2479 results about "Fluorine" patented technology

The invention discloses a refined disassembly system and method for a battery monomer, and belongs to the technical field of battery disassembly. The production line comprises a perforating device, a cutting device, a cutting device, a scattering device, a sorting device, a color sorting device, a defluorination device and a powder removal device. The method comprises the following steps: perforating a battery to discharge electrolyte, separating a shell from an inner core by a cutting device, cutting the inner core by a cutting device, scattering by a scattering device, sorting a diaphragm by a sorting device, sorting positive and negative electrode materials by a color sorting device, and respectively removing fluorine by a defluorination device. And finally, the metal foil and the powder are separated through the powder removing device, the damage degree of the crystal structure of the black powder can be reduced, the black powder and the metal fragments are efficiently separated according to the density difference, the metal foil and the black powder are not likely to be excessively mixed, the separation purity is high, the secondary treatment situation is reduced, efficient separation and recycling of the electrode material are achieved, and the production cost is reduced. And the comprehensive function and the resource utilization rate of the system are obviously improved.

The invention belongs to the technical field of optical materials, and discloses a holographic polymer dispersed liquid crystal composition, a holographic grating and a preparation method. The composition comprises the following components in parts by mass: 0.5-1.5 parts of a photoinitiator, 2-5 parts of a co-initiator, 15-20 parts of a first monomer, 15-20 parts of a second monomer, 10-15 parts of a third monomer, 10-15 parts of a solvent and 10-20 parts of mixed liquid crystal. Wherein the first monomer is a monofunctional acrylic monomer, the second monomer is a bifunctional acrylic monomer, the third monomer is a polyfunctional acrylic monomer, the mixed liquid crystal comprises 10-25 wt% of a monomer liquid crystal and 75-90 wt% of a nematic liquid crystal, and the monomer liquid crystal contains fluorine as a benzene ring substituent and contains cyano or isothiocyano as an end group. Through cooperation of the monomer liquid crystal and the nematic liquid crystal in the mixed liquid crystal and cooperation of fluorine atoms and cyano / isothiocyano groups in the monomer liquid crystal, the holographic grating prepared from the composition has the characteristics of low haze and high diffraction efficiency, and the grating can be thinner, so that the requirements of light weight and clearness of AR glasses can be met.

The invention provides a high-stability lithium-rich manganese-based positive electrode material and a preparation method thereof, and relates to the technical field of lithium-rich manganese-based positive electrode materials, and the method comprises three steps of preparation of a homogeneous precursor, solid-state mechanical fusion doping and coating, and high-temperature sintering; a lithium-rich manganese-based precursor is prepared by adopting a homogeneous coprecipitation process, uniform distribution of metal ions is ensured, then an aluminum source, a zirconium source and a fluorine source are introduced as doping agents, phosphate and a titanate coating agent are combined, doping and coating integrated treatment is realized through mechanical ball milling, and the lithium-rich manganese-based composite material is obtained. And finally, mixing with a lithium source in an argon atmosphere, and carrying out high-temperature sintering of temperature programming and staged heat preservation to form a stable composite coating layer in situ. Therefore, manganese ion migration is effectively inhibited through lattice doping, a layered structure is prevented from being converted into spinel or rock salt phase, meanwhile, a nanoscale ion / electron transmission channel is constructed, interface impedance is reduced, and the charging and discharging efficiency under high voltage is improved.

The invention discloses a passive radiation refrigeration coating and a preparation method thereof, and relates to the technical field of industrial coatings. Comprising a fluoroacrylate emulsion, hollow glass beads, nano titanium dioxide, flaky silicon dioxide aerogel powder, polytetrafluoroethylene micro powder, hydroxyl-terminated polydimethylsiloxane, a hydroxyl acrylic acid modified silane coupling agent, a super-hydrophobic modified fluorosilicone surface additive, nano cerium oxide, aluminum fluoride doped zinc oxide infrared enhancement powder and deionized water. The paint is prepared on the basis of the formula. According to the invention, a multi-scale spectrum regulation and control and surface self-cleaning system is constructed cooperatively, so that the synergistic effect of high reflection of a sunlight region and high emission of a middle infrared region is realized. The coating can maintain continuous passive refrigeration in a day and night period, the surface of the coating has self-cleaning capability and excellent ultraviolet aging resistance, and high reflectivity and high radiation emissivity can be maintained for a long time in a complex outdoor environment, so that the thermal management efficiency of buildings and equipment is remarkably improved.

The invention relates to the technical field of insulating materials, in particular to insulating powder and a preparation method thereof. The invention discloses a flame-retardant coating which comprises the following components in parts by weight: 15-25 parts of epoxy resin, 10-20 parts of aluminum hydroxide, 5-12 parts of nano boron nitride, 1-3 parts of a silane coupling agent KH-560, 3-8 parts of polytetrafluoroethylene micro powder, 2-6 parts of fluorine-modified montmorillonite, 4-9 parts of melamine cyanurate, 2-5 parts of nano titanium dioxide, 1-4 parts of a fluorine-modified graphene oxide-polyaniline composite material and 0.5-2 parts of pentaerythritol stearate. The anti-corrosion coating is prepared from the following components in parts by weight: 1 to 3 parts of nano zinc oxide, 5 to 10 parts of glass fiber, 2 to 5 parts of polyhedral oligomeric silsesquioxane-polyimide copolymer, 1 to 4 parts of ferrocenyl epoxy resin and 0.5 to 2 parts of perfluorooctyltriethoxysilane. The insulation powder is high in corrosion resistance, excellent in insulation, heat dissipation and mechanical performance, environmentally friendly in processing, good in adaptability, capable of prolonging the service life of equipment and reducing the cost, suitable for special environments and wide in popularization prospect.

The invention relates to the technical field of quantum computing and molecular electronic devices, in particular to a probabilistic bit device based on polyfluoroaryl methyl free radicals and a preparation method of the probabilistic bit device. According to the probabilistic bit device, the coupling efficiency of molecules and electrodes is improved by virtue of the characteristic that the paramagnetic unpaired electron spin state of tri (polyfluoroaryl) methyl free radical molecules can be used as a random expansion physical entropy source and high electronegativity and stability formed by modification of a plurality of strong electron-withdrawing fluorine atoms in the molecules. During the operation period of the device, the spin fluctuation can efficiently regulate and control tunneling current passing through molecules, promote random conversion between output high and low current states, show excellent random binary fluctuation characteristics, and simultaneously have high sensitivity and long coherence time. Compared with the prior art, the device has remarkable advantages in the aspects of device stability, energy efficiency ratio and external field controllability. The preparation method is simple and convenient to operate, mild in reaction condition and beneficial to large-scale production.

The invention relates to the technical field of surface engineering, discloses a method and a system for preparing a yttrium fluoride composite ceramic coating through atmospheric plasma spraying, and aims to solve the problems that the yttrium fluoride coating generates a brittle aluminum fluoride layer on the surface of an aluminum substrate due to fluorine ion diffusion, so that the bonding strength is low, and the yttrium fluoride coating is easy to peel off and lose efficacy. The method comprises the following steps: sequentially carrying out mechanical polishing, ultrasonic cleaning and sand blasting roughening on an aluminum base material; preparing composite powder formed by mixing yttrium fluoride, yttrium oxide and nanometer aluminum oxide according to the mass ratio of 75: 20: 5; sequentially depositing a yttrium oxide transition layer, a composite barrier layer and a yttrium fluoride functional layer by adopting atmospheric plasma spraying; and finally carrying out vacuum post-heat treatment. According to the system, through the synergistic effect of the three layers of gradient structures, the transition layer forms an yttrium aluminate metallurgical bonding interface, the barrier layer inhibits fluorine ion diffusion through the dual mechanisms of nanometer aluminum oxide physical barrier and yttrium oxide chemical adsorption, and the functional layer guarantees the plasma erosion resistance. According to the method, the bonding strength of the coating is remarkably improved to 50 MPa or above, the porosity is lower than 3%, stripping is avoided under 500-hour high-energy plasma bombardment, the process cost is reduced by 40%, and the method is suitable for cavity protection of semiconductor etching equipment.

The invention discloses a fluoride-free flotation-microbiological leaching-multistage magnetic separation synergistic tailing purification process, which takes mine tailings as raw materials and is realized by the following steps: 1, fluoride-free flotation desliming and impurity removal: replacing hydrofluoric acid with a novel anion collector (fatty acid derivative), and preferentially removing mica and feldspar under the condition that the pH is 2.5-3.5; 2, removing iron and aluminum by microbiological leaching: leaching for 48 hours at the temperature of 35 DEG C by utilizing an acidophilus bacillus ferroxidans bacterial solution, and dissolving Fe2O3 and Al2O3 in a wrapped state; 3, high-gradient magnetic separation refining: removing magnetic minerals through 1.2 T strong magnetic separation, and then separating weak magnetic impurities through 0.8 T weak magnetic separation; the indexes of the final product are as follows: the purity of SiO2 is greater than or equal to 99.9%, the whiteness is greater than or equal to 94% (ISO standard), the content of Fe2O3 is less than or equal to 80ppm, Al2O3 is less than or equal to 1200ppm, and the requirements of electronic grade (IOTA-4 standard) quartz powder are met.

The invention provides a step-by-step etching method for extracting an extremely trace amount of solar wind 10Be from a moon sample. Comprising the following steps: 1, screening samples; step 2, etching; step 3, element content analysis; step 4, performing complete digestion; step 5, fluorine removal; step 6, ion exchange; step 7, preparing Be (OH) 2; and step 8, preparing a BeO target sample. According to the method, the etching step length is accurately regulated and controlled by monitoring the element contents of different etching layers, so that fine etching is realized; compared with an existing full dissolution technology, the method is a brand-new step-by-step etching method, and by combining an ion exchange method, layer-by-layer etching of the moon and other extraterrestrial samples and extraction of 10Be in the moon and other extraterrestrial samples are achieved; according to the method, the solar wind injection rate can be determined, and the solar wind injection resource generation rate of the moon and other extraterrestrial celestial bodies can be estimated.

The invention belongs to the field of rapid detection of environment-friendly water quality, and particularly relates to a kit for rapidly detecting the concentration of fluorine ions in water and a use method thereof. The invention discloses a rapid detection kit for the concentration of fluorine ions in water. The rapid detection kit comprises a fluorine ion rapid detection reagent, a fluorine ion rapid detection color card, a detection accessory and a use method of the rapid detection kit. According to the invention, tedious operations such as solid powder, dangerous organic solvent and multi-step pipetting addition are not needed, the device is convenient to carry, and rapid, simple, high-precision and high-interference-resistance fluorine ion detection of non-specialized personnel under field conditions is realized.

The invention discloses a negative electrode active material and a preparation method thereof, a negative electrode pole piece and a secondary battery, the negative electrode active material provided by the invention comprises a silicon-carbon composite material and an aluminum oxide layer coated on the surface of the silicon-carbon composite material, and the silicon-carbon composite material is a composite material of nitrogen-fluorine co-doped porous carbon and nano silicon particles. By optimizing and regulating the porosity and pore size distribution of the porous carbon, the ion transmission kinetics and the structural stability are improved, and the problems of poor rate capability, short cycle life and the like caused by single pore size of the traditional porous carbon are solved. By adopting the nitrogen and fluorine co-doped porous carbon skeleton, the conductivity of the electrode material is enhanced, and the cycling stability of the battery is improved. The nano silicon component uniformly deposited through a chemical vapor phase method provides high specific capacity, the aluminum oxide coating layer can effectively inhibit the decomposition reaction of the solid electrolyte, and the long-term stability and cycle performance of the electrode structure are jointly guaranteed through the dual effects.

The application discloses a cross-linked ETFE composite film with gradient ultraviolet shielding function and a preparation method and application thereof, and belongs to the technical field of ETFE film preparation. The cross-linked ETFE composite film is composed of three layers of a surface layer, a middle layer and a bottom layer. The surface layer material comprises ETFE resin and fluorinated carbon quantum dots; the middle layer material comprises ETFE resin, allyl-containing comonomer A and phenyl-containing comonomer B; and the bottom layer material comprises ETFE resin and CeO2 nanowires. The fluorinated carbon quantum dots have a particle size of 3-5 nm and contain a -C4F9 structure. The comonomer A is an allyl-containing fluorine olefin monomer, and the comonomer B is a phenyl-containing organic fluorinated compound. Through the synergistic effect of the surface layer self-migration fluorinated carbon quantum dots, the middle layer copolymerization modification and the bottom layer CeO2 nanowires, high light transmittance, full-waveband ultraviolet shielding and long-term weather resistance are achieved.

The invention provides a metal material recycling device and a method for leaching fluorine beryllium thallium and lithium rubidium cesium in lithium slag. Relates to the field of metal material recycling, and comprises a leaching tank placed on the ground through four supporting frames, the top of the leaching tank is fixedly provided with a top cover, and the bottom of the leaching tank is fixedly provided with a bottom cover. According to the metal material recycling device and the leaching method for fluorine beryllium thallium and lithium rubidium cesium in the lithium slag, the ultrasonic generator is arranged to supply energy to the first ultrasonic transducer and the second ultrasonic transducer to generate ultrasonic waves, the ultrasonic waves generate microjet flow to impact the surface of minerals, acid liquor permeation and ion diffusion are accelerated, the leaching time is shortened, and the efficiency is improved; the surface of the lithium slag is not prone to passivation, the leaching rate of target metal ions is increased, the leaching liquid is pumped out through the water suction pump, manual contact with the leaching liquid in the next solid-liquid separation procedure is facilitated, dilute sulfuric acid is supplemented through the acid supplementing pipe, then the lithium slag is placed through the funnel, and the consistency and controllability of starting of the leaching reaction are guaranteed.

The invention discloses fluoride salt-free and nitrate-free low-temperature matte glaze for steel plate enamel as well as a preparation method and application of the low-temperature matte glaze, and belongs to the technical field of enamel. The matte glaze is prepared from quartz, borax pentahydrate, sodium carbonate, titanium dioxide, magnesium oxide, monopotassium phosphate, calcium carbonate, zinc oxide, magnesium carbonate, lithium carbonate, aluminum oxide and zirconium silicate according to a specific mass ratio. The preparation method comprises the following steps: mixing the raw materials, melting at 1300 + / -10 DEG C in a pure oxygen environment, and quenching after wiredrawing to detect a molten state. The matte glaze completely avoids the use of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are eliminated from the source, the fluorine content of the product is not detected through detection, and the limit value requirements of European Union REACH regulations are met. Zinc oxide and ZnO / TiO2 are added, so that the liquid phase viscosity is reduced, ion diffusion is accelerated, and the opacity (opacification performance) and gloss of the porcelain glaze are enhanced.

The invention discloses a fluoride-salt-free and nitrate-free cast iron enamel zirconium white glaze as well as a preparation method and application thereof, and belongs to the technical field of enamel. The zirconium white glaze is prepared from quartz, borax pentahydrate, magnesium carbonate, potassium carbonate, potassium feldspar, zinc oxide, aluminum hydroxide, calcium carbonate, zirconium silicate, sodium tripolyphosphate and lithium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The zirconium white glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, and meanwhile, the zirconium white glaze has good porcelain surface, luster and firing adaptability, is suitable for cast iron matrixes, has the firing temperature of 740-760 DEG C and the firing time of 87-87 hours, and can be widely applied to cast iron substrates. The method can be used for producing green and environment-friendly enamel products.

The invention discloses high-temperature-resistant fluorine-modified estersil and a preparation method thereof, and relates to the technical field of organosilicon materials.The high-temperature-resistant fluorine-modified estersil comprises a group A and a group B. The group A serves as a main base material and functional filler and is used for providing a film-forming framework and the high-temperature-resistant characteristic; the group B is a cross-linking curing unit and is used for regulating and controlling the reaction rate and the final cross-linking density; the component A comprises the following raw materials: a fluorine-terminated vinyl estersil prepolymer, a vinyl estersil diluent, surface fluorinated nano silicon dioxide, spherical aluminum oxide, an antioxidant and a defoaming agent; the component B comprises the following raw materials: a hydrogen-containing silyl ester cross-linking agent, a platinum catalyst and an inhibitor. A fluorine-terminated structure is introduced into a vinyl estersil prepolymer, and surface fluorinated nano silicon dioxide and spherical aluminum oxide are adopted for synergistic filling, so that the thermal stability and interface bonding force of the material are improved; the obtained high-temperature-resistant fluorine-modified estersil can still keep excellent mechanical strength and electrical insulation performance under the condition of 250-300 DEG C, and has the characteristics of low surface energy and pollution resistance at the same time.

The invention discloses a high-weather-resistance photocuring coating with radar infrared stealth and intelligent anti-counterfeiting functions and preparation, and relates to the technical field of special functional materials. According to the coating, stealth, anti-counterfeiting and extreme environment tolerance are realized through multi-component collaborative design: matrix resin is prepared by compounding organic fluorine modified epoxy acrylate and polyurethane acrylate, and trifluoro propyl trimethoxy silane and polyoxyethylene ether block copolymer are introduced, so that weather resistance is improved; the photo-initiation system contains a free radical / cation composite initiator and a low-temperature initiator, and supports wide-temperature-range curing. The functional filler comprises a core-shell complex and carbon nanotube / graphene composite powder, and uniform dispersion of the filler is realized through a gradient grinding process. The method is suitable for military equipment camouflage, aerospace protection and criminal investigation anti-counterfeiting, 800-1400 [mu] m thermal radiation matching, radar wave absorption and mobile phone camera readable encryption information are achieved, and an innovative solution is provided for high-end equipment protection and information safety.

The invention relates to the technical field of etching liquid, in particular to a copper metal etching liquid composition. Comprising the following components in percentage by weight: 5-10% of hydrogen peroxide, 0.1-0.3% of a first fluorine source, 1-5% of first inorganic acid, 1-5% of alkali, 0.01-0.8% of a first metal corrosion inhibitor and the balance of deionized water; and the auxiliary agent comprises 2-8% of a second fluorine source, 10-55% of second inorganic acid, 0.1-2% of a second metal corrosion inhibitor and the balance of deionized water. The etching liquid is excellent in etching effect, CD-loss reaches 0.6-0.8 [mu] m, the slope angle reaches 40-50 degrees, the highest copper load reaches 20000 ppm, and meanwhile the problem that when copper is high, due to the fact that the nitric acid concentration is too high, metal etching is abnormal is solved.

The invention belongs to the technical field of lithium batteries, and particularly relates to a composite defoaming agent as well as a preparation method and application thereof. The composite defoaming agent comprises an epoxypropane-ethylene oxide segmented copolymer, a ZIF-8 packaging material, a temperature-sensitive copolymer and a conductive synergist, the ZIF-8 packaging material comprises ZIF-8 and a modified organic silicon polymer packaged in the ZIF-8, and the modified organic silicon polymer contains fluorine ions. According to the invention, the ZIF-8 packaging material and the thermo-sensitive copolymer are adopted, and other components are combined, so that the gas content of the negative electrode slurry and the resistance amplification of a pole piece can be reduced, and the storage stability, the thermal stability and the defoaming response efficiency can be improved; the defoaming agent has a good defoaming effect and a slow release effect, can inhibit thermal migration, and avoids interface resistance rise and phase separation.

The invention provides a metal plate frame and fluororubber sealing assembly and a preparation method thereof, and the preparation method is applied to the technical field of semiconductor sealing and comprises the steps that S1, a metal plate frame is coated with an adhesive, dried and then cooled, and the adhesive is a trithiocyanuric acid derivative solution; s2, a cross-linking agent and an addition agent are added in the thin-passing mixing process of the perfluoroether elastomer, a mixed rubber compound is obtained, the addition agent comprises fluorinated silicon dioxide, fluorinated titanium dioxide or PFA micro powder, and the mass of the addition agent is 2-10% of the mass of the perfluoroether elastomer; and S3, the mixed rubber sheet is placed in a metal plate frame, the metal plate frame with the mixed rubber sheet is placed in a mold to be subjected to hot pressing vulcanization forming, then secondary vulcanization is conducted, then radiation vulcanization is conducted, and the assembly is obtained. The assembly prepared through the method is resistant to plasma etching and high in cleanliness, the bonding performance of the perfluoroether rubber and the metal plate frame is good, and the rate of finished products is high.

The invention belongs to the technical field of environment-friendly materials and wastewater treatment, and particularly relates to a tungsten slag-based fluorine removal agent and a preparation method thereof.The preparation method of the tungsten slag-based fluorine removal agent comprises the following steps that S1, tungsten slag and lithium slag are obtained; s2, sequentially drying, grinding and sieving the tungsten slag to obtain a first raw material, and sequentially drying, grinding and sieving the lithium slag to obtain a second raw material; s3, mixing the first raw material, the second raw material and water according to a certain proportion to obtain a slag-water mixture; s4, the slag-water mixture is adjusted to be acidic, the slag-water mixture is subjected to a hydrothermal synthesis reaction, washing and drying are conducted after filtering, and the tungsten slag-based fluorine removal agent is obtained; according to the method, the tungsten slag and the lithium slag are mixed, then the tungsten slag-based fluorine removal agent is synthesized through the hydrothermal method, the obvious removal effect on fluorine in waste water is achieved, the purpose of treating waste with waste is achieved, and high-value utilization of the tungsten slag and the lithium slag is achieved.

The invention discloses fluoride-salt-free and nitrate-free low-temperature pearlescent glaze for steel plate enamel as well as a preparation method and application of the pearlescent glaze, and belongs to the technical field of enamel. The pearlescent glaze is prepared from quartz, anhydrous borax, titanium dioxide, magnesium carbonate, sodium tripolyphosphate, potassium carbonate, lithium carbonate, potassium feldspar, zinc oxide and V-26 according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The pearlescent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the pearlescent glaze has good porcelain surface, luster and low-temperature firing adaptability, is suitable for a steel plate matrix, has the firing temperature of 760-800 DEG C and the firing time of 10-20 minutes, and is suitable for a steel plate. The method can be used for producing green and environment-friendly enamel products.

The invention discloses fluoride-salt-free and nitrate-free low-temperature acid-resistant translucent glaze for steel plate enamel as well as a preparation method and application of the translucent glaze, and belongs to the technical field of enamel. The semitransparent glaze is prepared from quartz, anhydrous borax, titanium dioxide, trisodium phosphate, potassium carbonate, lithium carbonate, aluminum oxide, zinc oxide and sodium carbonate according to a specific mass ratio. The preparation method comprises the steps of raw material mixing, high-temperature melting under a pure oxygen condition, wiredrawing detection, quenching and the like. The semitransparent glaze is completely free of fluoride salt and nitrate, the problems of fluoride emission and environmental protection equipment blockage are avoided from the source, the fluorine content of the product is not detected through detection, the product meets the requirements of European Union REACH regulations, meanwhile, the product has good porcelain surface, luster and low-temperature firing adaptability, and is suitable for steel plate substrates, the firing temperature is 760-800 DEG C, and the firing time is 2-3 hours. The method can be used for producing green and environment-friendly enamel products.

The invention discloses a sealing gasket for an energy storage hydrogen production electrolytic cell and a preparation method of the sealing gasket, and belongs to the technical field of sealing gasket production. Comprising the following steps: carrying out surface treatment on glass fibers, and carrying out hot-pressing mixing with a polyimide block copolymer to obtain a supporting layer; glass fibers are subjected to surface treatment and then hot-pressed and mixed with the polyimide block copolymer to obtain a supporting layer; the polytetrafluoroethylene, the triallyl isocyanurate and the nano silicon dioxide are mixed and stirred, and the sealing layer is obtained through injection molding after radiation crosslinking; the epoxy resin matrix, the modified fluororubber and the anti-aging agent are subjected to banburying and vulcanization to obtain the protective layer; and the supporting layer, the sealing layer and the protective layer are sequentially stacked, hot-pressed and compounded to obtain the sealing gasket. The sealing gasket for the energy storage and hydrogen production electrolytic cell is improved in structural stability and has good creep resistance and chemical resistance.

The present invention provides a composition for forming a gel polymer electrolyte which includes a lithium salt; an organic solvent; and a crosslinking compound represented by Formula 1. wherein in Formula 1, L1, L2, L3, and L4 are each independently selected from a direct bond or an alkylene group having 1 to 3 carbon atoms, L5 and L6 are each independently an alkylene group having 1 to 20 carbon atoms in which at least one methylene group is optionally substituted with an ether group and at least one hydrogen is substituted with fluorine, and R1 and R2 are each independently selected from hydrogen, an alkyl group having 1 to 3 carbon atoms, or a halogen.

The invention discloses a green data center key cooling system, and relates to the technical field of data center energy saving and heat management. The system comprises a cabinet, a cold and hot channel, a refrigeration device, a waste heat recovery device and a control system. The refrigeration device comprises an indoor refrigeration unit, an outdoor heat dissipation unit and a fluorine pump energy-saving unit, and heat exchange and cooperative operation are achieved through pipelines. The cold and hot channel is provided with a guide plate and an adjustable air valve to optimize airflow distribution; the waste heat recovery device comprises a fluorine-fluorine heat exchanger, a heat pump system and a circulating medium box, and recovery and reutilization of heat energy are achieved. The control system integrates a lightweight edge AI module, constructs a multi-stage temperature sensing and load prediction mechanism, dynamically adjusts the power output of each cooling unit, and supports redundant fault-tolerant switching. The system intelligently switches the operation modes of the fluorine pump and the heat dissipation unit based on the external temperature and the thermal load prediction result, energy consumption is effectively reduced, and the energy efficiency ratio is increased.

The invention relates to the technical field of biological medicines, and particularly discloses a BODIPY (boron dipyrromethene)-based compound and an application of the BODIPY-based compound in photodynamic oxidation of beta-amyloid protein (Abeta). The compound takes iodo-BODIPY as a photosensitive core and is connected with 4-t-butyloxycarboryl benzene as an A beta recognition group. The introduction of iodine atoms significantly enhances the intersystem crossing ability of molecules, so that the molecules have excellent reactive oxygen species (ROS) generation ability. The compound has high ROS yield, good optical stability and biocompatibility, can specifically target A beta aggregate, realizes photodynamic oxidative degradation, and provides a novel potential tool for treatment of Alzheimer's disease.

The utility model discloses a weighing type sulfuric acid anti-corrosion filling machine which comprises a first filling area and a second filling area which are arranged in parallel, and each of the first filling area and the second filling area is composed of a rack and a conveying mechanism penetrating through the rack. A sulfuric acid conveying assembly parallel to the conveying mechanism is installed on the portion, behind the conveying mechanism, of the supporting plate face of the machine frame, a height lifting mechanism is arranged on the portion, between the conveying mechanism and the sulfuric acid conveying assembly, of the supporting plate face, a PFA lining structure is arranged on the inner wall of a pipeline of the sulfuric acid conveying assembly, and the adjacent pipelines are in sealed connection through flanges. The surface of the stainless steel pipe is lined with a PFA material, conveying and filling of high-corrosion liquid such as sulfuric acid are achieved through the fluorine lining valve and the corrosion-resistant hose, the whole machine achieves high-precision filling metering through the two sets of filling stations, and gas generated by the solution is collected and treated through the cover structure and the acid mist collecting device. And high-speed precise filling operation of high-corrosivity materials such as sulfuric acid is achieved.

The invention provides a nitrogen and fluorine co-doped three-dimensional carbon material as well as a preparation method and application thereof. The preparation method comprises the following steps: in a protective atmosphere, heating a uniform mixture containing an organic carbon source, a fluorine source and a nitrogen source at 400-1000 DEG C to obtain the nitrogen-fluorine co-doped three-dimensional carbon material. When the nitrogen and fluorine co-doped three-dimensional carbon material is used for preparing a sodium ion battery without a negative electrode active layer, the sodium ion deposition process can be well homogenized, sodium dendrite growth and negative electrode volume expansion are inhibited, and the sodium ion battery has relatively low polarization and longer cycle life.

The invention discloses a super-amphiphobic flame-retardant ice-resistant coating as well as a preparation method and application of the super-amphiphobic flame-retardant ice-resistant coating with a multi-layer surface coating, and belongs to the technical field of functional materials of electrical equipment. The coating comprises micron-sized ammonium polyphosphate, a nano-sized inorganic filler, fluorinated alkyl silane and a fluorine surfactant, the super-amphiphobic, flame-retardant and ice-resistant coating is constructed through multi-scale components, and the super-amphiphobic, flame-retardant and ice-resistant coating is spontaneously assembled on the surface of a base material in the coating process to form a coating surface with a molecular nanometer, micrometer and macroscopic multi-level structure; the coating shows good super-amphiphobic characteristics, the contact angle of the structure surface after long-time placement under the room temperature condition is basically kept unchanged, the contact angle to water and oil is still larger than 150 degrees after multiple times of cyclic friction and washing, meanwhile, the coating has excellent flame retardance, ice resistance and wear resistance, the icing delay time is greatly prolonged, and the coating has the good anti-freezing effect. And no open fire is generated when the cable is in contact with an external fire source, so that the cable has important engineering application value for electric power facilities under harsh environmental conditions.