722 results about "Organic base" patented technology

The invention discloses a preparation method of an ultra-pure hydroxylamine aqueous solution, and relates to the field of organic chemistry and chemical industry production. The method comprises the following steps: reacting electronic-grade hydroxylamine salt with organic alkali in a proper solvent to generate hydroxylamine, then separating and removing salt and unreacted hydroxylamine in a reaction solution through a mercaptopyridine ion exchange modified membrane, and finally concentrating the solution into 50wt% ultra-high-purity hydroxylamine aqueous solution by adopting reduced pressure evaporation or multi-effect evaporation. The process has the characteristics of high efficiency, environmental protection, simplicity and easiness in operation, effectively improves the purity, yield and separation efficiency of hydroxylamine, and meets the strict requirements of electronic grade hydroxylamine on purity and metal ion content.

The invention relates to a method for catalytically degrading a polyester material by using an ionic liquid and application of the polyester material, and mainly solves the technical problems of high energy consumption, environment unfriendliness and complex process in polyester material recovery research in the prior art. According to the technical scheme, the novel method for catalytically degrading the polyester material through the ionic liquid comprises the steps that the ionic liquid is used as a catalyst, diol is used as an alcoholysis agent, polyester is catalytically degraded, and the ionic liquid has the following general formula: A + B-(I); in the formula, A < + > is an organic alkali cation, and B <-> is an alkoxy anion, the problem is well solved, and the method can be applied to polyester recovery industry.

The invention relates to an indole hair dye based on air oxidation. The hair dye provided by the invention is characterized in that a chemical strong oxidant is not added, and oxygen in air can be catalyzed by using an air oxidation catalyst and a metal ion catalyst to naturally finish the oxidative polymerization process of indole substances (natural bionic melanin precursor substances). The used reducing agent is a combination of cysteine and a derivative thereof and sodium sulfite and a derivative thereof, the oxidative polymerization speed of indole substances can be controlled, and finally generated melanin macromolecules are embedded in hair cortex, so that white hair is obviously blackened. The natural oxidation process does not need hydrogen peroxide, destructive strong base or organic base, so that the use of harmful chemical reagents is reduced, the formula is simplified, the hair dyeing process is milder, potential hazards to hair and scalp are reduced, and the natural oxidation hair dye is safe, environmentally friendly and sustainable.

The invention discloses a fertilizer suitable for saline-alkali soil and a preparation method and device thereof, and relates to the field of saline-alkali soil fertilizers.The fertilizer particles are of at least N layers of core-shell structures, first compositions are arranged on the odd layers from inside to outside, second compositions are arranged on the even layers from inside to outside, N is an odd number larger than or equal to 3, and the core-shell structures are of a core-shell structure. The composition I is prepared from the following raw materials: an organic base fertilizer, a nitrogen-phosphorus-potassium base fertilizer, ammonium lignosulfonate, amino acid, a microbial agent and a mariculture product extract. The fertilizer particle has an odd-layer core-shell structure, the outermost layer is nutrient substances, the problem that the composition I on the surface is rapidly dissolved along with irrigation when the fertilizer is just put into the saline-alkali soil is solved, the effect of rapidly improving the saline-alkali soil is achieved, and the survival rate of seedlings is increased. After the irrigation period is finished, the composition II protects the composition I on the inner layer and waits for the next irrigation period, so that the excessive concentration of the fertilizer in a short time can be avoided, the purpose of slowly releasing the fertilizer can be achieved, and the fertilization frequency of the saline-alkali soil is reduced.

The invention relates to the field of polyimide films, and discloses a catalytic polyimide film preparation method, which comprises: S1, preparing a prepolymer, dissolving a fluorine-containing diamine monomer in a polar solvent, placing in a reaction kettle, adding an aromatic dianhydride monomer at a low temperature of 0-10 DEG C, stirring, mixing, and reacting to generate a polyamide acid solution; s2, primary catalysis: adding an organic base catalyst into the polyamide acid solution prepared in the step S1; s3, second-stage catalysis: after the step S2 is completed, adding a coordination type organic basic catalyst into the first-stage catalyst; and S4, film formation and post-treatment. Amidation and ring-closure reactions are promoted in stages through the synergistic effect of the double catalysts, the reaction rate matching performance is remarkably improved, accurate control over molecular chains is achieved, a high-purity polymer matrix with uniform molecular weight distribution and complete ring closure is obtained, and the structural uniformity and mechanical strength of the film are fundamentally improved; the structure defect caused by incomplete reaction under a traditional single catalytic system is avoided.

The present invention belongs to the technical field of petrochemical catalysis, and relates to a preparation method for improving the stability of a Cu-Beta zeolite catalyst for preparing caprolactam from caprolactone, and the use thereof. In the present invention, a cavity-modified dealuminated Beta zeolite is used as a carrier, and copper is loaded in pore channels of the zeolite carrier by means of an improved ammonia distillation method. The cavity modification refers to subjecting the dealuminated Beta zeolite carrier to a desiliconization technique controlled by the use of a weak organic base so as to enlarge silanol nests generated by dealumination of the dealuminated Beta zeolite carrier, thereby better accommodating and stabilizing the nano and sub-nano copper particles. The core of the improved ammonia distillation method involves impregnating a zeolite carrier with an equal volume of a copper-ammonia complex solution, such that the copper-ammonia complex mainly undergoes, during ammonia distillation, a reaction of depositing copper hydroxide in zeolite pore channels, thereby improving the sintering resistance. The Cu-Beta catalyst prepared using the method provided by the present invention exhibits high activity, selectivity and stability when applied to the reaction of caprolactam prepared from caprolactone via gas-solid phase hydroamination.

The invention relates to the technical field of etching solutions, in particular to a Cu-MTD alloy etching solution composition and application thereof. The composition comprises a main agent and an auxiliary agent, and the main agent comprises the following components in percentage by weight: 12-20% of hydrogen peroxide, 6-15% of first organic acid, 0.001-0.08% of a first pH regulator, 2-8% of organic alkali and the balance of deionized water; and the auxiliary agent comprises 20-55% of second organic acid, 2-10% of inorganic acid, 0.05-0.5% of a second pH regulator, 10-30% of an alkaline compound and the balance of deionized water. According to the etching solution, the main agent and the auxiliary agent are compounded, the taper angle of a Cu layer can be larger than 42 degrees, and the service life cycle can reach that the Cu concentration is larger than or equal to 10000 ppm.

The invention relates to the technical field of synthesis of organic compounds, and discloses a synthesis method of an o-aminoanisole compound, which comprises the following steps: preparing a composite alkali slow-release system consisting of inorganic alkali and organic alkali; preparing a catalytic reduction reaction system containing a metal complex stabilizer, a transition metal catalyst and a hydrophilic ether cosolvent; a catalytic reduction reaction of o-nitroanisole is carried out, and the slow-release alkali-coated material gradually releases the composite alkali to maintain a stable pH environment; after the reaction is completed, adding a packing material rapid digesting agent to remove a packing material structure, and meanwhile, rapidly separating and protecting a product by using a product protective extracting agent and an antioxidant synergistic protective agent; and purifying and recovering the final product to obtain a high-purity o-aminoanisole product. The reaction efficiency, the product purity, the service life of the catalyst and the separation efficiency are comprehensively improved through the synergistic effect of the eight components, the product purity reaches 99.5% or above, the catalyst can be recycled for 5-8 batches, and the separation time is shortened to 0.5-1 hour.

The invention discloses a silicon dioxide anti-blocking agent and a preparation method thereof, and relates to the technical field of chemical preparation. Comprising the following steps: taking a water glass solution and a dilute sulphuric acid solution as raw materials, and carrying out parallel flow mixing reaction to prepare silica gel; the method comprises the following steps: crushing silica gel, transferring the crushed silica gel into a reaction kettle, adding an aprotic organic solvent, adding a pH buffer solution and organic alkali into the reaction kettle to adjust the pH value of the solution, carrying out heating reflux to carry out an aging reaction, stopping heating after the reaction is completed, opening a filter valve, and filtering the liquid into an alkaline recovery tank; continuously adding an aprotic organic solvent and an organic acid acidification system into the reaction kettle to adjust the pH value of the solution, aging, opening a filter valve to filter the liquid into an acidic recovery tank, washing gel to be neutral, and filtering washing water into a water recovery tank; and adding high-purity water into the reaction kettle, homogenizing and emulsifying to prepare slurry, drying and crushing to obtain the silicon dioxide anti-blocking agent product. The preparation cost is reasonable, the treatment method is simple, and the obtained product is fine and smooth in hand feeling, high in transparency and high in yield.

The invention discloses a preparation method of 3-chloro-5, 5-dimethyl-4, 5-dihydroisoxazole, which comprises the following steps: taking a hydroxylamine oxygen sulfonic acid aqueous solution and isopentenal as raw materials, carrying out oximation reaction in an organic solvent under an alkaline condition, then directly adding an acid or an organic base catalyst into the reaction system, and reacting for 2-4 hours to obtain 3-chloro-5, 5-dimethyl-4, 5-dihydroisoxazole, thereby obtaining the 3-chloro-5, 5-dimethyl-4, 5-dihydroisoxazole. Under the catalytic action of the catalyst, a cyclization reaction is carried out, after the reaction is finished, an intermediate solution containing 5, 5-dimethyl-4, 5-dihydroisoxazole is obtained, and the next step is directly carried out; and carrying out a chlorination reaction by taking the intermediate solution as a raw material and sodium hypochloride or chlorine as a chlorination reagent, and after the reaction is finished, carrying out post-treatment to obtain the 3-chloro-5, 5-dimethyl-4, 5-dihydroisoxazole. The hydroxylamine oxygen sulfonic acid is used for enabling the isopentenal to be subjected to oximation reaction under the alkaline condition, then cyclization is carried out under the catalytic action of acid or alkali, the 5, 5-dimethyl-4, 5-dihydroisoxazole is generated, and the process has the advantages that the yield is high, the production steps are simplified, and the production cost is reduced.

The preparation method comprises the following steps: by taking cephalosporin carboxylic acid containing the side chain of the 2-aminothiazole-4-oxime as a raw material, carrying out carboxyl protection reaction on the cephalosporin carboxylic acid containing the side chain of the 2-aminothiazole-4-oxime and a trimethylsilylation reagent; cooling the reaction liquid, directly carrying out amidation reaction on the reaction liquid and AE-active ester under the action of organic alkali, directly adding water into the reaction liquid to carry out hydrolysis deprotection, and growing crystals to obtain a crude product of cephalosporin dioxime; and purifying and drying to obtain the cephalosporin dioxime compound. According to the method, carboxyl is protected firstly, then the organic base is added to serve as the catalyst, amino is activated, the reaction can be effectively carried out, the purity of the cephalosporin dioxime obtained through aftertreatment and preparative chromatography purification is high, and the method can be used for impurity research of the cephalosporin antibiotics containing the aminothiazoly loxime side chain.

The invention relates to a preparation method and application of an ethylene sulfite compound, and the preparation method comprises the step of reacting an epoxy compound with sulfur dioxide under the action of an immobilized organic base catalyst to obtain the ethylene sulfite compound. The immobilized organic base catalyst is formed by connecting organic base and chloromethylated resin through chemical bonds, and has good catalytic activity and chemical stability. According to the preparation method provided by the invention, the raw material cost is low, the product is easy to purify, the yield is relatively high, continuous automatic production is easy to realize, and the prepared ethylene sulfite compound is added into the lithium battery electrolyte as an additive, so that the electrochemical window of an electrolyte system can be widened, and the high-voltage interface stability and the cycle performance of the battery can be improved.

The invention relates to a high-entropy metal oxide catalyst and a preparation method and application thereof.The preparation method comprises the following steps that S1, ferric salt, cobalt salt, manganese salt, nickel salt, copper salt and organic alkaline matter are mixed to obtain a mixed solution, hydrothermal reaction is conducted, and a precursor is obtained; and S2, calcining the precursor at the temperature of 500-600 DEG C to obtain the high-entropy metal oxide catalyst. The high-entropy metal oxide catalyst uniformly doped with iron, cobalt, manganese, nickel and copper is prepared by adopting a hydrothermal reaction and calcination method, and the high-entropy metal oxide catalyst not only can efficiently catalyze ozone to remove antibiotics, but also can still keep an excellent antibiotic removal rate constant in a water body containing hetero ions and humic acid; and the anti-interference capability is excellent.

The invention provides a preparation and purification method of a p-xylylene dicamphor sulfonate crystal form, which comprises the following steps: carrying out condensation polymerization on camphorsulfonic acid and terephthalaldehyde under the action of organic alkali to prepare p-xylylene dicamphor sulfonate, carrying out post-treatment, dissolving, clarifying and layering, dropwise adding ethanol, and sequentially carrying out first crystal growing and second crystal growing to obtain the p-xylylene dicamphor sulfonate crystal form. The preparation method comprises the following steps: dissolving p-xylylene dicamphor sulfonate in water to obtain a crude product of the p-xylylene dicamphor sulfonate crystal form, decolorizing the crude product, and carrying out gradient cooling crystallization, so that the high-purity p-xylylene dicamphor sulfonate crystal form product with high yield can be prepared, the content of impurities in the product is effectively controlled, the irritation of the impurities to the skin is reduced, and the safety of the product is improved. Meanwhile, the product has a crystal form, the moisture absorption of the product can be improved, and storage is easy.

The invention discloses a ketoazine-based polymer, an anion exchange membrane and a preparation method and application of the ketoazine-based polymer and the anion exchange membrane. A first linking group and a second linking group are mixed and then mixed with an aryl monomer A in an aprotic solvent of halogen atoms; slowly adding a super acid mixture; performing polymerization reaction in an environment of-5 to 3 DEG C to obtain a reaction solution; pouring the reaction liquid into a first mixed solvent to obtain PAAz; carrying out primary quaternization reaction on PAAz through carbonate, bicarbonate or hydroxide salt of alkali metal, and adding an organic base catalyst to assist the primary quaternization reaction; in the first quaternization reaction, a quaternization reagent is added; and pouring into a second mixed solvent, and precipitating to obtain purified PAAz. Under the condition of super acid catalysis, two or more alicyclic amine derivatives containing ketone groups react with one or more aromatic fused rings to generate a polymer containing secondary or tertiary amine. And carrying out quaternization treatment to finally form the cationic polymer.

The invention provides a preparation method of a cyano chlorosilane compound, and the preparation method of the cyano chlorosilane compound comprises the following steps: reacting methyl dichlorosilane with a cyano-containing olefin compound under the action of a catalyst to obtain the cyano chlorosilane compound, the catalyst comprises a combination of cuprous salt, organic alkali and tetramethylethylenediamine. According to the method, methyl dichlorosilane and cyano-containing olefin are used as raw materials to react, and the cyano chlorosilane compound is prepared under the action of a specific catalyst; the preparation method is simple in reaction operation, the yield is 76% or above, the purity is 99.1% or above, and the preparation method is suitable for industrial production.

The invention provides an etching solution compatible with Cu / Mo and Cu / MTD and application of the etching solution. The etching solution comprises a main agent and an auxiliary agent, the main agent comprises the following components in parts by weight: 5-22 parts of an oxidizing agent, 1-15 parts of organic acid, 0.01-5 parts of inorganic acid, 0.5-15 parts of organic alkali, 0.01-5 parts of a stabilizer, 0.01-1 part of a metal inhibitor and 1-100 parts of water. The etching solution provided by the invention can be effectively compatible with two different metal structures, namely Cu / Mo and Cu / MTD, and can realize a good etching effect on different metal film layers in the etching process, so that the problem of poor etching caused by poor compatibility of the etching solution is reduced, and the yield of products is improved; the etching solution has excellent etching performance on Cu / Mo and Cu / MTD alloy double-layer films and the like, no residue is left after etching, substrate materials such as a glass substrate and the like cannot be damaged, and the high requirement of the modern electronic manufacturing process on the etching solution is met.

The invention discloses a preparation method of an electronic-grade hydroxylamine aqueous solution, and relates to the field of chemical preparation. The preparation method comprises the following steps: reacting electronic-grade ammonia water or organic alkali with electronic-grade hydroxylamine salt to generate a hydroxylamine aqueous solution; and after the reaction, separating through a POSS (Polyhedral Oligomeric Silsesquioxane) nano blending modified membrane, and removing salt, impurities and unreacted raw materials to obtain a high-purity hydroxylamine aqueous solution. And concentrating the solution into a 50% hydroxylamine aqueous solution by adopting a low-temperature vacuum concentration technology. The method can effectively remove metal ions and inorganic impurities, and ensures that the final product is high in purity and meets the electronic grade requirement.

The invention belongs to the technical field of aerogel materials, and particularly relates to modified polyamide acid aerogel as well as a preparation method and application thereof. Comprising the following steps: preparing POSS modified polyamide acid by taking dianhydride, diamine and a polyamino POSS monomer as raw materials; adding the POSS modified polyamide acid into deionized water, and precipitating to obtain POSS modified polyamide acid powder; adding the POSS modified polyamide acid powder and an organic alkaline compound into deionized water, and carrying out sol-gelation to obtain POSS modified polyamide acid hydrogel; and drying the POSS modified polyamide acid hydrogel, carrying out partial thermal imidization, and crushing to obtain the modified polyamide acid aerogel. A large number of active groups are still reserved on the aerogel, so that the compatibility of the aerogel and an adhesive is improved, and the aerogel adopts two modes of pore infiltration and active group connection to enhance the mechanical property of the adhesive.

The present application relates to a kind of carbon dioxide mineralization method and carbon dioxide mineralization device.The carbon dioxide mineralization method includes the following steps: mixing absorption liquid and industrial solid waste at room temperature, obtain mortar;Make mortar solid-liquid separation, obtain clear liquid and thick slurry;Carbon dioxide in flue gas is absorbed by clear liquid, obtain carbon-rich absorption liquid;Carbon-rich absorption liquid and thick slurry occur mineralization reaction at 180 DEG C-220 DEG C, obtain mineralized slurry;Make mineralized slurry solid-liquid separation, obtain mineralized ash and mineralized clear liquid;Wherein, absorption liquid includes inorganic base and organic base, organic base includes monoethanolamine, diethanolamine, triethanolamine, 3-methylaminopropylamine, N-methyl diethanolamine, piperazine, diethylene triamine, triethylene tetramine, tetraethylene pentamine and 2-amino-2-methyl-1-propanolamine at least two kinds.The method greatly improves CO2 capture rate and CO2 utilization rate, and organic base consumption is less, absorption liquid regeneration energy consumption is low, and overall economy is good.

The invention relates to the technical field of nano materials, in particular to a silicon dioxide nanosheet and a preparation method thereof. According to the preparation method, organic alkali and a surfactant G400 are taken as a composite template agent, tetraethyl orthosilicate is induced to be subjected to hydrolytic condensation in a solvent, generated precipitates are washed, dried and calcined, and the silicon dioxide nanosheets can be obtained; the method is simple to operate, low in cost and high in efficiency, and the obtained silicon dioxide nanosheet is ultrathin, high in crystallinity and large in specific surface area.

The invention discloses a preparation method of 3-quinuclidinone hydrochloride, which comprises the following steps: carrying out temperature control reaction on 4-picolinic acid and chloroacetic acid under alkaline water conditions to obtain an aqueous solution of a compound a, and directly entering the next reaction without post-treatment after the reaction is finished; adding a reducing agent alkaline water system into the aqueous solution of the compound a, controlling the temperature to react, controlling the temperature to adjust the pH value to 5-5.5 after the reaction is finished, extracting with n-butyl alcohol, and drying to obtain an n-butyl alcohol solution of a compound b, and directly entering the next reaction step; wherein the reducing agent is one of sodium borohydride and potassium borohydride; dropwise adding thionyl chloride into an n-butyl alcohol solution of the compound b, controlling the temperature to react after dropwise adding is ended, and concentrating to remove the solvent and unreacted thionyl chloride after the reaction is ended, so as to obtain a compound c; carrying out Dieckmann condensation reaction on the compound c at controlled temperature under the condition of organic alkali by using toluene as a solvent, carrying out hydrochloric acid quenching reaction after the reaction is finished, and directly carrying out next-step reaction after extracting and removing impurities from a water phase containing a hydrochloride solution of a compound d by using toluene; and carrying out a decarboxylation reaction on the compound d in a hydrochloric acid aqueous solution at controlled temperature, after the reaction is finished, adjusting the pH value to 10-13, extracting, and salifying to obtain a target compound TM, namely 3-quinuclidinone hydrochloride. The preparation method of 3-quinuclidinone hydrochloride provided by the invention has the advantages of economical and easily available raw materials, mild reaction conditions, efficient reaction, simple operation and low cost, and is suitable for industrial application.

The present application relates to the low temperature curing high-strength benzoxazine type silicone adhesive formula and use method, the formula includes the benzoxazine group containing organic silicon compound and organic alkali compound, the mass ratio of benzoxazine group containing organic silicon compound, organic alkali compound is 100:0.1-20.The adhesive of the present application is based on the cooperation between the benzoxazine group containing organic silicon compound and the basic catalyst, can be cured at low temperature, realize the higher strength bonding.The benzoxazine type silicone adhesive formula provided by the present application can be directly used as adhesive, and the bonding strength is high;It can also be used as a basic formula, used as an adhesive after adding other fillers, to meet the different needs of various special occasions.

The invention provides a method for improving the L * color of polymerized MDI by using organic alkali and an oxidizing agent. By using the method, the L * color of a polymerized MDI product can be improved. Comprising the following steps: 1) adding organic alkali and an oxidizing agent into polymerized MDI; and 2) reacting the mixed solution obtained in the step 1) under a stirring or standing condition to obtain the treated polymerized MDI.

The invention relates to a high-activity catalyst for synthesizing propylene carbonate from CO2 and epoxypropane and a preparation method and application thereof.The catalyst comprises a molecular sieve and metal oxide loaded on the molecular sieve, the molecular sieve is a pure silicon molecular sieve, the metal oxide is one or a combination of more of ZnO, Fe2O3, NiO, CoO and Cr2O3, the metal content accounts for 1-7 wt% of the mass of the catalyst, and the metal content accounts for 1-5 wt% of the mass of the catalyst. The particle size of the catalyst is 0.1-4 [mu] m. The preparation method comprises the following steps: treating a molecular sieve with an organic alkali, dipping the treated molecular sieve in a metal precursor solution subjected to acid treatment, controlling the pH value of the prepared metal precursor solution to be 2-4, shaking with an orbital shaking table, standing, drying, and roasting to obtain the catalyst. According to the invention, rich silicon hydroxyl nest sites on the surface of the molecular sieve with small particle size are utilized to effectively anchor metal species, and under the appropriate metal loading capacity, the synergistic catalysis of the metal and the adjacent silicon hydroxyl sites enables the molecular sieve to have high reaction performance for synthesizing propylene carbonate from CO2 and epoxypropane.

The present invention provides a poly(O,O'-monothiocarbonate) compound and its preparation method and application, belonging to the technical field of sulfur-containing polymers. The present invention carries out a polymerization reaction of silyl ether, elemental sulfur and difluorocarbene reagent under the action of an organic base, dissolves the obtained polymer product in an organic solvent and adds a precipitant for precipitation, and the obtained precipitate is a poly(O,O'-monothiocarbonate) compound. The poly(O,O'-monothiocarbonate) compound prepared by the present invention has a clear chain structure, and the prepared film refractive index reaches 1.6188, with outstanding optical properties; and the reaction raw materials of the preparation method of the present invention are easily available and can be directly purchased commercially, with the advantages of low raw material price, mild synthesis conditions, simple process and high polymerization efficiency.

The invention discloses a preparation method and application of a wormcast granular bacterial fertilizer, and the wormcast granular bacterial fertilizer is prepared by adopting a base material ratio of wormcast to humus of 7: 3 through mechanical granulation, 80 DEG C constant temperature drying, particle cooling and functional bacterial agent spraying. The product has a remarkable application effect on various crops such as corn (grain corn, fresh corn and silage corn), hot peppers, tomatoes, traditional Chinese medicinal materials (radix glehniae, radix saposhnikoviae and radix achyranthis bidentatae) and the like, can give full play to the synergistic interaction effect of organic matrixes and functional microorganisms, and is stable in fertilizer efficiency, convenient to apply and suitable for industrial continuous production and large-area popularization and application.

The invention provides a liquid red direct dye and a preparation method thereof, and the method comprises the following steps: S1, dispersing 2-amino-5-naphthol-7-sulfonic acid and bis (trichloromethyl) carbonate in water, adjusting the pH value of a reaction system by using a first organic base, and reacting to obtain a scarlet acid aqueous solution; s2, dispersing a sulfo aromatic amine compound and nitrite in water, adjusting the pH value of a reaction system by using inorganic acid, reacting to obtain sulfo aromatic amine diazonium salt precipitate, and performing solid-liquid separation to obtain sulfo aromatic amine diazonium salt; and S3, adding the sulfonic aromatic amine diazonium salt in the step S2 into the scarlet acid aqueous solution in the step S1, adjusting the pH value of the reaction system by using second organic alkali, and reacting to obtain the liquid red direct dye. Through the preparation method, the red direct dye which can stably exist in a liquid form and is suitable for direct use can be obtained.

The present application relates to the technical field of molecular sieve preparation, and particularly relates to a mesoporous pore size adjustable SAPO-34 / pure silicon molecular sieve and a preparation method thereof, which comprises the following steps: uniformly stirring an aluminum source, a silicon source, a phosphorus source, a structure directing agent and distilled water to obtain an initial gel; placing the initial gel in a reaction kettle and performing hydrothermal crystallization in a static oven; sequentially performing filtration, washing, drying and calcination on the obtained product to obtain a SAPO-34 molecular sieve; adding the SAPO-34 molecular sieve into a functional solution of a cationic surfactant, performing water bath heating, and sequentially performing filtration, washing, drying and calcination on the obtained product to obtain a mesoporous pore size adjustable SAPO-34 / pure silicon molecular sieve; wherein the functional solution of the cationic surfactant comprises a cationic surfactant, an organic alcohol, a silicon source, an organic base and distilled water. The preparation method of the present application significantly improves the service life of the SAPO-34 / pure silicon molecular sieve as a catalyst in MTO reaction and the selectivity of the SAPO-34 / pure silicon molecular sieve to low carbon olefins.

An improved solvent system for the formulation and application of N-alkyl thiophosphoric triamide urease inhibitors. These formulations provide safety and performance benefits relative to existing alternatives and enable storage, transport and subsequent coating or blending with urea based or organic based fertilizers. These formulations are comprised primarily of environmentally friendly aprotic and protic solvents (particularly dimethyl sulfoxide and alcohols / polyols) to stabilize the urease inhibitor.