339results about "Molecular sieve catalyst" patented technology

The present invention provides an integrated plasma catalytic system for biogas conversion comprising a plasma treated mesoporous or microporous catalyst and a plasma source for converting biogas containing methane and carbon dioxide to liquid oxygenates rich in methanol or acetic acid. Biogas from different solid wastes can be converted into liquid oxygenates including methanol and acetic acid under normal temperature and pressure conditions.

The method is for producing para-xylene using, as a main raw material, a mixed gas of carbon dioxide or carbon monoxide or both thereof and hydrogen. The method including: a reaction step of bringing a raw material mixed gas including the mixed gas into contact with a reaction catalyst under high temperature and high pressure to cause a reaction, to thereby obtain a product gas mixture containing para-xylene; a separation step of cooling the product gas mixture obtained in the reaction step to condense a high boiling point component, to thereby separate the product gas mixture into a water phase containing a water-soluble component, an oil phase containing a xylene mixture, and a gas phase containing an unreacted gas; and a circulation step of mixing at least part of the gas phase having been separated in the separation step into the raw material mixed gas.

A method of converting a polymer including contacting a catalyst with a low-density polyethylene polymer to form a mixture and heating the mixture to a temperature of 200 degrees Celsius (° C.) to 600° C. in a microwave reactor to form a product. The catalyst includes an HZSM-5 zeolite, and 1 weight percent (wt. %) to 10 wt. % gallium and 0.1% to 5 wt. % copper, based on the total weight of the catalyst.

The venturi-type scrubber may be used in conjunction with the removal of solids and quench gas-phase reaction products from the gas-phase reaction products. A method can include: providing a reaction product comprising a hydrocarbon gas and a solid; introducing the reaction product into a venturi type scrubber; introducing a scrubbing fluid into the venturi-type scrubber, wherein the scrubbing fluid is at a lower temperature than the reaction product; generating, by the venturi scrubber, a heterogeneous product comprising a scrubbed reaction product and a waste scrubbing fluid, the scrubbed reaction product comprising the hydrocarbon gas, and the waste scrubbing fluid comprising the scrubbing fluid and the solids; and separating the hydrocarbon gas from the multiphase fluid. A system may include a reactor; a venturi-type scrubber having a first inlet fluidly connected to the reactor and a second inlet configured to receive a scrubbing fluid; and a separation column configured to receive a multiphase stream from the venturi scrubber after solids are removed.

The disclosure provides an MTW framework-type molecular sieve with crystallites having an average size of 70nm or below. The sieve includes a structure-directing composition comprising 2-pyrrolidone or its N-alkyl derivative and a quaternary ammonium cation. A method for preparing the sieve and its use in producing olefins from alkanes are also described.

A process for dimerizing and oligomerizing olefins to distillate fuels which utilizes a solid acid catalyst for ethylene oligomerization in a first stage and a metal catalyst for further oligomerization in a second stage. Distillate fuels can be produced from the process. Oligomerized olefins may be recycled to the first stage oligomerization reaction to ensure sufficient oligomerization of smaller olefins.

This invention relates to the field of molecular sieves, specifically to a P-modified metal-doped MWW molecular sieve, its preparation method, and its applications. In this molecular sieve, A... Pδ‑7 / A P ≥50%, A Pδ‑7 represent 31 The peak area of ​​the P species signal peak at the terminal group with a P chemical shift of -7ppm ± 15ppm in the P MAS NMR spectrum, A P It represents 31 The peak area of ​​the total signal peak in the pMAS NMR spectrum. The molecular sieve of this invention has high activity, selectivity, and stability, and excellent resistance to carbon deposition.

A fluidized bed device for coupling naphtha and methanol to prepare aromatics and co-produce olefins and its application method are provided. By using the device, under the action of a catalyst, naphtha reacts with methanol to generate product gas containing aromatics and light olefins as main components. The method can efficiently and selectively convert linear and branched aliphatic hydrocarbons into aromatics, while also increasing p-xylene production through aromatic methylation reactions, with the p-xylene content in the xylene mixture exceeding 75 wt %. The fluidized bed reactor achieves increased p-xylene production by controlling the progression of cascade reactions (naphtha→benzene / toluene→p-xylene). Additionally, it utilizes the methylation reaction of benzene / toluene with methanol to provide in-situ heat for the coupled naphtha-methanol aromatization process, thereby achieving autothermal balance.

An integrated catalyst can be used in an olefin disproportionation reaction. The integrated catalyst contains a plurality of different integrated active phases. The relative positions among different active phases remain substantially unchanged during the olefin disproportionation reaction. The effective distance between respective bisecting planes of two adjacent different active phases is 0.5-5 mm, preferably 1-3 mm.

Provided are (1) a method for converting ethanol, comprising contacting a raw material mixture containing ethylene and ethanol with a catalyst in an adiabatic reactor to obtain a reaction gas containing an olefin having 3 or more carbon atoms, (2) a method for converting ethanol, comprising contacting a raw material mixture containing methanol and ethanol with a catalyst in an adiabatic reactor to obtain a reaction gas containing an olefin having 3 or more carbon atoms, and (3) a method for converting ethanol, comprising: contacting a raw material mixture containing ethanol and ethylene with a catalyst in an adiabatic reactor to obtain a reaction gas containing an olefin having 3 or more carbon atoms; separating the reaction gas into fraction A mainly containing a hydrocarbon having 2 to 3 carbon atoms and fraction B mainly containing a hydrocarbon having 4 to 6 carbon atoms by a first distillation column; and recycling at least a portion of the fraction A as a portion of the raw material mixture to the reaction step.

A quaternary ammonium salt that has a specific structure, an organic structure-directing agent that contains this quaternary ammonium salt, and a method for producing a quaternary ammonium salt. Also, a CON-type zeolite that is mixed crystal in which the molar ratio (Si / Al) of silicon (Si) and aluminum (Al) is from 200 to 2000 and that contains 25 mass% or more of polymorph A, a catalyst containing a CON-type zeolite, and a method for producing a lower olefin using this catalyst.

Provided are: a production method for a modified aluminosilicate that makes it possible to highly selectively produce a hydroquinone via a reaction between a phenol and hydrogen peroxide, with industrially advantageous conditions; a production method for a catalyst that is for producing an aromatic dihydroxide compound and that includes the modified aluminosilicate; a production method for an aromatic dihydroxide compound that uses the catalyst; and a modified aluminosilicate.　A production method for an aluminosilicate according to the present invention comprises: a first step for preparing a liquid obtained by contact between a metal compound (AL) containing aluminum and oxygen and silica in the form of a sol containing water, and obtaining an aluminosilicate in which the molar ratio (HMR) between water and silica is in a specific range; a second step for treating, with acid, the aluminosilicate obtained in the first step; a third step for performing primary firing with respect to the treated product obtained in the second step; and a fourth step for bringing into contact the primary fired product obtained in the third step and a liquid containing one or more elements selected from the group consisting of group 4 elements and group 5 elements of the periodic table, and thereafter performing drying and secondary firing. The metal compound (AL) is preferably a zeolite. The first step preferably includes a step for removing the water.

This disclosure relates to a single stage process for the direct conversion of alcohols, e.g. ethanol, to olefinic mixtures (C2-C7) with low levels of aromatics carried out in a single reactor with two fixed catalyst beds in series, or two catalytic fixed bed reactors in series wherein the first reactor operates at a lower or higher temperature than the operating temperature of the second reactor. The process transformation of ethanol is comprised of ethanol dehydration to ethylene and water in high yield with the first catalyst in the first reactor, or via the first fixed catalyst bed, followed by directly feeding the ethylene and water to the second reactor, or second fixed catalyst bed, with conversion of said ethylene and water to a C2-C7 olefinic mixture with the second catalyst(s) in high yields with minimal aromatic compound formation.

The invention is related to a process for synthesizing a sustainable aviation fuel composition. The process comprises providing a reaction mixture comprising a first compound that is at least one of mevalonolactone, mevalonic acid, mevalonate salt, dehydromevalonic acid, dehydromevalonate salt, dehydromevalonolactone or combinations thereof. The process then involves converting the first compound in the reaction mixture to provide a first intermediate comprising isoprene. Then, the isoprene in the first intermediate is reacted in the presence of a first heat transfer agent to provide a second intermediate comprising terpenes. Finally, the second intermediate is allowed to react in the presence of a second heat transfer agent, or alternatively in neat conditions, and optionally in presence of a catalyst to provide the sustainable fuel composition. The sustainable aviation fuel composition made available from the process of the invention is found to comprise monocyclic aromatic hydrocarbons (MAHs) at useful concentration ranges (along with cycloalkanes) while they are substantially devoid of Polycyclic aromatic hydrocarbons (PAHs).

The present application relates to the technical field of catalyst preparation, and is a catalyst for producing mesitylene from C9 mixed aromatic hydrocarbons and a preparation method thereof.The former is a non-noble metal supported molecular sieve catalyst, the catalyst carrier comprises a molecular sieve and a binder, the molecular sieve accounts for 70% to 90% of the weight percentage of the catalyst carrier, the loading of each element accounts for 1wt% to 10wt% of the weight percentage of the catalyst carrier, and the total loading of elements accounts for 5wt% to 15wt% of the weight percentage of the catalyst carrier.The catalyst for producing mesitylene from C9 mixed aromatic hydrocarbons has good catalytic performance, is applied to the process of producing mesitylene from C9 mixed aromatic hydrocarbons as a catalyst for alkylation reaction and isomerization reaction, finally eliminates the interference of methyl ethyl benzene, maximizes the production of mesitylene, the content of methyl ethyl benzene is less than 0.5%, and the yield of mesitylene is greater than 25%.

The invention relates to a process comprising reacting mevalonic acid, or a solution comprising mevalonic acid, to yield a first product or first product mixture, optionally in the presence of a solid catalyst and / or at elevated temperature and / or pressure. The invention further relates to a process comprising: (a) providing a microbial organism that expresses a biosynthetic mevalonic acid pathway; (b) growing the microbial organism in fermentation medium comprising suitable carbon substrates, whereby biobased mevalonic acid is produced; and (c) reacting said biobased mevalonic acid to yield a first product or first product mixture.

The present invention relates to the field of molecular sieves, and particularly relates to a P-modified MWW molecular sieve, and a preparation method therefor and the use thereof. The molecular sieve shows APδ-7 / AP ≥ 40%, and preferably ≥ 50%, wherein APδ-7 represents a peak area of a P-species signal peak, which has a chemical shift within the range of -22 ppm to 8 ppm in a 31P MAS NMR spectrogram, and AP represents the total peak area of all signal peaks in the 31P MAS NMR spectrogram. A catalyst which contains the molecular sieve of the present invention has high levels of activity, selectivity and stability, and has an excellent carbon deposition resistance capability.

The present invention relates to an isomerizing dehydration process for a feed comprising at least one primary monoalcohol of formula R-CH2-OH, wherein R is a nonlinear alkyl radical of general formula CnH2n+1, where n is an integer between 3 and 20. The process comprises an isomerizing dehydration step carried out in the gas phase at a weighted average temperature between 200 and 300°C, a pressure between 0.1 and 1 MPa, and a weight-hourly spatial velocity (WHV) between 1 and 25 h⁻¹, in the presence of a catalyst comprising at least one zeolite. The zeolite has at least one series of channels whose pore opening is defined by an 8-oxygen ring (8MR) and a mesoporous volume greater than or equal to 0.10 mL / g. Figure 2 to be published

Provided is a method for producing an olefin-containing composition, the method comprising a step of decomposing a plastic in the presence of a zeolite to produce an olefin-containing composition containing an olefin having 2 to 5 carbon atoms, and the zeolite is an MFI-type zeolite containing Rb +.

The present invention provides a solid acid alkylation catalyst and its preparation method and use, the preparation method includes the steps of: S1: mixing aluminum source, water, alkali source, template agent, silicon source and seed crystal to form gel, carrying out crystallization reaction to obtain MWW structure molecular sieve (wherein the template agent is composed of main template agent and sub-template agent with a molar ratio of 0.5-20:1); S2: calcining the MWW structure molecular sieve obtained in S1 to remove template agent, then carrying out ammonium exchange, and calcining again to obtain H type molecular sieve; S3: mixing the H type molecular sieve obtained in S2 with inorganic oxide and nitric acid solution, kneading and molding to obtain solid acid alkylation catalyst. The present invention uses the method of seed crystal and two kinds of template agents to cooperate in crystallization, directly synthesizing MWW structure molecular sieve without using hexamethyleneimine, piperidine, homopiperazine, and further obtaining solid acid alkylation catalyst.

The application discloses a Beta-ZSM-12 composite structure zeolite and a preparation method thereof. In the composite structure zeolite, the Beta zeolite is a core phase, and the ZSM-12 zeolite is a shell phase. The preparation method comprises the following steps: (1) uniformly mixing Beta zeolite, a silicon source, ammonium hydroxide, alcohol and water, then dynamically treating for a certain time and then statically treating, separating, drying, and obtaining a silicon oxide-Beta zeolite composite, wherein the silicon source is selected from organic silicate; (2) mixing the silicon oxide-Beta zeolite composite obtained in the step (1), nano iron oxide particles, water and sugar, evaporating water, then heating under inert conditions, then acid treating, and then separating and drying to obtain a carbon-silicon oxide-Beta zeolite composite; and (3) mixing water, the carbon-silicon oxide-Beta zeolite composite, an inorganic alkali, a template agent and an aluminum source, then loading into a reactor for crystallization reaction, and then separating, drying and calcining to obtain the Beta-ZSM-12 composite structure zeolite. The composite structure zeolite has a stable core-shell structure and can be used as a catalyst or a catalyst carrier.

Described herein are methods for converting butene. In some embodiments, butene is converted to an ethylene-containing products. In additional embodiments, butene is converted to an propylene-containing products. In additional embodiments, butene is selectively converted to an ethylene-containing product and a propylene-containing product. These methods generally include metathesis and cracking reactions, as described.

Processes for converting one or more C1-C5 linear or branched alcohols to one or more C2-C5 olefins are provided. In one exemplary embodiment, the process can be a single stage process for the direct conversion of C1-C5 alcohols to olefinic mixtures (e.g., C2-C5) carried out in a reactor using a catalyst that includes zeolite doped with boron and phosphor. Systems for carrying out these processes are also provided.

The invention is related to a process for synthesizing a polymer for various uses including as a tackifying composition. The process comprises providing a reactant mixture for conducting multistep reactions to produce products with high selectivity and yields. The reactant mixture comprises a first compound comprising at least one carbon-carbon double bond or a precursor therefor; a heat transfer fluid; and at least one stabilizer. The process comprises reacting the first compound or the precursor with a first intermediate mixture in the presence of a heat transfer agent to provide a monomer composition. Optionally the obtained monomer composition may be fractionated. Then, the process involves polymerising one or more fractions of the monomer composition to provide the polymer composition that can be tuned to be tackifying or longer chain.

Provided is a method for preparing aromatic hydrocarbons by means of coupling conversion of carbon monoxide and a polyolefin, belonging to the technical field of polyolefin plastic conversion and recycling. The method uses carbon monoxide and polyolefin type plastic as reaction raw materials, uses as a catalyst a bifunctional catalyst consisting of metal, a metal oxide and a molecular sieve, and comprises performing a conversion reaction under the action of the catalyst. Because carbon monoxide may come from carbon resources such as coal, biomass and natural gas, the reaction process not only achieves optimized utilization of carbon resources, but also converts polyolefin waste plastic into valuable resources, achieving high-value utilization and producing aromatic hydrocarbon products having high added value. The reaction has a very high product yield and product selectivity, the yield of the aromatic hydrocarbons can reach 50%-80%, the proportion of benzene, toluene and xylene in the aromatic hydrocarbons is greater than 60%, and the catalyst can be repeatedly used after simple regeneration treatment. The present application is a new technology for comprehensive utilization of polyolefin type waste plastic and carbon monoxide utilization, and has a good application prospect.

The invention provides a composition used for fuel blending made by a process for reacting a reactant mixture at a reaction temperature to form the composition, wherein the reactant mixture comprises a first compound; a heat transfer fluid; and at least one stabilizer. The composition made from the reactant mixture is found to be substantially free of C7 hydrocarbons. The invention also provides a fuel composition comprising the composition of the invention.

A method for processing a hydrocarbon-containing mixture includes the steps of: I) separating the hydrocarbon-containing mixture into a light fraction and a heavy fraction; II) reacting the light fraction from step I) in an aromatization unit and separating the resulting reaction product into a C5− component and a C6+ component; III) reacting the heavy fraction from step I) and optionally the C6+ component from step II) in an aromatics conversion unit and separating the resulting reaction product into a C5− component, a C6-C7 component, a C8 component, and a C9+ component; and IV) optionally, steam cracking or catalytic cracking one or both of the C5− component from step II) and the C5− component from step III). The method can convert low-value hydrocarbon mixtures into C8 aromatic hydrocarbons and cracking raw materials, and improve the product value. A system for practicing this method is also provided.

The present invention relates to an improved porous solid catalyst (C) adapted for the conversion of methanol and derivatives thereof into low-molecular weight hydrocarbons, based on a zeolite, such as ZSM-5, and on inorganic oxide, such as ceria, in a preferable weight ratio of zeolite:inorganic oxide between 1:1 and 1:5. It further relates to a conversion process and to a system using such a catalyst.

A method for preparing a cracking catalyst includes combining a zeolite, an alumina binder, and phosphoric acid to form an extrusion mixture. The phosphoric acid acts as a peptizing agent. The extrusion mixture comprises from 0.000271 weight percent to 0.1 weight percent phosphoric acid based on the total weight of the extrusion mixture. The method further includes extruding the extrusion mixture to produce an extrudate. During the extruding, the phosphoric acid peptizes the alumina binder in the extrudate. The method further includes drying and calcining the extrudate to produce the cracking catalyst.

The application provides a method for preparing a multi-carbon methyl ketone from acetone. In the method, the acetone is reacted with itself or a corresponding aldehyde to obtain the multi-carbon methyl ketone. In order to improve the yield of the multi-carbon methyl ketone, the acetone used in the reaction has a methanol content of less than or equal to 250 ppm, and preferably a methanol content of less than or equal to 200 ppm. After the acetone is reused, the methanol concentration in the reactor is less than or equal to 1.5%, so that the selectivity of the acetone to the multi-carbon methyl ketone is greater than or equal to 90%. The process flow of the application is simple, the product has good selectivity, and the device has high economic efficiency.