Improved performance ion exchange membranes for use in REM, AEM and DMFC
fuel cells, buffered
fuel cells,
hydrolysis, other applications comprise a molecular matrix of homopolymers, di-
monomer, heteropolymers, copolymers, or block-polymers of
fluorocarbon and
hydrocarbon compounds combined with (i) skeletal support grid to improve durability, handling, reduce membrane swelling, and sequester dopants and nanoparticles from leakage; (ii) microporous membrane formed using a sacrificial filler process enhancing
conductivity and limiting fuel
crossover; (iii) hetero-ionomeric matrix of two-or-more membrane-bound acids e.g. sulphonic and phosphonic acid expanding
usable range; (iv) permanent fillers enhancing
conductivity and
porosity including nanoparticles,
metal-oxides, zeolites, silicates, GOs, CNTs, MOFs, POSS, and others; (v)
ionic liquid doping to enhance
membrane conductivity; (vi) membrane nanocoating preventing H2O2
diffusion; and / or (vii) catalytic nanocoating with metals,
metal-oxides, and MOFs preventing atmospheric
toxin catalyst poisoning. Combined with a heterogenous GDI, the IEM is integrated into iBFC power blade and energy
bank applications.