a nylon material PM; and carrying out quaternization reaction on the nylon PM solution and alkyl halide, and purifying to obtain the full-bio-based multifunctional nylon material P. The preparation method completely abandons the use of petroleum-based raw materials, realizes the multifunctional synergistic effect of antibacterial property, biocompatibility, antibacterial biofilm property, thermosensitivity and the like, and can be applied to the fields of antibacterial materials, biomedical materials, antibacterial biofilms and thermosensitivity materials.
Owner:CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES

Making catalysts for oxidative dehydrogenation

Methods for preparing catalysts for oxidative dehydrogenation (ODH) of alkanes such as ethane are provided. An exemplary method includes forming a slurry including metal oxides; one or more of a bismuth compound, an antimony compound, and a tellurium compound; a reducing agent; and water; and heating the slurry to form the catalyst. The metal oxides include an oxide of molybdenum and an oxide of vanadium. The bismuth compound includes bismuth oxide, bismuth hydroxide, or a bismuth carbonate. The antimony compound includes an oxide of antimony, an antimony acetate, or an antimony ethoxide. The tellurium compound includes tellurium dioxide. The reducing agent includes molybdenum dioxide and may further include vanadium dioxide. The methods use all inorganic reagents, with no build up COx pressure observed during the hydrothermal synthesis.
Owner:NOVA CHEM (INT) SA

System and method for preparing low-carbon olefin through carbon dioxide adsorption and in-situ oxidative dehydrogenation

The invention discloses a system and a method for preparing low-carbon olefin through carbon dioxide adsorption and in-situ oxidative dehydrogenation. The invention provides a system and a method for integrating carbon dioxide capture and in-situ oxidation low-carbon alkane (ethane / propane) dehydrogenation, a bifunctional material is composed of an adsorbent and a catalyst, and capture of carbon dioxide and in-situ oxidation low-carbon alkane dehydrogenation can be realized in the same reaction tower, so that the highest one-way carbon dioxide conversion rate can reach 100%, and the conversion rate of carbon dioxide can reach 100%. And meanwhile, the ethylene yield reaches 26%. According to the method, the problems of additional product separation and product gas recycling caused by low carbon dioxide conversion efficiency in the prior art are avoided, and effective heat management is realized, so that the process of integrating carbon dioxide capture and preparing low-carbon olefin by oxidizing low-carbon alkane has more economic advantages.
Owner:EAST CHINA UNIV OF SCI & TECH

Trichlorbacterium and application thereof in bioremediation of pollutants

The invention relates to the field of environmental microbial remediation, in particular to a strain of trichlorobacterium and application thereof in bioremediation of pollutants. According to the present invention, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, the bacillus subtilis is bacillus subtilis, and the bacillus subtilis is bacillus subtilis. The strain NB-12 obtained by the invention is a strain of self-synthesized cobalamin screened from river bottom sediments, is suitable for extensive industrial production and degrades a plurality of halogenated alkanes in the environment.
Owner:SHENYANG INST OF APPL ECOLOGY CHINESE ACAD OF SCI

A method for producing bio-jet fuel using ultra-low hydrogen oil

The application provides a continuous hydrogenation-isomerization method capable of meeting the treatment requirements of biological oils, especially waste oils, using a homogeneous hydrogenation process with strong adaptability to raw materials as a raw material pretreatment process, and matching a high-activity nanometer transition metal sulfide catalyst. On this basis, a catalytic distillation process is used for selective cracking of long-chain alkanes to improve the yield of medium and long-chain alkanes; an ultramicro flow hydrogen gas mixer and a reduced non-noble metal hydrogenation-isomerization catalyst are used to reduce the hydrogen / oil ratio and the energy consumption of the circulating hydrogen system, and to reduce the production cost of the catalyst, so as to finally realize efficient and low-carbon conversion of waste oils, and low-cost and high-selectivity preparation of biological aviation kerosene.
Owner:LONGYAN ZHUOYUE NEW ENERGY CO LTD +1

Nickel metal hydroisomerization catalyst as well as preparation method and application thereof

The invention provides a nickel metal hydroisomerization catalyst as well as a preparation method and application thereof. The catalyst comprises nickel, an alumina carrier and a molecular sieve, the nickel is loaded on the alumina carrier, and the content of the nickel in the catalyst is 1-10wt%; the molecular sieve is an SAPO molecular sieve. According to the invention, alumina is used as a carrier, non-noble metal nickel is loaded through a wet immersion method and is mixed with the molecular sieve to prepare the alkane isomerization catalyst, so that active metal with smaller particle size and higher dispersity can be provided, metal agglomeration at high temperature is avoided, and the utilization rate of metal is increased; the catalyst with excellent catalytic activity can be obtained only by loading low-content nickel metal, the catalyst has higher catalytic activity and selectivity, the obtained product contains more isomers, and the low-temperature fluidity of the product can be remarkably improved.
Owner:SHANGHAI ADVANCED RES INST CHINESE ACADEMY OF SCI

Synthesis method of nano magnesium metal and application of nano magnesium metal in hydrogen storage

The invention discloses a synthesis method of nano magnesium metal and application of the nano magnesium metal in hydrogen storage, and the synthesis method of the nano magnesium metal comprises the following steps: dissolving lithium metal and 4, 4-bis (tert-butylbiphenyl) into a polar organic solvent to obtain a 4, 4-bis (tert-butylbiphenyl) lithium solution, and then adding the 4, 4-bis (tert-butylbiphenyl) lithium solution into the polar organic solvent to obtain the nano magnesium metal. Adding the 1, 4-bis (tert-butylbiphenyl) lithium solution into a non-polar alkane organic solvent to obtain a mixed solution; adding anhydrous magnesium chloride into a polar organic solvent to obtain an anhydrous magnesium chloride organic solvent solution; and adding the anhydrous magnesium chloride organic solvent solution into the mixed solution, carrying out a reaction in an argon atmosphere, and carrying out post-treatment to obtain the nano magnesium metal, wherein the molar mass ratio of the 4, 4-bis (tert-butylbiphenyl) to the anhydrous magnesium chloride is (0.5-3): 1. The nano magnesium metal synthesized by the synthesis method has the advantages of high hydrogen storage capacity, low hydrogen absorption and desorption operation temperature and high hydrogen absorption and desorption speed.
Owner:ZHEJIANG UNIV

Non-noble metal long-chain alkane dehydrogenation catalyst as well as preparation method and application thereof

The present invention relates to a non-noble metal long-chain alkane dehydrogenation catalyst, which uses CeO2 and a transition metal M as main active components, and the mass percentage of the transition metal M is 0-30 wt%; wherein M is one or a combination of more of Fe, Co and Ni. Meanwhile, the invention also discloses a preparation method and application of the catalyst. The catalyst provided by the invention shows good dehydrogenation activity and stability in an inert atmosphere. An alternative solution which is low in cost, high in performance and easy to operate is provided for a long-chain alkane dehydrogenation process.
Owner:LANZHOU INSTITUTE OF CHEMICAL PHYSICS CHINESE ACADEMY OF SCIENCES

Method for catalyzing degradation of polyolefin mixed plastic by using molten salt

The invention discloses a method for catalyzing degradation of polyolefin mixed plastic by using molten salt. The catalyst is composed of gallium chloride or gallium chloride and other metal chlorides, has a low melting point, high fluidity and strong Lewis acidity, and can degrade polyethylene (PE), polypropylene (PP), polystyrene (PS) plastics and mixtures thereof at 70-170 DEG C under a solvent-free condition to obtain C4-C16 + alkane, olefin and aromatic hydrocarbon. The method is suitable for actual waste plastic resource recovery, and has the advantages of mild conditions, low energy consumption, product controllability and the like.
Owner:EAST CHINA NORMAL UNIV

Bimetal Ni-Pt / RFE hydroisomerization catalyst as well as preparation method and application thereof

The invention belongs to the field of petrochemical engineering, and discloses a bimetallic Ni-Pt / RFE hydroisomerization catalyst and a preparation method and application thereof. The preparation method comprises the following steps: dissolving a nickel precursor in water, stirring until clarification, and dropwise adding ammonia water to obtain a mixed solution 1; rFE is added into the mixed solution 1, the pH value is adjusted to be 9-11.5, suction filtration, washing and drying are conducted after stirring, and Ni / RFE is obtained; dissolving a platinum precursor in water, stirring until the solution is clear, and dropwise adding ammonia water to obtain a mixed solution 2; and adding the Ni / RFE into the mixed solution 2, adjusting the pH value to 9-11.5, stirring, and carrying out suction filtration, washing, drying and roasting to obtain the Ni-Pt / RFE. The method is simple and convenient to operate and mild in condition, the catalyst activity and the isomerization efficiency are remarkably improved through the synergistic effect of Ni and Pt, the catalyst preparation cost is greatly reduced while the use amount of precious metal is reduced, efficient conversion of long straight-chain alkane can be achieved, and the isomerization conversion rate of n-dodecane within 60 minutes can reach nearly 90%.
Owner:JIANGSU UNIV

Aqueous zinc ion battery electrolyte, preparation method thereof and zinc ion battery

The invention provides an aqueous zinc ion battery electrolyte, a preparation method thereof and a zinc ion battery, and belongs to the technical field of aqueous zinc ion batteries. The aqueous zinc ion battery electrolyte comprises an additive, an inorganic zinc salt and a solvent, the additive comprises at least one of trimethylamine substituted by 1-3 substituent groups, benzene and C3-C10 straight-chain alkane, and the substituent groups comprise phosphonic acid groups or phosphinic acid groups; the solvent comprises a sodium chloride aqueous solution. By adopting the additive with a specific structure and the solvent containing the sodium chloride aqueous solution, the cycle performance of the zinc negative electrode in the water-based zinc ion battery can be remarkably improved, and the service life of the water-based zinc ion battery is prolonged.
Owner:SONGSHAN LAKE MATERIALS LAB

System and method for directionally converting biomass into synthesis gas by full carbon through cascade energy supply and green hydrogen coupling

The invention discloses a cascade energy supply and green hydrogen coupling biomass all-carbon directional conversion synthesis gas system and method, and belongs to the technical field of biomass energy conversion. The system comprises a first-stage gasification furnace, a second-stage gasification furnace, a gas-solid separator, an alkane reforming device, a reverse water-gas shift device and a water electrolysis device. The method comprises the following steps: pyrolyzing a biomass raw material and a catalyst in a primary gasifier (500-700 DEG C) to generate semicoke and tar-containing fuel gas; carrying out catalytic co-gasification on the semicoke and tar-containing fuel gas in a secondary gasifier (800-900 DEG C), and realizing tar cracking and CH4 reforming by using a catalyst to obtain crude synthesis gas; after being subjected to high-temperature dust removal, the crude synthesis gas sequentially passes through a self-heating alkane reforming device (CH4lt; 1%) and a reverse water-gas shift device, and finally synthesis gas with the H2 / CO ratio of 2: 1 is produced, so that the chemical application requirements of methanol, Fischer-Tropsch synthesis and the like are completely met, the high energy consumption bottleneck of a traditional process is broken, and full-life-cycle negative carbon emission is achieved.
Owner:ENERGY RES INST OF SHANDONG ACAD OF SCI

Real-time porosity prediction method and system based on alkane gas and carbon isotope characteristics thereof and storage medium

The invention discloses a porosity real-time prediction method and system based on alkane gas and carbon isotope characteristics thereof and a storage medium, relates to the technical field of oil and gas reservoir development, and aims to solve the problem of insufficient precision in a heterogeneous reservoir due to neglect of dynamic characteristics of alkane gas carbon isotope in an existing method. The method is characterized by comprising the following steps: S100, collecting alkane gas concentration and carbon isotope data thereof in real time, and performing time-frequency decomposition on the data to obtain characteristic data on different time and frequency scales; s200, performing multi-scale feature extraction on the data to obtain multi-scale features; s300, performing feature fusion on the multi-scale features; s400, constructing a GNN network model, introducing an adaptive attention mechanism, residual connection, jump aggregation and time sequence dynamic fusion, constructing a graph structure by taking a reservoir unit as a node, and mapping a fusion feature to a graph node attribute; and S500, constructing a reservoir space structure based on the GNN network model, and combining physical constraint optimization to realize real-time prediction of the porosity.
Owner:JILIN UNIVERSITY

Preparation method of alpha, omega-diiodo perfluoroalkane

The invention provides a preparation method of alpha, omega-diiodo perfluoroalkane, and belongs to the technical field of iodo perfluoroalkane synthesis. The preparation method disclosed by the invention comprises the following steps: under a protective atmosphere, enabling a nano flower type magnesium fluoride catalyst, 1, 2-diiodo tetrafluoroethane and tetrafluoroethylene to react, so as to obtain 1, 4-diiodo perfluorobutane and 1, 6-diiodo perfluorohexane. The nano flower type magnesium fluoride catalyst has high specific surface area and abundant coordination unsaturated sites, can effectively activate reactant molecule bonding sites, and avoids the problems of side reaction and catalyst deactivation caused by free radical paths; by optimizing the pore structure and reaction conditions of the catalyst, efficient synergistic conversion of IPF-2 and TFE can be realized, and the selectivity and yield of IPF-4 and IPF-6 are remarkably improved. The method provided by the invention has the advantages of mild conditions, safe operation, adjustable product distribution and the like, and meets the requirements of industrial production on high-selectivity fluorine-containing bifunctional compounds.
Owner:ZHEJIANG NORMAL UNIV +1

Preparation method of low-temperature phase change microcapsule with high thermal conductivity and high durability

The application discloses a kind of high heat-conducting high endurance low-temperature phase change microcapsule preparation methods, comprising: step 1: using C7, C9 alkane preparation cryogenic phase change material emulsion;Step 2: using melamine resin prepolymer containing polyethylene glycol and hydrophobic silicon carbide powder containing nano silicon carbide preparation modified wall material prepolymer;Step 3: using cryogenic phase change material emulsion and modified wall material prepolymer preparation phase change microcapsule;Step 4: using silver mirror reaction to phase change microcapsule surface silver plating, obtain surface silver plating microcapsule.The low-temperature phase change microcapsule prepared, using C7, C9 low-temperature mixed alkane as microcapsule core material;Using melamine resin as microcapsule wall material, and wall material contains polyethylene glycol modified material, nano silicon carbide modified material to improve the toughness of microcapsule, thermal conductivity;Microcapsule surface silver plating to resist volatility, eliminate residual formaldehyde in wall material.The application solves the problem of low thermal conductivity and poor durability of cryogenic phase change material microcapsule.
Owner:NANJING TECH UNIV

Polyether base oil as well as preparation method and application thereof

The invention provides polyether base oil and a preparation method and application thereof.According to the polyether base oil, a melt polycondensation method is adopted, a diester group-COO-R-COO-is introduced into a molecular structure through hydroxyl groups at the two ends of polyalkylene oxide, a polyether ester molecular chain with ether bonds and diester bonds distributed alternately is formed, and the polyether base oil is prepared. Then, carboxyl at the end group of a molecular chain is further subjected to an end-capping reaction with an amine compound, a unique amine double-end-capped polyether ester structure is obtained, and the polyether base oil has excellent viscosity-temperature performance, oxidation resistance, anti-rust performance and anti-wear and anti-friction performance.
Owner:PETROCHINA CO LTD