516 results about "Aluminosilicate" patented technology

The invention provides an iron tailing-based geopolymer electromagnetic wave attenuation performance optimization control method and system, and relates to the technical field of electromagnetic wave attenuation, and the method comprises the steps: 1, setting a synthesis condition parameter set of an iron tailing-based geopolymer in a simulation environment, comprising virtual matching of raw materials, particle size distribution, concentration gradient of an alkali activator and curing temperature-time coupling parameters, and a forming process is deduced through an amorphous phase topological configuration and a pore network evolution rule of aluminosilicate gel in a geopolymer microstructure; and step 2, constructing an interface reaction kinetics process based on the synthesis condition parameter set, and generating an enhanced interface digital mapping system with periodically arranged aluminum oxide and silicon oxide regular tetrahedrons through virtual iteration of mineral admixture ratio and forming process parameter boundary conditions. According to the method, a strengthened interface is constructed through simulation synthesis, a loss layer database is established, and microstructure regulation and control and multi-band electromagnetic wave efficient attenuation are achieved.

A vacuum insulating panel includes first and second substrates (e.g., glass substrates), a hermetic edge seal, a pump-out port, and spacers sandwiched between at least the two substrates. The gap between the substrates may be at a pressure less than atmospheric pressure to provide insulating properties. The vacuum insulating panel may include ceramic (e.g., aluminosilicate glass) spacers, which may be chemically strengthened.

The invention discloses a red-mud-based multi-element solid waste cementing material as well as a preparation method and application thereof, and belongs to the technical field of building materials. The red-mud-based multi-element solid waste cementing material comprises the following components in parts by mass: 30-40 parts of red mud, 5-15 parts of fly ash, 10-20 parts of superfine slag powder, 30 parts of Portland cement, 4 parts of dihydrate gypsum and 2-25 parts of an alkali activator, alkaline components of the red mud are utilized to excite potential activity of the superfine slag powder and the fly ash, the additional alkaline activator excites potential activity in the red mud, and meanwhile, several industrial solid wastes and the Portland cement generate gel substances such as hydrated aluminosilicate under the synergistic effect, so that the mechanical property of the cement is improved; the building material meeting the strength requirement is provided while a large amount of red mud is consumed.

The invention relates to the technical field of solid waste treatment, in particular to a cementing material as well as a preparation method and application thereof. The invention provides a preparation method of a cementing material, which comprises the following steps: S1, adding water into waste incineration fly ash, electrolytic manganese residue and carbide slag, and carrying out mechanical activation to obtain mixed slurry; s2, after the mixed slurry is subjected to pouring forming, curing is conducted, and a cementing material is obtained; the doping amount of the carbide slag accounts for 5-10 wt% of the total mass of the waste incineration fly ash, the electrolytic manganese slag and the carbide slag solid. According to the method, the waste incineration fly ash, the electrolytic manganese residues and the carbide slag are subjected to mechanical activation and synergistic treatment, self-cementation solidification is achieved in an alkaline environment provided by the carbide slag by utilizing the complementary effect of potential gelation activity of aluminosilicate in the electrolytic manganese residues and calcium-rich substances in the waste incineration fly ash, traditional excitants such as cement and lime do not need to be additionally added, and the cost is reduced. The dependence on additional raw materials is obviously reduced, and an effective solution is provided for recycling of a large amount of solid wastes.

Pumpable slurry compositions including at least one aluminosilicate additive and optional pozzolanic cement additives and methods including the pumpable slurry compositions improve development of compressive strengths in the pumpable cement slurry compositions. The methods utilize one or more pumpable cement slurry compositions including at least one cement component, water, at least one first aluminosilicate additive, at least one optional second aluminosilicate additive, and one or more optional pozzolanic additives, where the at least one first aluminosilicate additive has an amorphous phase of greater than about 50% and a weight ratio of silica oxide to aluminum oxide of about 1.0 to about 2.5, and the at least one optional second aluminosilicate additive has a weight ratio of silica oxide to aluminum oxide of about 1.7 to about 3.3.

The invention provides a mixed type shield synchronous grouting material and a grouting process, and relates to the technical field of building materials, the grouting material is composed of fast hydration Portland cement, activated aluminosilicate minerals, nanometer silicon powder, bentonite, a reversible thixotropic polymer, a delayed hydration agent, coated calcium aluminate fast setting powder and a coated silicate gel precursor. The early-stage reaction is inhibited by delaying hydration, and a controllable solidification sequence of slurry from a flowable stage, a rearrangement structure stage to a rapid solidification stage is realized by breaking a membrane under the action of temperature or pressure gradient. In the process, by monitoring the conductivity, the concentration of Ca < 2 + > / Mg < 2 + > and the temperature in real time, the adding amount of an additive and grouting parameters are automatically adjusted, so that the stable diffusivity of the material is kept and the curing speed is accelerated under different stratum conditions. The solidified body forms a C-S-H, C-A-S-H and N-A-S-H gel interpenetrating network, the permeability coefficient is low, the water dispersion resistance is high, and the shield grouting quality and the tunnel structure safety can be remarkably improved.

The invention discloses a spinel and aluminosilicate composite Fenton-like catalyst derived from iron tailings as well as a preparation method and application of the spinel and aluminosilicate composite Fenton-like catalyst. Solid waste iron tailings are used as raw materials, a powdery spinel and aluminosilicate composite material is prepared through an improved sol-gel-calcination technology, then the powdery spinel and aluminosilicate composite material, biochar and water glass are mixed, molded and calcined, and the granular composite catalyst is prepared. The method is simple and convenient to operate and low in cost, and has industrial preparation feasibility. The prepared catalyst can efficiently activate oxidizing agents such as persulfate and hydrogen peroxide to generate active oxygen species, and organic pollutants in mineralized water can be rapidly degraded. The method is characterized in that the catalyst is prepared from iron tailings in a high-valued manner, the specific surface area of the material, the generation efficiency of active species and the cycling stability are remarkably improved through structure optimization, the problems that a traditional catalyst is high in cost, poor in industrial adaptability and the like are solved, and an economical and environment-friendly new thought is provided for large-scale treatment of organic pollution through an advanced oxidation technology; the method has double benefits of tailing recycling and environmental pollution treatment.

The invention discloses a desulfurizing agent for a cement kiln as well as a production method and application of the desulfurizing agent. The desulfurizing agent is prepared from the following raw material components in percentage by weight: 88-96 wt% of limestone; 2-6 wt% of an iron raw material; 1-6 wt% of gypsum; and 0-4 wt% of a silicon-aluminum material. The desulfurizer is produced by utilizing a kiln line of a cement enterprise, is dried and ground with raw materials according to a mass ratio of 1: 100 to 3: 100, and then is put into a cement kiln system for cement clinker production, so that the emission concentration of sulfur oxides in kiln tail flue gas produced by sulphoaluminate cement clinker can be reduced from more than 2000mg / Nm < 3 > to less than 35mg / Nm < 3 >; and for other types of cement clinker, the content of the cement clinker can be reduced from 1000 mg / Nm < 3 > or above to 35 mg / Nm < 3 > or below, the desulfurization effect is stable, and the environment-friendly emission requirement can be continuously met.

The invention relates to the field of glass, in particular to lithium-free alkali aluminosilicate glass as well as a preparation method and application thereof. According to the glass, SiO2, Al2O3, Na2O, K2O, MgO and ZrO2 serve as main components, the content of Li2O is lower than 100 ppm, a nitrate-sulfate-carbon powder composite clarifying agent is adopted, the number of bubbles and the content of residual sulfur are effectively reduced, and use of a toxic or ultraviolet absorption type clarifying agent is avoided. ZrO2 is obtained by calcining a zirconium-based metal-organic framework material and is good in dispersity, and the devitrification resistance is improved. During float forming, through micro-positive pressure, high-purity protective atmosphere and four-zone gradient temperature control, the tin penetration depth is controlled within 15 microns, and the surface tin content is smaller than or equal to 4 micrograms / cm < 2 >. The obtained glass has high light transmittance, high hardness and excellent chemical strengthening performance, and is suitable for the high-end fields of electronic display cover plates, vehicle-mounted screens, touch panels, photovoltaic substrates and the like.

A method can include heating an aqueous reaction mixture comprising a silicon source and a boron source and / or an aluminum source in the presence of a quaternary structure directing agent to a temperature of at least 75° C. to produce a zeolite. A composition can include a borosilicate zeolite, an aluminosilicate zeolite, or an aluminoborosilicate zeolite having a framework symmetry of C2 / m and a unit cell with measurements of a of 3.5 Å to 4.5 Å, b of 20.1 Å to 21.1 Å, c of 15.5 to 16.5 Å, and β of 97° to 98°.

The invention discloses a method for synthesizing a high-crystallinity zeolite molecular sieve through in-situ crystallization of aluminosilicate minerals, and belongs to the technical field of zeolite molecular sieve synthesis. The preparation method comprises the following steps: preparing a crystal nucleus liquid containing zeolite molecular sieve microcrystals and a solid-phase wafer; mixing aluminosilicate minerals with the crystal nucleus liquid, and respectively roasting at 850-1000 DEG C and 650-800 DEG C to prepare an active mineral silicon source and an active mineral aluminum source; and mixing the active mineral source with additional silicon species, NaOH, a template agent, a crystal nucleus liquid, a solid-phase wafer and water, crystallizing at 90-150 DEG C, and post-processing to obtain the high-crystallinity zeolite molecular sieve. By introducing the crystal nucleus liquid and the solid-phase wafer, silicon and aluminum components in the aluminosilicate mineral are promoted to be converted into the target molecular sieve in situ, the crystallinity of the product is remarkably improved, the synthesis cost is reduced, and the method is suitable for the fields of petrochemical engineering, environmental protection and the like.

The present invention aims to provide a composition with higher ability to enhance early strength development compared to conventional compositions. The present invention relates to an aluminosilicate-containing composition containing: an aluminosilicate; and a water-soluble polymer, the aluminosilicate-containing composition further containing at least one of an amine having a molecular weight of not more than 1,000 or a metal compound.

The invention relates to the technical field of roadbed materials, in particular to a composite filling material and a preparation method and application thereof. The composite filling material provided by the invention is prepared from the following raw materials in parts by weight: 18 to 26 parts of pretreated phosphogypsum, 30 to 45 parts of pretreated household garbage incineration bottom ash, 8 to 18 parts of alkaline excitation material, 6 to 20 parts of aluminum-silicon material, 5 to 25 parts of aggregate and 1 to 4 parts of sodium sulfate aqueous solution, the pretreatment of the phosphogypsum comprises lime milk aging treatment; the pretreated household garbage incineration bottom ash comprises gelation active fine powder and structural aggregate. The composite filling material formed by taking the ardealite, the household garbage incineration bottom ash, the alkaline excitation material and the aluminum-silicon material as main raw materials is high in industrial solid waste mixing amount, stable in performance and environment-friendly, reduces the pollutant leaching risk, is suitable for roadbed structures such as an embankment filling layer, a semi-rigid base layer and a flexible subbase layer, and has a wide application prospect. And the benefit is obvious.

The invention relates to a preparation method and application of an alkali-activated iron tailing geopolymer adsorbent. According to the method, an iron tailing geopolymer is prepared through an alkali activation method, that is, an aluminosilicate structure in iron tailings is destroyed in an alkali activation mode, so that silica tetrahedron and alumina tetrahedron structures of the iron tailings are reconstructed, and a geopolymer material with adsorption capacity is prepared; on the basis, a foaming agent hydrogen peroxide solution is introduced to adjust the performance, and parameters such as modulus, water cement ratio and curing temperature of the alkali activator are respectively adjusted to prepare an optimal sample. The iron tailing geopolymer adsorbent material which is high in adsorption rate and good in stability is obtained, and the effect of adsorbing residual ciprofloxacin in wastewater is remarkable.

The invention belongs to the technical field of soil amendments, and particularly relates to a saline-alkali soil biological-mineral composite amendment prepared from industrial waste and a preparation method thereof. Alkali fusion activated steel slag provides a quick-acting active calcium source, hydrothermal modification neutralized red mud forms hydrated aluminosilicate gel solid sodium, modified biochar enhances cation exchange capacity, a composite functional bacterial agent drives MICP biomineralization reaction, a quick-acting-slow-release-storage three-stage gradient improvement system is established, and the quick-acting-slow-release-storage three-stage gradient improvement effect is achieved. According to the present invention, the effects of 0-50 cm soil profile full-layer improvement and 12-24 month continuous improvement are achieved, 90 d after the modifier is applied, the soil pH value of the severe saline-alkali soil is reduced to 7.8 from 10.1, the conductivity is reduced to 3.2 dS / m from 11.5 dS / m, the sodium adsorption ratio is reduced to 11 from 42, the crop yield increase amplitude reaches 40-60%, 15-25 kg of the modifier is fixed per ton, and the industrial waste resource utilization rate gt is achieved; 90%.

The invention relates to a preparation method and application of a hardness removal agent, and the method comprises the following steps: 1) alkali fusion reaction: mixing and fusing bauxite and NaOH to generate soluble sodium aluminate NaAlO2; 2) compounding silicon and aluminum: dissolving aluminum silicate in hot water, adding silica sol, stirring and mixing, and regulating the pH value to 11-12 by using NaOH; an aluminosilicate precursor gel is formed; 3) hydrothermal crystallization: transferring the aluminosilicate precursor gel into a high-pressure reaction kettle, and carrying out hydrothermal reaction to promote polymerization of a silicon-aluminum network; and 4) post-treatment: cooling aluminosilicate, centrifugally washing the aluminosilicate until the aluminosilicate is neutral, drying the aluminosilicate at 110 DEG C, and grinding the aluminosilicate to obtain a white powder product. A silicon-aluminum network structure of the hardness removal agent prepared by the method has regular pore channels, the highest calcium and magnesium removal rate can reach 90% or above, the hardness removal agent is high in anti-interference performance, is kept stable in a pH range of 6-12, is not influenced by common Cl <-> and SO4 < 2-> in water, and is high in stability.

The invention belongs to the technical field of green building materials, and provides fly ash-based geopolymer concrete and a preparation method thereof. The method provided by the invention comprises the following steps: mixing fly ash, natural sand, a composite activator and water, and sequentially carrying out vibration molding and sealed maintenance on the mixture to obtain the fly ash-based geopolymer concrete. The mixing proportion and the curing process are optimized through orthogonal design, and the compressive strength and the breaking strength of the geopolymer concrete are remarkably improved; the composite activator (6mol / L NaOH solution + 0.4 mol / L Na2SiO3 solution) can effectively promote the depolymerization of aluminosilicate to form compact N-A-S-H gel, so that the strength and durability of the concrete are enhanced; the process is simple, the cost is low, the fly ash can be treated on a large scale, the use amount of cement is reduced, carbon emission is further reduced, and the method conforms to the development trend of green building materials.

The application discloses a method for separating aluminosilicate minerals and purifying quartz sand under neutral conditions and application thereof. The method for separating aluminosilicate minerals and purifying quartz sand under neutral conditions adopts one or more times of reverse flotation operations, and the reverse flotation operation comprises the following steps: adding a quartz depressor into quartz raw sand slurry or low-aluminum-content fine quartz sand slurry obtained through previous reverse flotation operation and mixing; then adding an aluminosilicate mineral collector and mixing; subsequently, adding a foaming agent under the condition of air agitation and stirring, and performing quartz reverse flotation, during which, stirring is kept and bubbles are scraped; and finally, washing the remaining slurry to obtain low-aluminum-content fine quartz sand. The reverse flotation process of the application is performed under neutral conditions, avoids the use of traditional strong acid and strong alkali, and further reduces the harm of the purification process to production equipment, ecological environment and operating personnel.

The invention provides a phosphoric acid-activated modification admixture of a silico-aluminate-containing tailing cementing material. The phosphoric acid-activated modification admixture is a mixture of a modification component and water, the modified component is prepared from the following components in parts by weight: 0.4 part of a high-efficiency polycarboxylate superplasticizer, 1 to 5 parts of citric acid and 25 to 50 parts of a silane coupling agent. The invention also provides a method for preparing the modified admixture of the phosphoric acid activated aluminosilicate-containing tailings cementing material, and an application of the modified admixture in preparation of the cementing material based on the phosphoric acid activated aluminosilicate-containing tailings. The modified admixture provided by the invention can improve the hydrophilicity of the aluminosilicate-containing tailing cementing material activated by phosphoric acid, provides a water reducing function, and is beneficial to resource utilization of the cementing material in building materials.

A solid-state electrolyte as well as a preparation method therefor and the use thereof. The solid-state electrolyte comprises aluminosilicate and an oxide electrolyte body, the solid-state electrolyte is of a porous Na-Y type cage-shaped structure, and the solid-state electrolyte has excellent ion conduction capability.

An article according to an exemplary embodiment of the present disclosure includes, among other possibilities, a substrate and a barrier layer on the substrate. The barrier layer includes a bond coat including a matrix, diffusing particles disposed within the matrix, and gettering particles disposed within the matrix, and a top coat including a component reactive with calcium-magnesium-aluminosilicate (CMAS). Articles and methods for applying the calcium-magnesium-aluminosilicate (CMAS)-resistant top coat are also disclosed.

The invention discloses a green process method for extracting alkali metal from composite ore, and relates to the field of metal extraction.The green process method comprises the following steps that S1, aluminosilicate composite ore containing alkali metal and ammonium carbonate are mixed and roasted, and activated clinker is obtained; s2, mixing the activated clinker with an ammonium citrate solution, carrying out a leaching reaction at 80-95 DEG C, and carrying out solid-liquid separation after the reaction to obtain a leaching solution and leaching residues; according to the green process method for extracting the alkali metal from the composite ore, through systematic coupling of a low-temperature ammonium carbonate activation-ammonium citrate complexing leaching-manganese system / ammonium phosphomolybdate specific adsorption-bipolar membrane electrodialysis closed-loop regeneration technology chain, a synergistic interaction effect is formed; the activation step significantly improves the leaching efficiency of the subsequent mild leaching agent.

The invention relates to the field of preparation of doped glass, and discloses a method for preparing bismuth-doped yttrium aluminosilicate glass by a sol-gel method and a secondary melting method, which mainly comprises the following steps: mixing all components in a liquid environment by using a sol precursor, and quickly drying at high temperature to prepare a dry gel block. And carrying out heat preservation and heat treatment on the xerogel at a low temperature through subsequent two melting processes to prepare uniform bubble-free bismuth ion doped yttrium aluminosilicate glass, crushing the glass, carrying out ball milling, carrying out second high-temperature heat treatment, taking out the glass at a high temperature, and pouring the glass into a mold. In the process, the xerogel prepared in advance by adopting a sol-gel method improves the doping uniformity and reduces the melting point of the glass; gas is completely removed through the first-time pre-sintering treatment, holes are closed through sintering, and the defects of bubbles, stripes and the like of the glass are eliminated, so that the transmittance and the luminescence property are improved; ball-milled powder instead of cullet is adopted for secondary melting, so that the uniformity of the glass is improved, and the melting point is further reduced.

The application provides a method for preparing aluminum-silicon aerogel from coal gangue and a product prepared by the method, and relates to the field of heat insulation. The method for preparing aluminum-silicon aerogel from coal gangue comprises the following steps: coal gangue activation, preparation of a precursor solution, sol-gel, impurity washing, high-temperature aging and post-treatment. The method for preparing aluminum-silicon aerogel from coal gangue does not need to extract silicon dioxide and aluminum oxide from the coal gangue respectively, can directly prepare aluminum-silicon-based aerogel from the coal gangue, effectively shields the introduction of impurities contained in the coal gangue in the process of preparing the aerogel, avoids the adverse effects of the impurities on the performance of the aerogel, and further improves the mechanical performance, stability and temperature resistance of the aluminum-silicon aerogel.

This application relates to the field of lightweight building materials technology, and particularly to acid-activated foamed materials, their preparation methods, and components. The method for preparing acid-activated foamed materials includes: chemically reacting raw materials comprising active aluminosilicates, an acid activator solution, and a gas-generating component to obtain the acid-activated foamed material; wherein the acid activator solution contains phosphoric acid and / or acidic phosphates; the gas-generating component includes materials capable of reacting with the acid activator solution and releasing gas. This chemical reaction system includes an acid activation reaction and a gas-generating reaction. The acid activation reaction generates a phosphate-based polymer material through a dissolution-condensation reaction, exhibiting a certain strength. The gas-generating reaction and the acid activation reaction are coupled in terms of reaction sites and time, and the gas-generating process is also coupled with the process of increasing the viscosity of the reaction system. Therefore, the acid-activated foamed material has a uniform and stable pore structure and possesses advantages such as low density, thermal insulation, sound insulation, low energy consumption, fire resistance, and environmental friendliness.

This application relates to the technical field of solid waste utilization for preparing metal adsorbents, and particularly relates to an aluminosilicate solid waste heavy metal adsorbent, its preparation method and application. By mass, the aluminosilicate solid waste heavy metal adsorbent comprises 30-50 parts of modified aluminosilicate solid waste, 20-40 parts of modified sawdust biochar and 1.2-1.6 parts of sodium alginate; the preparation method of the modified sawdust biochar includes: S1. Prepare a modified solution: dissolve catechol in an aqueous solution of 25% ethanol, and then add a composite solvent to obtain a modified solution; S2. Mix the sawdust biochar with the modified solution in a mass ratio of 1:15, stir magnetically at room temperature for 1 h, filter and dry to obtain the modified sawdust biochar.

The invention relates to a method for selectively extracting lithium from clay lithium ore, in particular to the field of lithium extraction.The method comprises the steps that clay lithium ore powder is roasted and activated to obtain roasted ore powder; and mixing the obtained roasted mineral powder with a calcium leaching aid, carrying out water leaching, and carrying out solid-liquid separation to obtain a lithium extracting solution and filter residues. According to the method provided by the invention, the clay type lithium ore is firstly subjected to roasting activation treatment, and ore phase activation conversion of the clay type lithium ore is realized in the high-temperature roasting process, so that the lithium-containing minerals such as kaolinite, lithium chlorite and montmorillonite are subjected to hydroxyl removal and are converted into structures with high leaching activity; the clay lithium ore subjected to high-temperature roasting is subjected to water leaching by adopting a calcium leaching aid, the structure of aluminosilicate minerals is destroyed in a weakly alkaline environment, so that lithium in crystals is released, and meanwhile, impurity elements such as aluminum, silicon, magnesium and iron are fixed in a slag phase, so that efficient selective leaching of lithium is realized.

The disclosure relates to a modified aluminosilicate inorganic mesoporous material and a preparation method therefor. Through calcination modification of nitrate and modification of alkaline chitosan, and through the regulation of parameters such as a particle size and a specific surface area of the aluminosilicate, a concentration of a nitrate solution, a solid-to-liquid ratio of aluminosilicate particles to the nitrate solution, a calcination time, a calcination temperature, and a pH value, a mass fraction and a temperature of the chitosan solution, the modified aluminosilicate inorganic mesoporous material with a stable specific surface area ranging from 30 m2 / g to 40 m2 / g can be stably prepared. Moreover, the size of a pore channel inside the mesoporous material can be as small as sub-nanometer scale.