3175 results about "Polycarbonate" patented technology

The invention relates to the technical field of films, in particular to a flexible film special for a handwriting board and a preparation method of the flexible film. The flexible film is obtained by coating a release film with coating slurry and carrying out thermocuring, wherein the coating slurry contains modified polyurethane, a flatting agent, a defoaming agent and ethyl acetate. According to the modified polyurethane, polycarbonate diol, isophorone diisocyanate and other raw materials are subjected to a reaction, and a nano particle chain extender containing disulfide bonds is added. The nano particle chain extender containing disulfide bonds is prepared by modifying nano silicon dioxide and grafting cystamine dihydrochloride and diamino polyethylene glycol. Through nanoparticle surface modification and dynamic disulfide bond network construction, molecular-level coupling of a rigid reinforced phase and a flexible substrate, inhibition of nanoparticle aggregation and balance of strength and toughness are realized, the dynamic disulfide bond network can self-repair microcracks, and a high-quality special flexible film solution is provided for a high-performance handwriting board.

The invention provides a needle-flame-resistant flame-retardant polycarbonate composition and a preparation method thereof, and relates to the technical field of flame-retardant polycarbonate materials. The needle-flame-resistant flame-retardant polycarbonate composition is prepared from the following raw material components in parts by weight: 100 parts of polycarbonate and 1 to 15 parts of hyperbranched flame retardant, the hyperbranched flame retardant is obtained by reaction of reaction raw materials containing double-terminal hydroxyl polysiloxane and phosphorus oxychloride. The hyperbranched flame retardant is added into polycarbonate, the characteristics of polysiloxane and organophosphate are combined, and the polycarbonate material has good flame retardance and meanwhile achieves needle flame resistance flame retardance and UL-94 vertical combustion V-0 grade.

The invention discloses a therapeutic nano-vesicle preparation rich in mitochondrial functional protein, a preparation method of the therapeutic nano-vesicle preparation and application of the therapeutic nano-vesicle preparation in treatment of radioactive skin injury. The preparation method comprises the following steps: culturing, amplifying and cleaning umbilical cord mesenchymal stem cells, dispersing the umbilical cord mesenchymal stem cells in a suspension, mechanically extruding the umbilical cord mesenchymal stem cells into a crude solution through a multistage aperture polycarbonate membrane, and centrifuging, concentrating and purifying the crude solution to obtain the preparation. The preparation has the remarkable advantages that local administration can be realized, inflammation can be quickly inhibited, oxidative stress is reduced, and a repair pathway is activated, so that the preparation is suitable for treating acute radioactive skin injury; the preparation method is easy to standardize and scale, high in stability and convenient for emergency storage and delivery, and avoids the defects of cell therapy; a plurality of targets such as immune inflammation, oxidative stress and the like can be synergistically regulated, the biological effect of hUMSCs is simulated and partially replaced, and the limitation caused by the cell survival rate and the microenvironment dependency is avoided; the key function of hUMSCs is covered in function, and the clinical feasibility, safety and emergency suitability of the application level are higher.

The invention discloses a batch processing technology of micro-fluidic chips, and relates to the technical field of chip processing. The method comprises the following steps: firstly, providing at least two layers of polymer coiled materials, namely a first coiled material for forming a micro-channel structure and a second coiled material for closing a micro-channel, the coiled materials are continuous coiled materials selected from polyethylene glycol terephthalate (PET), cycloolefin polymer (COP), polycarbonate (PC) or polymethyl methacrylate (PMMA), and the coiled materials are continuous coiled materials selected from polyethylene glycol terephthalate (PET), cycloolefin polymer (COP), polycarbonate (PC) or polymethyl methacrylate (PMMA); the thickness of the coiled material is 50-500 microns; secondly, carrying out continuous compression molding processing on the surface of the first coiled material through a roll-to-roll processing platform; through a roll-to-roll continuous process, micro-channel mold pressing, functional deposition, precise alignment bonding and online cutting are integrated, high-efficiency, high-consistency and high-integration-level batch manufacturing of the micro-fluidic chip is realized, and manual intervention and production cost are remarkably reduced.

The invention relates to the technical field of high polymer materials, and particularly discloses a fluoride-free halogen-free flame-retardant polycarbonate material and a preparation method and application thereof.The fluoride-free halogen-free flame-retardant polycarbonate material is prepared from, by weight, 70-90 parts of polycarbonate resin, 8-15 parts of phosphorus-nitrogen flame retardant and 3-8 parts of silicon flame-retardant synergist, the composite material is prepared from the following raw materials in parts by weight: 20-30 parts of polypropylene, 2-5 parts of nano reinforcing filler, 0.1-0.5 part of hindered phenol antioxidant, 0.1-0.5 part of phosphite ester antioxidant and 0.1-0.5 part of pentaerythritol stearate. Through the synergistic effect of the composite flame-retardant system and the nanofiller, high flame retardance (UL94 V-0 level, 1.5 mm thickness), high heat resistance (the heat distortion temperature is greater than or equal to 130 DEG C) and excellent mechanical property are realized, the control is easy, the processing is stable, good balance of flame retardance and mechanical property is achieved on the premise of environmental protection, and the composite flame-retardant material is suitable for the fields of high-end household appliances and consumer electronics.

The invention discloses a polycarbonate / styrene composite material as well as a preparation method and application thereof, and belongs to the field of high polymer materials. The composite material is prepared from the following raw materials: polycarbonate, silicon copolymerized polycarbonate, styrene resin, a halogen-free flame retardant, a polynitroxide free radical compound, an anti-dripping agent, an antioxidant and a lubricant. The molecular structure of the multi-nitroxide free radical compound contains at least two nitroxide free radicals, and the molecular chain of the multi-nitroxide free radical compound has a flexible carbon chain structure. The polycarbonate / styrene composite material provided by the invention can realize 0.5-1.0 mm ultrathin halogen-free flame retardance under the combined action of the halogen-free flame retardant and the multi-nitroxide free radical compound, and can meet the molding of ultrathin parts, and the prepared product has excellent damp-heat aging resistance and weather resistance, and is suitable for industrial production. The shell can be widely applied to new energy battery shells, power bank shells and the like.

The invention provides an antistatic talcum powder and graphene composite reinforced material and an in-situ polymerization process thereof, and belongs to the technical field of polymer composite materials. According to the antistatic talcum powder and graphene composite reinforced material and the in-situ polymerization process thereof, the antistatic talcum powder and graphene composite reinforced material is prepared from the following raw materials in parts by weight: 100 parts of matrix resin, 5-30 parts of modified talcum powder, 0.5-5 parts of functionalized graphene and 0.1-2 parts of an antistatic synergist, the modified talcum powder is subjected to surface treatment by a silane coupling agent, the particle size range is 1-10 [mu] m, and the functionalized graphene is graphene oxide or reduced graphene oxide. Through the synergistic effect of the silane coupling agent modified talcum powder and the functionalized graphene and in combination with the ionic liquid antistatic agent, the surface resistance of the material is remarkably reduced. Nanoscale dispersion is realized by adopting an in-situ polymerization process, and the method is suitable for the field of high-performance engineering plastics.

The invention provides a diaphragm and a preparation method thereof, and a lithium ion battery, the diaphragm comprises a base membrane, a composite ceramic coating and an interface layer, the composite ceramic coating contains inorganic ceramic particles and organic microcapsule particles, the organic microcapsule particles comprise a core material with a melting point range of 55-65 DEG C and a polymer shell coating the surface of the core material, and the polymer shell is coated on the surface of the core material. The polymer shell is selected from at least one of polyurethane, polyurea, polyamide and polycarbonate, the interface layer is formed by depositing an interface modification polymer on the surface of the composite ceramic coating, and the interface modification polymer is selected from at least one of polycatechol derivatives, polyaniline, polyvinyl pyridine, polyacrylic acid and polyacrylamide. The core material in the organic microcapsule particles is melted when heated to trigger hole closing at the initial stage of thermal runaway at 60-80 DEG C, the hole closing rate can reach 92%, the hole closing response time is shortened by 30%, and the porous structure of the interface layer can enhance the liquid absorption rate.

The invention belongs to the technical field of polyurethane resin, and provides polyurethane resin, polyurethane synthetic leather and a preparation method and application thereof. The preparation raw materials of the polyurethane resin comprise the following components: 9%-23% of first bio-based polyol, 3%-18% of a polyurethane intermediate, 0.005%-0.02% of a first antioxidant, 0.001%-0.003% of a first catalyst, 3-6% of first isocyanate, 0.5%-2% of a first chain extender, 0.01%-0.05% of a first terminator, 0.01%-0.05% of a first anti-visbreaking aid, 0.7%-2.2% of an astringent aid, 0.5%-3% of a polyether aid and 50%-70% of a first solvent. The first bio-based polyol includes a bio-based polytrimethylene ether glycol and a bio-based polycarbonate glycol. The preparation raw materials are all derived from bio-based materials, and the polyurethane synthetic leather is soft in texture, good in astringent feeling and excellent in strength and hydrolysis resistance.

The invention discloses a flame-retardant reinforced polycarbonate composite material and a preparation method thereof, and belongs to the technical field of polycarbonate composites.The flame-retardant reinforced polycarbonate composite material comprises 70%-90% of polycarbonate resin, the polycarbonate resin is aromatic polycarbonate with the viscosity average molecular weight ranging from 20000 to 35000; the glass fiber is alkali-free chopped E glass fiber, and the surface of the glass fiber is treated by an amino silane coupling agent; the flame retardant comprises 5-15% of a phosphorus-nitrogen-silicon composite flame retardant, the composite flame retardant is a synergistic system formed by physically premixing a phosphate ester compound, a nitrogen charring agent and a silicone polymer, and the phosphate ester compound plays a role in gas-phase flame retardance and partial condensed-phase flame retardance during combustion. By adopting a phosphorus-nitrogen-silicon composite flame-retardant synergistic system, high flame-retardant efficiency is realized under the condition of low additive amount, the halogen-free and environment-friendly effects are realized, and the environmental and health hidden dangers of the traditional brominated flame retardant are overcome.

The invention discloses a phosphorus-nitrogen-silicon synergistic flame retardant containing a POSS (Polyhedral Oligomeric Silsesquioxane) structure and a preparation method of the phosphorus-nitrogen-silicon synergistic flame retardant. The flame retardant integrates three elements of phosphorus, nitrogen and silicon, and can generate a better flame-retardant synergistic effect; meanwhile, the POSS structure and the phenyl structure in the flame retardant endow the flame retardant with good heat resistance and good compatibility with a matrix material polycarbonate (PC), and the flame retardant is suitable for high-temperature processing conditions. In addition, the preparation method of the flame retardant is simple in process, the yield reaches up to 85% or above, and industrial production is easy to achieve.

The invention relates to the technical field of preparation of water-based functional polymer materials, in particular to a preparation method of water-based polyurethane slurry for sports shoe leather, which comprises the following steps: mixing polycarbonate diol, core-shell structure graphene oxide-polycaprolactone hybrid nanoparticles and dimethylolpropionic acid, and carrying out vacuum dehydration treatment, isophorone diisocyanate is added for a reaction, and a polyurethane prepolymer is obtained; after the polyurethane prepolymer is cooled, triethylamine is added for a neutralization reaction; under violent stirring, adding a mixture composed of 1, 4-butanediol and a hyperbranched organosilicon amino chain extender serving as a flexible functional core into the neutralized prepolymer to carry out chain extension reaction, and adding deionized water to carry out reversed-phase emulsification, so as to obtain a waterborne polyurethane emulsion; standing and curing the waterborne polyurethane emulsion at a preset temperature to obtain waterborne polyurethane slurry; the finally prepared shoe leather material has excellent wear resistance and excellent low-temperature bending durability.

A polycarbonate resin including a unit of Chemical Formula 1 and a unit of Chemical Formula 2, a method for preparing the same, a polycarbonate resin composition including the same, and a molded article are disclosed herein:Ar1 and Ar2 are independently an aryl group, or a heteroaryl group, R1 is hydrogen, deuterium, a halogen group, a cyano group, an alkyl group, a cycloalkyl group, an alkoxy group, a silyl group, an aryl group, or a heteroaryl group, R2 and R3 are different from each other, r1 is 1 or 2, r2 and r3 are each an integer from 1 to 4, L1 and L2 are independently an arylene group, X1 to X8 are independently O or S, Z1 to Z4 are independently an alkylene group, or a cycloalkylene group, and a, b, c and d are independently an integer from 1 to 10.

The invention discloses a temperature-resistant, flame-retardant and anti-corrosion composite material for a building as well as a preparation method and application of the composite material, and belongs to the technical field of polycarbonate building materials. The composite material is prepared from the following components in parts by weight: 60 to 80 parts of polycarbonate, 8 to 10 parts of a dispersing agent, 10 to 20 parts of epoxidized silicone rubber, 1 to 5 parts of benzotriazole, 1 to 5 parts of a flame retardant, 3 to 5 parts of a compatible aid, 0.3 to 0.5 part of an antioxidant, 0.2 to 0.5 part of a light stabilizer, 0.15 to 0.3 part of an anti-dripping agent and 0.2 to 0.4 part of a catalyst. According to the composite material, polycarbonate is used as a base material, the flame retardance and the corrosion resistance of the composite material can be remarkably improved by adding the epoxidized silicone rubber and the benzotriazole, the temperature resistance of the material is not obviously reduced, and the service life of the material is prolonged.

The invention provides a method 100 for separating different polymeric spectacle lens materials in a mixture comprising at least two different polymeric spectacle lens materials by separating at least one polymeric spectacle lens material of the at least two different polymeric spectacle lens materials by using their different physical behavior and / or chemical behavior, wherein the at least two different polymeric spectacle lens materials are selected from the group consisting of polyallyl carbonate, polyurea, polyurethane, polyurethane / polyurea, polycarbonate, polyepisulfide and polythiourethane. The invention further provides a method for separating at least one polythiourethane from a mixture comprising at least two different polythiourethanes by thiolysis.

The invention belongs to the technical field of lithium metal batteries, and relates to preparation of an ultrathin polymer electrolyte with a wide electrochemical window and application of the ultrathin polymer electrolyte in a solid-state lithium metal battery, a preparation method comprises the following steps: firstly, coating a substrate with polymer slurry, and then soaking, stripping and drying to obtain a porous membrane matrix; the preparation method comprises the following steps: mixing an electrolyte, a conductive lithium salt, a cross-linking agent, 4-fluorine-alpha-methyl styrene and an initiator to obtain an electrolyte precursor solution; and then supporting the electrolyte precursor liquid on the porous membrane substrate, and carrying out in-situ polymerization and curing to obtain the polymer electrolyte. Compared with the prior art, the thickness of the polycarbonate solid electrolyte is 7.8 microns, and the polycarbonate solid electrolyte shows high room-temperature ionic conductivity, a wide electrochemical window and excellent dendritic crystal resistance. And the corresponding 4.5 V high-voltage LiLCO solid-state battery can stably circulate for 1500 circles at room temperature. The electrolyte is ultrathin, the preparation process is simple, the scale is easy to enlarge, and the electrolyte shows a good practical application prospect.

The invention relates to the technical field of injection molding processes, in particular to an injection molding process for an ultrathin capacitor shell, which comprises the following steps: premixing ABS (Acrylonitrile Butadiene Styrene), polycarbonate and a reinforcing aid, and carrying out melt blending granulation on the obtained premix to obtain reinforced particles; the multi-cavity mold is preheated in advance; and the reinforced particles are fed into a screw extruder to be molten, then the molten reinforced particles are injected into a preheated multi-cavity mold, pressure maintaining treatment is carried out, then cooling and demolding are carried out, and the capacitor shell is obtained. The MBS and the modified glass fiber are added into the ABS / polycarbonate composite material to prepare the reinforced particles, so that the mechanical property of a product prepared from the reinforced particles is greatly improved, the product has good rigidity and toughness, and the tensile strength, bending strength and impact strength of the capacitor shell can be improved when the product is applied to the capacitor shell, and the service life of the capacitor shell is prolonged. Therefore, the shell of the capacitor can be made thinner on the premise of ensuring the quality, and the miniaturization of the capacitor is facilitated.

The invention provides a carbon dioxide based polycarbonate-polyester-polyether block copolymerized diol, a star-shaped carbon dioxide based polycarbonate-polyester-polyether copolymerized polyol, and a star-shaped carbon dioxide based polycarbonate-polyester-polyether copolymerized polyol with a low molecular weight. By adjusting the specific polyether content, chain segment distribution and molecular weight, the three polyols can be used for preparing polyurethane elastomers, soft foam and hard foam respectively. The low-temperature brittleness of the polyurethane material is improved while the elasticity of the polyurethane material is improved.

The invention belongs to the technical field of resin particle production, and particularly relates to polycarbonate resin particle manufacturing equipment and a manufacturing method thereof.The polycarbonate resin particle manufacturing equipment comprises a box body, a feeding hopper is arranged at the top of the box body, a discharging pipe is arranged at the bottom of the box body, a sieve plate is arranged in the box body, and a plurality of evenly-distributed springs are fixed to the two ends of the sieve plate respectively; the other ends of the springs are fixed to the corresponding inner walls of the box body respectively, a vibration detection module and a vibration control module are arranged on the sieve plate, a flow adjusting valve and a feeding speed sensor are arranged in the feeding hopper, a screening detection module is further arranged in the box body, and a central processing module is fixed to the outer wall of one side of the box body. Through cooperative work of all the modules of the intelligent equipment, key parameters in the screening process can be monitored and adjusted in real time, and the screening efficiency is effectively improved.

An automotive sun visor is disclosed with enhanced functionality and aesthetic appeal for vehicle interiors. The sun visor includes a frame with a rotary detent mechanism housed within a hinge tube, facilitating precise rotational movement and secure positioning. The frame is constructed from two heat-welded plastic frame halves, eliminating the need for an expanded polypropylene layer, and reducing thickness. The sun visor features an integrated mirror made from advanced materials such as gorilla glass or polycarbonate, and LED lamps for illumination. The rotary detent mechanism comprises a detent bar, detent springs, and a detent subframe, providing a clicking action for tactile feedback when the sun visor reaches a stowed position. The sun visor's design allows for axial adjustment and pivotal movement between stowed and operational positions, contributing to safety and comfort within the vehicle.

The invention discloses an unmanned underwater vehicle floating material fixing structure, and relates to the technical field of underwater vehicle buoyancy materials. In order to solve the problems that in the prior art, a buoyancy material of an underwater vehicle is generally fixedly connected with the vehicle through a bolt, a polycarbonate protective layer is sprayed outside a hollow glass bead floating material, the floating material is easily damaged by replacing the buoyancy material and disassembling the bolt in the later period, and the buoyancy material is relatively fragile and cannot be damaged. The floating material is abraded due to repeated disassembly, and the polycarbonate protective layer is easy to fall off after long time, and the like. The device comprises a floating material, a screw sleeve, a nut sleeve and a protective layer, the floating material is arranged in an aircraft cabin composed of a framework and a non-pressure-resistant shell, a bolt through hole is machined in the floating material, a screw sleeve and a nut sleeve are embedded in the bolt through hole, and the outer portion of the floating material is integrally wrapped with a protective layer. The method is used for mounting and fixing the floating material of the unmanned underwater vehicle.

The invention relates to the technical field of macromolecules, in particular to a ceramic flame-retardant PC / ABS alloy material and a preparation method thereof. Comprising the following raw materials in parts by weight: 55-65 parts of polycarbonate, 30-40 parts of an acrylonitrile-butadiene-styrene copolymer, 0.1-1 part of a compatilizer, 0.1-1 part of a flexibilizer, 1-10 parts of ceramic powder, 3-8 parts of an inorganic composite nano filler, 1-10 parts of a flame retardant, 0.1-1 part of a silane coupling agent and 0.1-0.5 part of an antioxidant. The preparation method of the ceramic flame-retardant composite material mainly comprises the following steps: drying the raw materials, uniformly mixing the raw materials, processing and extruding, and carrying out injection molding, and by adopting the synergistic effect of the ceramic powder and the flame retardant, the PC / ABS alloy material is endowed with excellent flame retardance while good mechanical properties of the PC / ABS alloy material are ensured.

The invention relates to an interfacial polycondensation tubular reactor for preparing polycarbonate, which is characterized in that a U-shaped structure is adopted, a spiral turbulent flow device is arranged in a straight pipe section, and a high-viscosity melt is disturbed, laminar flow is eliminated and mixing is enhanced in an active or passive mode; a multi-stage independent temperature control module is arranged outside, so that the temperature of each reaction section is accurately regulated and controlled. The inlet, the outlet and the temperature control interface of the reactor adopt high-temperature-resistant and corrosion-resistant sealing design, and U-shaped modular flange connection is convenient for disassembly, assembly, cleaning and continuous expansion. The design solves the problems of non-uniform heat transfer and material residue of a traditional horizontal disc reactor, poor flow distribution of a tubular reactor and the like, and has the following advantages: the melt flow uniformity is improved, and local overheating and excessive polycondensation are avoided; the reaction efficiency and molecular weight distribution are optimized through segmented temperature control; the structure is compact without dead angles, the side reaction and inner wall corrosion risks are reduced, and the device is suitable for efficient continuous synthesis of polycarbonate.

Disclosed in the present invention are a flame-retardant PC / ABS composition with a fiber point effect, a preparation method therefor, and a use thereof. The flame-retardant PC / ABS composition with the fiber point effect according to the present invention comprises the following components: a polycarbonate, an ABS resin, a flame retardant, a high-temperature-resistant fiber point, and an anti-dripping agent, wherein the high-temperature-resistant fiber point is a regenerated cellulose fiber having a melting point of greater than or equal to 300ºC. In the flame-retardant PC / ABS composition with the fiber point effect according to the present invention, the high-temperature-resistant fiber point is used instead of a conventional carbon fiber- or glass fiber-reinforced conventional material, so that when the PC / ABS composition is combusted and contracted under heat, the anti-dripping agent can contract and gather at the high-temperature-resistant fiber point serving as a node to greatly slow down the perforation rate, and a carbon layer structure with a star-net-shaped dense distribution can be formed to isolate flame and heat, thus significantly improving flame-retardant properties. Moreover, the impact properties of the PC / ABS composition can also be better maintained, and the surface of the PC / ABS composition has a point-like aesthetic appearance effect similar to that of paint spraying.

The invention relates to the technical field of PU synthetic leather, and discloses flame-retardant PU synthetic leather, which comprises a base layer, a flame-retardant middle layer and a surface functional layer, the flame-retardant middle layer is prepared by mixing modified PU resin, a composite flame retardant, a synergist and a cross-linking agent, the composite flame retardant is prepared by compounding an organic phosphorus-nitrogen flame retardant and nano magnesium hydroxide according to a mass ratio of 3: 1-5: 1, and the surface functional layer is prepared by mixing modified PU resin, a composite flame retardant, a synergist and a cross-linking agent. The synergist is modified montmorillonite, the surface functional layer is a blend of fluorine-containing polyurethane resin and flame-retardant silicone oil, and the three-layer structure is integrally formed through a hot melting compounding process. The modified PU resin is prepared from polycarbonate diol, isophorone diisocyanate and a chain extender through a reaction. Three-dimensional flame-retardant protection from inside to outside can be achieved through the collaborative design of the base layer flame-retardant pretreatment layer, the flame-retardant middle layer and the surface functional layer, a finished product can reach a high flame-retardant grade, combustion spreading is effectively inhibited, release of smoke and toxic gas is reduced, and the problems that traditional PU synthetic leather is poor in flame retardance and prone to melting and dripping are solved.

The present invention provides a halogen-free flame-retardant multi-color anti-static PC composite material having high fluidity. The composite material comprises the following components in parts by weight: 70-93.4 parts of polycarbonate (PC), 1-10 parts of a toughening agent, 0.5-10 parts of an anti-static agent, 5-20 parts of a flame retardant, 0.05-2 parts of an anti-dripping agent, and 0.05-2 parts of an antioxidant. The present invention has the following beneficial effects: the composite material of the present invention does not contain any dangerous halogen compounds, and therefore the risk of secondary pollution during the recycling thereof can be reduced, environmental protection is achieved, and the anti-static ability of the composite material is improved; moreover, the color can be customized on the basis of product requirements, thereby meeting the market demand for colorful products; and the composite material has good flame retardancy and fluidity.

The invention relates to the technical field of PC alloys, in particular to an impact-resistant flame-retardant PC alloy with melt flowability and a preparation method of the impact-resistant flame-retardant PC alloy with melt flowability, and the impact-resistant flame-retardant PC alloy with melt flowability comprises the following components in parts by mass: 60-70 parts of PC resin; 30 to 40 parts of ABS resin; 6-10 parts of a core-shell flame retardant; 5-8 parts of a toughening agent; 0.5 to 1.0 part of a compatilizer; 0.3 to 0.5 part of an antioxidant; 1.0 to 1.5 parts of other auxiliary agents; the core-shell flame retardant comprises nano SiO2 loaded with sulfonate, low-molecular-weight PC (polycarbonate) and epoxy polysiloxane in sequence from inside to outside, wherein the weight-average molecular weight of the low-molecular-weight PC is 5000-8000; the toughening agent is prepared by mixing an organic silicon toughening agent, MBS and hydrogenated SBS; the serious negative influence of the existing flame retardant on the mechanical property and the processability of the PC / ABS alloy is overcome, so that the material meets the UL94 V0 level, and meanwhile, the balance optimization among the properties is realized.

The invention relates to the technical field of flame-retardant materials, and provides a polysiloxane-based flame retardant, a preparation method thereof and a polycarbonate composite flame-retardant material.The polysiloxane-based flame retardant comprises a structure shown in the formula (I), a structure shown in the formula (II) and a structure shown in the formula (III); the invention further provides a preparation method and application of the polysiloxane-based flame retardant. The polysiloxane-based flame retardant provided by the invention has the advantages of high flame-retardant efficiency, low addition amount and small influence on transparency and mechanical properties, and experimental results show that the polycarbonate composite material added with 1wt% of the polysiloxane-based flame retardant can reach UL94 V-0-level flame retardance of a sample with the thickness of 1.6 mm, the limit oxygen index LOI is improved to 36.4% from 26.6% of pure PC, and the flame retardance of the polycarbonate composite material is greatly improved. The transparency and the mechanical property are basically unchanged.

The invention relates to the technical field of polycarbonate ASA materials, and discloses an ASA composite material, a preparation method and application of the ASA composite material in an electric vehicle charging pile shell. Polycarbonate, ASA acrylonitrile-styrene-acrylate copolymer, poly (acrylonitrile-acrylate benzyl carbonate), an antioxidant and a processing aid are mixed and subjected to melt extrusion; the ASA composite material is obtained. Poly (acrylonitrile-acrylate benzyl carbonate) contains a carbonate group which is the same as that of polycarbonate, the polycarbonate and the poly (acrylonitrile-acrylate benzyl carbonate) have good compatibility, and contain polyacrylonitrile and polyacrylate block molecular chains, and the side chain contains a benzene ring structure which is similar to the structure of an ASA acrylonitrile-styrene-acrylate copolymer, so that the effect of compatibilizing the polycarbonate and the ASA is achieved; therefore, the material has higher impact strength, tensile strength and elongation at break.

The invention belongs to the technical field of polymer composite materials, and particularly relates to a polycarbonate modified composite material as well as a preparation method and application thereof, and the polycarbonate modified composite material comprises 60-85 parts of a PC base material, 10-30 parts of a bio-based monomer, 1-8 parts of surface modified nano cellulose and 0.1-2 parts of a transesterification catalyst. According to the polycarbonate modified composite material as well as the preparation method and the application thereof provided by the invention, chemical bonding of a bio-based monomer and a PC main chain is realized through transesterification, phase separation is avoided, and the core pain point of traditional blending modification is solved; the biodegradation rate is increased by 30% or above compared with pure PC, and meanwhile, the excellent mechanical properties (the tensile strength is larger than or equal to 60 MPa, and the notch impact strength is larger than or equal to 5 kJ / m) of PC are reserved; the melt flow rate is increased by more than 25%, the processing energy consumption is reduced, and the application scene is widened; the carboxylic acid modified nano cellulose and the block copolymer form a synergistic network, so that the mechanical property, the thermal stability and the degradation uniformity are synchronously improved.