1655 results about "Polycarbonate" patented technology

The invention belongs to the technical field of polyurethane resin, and provides polyurethane resin, polyurethane synthetic leather and a preparation method and application thereof. The preparation raw materials of the polyurethane resin comprise the following components: 9%-23% of first bio-based polyol, 3%-18% of a polyurethane intermediate, 0.005%-0.02% of a first antioxidant, 0.001%-0.003% of a first catalyst, 3-6% of first isocyanate, 0.5%-2% of a first chain extender, 0.01%-0.05% of a first terminator, 0.01%-0.05% of a first anti-visbreaking aid, 0.7%-2.2% of an astringent aid, 0.5%-3% of a polyether aid and 50%-70% of a first solvent. The first bio-based polyol includes a bio-based polytrimethylene ether glycol and a bio-based polycarbonate glycol. The preparation raw materials are all derived from bio-based materials, and the polyurethane synthetic leather is soft in texture, good in astringent feeling and excellent in strength and hydrolysis resistance.

The invention discloses a flame-retardant reinforced polycarbonate composite material and a preparation method thereof, and belongs to the technical field of polycarbonate composites.The flame-retardant reinforced polycarbonate composite material comprises 70%-90% of polycarbonate resin, the polycarbonate resin is aromatic polycarbonate with the viscosity average molecular weight ranging from 20000 to 35000; the glass fiber is alkali-free chopped E glass fiber, and the surface of the glass fiber is treated by an amino silane coupling agent; the flame retardant comprises 5-15% of a phosphorus-nitrogen-silicon composite flame retardant, the composite flame retardant is a synergistic system formed by physically premixing a phosphate ester compound, a nitrogen charring agent and a silicone polymer, and the phosphate ester compound plays a role in gas-phase flame retardance and partial condensed-phase flame retardance during combustion. By adopting a phosphorus-nitrogen-silicon composite flame-retardant synergistic system, high flame-retardant efficiency is realized under the condition of low additive amount, the halogen-free and environment-friendly effects are realized, and the environmental and health hidden dangers of the traditional brominated flame retardant are overcome.

The invention discloses a phosphorus-nitrogen-silicon synergistic flame retardant containing a POSS (Polyhedral Oligomeric Silsesquioxane) structure and a preparation method of the phosphorus-nitrogen-silicon synergistic flame retardant. The flame retardant integrates three elements of phosphorus, nitrogen and silicon, and can generate a better flame-retardant synergistic effect; meanwhile, the POSS structure and the phenyl structure in the flame retardant endow the flame retardant with good heat resistance and good compatibility with a matrix material polycarbonate (PC), and the flame retardant is suitable for high-temperature processing conditions. In addition, the preparation method of the flame retardant is simple in process, the yield reaches up to 85% or above, and industrial production is easy to achieve.

The invention provides a method 100 for separating different polymeric spectacle lens materials in a mixture comprising at least two different polymeric spectacle lens materials by separating at least one polymeric spectacle lens material of the at least two different polymeric spectacle lens materials by using their different physical behavior and / or chemical behavior, wherein the at least two different polymeric spectacle lens materials are selected from the group consisting of polyallyl carbonate, polyurea, polyurethane, polyurethane / polyurea, polycarbonate, polyepisulfide and polythiourethane. The invention further provides a method for separating at least one polythiourethane from a mixture comprising at least two different polythiourethanes by thiolysis.

The invention provides a carbon dioxide based polycarbonate-polyester-polyether block copolymerized diol, a star-shaped carbon dioxide based polycarbonate-polyester-polyether copolymerized polyol, and a star-shaped carbon dioxide based polycarbonate-polyester-polyether copolymerized polyol with a low molecular weight. By adjusting the specific polyether content, chain segment distribution and molecular weight, the three polyols can be used for preparing polyurethane elastomers, soft foam and hard foam respectively. The low-temperature brittleness of the polyurethane material is improved while the elasticity of the polyurethane material is improved.

The invention relates to the technical field of macromolecules, in particular to a ceramic flame-retardant PC / ABS alloy material and a preparation method thereof. Comprising the following raw materials in parts by weight: 55-65 parts of polycarbonate, 30-40 parts of an acrylonitrile-butadiene-styrene copolymer, 0.1-1 part of a compatilizer, 0.1-1 part of a flexibilizer, 1-10 parts of ceramic powder, 3-8 parts of an inorganic composite nano filler, 1-10 parts of a flame retardant, 0.1-1 part of a silane coupling agent and 0.1-0.5 part of an antioxidant. The preparation method of the ceramic flame-retardant composite material mainly comprises the following steps: drying the raw materials, uniformly mixing the raw materials, processing and extruding, and carrying out injection molding, and by adopting the synergistic effect of the ceramic powder and the flame retardant, the PC / ABS alloy material is endowed with excellent flame retardance while good mechanical properties of the PC / ABS alloy material are ensured.

The invention belongs to the technical field of polymer composite materials, and particularly relates to a polycarbonate modified composite material as well as a preparation method and application thereof, and the polycarbonate modified composite material comprises 60-85 parts of a PC base material, 10-30 parts of a bio-based monomer, 1-8 parts of surface modified nano cellulose and 0.1-2 parts of a transesterification catalyst. According to the polycarbonate modified composite material as well as the preparation method and the application thereof provided by the invention, chemical bonding of a bio-based monomer and a PC main chain is realized through transesterification, phase separation is avoided, and the core pain point of traditional blending modification is solved; the biodegradation rate is increased by 30% or above compared with pure PC, and meanwhile, the excellent mechanical properties (the tensile strength is larger than or equal to 60 MPa, and the notch impact strength is larger than or equal to 5 kJ / m) of PC are reserved; the melt flow rate is increased by more than 25%, the processing energy consumption is reduced, and the application scene is widened; the carboxylic acid modified nano cellulose and the block copolymer form a synergistic network, so that the mechanical property, the thermal stability and the degradation uniformity are synchronously improved.

The invention discloses a flame-retardant PC (polycarbonate) composite material based on high-temperature interface crosslinking and an in-situ reinforcement process thereof. The composite material comprises polycarbonate resin, reinforced fibers with a thermal response interface, a flame-retardant synergist and a processing aid. The core is that a thermal response interface layer and a sacrificial protection layer are sequentially constructed on the surface of the reinforced fiber, the thermal response interface layer is formed by grafting a silane coupling agent containing peroxide bonds through covalent bonds, and the sacrificial protection layer is a low-melting-point coating material. According to the design, the material has the temperature-triggered intelligent response characteristic; in daily processing and use, the protective layer ensures that an interface is stable and the binding force is slowly repaired; under the condition of high-temperature fire, the interface layer is quickly triggered to form carbon through crosslinking, so that the flame-retardant efficiency is remarkably improved, and melt dripping and a candlewick effect are effectively inhibited. The high mechanical strength, the long-acting durability and the intrinsic flame-retardant safety of the material are synchronously realized, and the material is suitable for the high-requirement fields of electronic appliances, new energy automobiles and the like.

The invention discloses a modified waterborne polyurethane adhesive and a preparation method thereof, and relates to the technical field of adhesives. The carbon dioxide-based polycarbonate polyol is prepared from the following raw materials in parts by mass: 70 to 84 parts of carbon dioxide-based polycarbonate polyol, 8 to 9.6 parts of hexamethylene diisocyanate, 3 to 3.6 parts of isophorone diisocyanate, 0.01 to 0.012 part of dibutyltin dilaurate, 10 to 12 parts of N-methyl pyrrolidone, 3.5 to 4.2 parts of dimethylolpropionic acid, 0.1 to 0.5 part of 1, 3-butanediol, 0.1 to 0.5 part of a catalyst and 0.1 to 0.5 part of a catalyst. The adhesive is prepared from the following components in parts by weight: 1 to 1.2 parts of 1, 4-butanediol, 21 to 25.2 parts of modified polyurethane dispersion, 2 to 2.5 parts of silane-terminated dynamic cross-linking agent, 2.8 to 3.4 parts of triethylamine, 40 to 60 parts of acetone, 200 to 220 parts of deionized water and 10 to 12 parts of ethylenediamine aqueous solution. By introducing the modified polyurethane dispersion and the silane-terminated dynamic cross-linking agent, the base material universality, water resistance and temperature resistance of the adhesive are effectively improved.

The invention discloses a high-flame-retardant polyurethane insulation board and a preparation method thereof, and belongs to the technical field of polyurethane insulation boards. The high-flame-retardant polyurethane insulation board is prepared from the following components in parts by mass: 90 to 110 parts of polyol, 110 to 130 parts of isocyanate, 80 to 120 parts of an inorganic flame retardant, 30 to 40 parts of a modified flame retardant, 10 to 20 parts of modified polyether polyol, 6 to 10 parts of graphene oxide, 20 to 25 parts of a foaming agent and 0.5 to 1.5 parts of a first catalyst, the polyol comprises polycarbonate diol and polyester diol in a ratio of 1: (2-4); the modified flame retardant is obtained by modifying hydrogen group-terminated siloxane through hexaanilino cyclotriphosphazene; the modified polyether polyol is obtained by modifying polyether polyol through diphenylphosphinic acid ethylene oxide methyl ester. The modified flame retardant and the modified polyether polyol are added into the high-flame-retardancy polyurethane insulation board, so that the dispersity of the flame retardant can be improved, and the uniformity and consistency of the flame retardancy of the polyurethane insulation board are improved.

The present invention relates to a method for alcoholysis of a plastic, in which the plastic is subjected to an alcoholysis reaction using a specific binuclear metal complex catalyst in the presence of an alcoholysis agent to obtain a monomer, and the plastic is one or more selected from the group consisting of polyester, polycarbonate, polyamide and polyurethane. According to the alcoholysis method of the plastic, catalytic alcoholysis can be efficiently carried out, the purity of a monomer product is high, post-treatment is simple, and various plastics can be treated.

The invention discloses self-adhesive single-component liquid silicone rubber with low compression set and a preparation method thereof. The preparation method comprises the following steps: kneading high-viscosity double-end vinyl polydimethylsiloxane, white carbon black, hexamethyldisilazane and water to prepare base rubber; and uniformly mixing and stirring the base rubber with double-end vinyl polydimethylsiloxane, polydimethylmethylvinylsiloxane, polydimethylmethylhydrosiloxane, a first functional aid, a second functional aid, an inhibitor and a catalyst in proportion to prepare the single-component liquid silicone rubber. The silicone rubber has excellent bonding performance on various substrates such as stainless steel, aluminum materials, copper materials, kovar alloys, nylon, polycarbonate and PBT (polybutylene terephthalate), has excellent mechanical properties and low compression set rate, is suitable for sealing and bonding of various automobile, industrial and electronic components, and has wide application prospects. The present invention relates to a sealing strip, in particular to a sealing adhesive scenario for in-situ curing sealing gasket (CIPG) applications, instead of a conventional sealing strip.

The invention relates to the technical field of films, in particular to a PFAS-free high-flame-retardant polycarbonate film and a preparation method thereof, and the PFAS-free high-flame-retardant polycarbonate film comprises the following raw materials by mass: 70-85% of PC resin; 0.5-3% of a silicon flame retardant; 4-8% of a phosphorus-based flame retardant; 5-10% of talcum powder; 5-10% of a low-temperature sintering agent; 0.05 to 0.2 percent of an antioxidant 168; 0.05 to 0.2 percent of an antioxidant 1010; 0.1-0.3% of lubricant silicone oil; and 0.05-0.2% of a 70% phosphorous acid solution.

The invention concerns a lamp module to be mounted on a motor vehicle comprising: a housing, a cover defining, with the housing, an inner space, the cover separating the inner space from the surrounding environment, and at least one light source housed within the inner space. The cover is made of one piece and comprises an outer wall comprising an outer surface in contact with said surrounding environment and facing away from the light source. The outer wall is made of translucent bio-polycarbonate resin, and the outer surface is devoid of any coating.

A polycarbonate composition includes particular amounts of a bisphenol A homopolycarbonate, a first polycarbonate-siloxane copolymer having a siloxane content of 4 to 10 weight percent, based on the total weight of the first polycarbonate-siloxane copolymer, and a second polycarbonate-siloxane copolymer having a siloxane content of greater than 30 to 70 weight percent, based on the total weight of the second polycarbonate-siloxane copolymer. The composition can provide a desirable combination of properties, including good flame performance, chemical resistance, and aesthetic properties.

The invention belongs to the technical field of coatings, and particularly relates to a water-based woodware varnish as well as a preparation method and application thereof. The water-based wood top-coat comprises a water-based emulsion, an organosilicon compound, a functional additive, a thickening agent, a wetting agent and water, the water-based emulsion comprises a self-crosslinking acrylic copolymer emulsion and an emulsion A; the emulsion A is selected from any one of self-crosslinking acrylic acid homopolymerized emulsion and polycarbonate modified polyurethane emulsion; the organosilicon compound comprises at least one of silane and silanol; the functional auxiliary agent comprises any one of a functional auxiliary agent 1 and a functional auxiliary agent 2; the functional additive 1 comprises a mildew preventive A and a mildew preventive B; the functional auxiliary agent 2 comprises a mildew preventive C, an ultraviolet light absorber and an ultraviolet light stabilizer; the thickeners include high shear, medium shear, and low shear polyurethane thickeners. The water-based woodware varnish disclosed by the invention has good comprehensive properties such as mildew resistance, weather resistance, chemical resistance and blocking resistance, and can be used for coating outdoor woodware or semi-outdoor woodware.

The invention relates to a polycarbonate / PBT / APT composite material and a preparation method thereof. The polycarbonate / PBT / APT composite material is characterized by being prepared by mixing polycarbonate, PBT, a polysiloxane-polycarbonate random copolymer, attapulgite treated by a PCA filler dispersant and KT-22. Due to the addition of polysiloxane-polycarbonate, KT-22 and APT, the interfacial compatibility and mechanical properties of the material are effectively improved, the cost performance is higher, the mechanical properties and processing fluidity of the composite material are improved, the requirements of the high-end application field are met, and the application prospect is wider.

The invention relates to the field of printing ink, and particularly discloses water-based silk-screen printing oil, an applied water-based silk-screen printing protective film and a construction technology of the water-based silk-screen printing oil. The water-based silk-screen printing oil is prepared from the following raw materials: water, filler, a film-forming agent, polydimethylsiloxane dispersion liquid, polyamide wax, a polyether siloxane copolymer, an amine neutralizer and a resin matrix; the resin matrix is a mixture of water-based polycarbonate resin or water-based polyurethane resin and water-based soft polyurethane resin; the invention also discloses a water-based silk-screen protective film prepared from the water-based silk-screen ink through a silk-screen process, and also discloses a construction process of the water-based silk-screen protective film, and the construction process comprises the following steps: respectively preparing a primer and a finish paint; the preparation method comprises the following steps: respectively preparing a primer and a finish paint, mixing, carrying out silk-screen drying to form a primer layer, mixing the finish paint with a water-based high-temperature-resistant curing agent, and carrying out silk-screen to form a finish paint layer. The preparation method has the characteristic of preparing the environment-friendly high-temperature-resistant strippable water-based silk-screen printing ink.

This invention relates to a retardation film comprising: an A layer having a slow axis, and a B layer having a slow axis at an angle of 85° to 90° to the slow axis of the A layer; the A layer is formed of a resin A having positive intrinsic birefringence; the B layer is formed of a resin B having negative intrinsic birefringence; the resin B comprises polyester, polycarbonate, or polyester carbonate, wherein the polyester, polycarbonate, or polyester carbonate contains a fluorene framework; the overall in-plane retardation of the A layer and the overall in-plane retardation of the B layer satisfy a specific relationship; the in-plane retardations Re(450) and Re(550) of the retardation film at wavelengths of 450 nm and 550 nm satisfy a specific relationship; the overall thickness T of the A layer... A The overall thickness T of layer B B The ratio of T A / T B It ranges from 30 / 70 to 65 / 35.

The application belongs to the field of catalyst synthesis, and relates to a polymer polynuclear boron organic catalyst, a preparation method and application thereof, the preparation method of the catalyst comprises the following steps: adding tetrahydrofuran into a catalyst precursor, then adding a borohydride reagent drop by drop, heating the reaction mixture at 25-80 DEG C for 22-26 h, vacuum concentrating the reaction mixture to obtain a crude product, purifying the crude product by washing with pentane for 2-5 times, and vacuum drying the product at normal temperature for 10-14 h to obtain the catalyst; the catalyst precursor and a preparation method thereof are also provided; the polymer polynuclear boron organic catalyst provided by the application has the advantages of high activity, simple preparation method and low cost, and the catalyst can control the polymer substrate type and the polymer type by adjusting the reaction conditions, the catalytic system and the substrate, and can efficiently prepare polymers such as polyether, polyester and polycarbonate due to the synergistic effect of the polynuclear boron center, so that the types of the organic catalyst and the polymer are greatly expanded.

This invention belongs to the field of polymer membrane material technology and discloses a method for extracting uranium (UO2) from seawater. 2+ This invention discloses a novel separation membrane material, specifically a amine-oxime-modified polycarbonate membrane, its preparation method, and its applications. The invention uses polycarbonate (PC) as a matrix. First, cyano-modified polycarbonate (PCAN) is prepared by grafting cyano groups. Then, PC and PCAN are blended, and a base membrane material is prepared using a phase inversion method. Finally, through in-situ amine-oxime modification, an amine-oxime-modified polycarbonate membrane (PCAO) is obtained, which possesses advantages such as high adsorption capacity, easy recovery, good stability, and excellent recyclability. Furthermore, the polycarbonate membrane modified with amine-oxime groups exhibits highly efficient selective adsorption capacity for uranium, enabling the effective development of uranium resources in seawater. This not only alleviates the domestic shortage of these key energy materials but also significantly improves economic benefits.

The utility model provides a building daylighting roof which comprises an outer frame, a daylighting assembly and a heat insulation assembly, the outer frame is made of high-strength aluminum alloy materials and fixed to the top of a building body through expansion bolts, the daylighting assembly is installed on the outer frame, and the daylighting assembly is composed of multiple layers of composite boards. Comprising an outer tempered glass layer, a middle polycarbonate sunlight plate layer and an inner dimming glass layer, and the heat insulation and heat preservation assembly is installed on the outer frame and located below the lighting assembly. The indoor temperature can be reduced in summer, the indoor temperature can be kept warm in winter, the energy consumption of an air conditioning system is reduced, and the energy-saving target of a building is achieved.

The invention belongs to the technical field of electromagnetic wave absorbing materials, and discloses a composite coating with electromagnetic protection and explosion-proof functions as well as a preparation method and application of the composite coating. The coating comprises 40 to 60 parts of polycarbodiimide modified diphenylmethane diisocyanate, 40 to 60 parts of a semi-prepolymer which is synthesized from polycarbonate diol with the equivalent weight of 1000 and has the NCO content of 10 to 20 percent, 73 to 100 parts of a polyether amine curing agent, 15 to 20 parts of diethyl toluenediamine or dimethyl thio toluenediamine, 0.5 to 2 parts of calcium carbonate and 3 to 6 parts of magnetic powder. And the two components are quickly reacted and molded through a spraying process. According to the invention, the polyurea elastomer is used as a matrix, so that the coating is endowed with excellent impact resistance, explosion-proof characteristics, water impermeability, oil resistance, low temperature resistance and other environmental tolerance; meanwhile, an adjustable electromagnetic wave absorption function is realized by doping specific magnetic powder. The coating is simple in preparation process and excellent in comprehensive performance, and is particularly suitable for equipment surfaces with high requirements on stealth and survival protection, such as oil storage equipment.

The application discloses an anti-ultraviolet aging polycarbonate modified material and application thereof, and belongs to the technical field of polymer material modification. The material comprises synergistically modified polycarbonate, an organic small-molecule functional regulator, an antioxidant, a light stabilizer, a lubricating dispersant and an inorganic filler, wherein the synergistically modified polycarbonate is constructed into a multiple synergistic network by introducing a borate dynamic covalent structure, a Schiff base structure and a rare earth coordination structure, and the organic small-molecule functional regulator is p-hydroxybenzophenone. The preparation method comprises preparation of the synergistically modified polycarbonate and a subsequent melt blending and extrusion process. Through the technical scheme, the synergistic effect of ultraviolet absorption, energy transfer and free radical inhibition is realized, the yellowing degree of the material is significantly reduced, the mechanical property retention rate and the optical stability are improved, and the material is suitable for the fields of automobile transparent parts, outdoor optical materials and electronic and electrical shell.

This application belongs to the field of polymer materials technology, specifically disclosing a modified PC / ABS alloy and its preparation method. By weight, it comprises: polycarbonate: 50-80 parts; ABS resin: 15-40 parts; comb-shaped reactive compatibilizer: 3-8 parts; halogen-free flame retardant: 8-18 parts; nano-talc powder: 3-10 parts; core-shell toughening agent: 2-8 parts; antistatic agent: 0.5-3 parts; antioxidant: 0.2-0.8 parts; lubricant: 0.2-1.0 parts. The tensile strength (56.3-66.8 MPa), flexural strength (88.4-98.5 MPa), flexural modulus (2480-2780 MPa), and notched impact strength (23℃: 52.4-62.5 kJ / m) are also disclosed. 2 -30℃: 28.5~36.2kJ / m 2 Heat distortion temperature (110~125℃), limiting oxygen index (30.0~32.0%), flame retardant rating (V-0), and surface resistivity (5.2×10⁻⁶) are also specified. 9 ~2.5×10 10 In terms of Ω), it is better, and the high performance of PC / ABS alloy is achieved by using reactive compatibilizers, nano talc powder, phosphorus-nitrogen-silicon ternary synergistic flame retardant system, core-shell toughening agent and polymeric antistatic agent.

Thermoplastic compositions include: a. from about 1 wt% to about 70 wt% of a polycarbonate homopolymer component; b. from about 10 wt% to about 40 wt% of a polybutylene terephthalate (PBT) component; c. from about 5 wt% to about 30 wt% of a polycarbonate copolymer component; and d. from about 1 wt% to about 15 wt% of a flame retardant component comprising a cyclic phosphazene compound having an oxaphosphorin ring-containing structure. The compositions have improved heat resistance and flame retardant properties.

According to the present invention, it is possible to provide a polycarbonate resin that contains a constituent unit (A) derived from a monomer represented by general formula (1), a constituent unit (B) derived from a monomer represented by general formula (2) and a constituent unit (C) derived from a monomer represented by general formula (3). Relative to the total amount of constituent units (A), (B) and (C) that constitute the polycarbonate resin, the proportion of constituent unit (A) is 20-50 mol %, the proportion of constituent unit (B) is 5-20 mol %, and the proportion of constituent unit (C) is 30-75 mol %.

The present invention relates to a polycarbonate composition comprising the following components, relative to the total weight of the composition A) 63-81 wt. % of an aromatic polycarbonate,B) 13-20 wt. % of a phosphorus flame retardant,C) 4-12 wt. % of impact modifiers containing 1-7 wt. % of a first impact modifier and 1-7 wt. % a second impact modifier, wherein the first impact modifier is acrylonitrile-butadiene-styrene, and the second impact modifier is selected from methyl methacrylate-butadiene-styrene and silicone-acrylic rubber based impact modifiers,D) 1-6 wt. % of a mineral filler, andE) 0.05-0.09 wt. % of polytetrafluoroethylene.The present invention also relates to a shaped article made from the composition. The polycarbonate composition according to the present invention has a good combination of flame retardancy and impact strength.

This invention provides a low-warpage composite PC reinforced material and its preparation method, relating to the field of composite material technology. The preparation method includes: mixing polycarbonate, polysiloxane-PC copolymer, aramid pulp-resin blend, and silica-alumina powder to obtain a first mixture; adding additives to the first mixture and mixing again to obtain a second mixture; feeding the second mixture and glass fiber into a twin-screw extruder for melt extrusion, cooling, and pelletizing to obtain the composite PC modified material. The composite PC modified material obtained by this method exhibits high strength and strong dimensional stability, and is less prone to warping when manufactured into products, making it widely applicable in products such as mobile phone lens holders.

Provided are a method for efficiently producing a recycled polybutylene terephthalate resin from a material for recycling that includes polybutylene terephthalate, a method for separating polybutylene terephthalate, and a method for recovering a solution that includes at least polybutylene terephthalate.　This method for producing a recycled polybutylene terephthalate resin from a material for recycling that includes polybutylene terephthalate and a polycarbonate includes step 1, which is a step for placing the material for recycling in a solvent (solvent S1) that has a set swelling rate with regard to polybutylene terephthalate, heating and stirring the result, and separating a solution A and insoluble matter B that includes at least the polybutylene terephthalate.